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Chapter 07 Test Bank
Energy Storage
1. Chemical energy is converted directly into electrical energy in
A. a galvanic cell.
B. an electrical power plant.
C. an electrolytic cell.
D. an automobile's engine.
Feedback: Only one of these that has energy as output is electrical and not mechanical in nature.
Feedback: Loss of electrons is oxidation and those electrons are gained by another substance.
7-1
Copyright © 2017 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Accessibility: Keyboard Navigation
Bloom's Level: 1. Remember
Chapter: 07
Section: 07.01
Subtopic: Batteries
Topic: Electrochemistry
7-2
Copyright © 2017 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
8. In this electrochemical cell, the reduction half reaction is
A. Cu2+(aq) + 2 e¯ → Cu(s)
B. Zn(s) → Zn2+(aq) + 2 e¯
C. Zn(s) → Cu(s)
D. Cu2+(aq) → Zn2+(aq)
10. Which is not a necessary consideration for a battery designed to run a cell phone or portable MP3 player?
A. It must develop a useful level of electrochemical potential
B. It must run for a reasonable amount of time
C. It must use liquid, aqueous solutions
D. It must be fairly light in weight
Feedback: As long as batteries are sealed the phase of material in the battery should not matter.
7-3
Copyright © 2017 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
11. What condition must be met for a battery to be rechargeable?
A. Either its anode or its cathode must generate a gas as a result of the electrochemical reaction
B. It must generate electricity via an acid-base reaction rather than via an oxidation-reduction reaction
C. The battery must be open to the outside so that it can vent any internal pressure that builds up from gases within it
D. The electrochemical reaction of the battery must be reversible
Feedback: There is no way to alter the voltage in a cell but to use different anode and cathode.
13. Very small mercury batteries have been made and used in a multitude of applications. Why have they been replaced by other kinds of batteries
for most applications?
A. Mercury has become far too expensive to use in batteries
B. Mercury is poisonous and difficult to dispose of
C. These batteries cannot generate enough current for any modern devices
D. Though they may be made very small, they are far too heavy to use in most applications
Feedback: Remember that considerations outside the electrochemical reaction itself have to be taken into account.
Feedback: One of these would be found as disposable flashlight batteries, while the others are in hand tools or computers.
15. Why can the lead-acid batteries used in cars generate electricity for several years before running down?
A. A lead-acid battery is so large that it holds large quantities of the chemicals whose electrochemical interaction creates the electricity
B. The mechanical motion of the engine drives an alternator that generates electricity to recharge the battery
C. These batteries are used only to generate the electricity that makes the first spark plug "spark." Therefore, they are hardly used at all when a car is
started, and never when it is driven
D. The electrons they generate, not the chemical components, provide almost all of the electricity
Feedback: Think about how quickly a car will stop running if the alternator goes out.
16. Which type of battery is widely used to store the excess energy generated by windmill farms and solar panels?
A. Alkaline
B. Lithium ion
C. Lead acid
D. Nickel-metal hydride
17. Which type of battery is best for use in heart (cardiac) pacemakers?
A. Alkaline
B. Lithium-iodine
C. Mercury
D. Nickel-cadmium
Feedback: Think about which has long life and little toxicity.
Feedback: Remember that the electrochemical process in a fuel cell is the same as in a regular battery.
Feedback: Remember that batteries must be recharged and that nothing is 100 percent efficient.
7-5
Copyright © 2017 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
Section: 07.09
Subtopic: Electrochemistry
Topic: Electrochemistry
Feedback: Remember that this is just like a battery except that fuel flows into the cell continuously.
22. How does using hydrogen as the fuel in an electric power plant compare with using hydrogen as the fuel in a fuel cell?
A. H2 used as a fuel in a power plant must be more pure than the H2 used in a fuel cell
B. Burning H2 in a power plant produces many more pollutants than using H2 in a fuel cell
C. A fuel cell using hydrogen operates at a higher overall efficiency than would a power plant burning hydrogen as a fuel
D. Using H2 in a fuel cell generates far more heat than burning it in a power plant
23. As fuel cells become more widely accepted and are used more, we will
A. become less dependent on electrical energy.
B. become more dependent on fossil fuels and less dependent on renewable resources for power generation.
C. be able to generate electricity in places where we cannot now do so.
D. use coal as our primary energy source.
Feedback: Think about these are more versatile batteries with continuous fuel supplied.
