ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT – JEE - 2019 CRASH COURSE (MAIN) MARKS: 90

TIME: 45 MIN. DATE:
TOPIC: CO-ORDINATION COMPOUNDS, METALLURGY, SALT ANALYSIS

SECTION–I (Multiple Choice Questions)

This section contains 30 multiple choice questions. Each question has 4 choices (1), (2), (3) and
(4) for its answer, out which ONLY ONE is correct.

1. Heating of concentrated ore in absence of air for conversion into oxide ore is known as-
(1) roasting (2) calcinations (3) reduction (4) none of these

2. The reducing agent in thermite process is

(1) Al (2) Mg (3) BaO 2 (4) MnO 2

3. In the extraction of aluminium from bauxite , cryolite is used to

(1) decrease the boiling point of aluminium
(2) purify the bauxite
(3) make the mass lighter
(4) decrease melting point of alumina and increase conductivity

4. A naturally occurring substance from which a metal can be profitably extracted is known as:
(1) mineral (2) gangue (3) ore (4) flux

5. Which is not a basic flux?

(1) CaCO3 (2) Lime (3) SiO 2 (4) CaO

6. Chemical method used in concentration of ore is known as-

(1) bleaching (2) leaching (3) roasting (4) calcinations

7. The metal extracted by leaching with a cyanide is

(1) Mg (2) Ag (3) Cu (4) Na

8. The chemical composition of ‘slag’ formed during the smelting process in the extraction of copper is
(1) Cu 2O  FeS (2) FeSiO3 (3) CuFeS2 (4) Cu 2S  FeO

9. Method used for obtaining highly pure silicon used as a semiconductor material, is
(1) Oxidation (2) Electrochemical (3) Crystallization (4) Zone refining

10. During the extraction of Fe, slag obtained is

(1) FeO (2) FeSiO3 (3) MgSiO3 (4) CaSiO3

11. Which of the following ore is chloride?

(1) Bauxite (2) Horn silver (3) Magnesite (4) Zincite

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA # 1

12. Calcination is used in metallurgy for removal of?
(1) Water and sulhide (2) Water and CO2
(3) CO2 and H2S (4) H 2 O and H2S

13. Cryolite is
(1) Na 3AlF6 and used in the electrolysis of alumina for decreasing electrical conductivity
(2) Na 3AlF6 and used in the electrolysis of alumina for lowering the melting point of alumina
(3) Na 3AlF6 and used in the electrolytic purification of alumina
(4) Na 3AlF6 and used in the electrolysis of alumina

14. Electromagnetic separation is used in the concentration of

(1) Copper pyrites (2) Bauxite (3) Cassiterite (4) Cinnabar

15. In forth flotation process many chemicals (frother, collector, activator, and depressant) are used.
Which is called a frothier:
(1) CuSO 4 (2) NaCN  alkali (3) Pine oil (4) Potassium xanthate

16. The coordination number of a central metal atom in a complex is determined by

(1) the number of ligands around a metal ion bonded by sigma and pi-bonds both
(2) the number of ligands around a metal ion bonded by pi-bonds
(3) the number of ligands around a metal ion bonded by sigma bonds
(4) the number of only anionic ligands bonded to the metal ion.

17. Which of the following is common donor atom in ligands?

(1) Arsenic (2) Nitrogen (3) Oxygen (4) Both ‘b’ and ‘c’

18. Among the following, the compound that is both paramagnetic and coloured is
(1) K 2Cr2O7 (2)  NH4  2  TiCl6  (3) CoSO 4 (4) K 3 Cu  CN  4 

19. Which kind of isomerism is exhibited by octahedral Co  NH3 4 Br2Cl ?

(1) Geometrical and Ionization (2) Geometrical and Optical
(3) Optical and Ionization (4) Geometrical only

20. The species having tetrahedral shape is

2 2 2 2
(1)  PdCl4  (2)  Ni  CN  4  (3)  Pd  CN  4  (4)  NiCl4 

21. The IUPAC name of  Ni  NH 3  4   NiCl4  is

(1) Tetrachloronickel (II) - tetraamminenickel (II)
(2) Tetraamminenickel (II) - tetrchloronickel (II)
(3) Tetraamminenickel (II) - tetrachloronickelate (II)
(4) Tetrachioronickel (II) - tetrachloronickelate(0)

22. IUPAC name of  Pt  NH3 3  Br  NO 2  Cl  Cl is

(1) Triamminechlorobromonitroplatinum (IV) chloride
(2) Triamminebromonitrochloroplatinum (IV) chloride
(3) Triamminebromochloronitroplatinum (IV) chloride
(4) Triamminenitrochlorobromoplatinum (IV) chloride

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA # 2

23. Which one of the following complexes will have four different isomers?
(1) Co  en 2 Cl2  Cl (2) Co  en  NH 3  Cl 2  Cl
(3) Co  PPH 2  2 Cl2  Cl (4) Co  en 3  Cl3

24. Which of the following does not have a metal carbon bond?
(1) Al  OC2H 5 3 (2) C 2 H5 MgBr (3) K  Pt  C 2 H 4  Cl3  (4) Ni  CO  4

3
25. The complex ion Co  NH 3 6  is formed by sp3d 2 hybridisation. Hence the ion should possess
(1) Octahedral geometry (2) Tetrahedral geometry
(3) Square planar geometry (4) Tetragonal geometry.

26. The number of unpaired electrons in the complex Cr  NH 3  6  Br3 (Atomic number Cr  24 )
(1) 4 (2) 1 (3) 2 (4) 3

27. Which of the following will give maximum number of isomers?

2 2
(1)  Ni  C 2 O 4  en 2  (2)  Ni  en  NH 3 4 

(3) Cr  SCN  2  NH 3 4  (4) Co  NH 3  4 Cl 2 

28. Atomic number of Cr and Fe are respectively 25 and 26, which of the following is paramagnetic?
4 3
(1) Cr  CO 6  (2)  Fe  CO 5  (3)  Fe  CN  6  (4) Cr  NH3 6 

29. Which of the following complex ions is expected to absorb visible light?
4 3
(1) Ti  en  2  NH 3  2  (2) Cr  NH3 6 
2 3
(3)  Zn  NH3 6  (4) Sc  H 2 O 3  NH 3 3 
(At. No. Zn  30,Sc  21, Ti  22, Cr  24 )

30. The complex,  Pt  Py  NH 3  BrCl  will have how many geometrical isomers?
(1) 3 (2) 4 (3) 0 (4) 2

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA # 3

 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
IIT – JEE - 2019 CRASH COURSE (MAIN) DATE:
TOPIC: CO-ORDINATION COMPOUNDS, METALLURGY, SALT ANALYSIS

ANSWER KEY

1. (2) 2. (1) 3. (4) 4. (3) 5. (3) 6. (2) 7. (2)

8. (2) 9. (4) 10. (4) 11. (2) 12. (2) 13. (2) 14. (3)

15. (3) 16. (3) 17. (4) 18. (3) 19. (1) 20. (4) 21. (3)

22. (3) 23. (2) 24. (1) 25. (1) 26. (4) 27. (3) 28. (4)

29. (2) 30. (1)

CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA # 4