ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE-2019 CRASH COURSE MARKS: 124

TIME: 75 MIN. TOPIC: S-BLOCK, P-BLOCK, D-BLOCK & F-BLOCK DATE:27/11/18

SECTION–I (Multiple Choice Questions)

This section contains 06 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONLY ONE is correct. (+3,- 1)

1. When H 2O 2 is added to ice – cold solution of acidified potassium dichromate containing ether and
the contents are shaken and allowed to stand
(A) A blue colour is obtained in ether due to formation of a Cr2  SO 4 3
(B) A blue colour is obtained in ether due to formation of CrO5
(C) CrO3 is formed which dissolves in ether to give blue colour.
(D) Chromyl chloride is formed.

2. If Cd 2 and Cu 2 both are present, both are complexed by CN  and H2S gas is passed, which one of
the following pairs of complexes and their relative stability enables the separation of Cu 2 and Cd 2 ?
(A) K 3 Cu  CN 4  : more stable and K 2 Cd  CN  4  : less stables
(B) K 2  Cu  CN  4  : Less stable and K 2 Cd  CN  4  : more stable
(C) K 2  Cu  CN  4  : more stable and K 2 Cd  CN  4  : more stable

(D) K 3 Cu  CN 4  : less stable and K 2  Cd  CN 4  : more stable.

3. Which of the following will not give a positive chromyl chloride test?
(A) CuCl2 (B) ZnCl2 (C) HgCl2 (D) NH 4Cl

4.
conc. Brown funes
H2SO4

Cu
Colourless salt (A) Blue + metal C solution

HCl white ppt.

soluble in NH4 OH
The salt A can be
(A) Cu  NO3 2 (B) NaNO3 (C) AgNO3 (D) Pb  NO3  2

5. A sulphate of metal ‘A’ on heating evolves two gases B and C and an oxide D. Gas ‘B’ turns
K 2Cr2O7 paper green while gas ‘C’ forms a trimer in which there is no S – S bond. Compound ‘D’

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1

 with HCl forms a lewis acid E which exists as a dimer. Compounds A, B, C, D and E are
respectively.
(A) FeSO4 ,SO2 ,SO3 , Fe 2O3 , FeCl3 (B) Al 2  SO 4 3 ,SO 2 ,SO 3 , Al2 O 3 , FeCl3
(C) FeS,SO 2 ,SO3 , FeSO 4 , FeCl3 (D) FeS,SO 2 , Fe  PO 4 3 , FeCl3 ,SO 3

6. Which is not true about borax?

(A) Contains 4B  O  B linkage
(B) Bicyclo compound
(C) Aqueous solution may act as a buffer solutions.
(D) Contains sp3 hybridized as well as sp 2 hybridized B

SECTION-II (Multiple Choice Questions)

This section contains 06 multiple choice questions. Each question has 4 choices (A), (B), (C) and
(D) for its answer, out which ONE OR MORE is/are correct. (+4,- 2)

7. Borazine is called inorganic benzene. It has a ring structure with alternative BH and NH groups.
Which of the following statements are correct about borazine?
(A) Each B and N atom is sp2 hybridized
(B) Borazine satisfies the  4n  2   electrons huckel’s rule.
(C) Like organic benzene, borazine does not give additional product with HCl.
(D) Borazine contains dative p  p bond

8. The noble gases which don’t form clathrates are

(A) He (B) Ne (C) Kr (D) Xe

9. Acids with peroxy linkage are

(A) H2S2O6 (B) H2SO5 (C) H 2S2 O7 (D) H2S2O8

10. The incorrect statement regarding the complex  Fe  H 2 O 5 NO  SO 4

(A) Oxidation state of iron in this complex is +2
(B) It is a diamagnetic complex
(C) NO+ ligand donate 2e  to Fe in the complex
(D) According to werner primary valency of iron is 3

2
11. The coordination complex, Cu  OH 2  6  has one unpaired electron. Which of the following
statements are not true?
(A) The complex is octahedral
(B) The complex is an outer orbital complex.
(C) All bond length of Cu – O are equal.
(D) The complex is diamagnetic

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2

12. Which of the following statements are correct about Ellingham diagram?
(A) It is a graph between free energy of formation of one gram mol of oxides of metals
(B) The free energy changes follow straight line unless there is a phase change for the material
(C) As per the diagram all oxides can be decomposed to give the metal if a sufficiently high
temperature is attained at which the formation of oxide is not favoured.
(D) Any metal will reduce other metal which lie above it in ellingham diagram.

SECTION – III (Paragraph Type)

This section contains 2 multiple choice questions relating to 1 paragraph. Each question has four
choices (A), (B), (C) and (D) out of which ONLY ONE is correct. (+3,- 1)

PARAGRAPH FOR QUE. NOS. 13 & 14

Cl
4
N
N H 160o C  2
 C
B 


 strongly
HCl or  Na or K
Borax 
H 2SO4
 H3 BO3 
strong  B2 O3 
 C  X 2 (halogen) Boron
NaOH
BX 3
NaBO 2
Sodium
metaborate
Choose the correct answer:
13. In the above reaction map the product ‘A’ formed resembles the characteristics of carbon in solid
state. The product ‘A’ and the form of carbon resembles are
(A) B3 N3H 6 , graphite (B)  BN  x , graphite
(C) BN and fullerene (D) Both (B) and (C)

14. The product ‘B’ and ‘C’ are

(A) BHO3 , B2O3 (B) HBO3 , H2 B4O7 (C) HBO2 , H2 B4O7 (D) HBO2 , H4 B2O6

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3

 PARAGRAPH FOR QUE. NOS. 15 & 16

Na 2SO3   X 

3O 2   Y 
H 2O 
r )
 B  2Nal (boil) (ai
I2 [P]
Br
Ag

s of
[A]
Cl2  aq 

Exces
[A]
NaHSO 4  HCl [Q]
Choose the correct answer:
15. X and Y in above flow diagram are
(A) S, Na 2S (B) HCl, Na 2S (C) S, Na 2S3 (D) S, NaHSO3