7-6
Copyright © 2017 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
24. How does the reaction of hydrogen and oxygen to produce energy in a fuel cell differ from their interaction during the direct combustion of
hydrogen and oxygen?
I. The direct combustion of hydrogen and oxygen produces several different products, whereas the fuel cell produces only water
II. Much less heat energy is produced in a fuel cell than via direct combustion of hydrogen and oxygen
III. In the fuel cell, there is an oxidation-reduction reaction between hydrogen and oxygen. In the direct combustion of hydrogen and oxygen, there is
no such reaction
IV. It is much easier to control the hydrogen and oxygen during direct combustion than during their reaction in a fuel cell
A. I and II only
B. I, II, and III only
C. I, II, III, and IV
D. I and III only
Feedback: Combustion can be explosive and leads to unnecessary loss of energy as heat.
25. What is the purpose of the hot KOH solution in the fuel cell?
7-7
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McGraw-Hill Education.
A. It is the product of the reaction between the hydrogen, the oxygen, and the electrodes
B. It keeps the electrodes conditioned and ready to work at high efficiency
C. It is part of the acid-base reaction that generates the electricity in most fuel cells
D. It maintains electroneutrality by working as an electrolyte; allowing transfer of ions between the half cells where the hydrogen and oxygen react
26. A fuel cell does not run down like a standard battery because
A. the reactants in a battery must be stored inside the battery, whereas the reactants for a fuel cell flow in as needed.
B. a fuel cell continually recycles the same electrons, whereas a battery must continually generate new ones.
C. a battery is completely dependent upon oxidation-reduction reactions, whereas a fuel cell depends on acid-base reactions.
D. a battery has many moving parts, whereas a fuel cell has none.
Feedback: This is the same reason your car doesn't run down as long as you purchase gasoline.
27. In general, a modern hybrid vehicle is less polluting than a standard vehicle because it runs on both a
A. gasoline engine and an electric motor run by a rechargeable battery.
B. gasoline engine and a fuel cell.
C. fuel cell and an electric motor run by a rechargeable battery.
D. gasoline engine and a cleaner diesel engine.
Feedback: Remember that running on electric power does not lead to tailpipe gasses.
28. The Prius, a hybrid car produced by Toyota, uses a battery that its maker claims should not have to be recharged or replaced during the lifetime of
the car. The type of battery used in the Prius is
A. alkaline.
B. lead acid.
C. nickel-cadmium.
D. nickel-metal hydride.
Feedback: This is the most common advanced battery. It has not been on the market for more than a decade.
29. What moves in the salt bridge from the cathode to the anode?
7-8
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McGraw-Hill Education.
A. Electrons
B. Zn+2 ions
C. Cu+2 ions
D. Anions
Feedback: These move to balance the negative charge that flows in the wire.
30. At present, it will be difficult and perhaps inappropriate to develop an economy based on burning hydrogen rather than natural gas or gasoline
because
A. hydrogen is a dirty fuel. Burning hydrogen produces significantly more pollutants than burning natural gas or gasoline.
B. hydrogen is not an efficient fuel. Per gram, hydrogen has about the lowest heat of combustion of any known substance, much lower than natural
gas or gasoline.
C. although hydrogen is abundant, pure hydrogen is not found naturally on earth. Hydrogen is difficult or expensive to isolate and collect.
D. being such a light element, hydrogen will not flow through pipelines the way natural gas or gasoline do. Hydrogen cannot easily be delivered from
where it is produced to the places where it is needed.
Feedback: Remember that hydrogen is an excellent fuel, but has financial barriers to it being commonly used.
31. What energy change is associated with the reaction to obtain one mole of H2 from one mole of water vapor? The balanced equation is 2 H2O(g)
→ 2H2(g) + O2(g) and the relevant bond energies are: H — H = 436 kJ/mol; H — O = 467 kJ/mol; O — O = 146 kJ/mol; O O = 498 kJ/mol.
A. -249 kJ
B. +249 kJ
C. -436 kJ
D. +436 kJ
7-9
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McGraw-Hill Education.
Bloom's Level: 3. Apply
Chapter: 07
Section: 07.10
Subtopic: Electrochemistry
Topic: Chemical Reactions
Feedback: Write a balanced equation and then take the energy of the bonds formed minus the bonds broken.
