1.

The difference in energy between a resonance hybrid and its most stable hypothetical
contributing structure is
a) Resonance b) Resonance energy c) hybridzation d) canonical forms
2. When two substituents occur on a benzene ring, it has ________ possible isomers
a) 2 b) 1 c) 3 d) 4
3. 2, 6, 10, 14, 18, pi electrons in the cyclic arrangement of 2p orbitals show
a) Aliphatic nature b) aromatic nature c) non-aromatic d) not any
4. Compound with one tertiary carbon and three alpha carbons will undergo_________reaction
a) SN2 b) SN1 c) E2 d) Not any
5. High concentration of nucleophile is not necessary in
a) SN2 b) SN1 c) E1 d) Not any
6. Reaction of primary alkyl halides ____________
a) First order b) Second order c) Third order d) Not any
7. In Girgnard reagents alkyl group act as
a) Electrophile b) Nucleophile c) free radical d) All
8. Ether as a solvent is used for preparation of Girgnard reagents must be
a) Aqueous b) Alcoholic c) hydrous d) not any
9. Complete Inversion of configuration takes place in
a) SN2 b) SN1 c) E1 d) Not any
10. Secondary alkyl halides undergo
a) SN2 b) SN1 c) E2 d) All
11. Which is the organo metal in nature
a) Tetra ethyl lead b) Girgnard reagents c) monosodium acetylide d) not any
12. Partial racemization takes place in
a) SN2 b) SN1 c) Elimination reactions d) All
13. Carbon dioxide on reaction with Girgnard reagents followed by hydrolysis produce
a) Alchol b) Aldehyde c) Carboxylic acid d) Ketone
14. HCHO reacts with Grignard reagent to produce
a) Primary alcohol b) Secondary alcohol c) Ketone d) Aldehyde
15. Carbon of Grignard reagent is -________ in nature
a) Acidic b) Basic c) Neutral d) Not any
16. 3-Butanone on reaction with Grignard reagent will produce
a) Tertiary alcohol b) Secondary alcohol c) Ketone d) Aldehyde
17. Alkyl halides with beta hydrogen favoures
 a) SN reactions b) Elimination reactions c) Both d) Not any
18. Which among the followings is first order reaction
a) SN2 b) SN1 c) E1 d) b & c
19. Molecularity of SN2 is
a) 1 b) 3 c) 2 d) 0
20. Reactions of alkyl halides with base mostly produce
a) Alkyl halides b) Alkene c) Phenol d) N.O.T
21. Transition state appear in
a) 2nd order reactions b) 1st order reactions c) Both d) Not any
22. Ionization is
a) Irreversible reaction b) Reversible reaction c) Both d) N.O.T
23. Slow step determine
a) Product formation b) order of reaction c) a & b d) Fast step
24. Alkyl groups are good to react in SN and elimination reactions when attached to
a) F b) Br c) Cl d) I
25. Presence of partially positive hydrogen is important for
a) For base b) Elimination reactions c) Both a&b d) Not any
26. Alcohol formation is not possible with
a) HCHO b) Ethanal c) R-CO-R d) CO2
27. Which is incorrect for alkyl halides
a) SN reaction b) Positive carbon c) Electrophilic carbon d) Nucleophilic
carbon
28. Which are electron pair donar
a) Electrophile b) Acids c) Cations d) not any
29. Which is independent from site of attack of nucleophile
a) SN2 b) SN1 c) E2 d) b & c
30. Which possess partial positive carbon atom
a) Primary alkyl halides b) Secondary alkyl halides c) Tertiary alkyl halides d) all
31. Dehydrohalogenation reaction is related with
a) SN reactions b) Elimination reactions c) Both d) Not any
32. Carbonyl compounds react with R-Mg-X will produce
a) R-OH b) R-O-R c) R-CO-R d) R-COO-R
33. Esters react with Grignard reagent will give
 a) Alcohol b) ketone c) carboxylic acid d) acid halides
34. Friedel craft reaction is
a) Halogenations and Hydrogenation b) Akylation and Accylation c) Hydrogenation and
Halogenations d) Nitration
35. Phenol reacts with halogen will give
a) Ortho product b) para product c) meta product d) a&b
36. Which reaction give aromatic product
ℎ𝛾
a) C6H6 + Cl2 →
b) C6H6 + 3H2 →
𝐹𝑒Br3
c) C6H6 + Br2 →
V 2 O5
d) C6H6 + O2 →
37. Which of the following is difficult to undergo Friedel Crafts reaction
a) Toluene b) xylene c) aniline d) benzaldehyde
38. Benzene is oxidized with V2 O5 major product is
a) Benzoic acid b) toluene c) maleic anhydride d) lactic acid
39. Which is halogenarene
a) Chloromethane b) toluene c) chlorobenzene d) benzaldehyde
40. In aniline functional group is
a) Acyl group b) amide group c) amino group d) amido group
41. Pick the odd one out
a) –OH b) –COOH c) –CO-R d) –NO2
42. Ethyl benzene reacts with KMnO4 to produce
a) CO2 + H2 O b) bezoic acid c) ozonoid d) nitrobenzene
43. Acetophenone is
a) Ether b) ester c) alcohol d) adehyde
44. Which has greater acidic nature
a) Phenol b) 2-nitrophenol c) 2,4,6-trinitrophenol d) 2-nitrotoluene
45. Reaction of aldehyde with Grignard reagent is type of _______________ reaction
a) Electrophilic addition b) nucleophilic addition reaction c) nucleophilic
substitution d) oxidation
2
46. Number of sp hybrid orbitals in benzene are
a) 1 b) 2 c) 3 d) 6
47. Carbocation contain _____________pair of electrons
a) 1 b) 2 c) 3 d) 4
1 st
48. In SN reaction geometry of reaction intermediate in 1 step is
a) Trigonal b) diagonal c) tetrahedral d) pyramidal
49. Leaving group is
a) Electrophile b) nucleophile c) free radical d) cation
50. Which one of the following is not nucleophile
a) NH2− b) BF3 c) NH3 d) −OH
51. Nucleophile increasing order of reactivity is
 a) Cl– < Br– < I– b) I– < Cl– < Br c) Br– < Cl– < F– d) I– < Br– < Cl–
52. SN1 reaction most readily is for
a) (CH3)3 C—F b) (CH3)3 C—Cl c) (CH3)3 C—Br d) (CH3)3 C—I
53. which among the following will give racemic mixture when halide group is rerplaced with strong
nucleophile

a) I b) II c) III d) I & III

54. Tertiary butyl chloride is
a) Di haloalkane b) mono haloalkane c) tri haloalkane d) all
55. Weak base favour
a) SN2 b) SN1 c) E2 d) E1
56. Pick the odd one out
a) Toulene b) aniline c) phenol d) benzoic acid