kmol AT Ac Analogg

Mole Mass ’ A
A

when
dCorvecianMT
1) 1·
Concenyahicng!) WassS
Rateof’Ya/se Die
N
’ usion
mdes Co Mass
fe
V
Mola) Tansfer
(MT)
M:T
mass
krgo-)) Houmweh
fux
Tran
Fratia
Mole rattjmMass
Fyacians
\WA = mSec -DA
kmol feS s (Ficka
o)
miuYeAt
Sec
FickS
laut
Sec
C Ca
 ina
water
AT M.T
Comvechos
M.T
Forod YjveY
Conyechsn
Fsee kg
clicient
Ai(r/s)
ffuian kmol
tho
ation
onunt
3
kmol! mX
kmo)
)a/sec)
Sec
Ac 2 X
dilerrcA Jnsion. Qm= lau]
[tousuen mSee
Qm= cofiien
i
jnansfou BetwenHT
Conarbatinkarj s dbar7ox
(M.T) (Kmol
ansfor
mass 2) mass
mass
(9nsecn Analogy
T) mas
goàriial: Cnusedtiorn -KA
dTd -DA
dc dc CTs-
-D doc
caRIPLhi
A
h
syskins, AswÝg Rate
sm:T -
Madas ( Ma
pwk Q
ka
 A
MassBajed
Mole
Based spoies/orngarant þer
(Kmole) unt
tu
at called ysdin.
mgang
sacs matich
melculae
aNas
s6e is
uhich
th
arsfon
Concoritaatin A
Splcias Ca
Juu: ndemthe
CnRdion
ymas nadium
:"anufo
katiarasy
:corcartuation
Ban
Mass
Consedlion Cenconiuation
Muss
doy m V
Mass CA
anlo
AkALsien Mela
JMass
 toA
coNCanthaion
rialie
stal B. qt
and
the e CA
in A C=
ortning .
A
Mela
mass
speaes. b
RHS
yrste =1
WBWA+
and
:wA)
action
Mass (YA)
fasion:
Nle ynelos
Ma mA m LHS +
YA
=
sunASy Aipdiung
=
WA urnle
a
oe
 MMA
M
MA
M
p
C
A
= C
las
ick CA
M
WA
= Ma A kJ/kmalk
x\8.o314-
N
Consl
lasUnisaoudl
rt
xM A
2c
-DAR
V miyture
MA
molecalar
averege
MA the
C d
ht Ma. M
weiq
MA
WA YA
Pa
MA
23.11.,2022
=
WA
abion
Average
U=y.
ton
Con

Concontain:
Mole
Ond velbcitg
iveloiy
A. Speies sec
mt
Sec
m
ls-Vaver)
’kmol
Mass
for Stalinay Upveage
Amalsg Escalo la
Betueon
’MoUinoyging = =
Dithusi
=
Relahon
shiP Escalatar2.
n N
=
n Hax
fux
1Molal
(Mass
Mass
 We c an Guanify. M.T