32. For safety and other practical reasons, the most logical use for hydrogen as a fuel in the near future is
A. in an electric power plant.
B. in a fuel cell.
C. for running an automobile.
D. for nuclear fusion.
33. Which has not been suggested as a reasonably practical way to store large amounts of hydrogen in relatively small spaces for its use as a fuel?
A. Liquefy hydrogen under pressure and store it much as we do with liquefied natural gas today
B. Absorb hydrogen onto activated charcoal; then heat the mixture to release the hydrogen
C. Store it in the form of ionic metal hydrides, such as LiH, which release hydrogen gas when they react with water
D. Encapsulate hydrogen molecules in fullerene molecules (large, carbon-based molecules that can act like cages) that may be heated later to release
the hydrogen
34. Batteries must be used in addition to solar cells when generating household electricity because
A. solar cells can generate electricity only via the output of a battery.
B. solar cells can generate only a small fraction of the total energy needed by a household at any one time.
C. solar cells generate so much electricity that they will overheat if they cannot transfer the excess electricity somewhere to dissipate the extra heat.
D. batteries must store and then supply the energy when sunlight is not available.
35. The aluminum-air battery is being considered for use in automobiles. In this battery, aluminum metal undergoes oxidation to Al3+ ions and forms
Al(OH)3. O2 from the air undergoes reduction to OH¯ ions. Which half-reaction occurs at the anode?
A. Formation of OH¯ ions from O2
B. Capturing O2 from the air so that it may form the OH¯ ions
C. Formation of Al3+ ions from aluminum
D. Reaction of Al3+ ions with hydroxide ions to produce Al(OH)3
36. A NiCd battery uses nickel and cadmium to produce a potential difference. Using these equations, answer the following questions.
I. 2NiO(OH) (s) + 2H2O (l) + 2 e¯ → 2Ni(OH)2 (s) + 2 OH¯ (aq)
7-10
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McGraw-Hill Education.
II. Cd(s) + 2OH¯ (aq) → Cd(OH)2 (s) + 2e¯
III. Cd (s) + 2NiO(OH) (s) + 2 H2O (l) → 2 Ni(OH)2 (s) + Cd(OH)2 (s)
Which equation represents what takes place at the anode?
A. I
B. II
C. III
D. I and II
Feedback: Remember that oxidation is loss of electrons and happens at the anode.
37. Which equation represents the whole chemical reaction within the galvanic cell?
A. I
B. II
C. III
D. I and II
Feedback: Remember that the overall reaction must be both an oxidation and a reduction to complete the circuit.
40. Which of the following statements is not true about PEM fuel cells?
A. PEM fuel cells rely on inexpensive catalysts
B. PEM fuels cells are cleaner than gasoline powered vehicles
C. PEM fuel cells have safe and efficient fuel storage
D. PEM fuel cells have limited driving range
Feedback: The molecule must contain hydrogen atoms to be reformed into hydrogen.
42. Why doesn't water naturally become hydrogen and oxygen gas when exposed to light?
A. Thermal energy is the only appropriate type of energy to split water
B. You must use electrons to split water
C. Water doesn't absorb the proper wavelength of light to split
Feedback: Remember that the wavelength of light absorbed is associated with its energy, which must be high to split water.
43. How do the interactions that are broken in water when it is boiled compare with those broken when water is electrolyzed?
A. Boiling water breaks intermolecular attractions and electrolysis breaks covalent bonds
B. Boiling water breaks covalent bonds and electrolysis breaks intermolecular attractions
C. Boiling water and electrolysis of water break covalent bonds
D. Boiling water and electrolysis of water break intermolecular forces
44. Why is it so expensive to ship hydrogen as a liquid as is often done with other gas?
A. Hydrogen is very heavy to ship
B. Hydrogen is very dense to ship
C. Hydrogen has to be shipped at a very low temperature
D. Hydrogen in very flammable
Feedback: Remember that things with low molar mass have low boiling points.
7-12
Copyright © 2017 McGraw-Hill Education. All rights reserved. No reproduction or distribution without the prior written consent of
McGraw-Hill Education.
46. For the compound Fe3O4, what is the oxidation state of Fe?
A. 2+
B. 3+
C. 4+
D. Mixture between 2+ and 3+
47. For the compound FeCl3, what is the oxidation state of Fe?
A. 2+
B. 3+
C. 4+
D. Mixture between 2+ and 3+
48. Which of the following automotive energy storage devices would give rise to the fastest acceleration from zero to 60 mph?