16. A is used in photography to fix AgBr. It reacts with decomposed AgBr on the film to give P initially
followed by Q on reaction with excess A to give Q. P and Q in the reaction are
(A) NaBr, Ag 2S2O3 (B) Ag 2S2 O 3 , Na 3  Ag  S2 O 3  2 
(C) Ag 2SO 4 , Na 3  Ag S2 O 3  2  (D) Na 5  Ag  S2 O 3   3 , Ag

PARAGRAPH FOR QUE. NOS. 17 & 18

An ore ‘A’ on roasting with sodium carbonate in presence of air gives two compounds ‘B’ and ‘C’.
The solution of ‘B’ in conc. HCl on treatment with K 4  Fe  CN  6  gives blue colour of ‘D’. The
aqueous solution of ‘C’ on treatment with conc. H 2SO4 gives a yellowish orange compound ‘E’. ‘E’
when treated with KCl gives on orange red compound ‘F’ which is used as ‘oxidising agent’. The
solution of ‘F’ on treatment with oxalic acid and then with excess of potassium oxalate gives blue
crystal of ‘G’.
Choose the correct answer:

17. A and B are respectively

(A) FeCr2O 4 , Fe2O3 (B) FeCr2O 4 , Na 2CrO 4
(C) FeCr2 O4 , CO 2 (D) FeCr2O 4 , Cr2 O3

18. D and G are respectively

3
(A) Fc3  Fe  CN 6  , Cr 3 (B) Fe 4  Fe  CN 6  ,  Cr  C 2 O 4 3 
4 3

(C) Fe4  Fe  CN 6  , CO2 (D) FeCl3 , CrO5

3

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4

 SECTION – IV (Integer Answer Type)
This section contains 08 questions. The answer to each of the questions is a single digit integer,
ranging from 0 to 9. The correct digit below the question number in the ORS is to be bubbled.
(+4, 0)

2
19. How many total isomer are possible for Co  NH 3  4 ClNO 2  ?

20. In solid PBr5 , maximum d orbital take part in hybridization is x then, value of x will be

21. The total number of  2C  2e  bond in B4 H10 is

22. The equivalent weight of NaOH when it’s cold and dilute solution is treated with Cl 2 is ______ times
of it’s molecular weight

23. 
How many maximum atoms are present in one plane of  PtCl3 n 2C2 H 4  ? 

24. How many geometrical isomers are possible for  Zn  NH 3  ClBr  PPh 3   ?
24. (0)

25. The no. of peroxylinkage in H 2S2 O7 is:-

26. A trivalent lanthanoid ion having yellow colour in aqueous solution have five 4f electrons. What
should be number of electrons in 4f orbital of another trivalent lonthanoid ion having yellow colour
in aqueous solution?

SECTION - V (Matrix Match Type)

This section 1 Question. Each question has four statements Given in Column - I and four statements
in Column – II. Any given statement in Column – I can have correct matching with one or more
statement (s) given in column II. (+8, 0)
27. Match column – I with Column – II

Column – I (Compound) Column – II (Hybrid state - shapes)

(A) BCl3 (P) Sp2
(B) H3BO3 (Q) Sp3
(C) B2 H6 (R) Bridge structure
(D) Hybrid state of B and N, in (S) Triangular planar shape
 H 3 NBF3 
(T) 2c – 2e bond is present.

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 5

28. Match Column I with Column II

Column – I Column – II
(A) XeF2 (P) Square pyramidal
(B) PCl5 (Q) Linear shape
(C) XeOF4 (R) Sp3d hybridization
(D) XeF4 (S) Sp3d 2
(T) Octahedral geometry

29. Match the following

Column – I Column – II
NH 4 OH
(A) Hg 2Cl2  product/s (P) Hg
(B)  product/s
Hg 2 Cl2  SnCl2  (Q) Hg  NH 2  Cl
(C) Hg 2  SnCl 2 
 product/s (R) Oxidation
(D) HgCl2  Cu 
 product/s (S) Metal – metal bond in product
(T) Reduction

30. Match the column:-

Column – I Column – II
(A) KHF2 (P) Hydrogen bonding in solid state
(B) CuSO 4 .5H 2O (Q) Co-ordination no. of metal is 4
(C) KHCO3 (R) Contains ionic bond
(D)  Ni  dmg 2  (S) Exist in dimer state

(T) Retain its characteristic in solution

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 6

 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
IIT – JEE-2019 CRASH COURSE MARKS: 124
TIME: 75 MIN. TOPIC: S-BLOCK, P-BLOCK, D-BLOCK & F-BLOCK DATE:27/11/18

ANSWER KEY

1. (B) 2. (A) 3. (C) 4. (C) 5. (A)

6. (A) 7. (ABD) 8. (AB) 9. (BD) 10. (ABD)

11. (CD) 12. (BCD) 13. (B) 14. (C) 15. (C)

16. (B) 17. (A) 18. (B) 19. (4) 20. (0)

21. (7) 22. (2) 23. (6) 24. (0) 25. (0)

26. (9)

27.  A   P,S, T;  B   P,S, T;  C   Q, R, T  D   Q, T

28.  A   Q, R;  B   R;  C   P,S, T  D   S, T

29.  A   P, Q, R, T;  B   P, R, T;  C   P, R,S, T  D   P, R, T

30. (  A   P, R;  B   P,Q, R,T;  C   P, R,S;  D   P, Q, T )

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 7

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 8