- laay syacies ATokak veloccy) Bulk veloc'y

Aasurrplios: irasy nituss iu

ARB
qadiant Escalato
Averape
velo
tày
Arnalog
mng

Wa
Esc.8}aignary

Esc.
noiny
N

Toal velociy Ug

beth motngeomponert velocitN

9- ony esealador (aveage veleity)
ast llalor stoliona
Ferson is wolkng

Vb# - Diffusion velociry

fue n; = l; t
Mass
fux i = C; V;
V= Mola
 Jasun-II
hange ASclune
= D
=-
Jay
pax
+ dt
CARA DAB A åy-dz Ra.dx-
TA
spucies -I
Lesum
dz
dy,
da, A
DAB t
J
A anto dz =
pocies dy, Qma
/diqlused
da, tine.
unt
E
I-iegm -I=
da alemert Subst:
+
ymassConductad
species
Mass
H
the
nto
.enter otRate
Nt
ofRate -eiem
Not the
fass
 A CasCA
A
B>2 A
YA
L L/De
UA2-A)
rudm:
medin: YA2-A
1 L
1
statiotazy
toragh
A,Diffusel dyA
diueugt
dfuian
ordy L
csnid
dya dc
use
3
4
 kmel/m
fene tene
Resis
eylnder
for DPegion
sphaye
Hor
o.005
s
Resi
Ditfusin iy
vdillusi
i Pr) Se)
dnd
macs Re, =f(Re, SUSace
ulace
f(
Pr
=
2 Se=2
AD = ines
A Nu Sh
CA-Ca2
Gandt!Junke
unben Bcmidt Nmben
NUSsaltNurley ire
AD
DL
21T at
D housoed
=
kmel/m
&mA
RraAS 0.02
is
 asuwe nes
25t.
total btir, Sh
mls
ot
kmol
/m aLenairexafor dt
DA Sh.
nass Im/s.ag
spou Numb
tnclan
in (encantatin
is lach Sherw
0.19 and DA
ass Sh
do fuacian
o.21 ynolag
ind
e nass Pr
atis
Be
in
Calculate
Quaction, staena Nu
24.11.2022.
0.4.
 each
of mixture?
at fraction
container
of
the
weight
mass
ain
are
is the
0.79and concentrations
=0.0085
kmol/m³
molecular
to
0.21fraction,
ratio average
mole molar
the
in the the
pressures
would
be by =C the
given 25)
density. K, +
RT (273
are Pi mol 105
0.21
x
mass 10°)
partial concentrationsJk
What
bar.
the 10 x
(8.314
their x
concentration. 8.314
With 1of
pressure Co;
molar as
N, R
of
and the value
molar
O, atotal (13.8),
of the the
mIxture Species
for Eqn. Taking
CalculateSolution
From
A
 =0.032
kmol/m
fractions
MA fractions.
pressure
kg/m kg/m?
25) molar (28)
+ 0.272 0.896 partial
(13.2) (0.79)
x105(273(13.1), =
as
0.79 Eqn. same
10) (0.0085) the 0.233 =0.767 +
Eqn. (0.032) p=1.168
kg/mto from the M, (32)
-}y,
x equal = (0.21)28.84.
(8.314
fromP=
MC (32) (28)
=0.21
'o, yN, calculated
=0.79
not
0.2721.168 0.8961.168
are
are fractions
= =
= =
evaluated Vpo, fractions M
PN, weight
be
now mass
is molecular
be density molar can
can the
the fractions that
densities mass
(13.9) see average
overall mass we
mass
The Eqn. ThusThe
Thus The By The
SO
wall while co the
mol/m³ mollm m'/s
05
kgmol
diffusion
mm mollm!, through
Stee
10 8 10-12
binary
of ke
container
hydrogen m
10-1
Og026x kg kg
2
is The
surface
Na. CA=2 CAz=0.5 x0.26
mol/m.of
steel flux kgma
2
inner ke mass
rectangular Ca, =
the 0.5 the
=
is
at surface in in DAR
is
a steel What hydrogenhydrogen
in in outer
hydrogen m²s.
pressure
the 10-12
Knol L=10mm surface surface
thickness
Wall for

=
elevated at * of of
of steel 0.26
concentration efficient
concentration
concentration
at in s i steel
in
shydrogen
stored hydrogen steel inner outer
in
hydrogen
is molar
hydrogen ofconcentration the the co
Diffusion
The at at
thickness. for steel molar
molar
steel
Gaseous efficient
the steel?
 8
N
m
ci
C;vi
N
n=
n weight
=
/m's Molecular
|2-0. mol hydrogen:
5] Ikg/m²s
=7.8x10
0.01
x2
C 1-CA2 10-10k x
10-12
x=0.26 flux 10-10
of
flux
x
x Molarx
Molo =0.39
Mass
n
=0.39
=
A
 m/s
with
1
of moving
velocity
(ii)
a stationary
with
moves
() velocity.
H, is
If which =0.6
0.4. average 0.6
of
surface be Yo,
is
O, will =0.4,
molar
and a O,
across
H, velocities.
with of yu,
of fluxes 0.4,
that
moving
mixture
average
molar
(ii)
is
a H,
in thevelocity
molar
H, fraction
Find and
of and massaverage
fraction
stationary.
mass mole
the
mole (a) (6) the Thus
Solution
is Since
The 0,
2.
 (13.lb} Eqn.
velocity
by
and given
(13.15) are
Eqns.
m/s
by kmol/m's
0.4 20 =0.04pkg/m's average S
= given kg/m?0.04)
(0) (13.11) =
(32) m/s
=0.04C
O2
% 0.04
= 0.04are mass ) p - of
(0.6)Eqn. (0.6) surface
-
( ,0.0384(0 that
(13.12) M
MË = with (0.96)
+ from + (0.4)
(2) (0) VH, V, P to
0 (1) (2) 20 stationary
(0.96) moving mu, (l-0.04)
= opposite
=-0.0384
-)= pkg/m's
pmu,
Vo, Eqn. (0.4)calculatcd
= by Cyn,
M,p given(0.4) =1-0.04
=
0.96 =
=Ly,M,= + = =0 = =0 surfaceJ- v)
m/s, by =V=Eyy}m,y Mu, .
(1) VH, P,(v,-) plo, and
V= is M a o, VH, Vo, (VA,
=1 given bo M
mixture YH,
across
(0.04)
PH, =Po,=CH,Co, a
p(0.04)
=Pu, mo,'
equal
y, can = = across
is
velocity velocity mu, mo, v=fluxes = is
the M H, no, MH, No, Jn, = Jo, H,
of molar fluxes of
average average weight flux
and diffusion diffusion
igiven
sAlso molecular
molar mas mass
Mass
flux:
The The Also This mass mass
The Thus().
(a) where The(13.17) The
and (b)
(i) and
opposite. änd (13.18)
Eqn.
from (m)
The
Jo,
molar-diffusion
Yo, =
C(Vo,

-V) fluxes

(0.6) JH,=CH, across

C(0.4) = a
(C
surface
0.4) VH,
(1-0.4) ,-
= moving
-0.24 V)=
=yA,
0.C24 with
kmol/m'sC(n,-V)
C molar
kmol/m's
average
which
velocity
are
again may
be
equal obtained
an