A. Li-ion rechargeable batteries
B. Fuel cells
C. NiMH rechargeable batteries
D. Supercapacitors
49. Batteries are still preferred over supercapacitors for portable electronic applications. What factor(s) give rise to this preference?
A. Supercapacitors have low energy densities
B. Supercapacitors are charged much more quickly than batteries
C. Supercapacitors have virtually unlimited cycle lives
D. All of these choices are correct
Category # of Questions
Accessibility: Keyboard Navigation 44
Bloom's Level: 1. Remember 9
Bloom's Level: 2. Understand 35
Bloom's Level: 3. Apply 6
Chapter: 07 50
Section: 07.01 7
7-13
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McGraw-Hill Education.
Section: 07.02 4
Section: 07.03 8
Section: 07.04 4
Section: 07.05 2
Section: 07.07 3
Section: 07.08 2
Section: 07.09 6
Section: 07.10 14
Subtopic: Batteries 14
Subtopic: Electrochemistry 29
Subtopic: Electrolysis 2
Subtopic: Ionic Bonding 2
Subtopic: Oxidation-Reduction Half Reactions 3
Subtopic: Photovoltaic 1
Topic: Chemical Bonding 2
Topic: Chemical Reactions 1
Topic: Electrochemistry 43
Topic: Electromagnetic Radiation 1
Topic: Environmental Chemistry 4
Topic: Study of Chemistry 1
7-14
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McGraw-Hill Education.
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chances. The only safe way is to employ picking gears making one
tooth to each pick of the loom, and then to change the gears when
different picking becomes necessary.
In many of the existing looms there has been no adequate
provision made for the weaver to let the web back to the reed
mechanically when a joining becomes necessary through the
breaking of the filling while weaving, or where a quill may have run
off unnoticed. It is almost impossible to make a joining satisfactorily
without proper mechanism being provided for this purpose. In some
of the slow running looms provision is made for this by the operation
of each set of rolls independently (see Fig. 1), by means of the
ratchet gear and pawl A and worm motion B. This plan has the one
disadvantage of taking up too much space between the individual
pieces. Where the fabric woven is say four or five inches wide, and
the space will admit, it is all that can be desired, and the individually
weighted rollers C associated with the motion are admirably adapted
to variable pressure.
For the very narrow elastic fabrics, which require considerable
roller pressure to hold the web snug and firm while weaving, and
where it is necessary to make very accurate joinings after a break
has occurred, a better movement is one in which the web roll is
placed on the main take-up shaft in the form of a sleeve. It is carried
around by the shaft as it turns while the goods are being woven, but
can be released and turned both backwards and forwards by a
conveniently placed hand wheel, which operates a series of
differential gears. This movement is entirely independent of the
movement of the main take-up shaft drive.
Let-Off Motion
Fig. 1.—Individual Take-Up Motion for Wide Space Looms
Fig. 2.—Individual Rubber Warp Let-Off Motion
When we remember that the front reed will pass by the rubber
threads possibly six or seven hundred times from their entrance into
the shed to their reaching the leaving line, it is not to be wondered at
that chafing is liable to take place. With all this liability of spoiling
goods it becomes readily apparent that any device employed to
regulate such an important feature as the tension of the rubber
warps must be very sensitive and dependable.
On looms making wide goods, and where space will allow,
regulation is accomplished by a worm and gear movement as shown
in Fig. 2. The iron rubber beam is threaded on to a square shaft A, at
one end of which a gear wheel B is fastened. In this gear is meshed
the worm C, which is operated by a heavy linen cord D passed twice
around a pulley E. The cord derives its movement from a rocking
shaft F, on which there is fastened a screw extension G, by which
adjustment can be made so as to deliver very accurately any amount
from the rubber beam.
With this kind of movement, and in order to feed the thread
uniformly into the web, it becomes necessary to use mechanically
made warps where the same uniformity has been maintained in
putting the warps on the beams. The warps so made must come
from the thread manufacturer in individual warps, which are done up
in chain form, each warp containing the requisite number of threads.
Friction Let-Off
Where there is limited loom space, and where a small number of
threads are employed, as in the narrower garter fabrics, it is not as
practical to have the warps made mechanically, and for this reason
they are not likely to be put on the beams with as much uniformity of
tension. In such cases it becomes necessary to have some
automatic device that will correct any irregularities and maintain a
uniform delivery throughout. The device for doing this is shown at
Fig. 4.
The warp carrier A is fastened to the back rail, which carries the
warp, over which is passed the friction cloth G which is hung from a
rod D. The friction cloth is fastened at the bottom to the graduated
warp lever E, which is bolted to the bottom rail H, as shown. The
rubber threads constituting the warp pass in a direct line to the
harness C, and then to the breast beam B. The lever E, and the
weights F, allow for proper adjustment of the friction cloth so as to
keep the lever level as the warp beam empties.
In making the rubber warps for narrow fabrics such as garters and
suspenders, where the last described method of warp delivery takes
place, it is customary to work from an entire sheet of rubber, splitting
it up into the required sections or strips of the various sizes called for
in the warps. This splitting and warping process must be done in a
long room where the warp can be stretched out to its full length, if
possible, after it is unchained. These warps are usually about 60
yards long. The “head” of the sheet, or the part where the cutting
knife has not gone through, is spread out flat on a series of hooks at
the beaming machine and the tail end is fixed securely on a strong
hook at the other end of the room.
The requisite number of threads for the several warps which are to
be beamed are counted off and each different section is fastened to
a beam. The end knot is laid snugly in the counter-sink made in the
beam barrel for this purpose. A wide reed is used, covering the
number of beams operated in the machine, which is usually about
four, and the threads are reeded over spaces opposite the different
beams. This reed can be moved sidewise across the face of the
beams and each warp properly centered so as to keep the warp
level. The operator then starts the beaming machine, which may be
operated either by hand or power, and the warps are wound up. At
the same time a helper walks towards the beamer carrying the tail
end of the warps and keeping the tension as nearly uniform as
possible. When the warps are all wound on the several beams, a
lease is taken in each of them in the ordinary manner, and each
separate section is securely fastened.
Fig. 4.—Automatic Friction Let-Off for Rubber Warps
Overshot Dobby
Another type of loom employed in the making of fancy goods is
what is known as the overshot loom. It is used for the introduction of
a silk weft figure effect, and is probably the most pronounced form of
elaboration introduced. It differs from the old rise and fall method in
the economy of operation. The overshot continues to weave the
body of the goods right along while the auxiliary shuttle is putting the
silk figure in at the same time. Not only is it economical in the
respect of greater yardage, but the method employed in binding the
figure limits the use of silk to the actual figure displayed, and does
not carry the silk, which is the most expensive material in the fabric,
to the extreme selvage at every pick, as is the case where the rise
and fall method is employed.
In the overshot system a specially designed dobby, shown at Fig.
3, is used for operating the lightly weighted threads of the binder
warps. Two pairs of knives are employed, one of each pair operating
far enough to raise the threads used in the binder warp to the level of
the top main shed, while the other one of each pair carries the
threads which are used for figure purposes to a higher level, so that
the overshot shuttle may pass under them. This occurs every
alternate pick of the loom, the body shuttle making two picks while
the upper or overshot shuttle makes only one.
In levelling the harness, setting or timing of the loom, and making
the shed for overshot work, the plans followed are identically the
same as in ordinary single shuttle work, as the upper shuttle and
upper shed are distinctly auxiliary and subordinate to the main shed.
The binder warp, being necessarily but lightly weighted in its
relationship to the upper and lower cloths it is binding together,
allows for the figure threads to be strained out of their normal
position, so that the upper shuttle may pass under them. In order to
conform to this strained position of the binder figure threads, the
upper shuttle must be acutely pitched downward at the nose so as to
get a good clearance, and thus avoid any binding in its passages
through the shed. This peculiar downward pitch of the shuttle is very
important and cannot be over emphasized. It is shown in Fig. 4.
The overshot dobby is so constructed that a different set of draw
knives operate on each alternate pick of the loom, one on the binder
lift and the other on the rubber lift. This not only allows for a silk
figure made with the shuttle but affords facilities for the introduction
of a warp figure also, a combination which can often be made very
effective, as shown in Fig. 5.
Fig. 4.—Showing Auxiliary Shed and Pitched Shuttle as Used in Overshot Work
Fig. 6A.—Harness Draft and Weave for Three-Quarter Inch Loom Web
Fig. 7A.—Harness Draft and Weave for One-Half Inch Lisle Web
Fig. 8A.—Harness Draft and Weave for Three-Quarter Inch French Web
Fig. 9A.—Harness Draft and Weave for Three-Quarter Inch Cable Web