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Adsorption – Dryers for Divided Solids
Industrial Equipment for Chemical Engineering Set
coordinated by
Jean-Paul Duroudier
Jean-Paul Duroudier
There are no such things as applied sciences,
only applications of science.
Louis Pasteur (11 September 1871)
Apart from any fair dealing for the purposes of research or private study, or criticism or review, as
permitted under the Copyright, Designs and Patents Act 1988, this publication may only be reproduced,
stored or transmitted, in any form or by any means, with the prior permission in writing of the publishers,
or in the case of reprographic reproduction in accordance with the terms and licenses issued by the
CLA. Enquiries concerning reproduction outside these terms should be sent to the publishers at the
undermentioned address:
Notices
Knowledge and best practice in this field are constantly changing. As new research and experience
broaden our understanding, changes in research methods, professional practices, or medical treatment
may become necessary.
Practitioners and researchers must always rely on their own experience and knowledge in evaluating and
using any information, methods, compounds, or experiments described herein. In using such information
or methods they should be mindful of their own safety and the safety of others, including parties for
whom they have a professional responsibility.
To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, assume any
liability for any injury and/or damage to persons or property as a matter of products liability, negligence
or otherwise, or from any use or operation of any methods, products, instructions, or ideas contained in
the material herein.
It is conceivable that humans will never understand all the truths of the
world. What is certain, though, is that we can and indeed must understand
what we and other humans have done and created, and, in particular, the
tools we have designed.
Even two thousand years ago, the saying existed: “faber fit fabricando”,
which, loosely translated, means: “c’est en forgeant que l’on devient
forgeron” (a popular French adage: one becomes a smith by smithing), or,
still more freely translated into English, “practice makes perfect”. The
“artisan” (faber) of the 21st Century is really the engineer who devises or
describes models of thought. It is precisely that which this series of books
investigates, the author having long combined industrial practice and
reflection about world research.
Since our very beginnings on this planet, humans have had to deal with
the four primordial “elements” as they were known in the ancient world:
earth, water, air and fire (and a fifth: aether). Today, we speak of gases,
liquids, minerals and vegetables, and finally energy.
The unit operation expressing the behavior of matter are described in
thirteen volumes.
It would be pointless, as popular wisdom has it, to try to “reinvent the
wheel” – i.e. go through prior results. Indeed, we well know that all human
reflection is based on memory, and it has been said for centuries that every
generation is standing on the shoulders of the previous one.
Therefore, exploiting numerous references taken from all over the world,
this series of books describes the operation, the advantages, the drawbacks
and, especially, the choices needing to be made for the various pieces of
equipment used in tens of elementary operations in industry. It presents
simple calculations but also sophisticated logics which will help businesses
avoid lengthy and costly testing and trial-and-error.
Herein, readers will find the methods needed for the understanding the
machinery, even if, sometimes, we must not shy away from complicated
calculations. Fortunately, engineers are trained in computer science, and
highly-accurate machines are available on the market, which enables the
operator or designer to, themselves, build the programs they need. Indeed,
we have to be careful in using commercial programs with obscure internal
logic which are not necessarily well suited to the problem at hand.
The copies of all the publications used in this book were provided by the
Institut National d’Information Scientifique et Technique at Vandœuvre-lès-
Nancy.
We shall base our discussion here on the most common case, which is
that of a mixture of air and water vapor. The conclusions drawn can easily be
transposed to apply to gaseous mixtures of a different nature.
The air is saturated with vapor when the partial pressure of the vapor PV
is equal to the vapor pressure π (t) corresponding to the temperature of the
mixture.
We shall let “B” represent the ratio 18/28.94 = 0.622, and Y is written:
B PV Bεπ
Y= = [1.1]
P − PV ( P − ε π )
H = U + PV
U: internal energy.
The enthalpy of water vapor at tοC is equal to the heat applied in one of
the following two processes:
These two values express the enthalpy of the water vapor in accordance
with the principle of initial state and final state. For a function of state,
t t
H V = L 0 + ∫ CV dt = ∫ CE dt + L t
0 0
t
HE =
0.2374 + 4.015 × 10−5 t − 2.721× 10−7 t 2
HV = 2500.8 + 1.8266 t + 2.818.10−4 t 2 − 1.0862.10−5 t 3
−1
H E and H V : gravimetric enthalpies of water and vapor: J.kg ;
t: temperature °C.
The gravimetric enthalpy of dry air varies little with the temperature:
The enthalpy of humid air in relation to the mass of dry air is, finally:
H GH = H G + Y H V [1.2]
Let PG0 be the density of dry air in normal conditions. The density of dry
air still at the pressure of 1 bar, but at the absolute temperature T is,
according to the Boyle–Mariotte law:
T0 MG P
ρG = ρG0 =
T RT
4 Adsorption – Dryers for Divided Solids
Now consider 1 m3 of humid air. The molar fraction of the water vapor is:
Y
18 Y
yV = =
1 +Y B+Y
29 18
T: absolute temperature: K;
P: pressure: Pa;
Y: in humid air, the ratio of the mass of water vapor to the mass of dry
air.
The mass of dry air occupying the volume V at the pressure P is:
PV
mG = M G n = M G
RT
mG M G P
ρG = = [1.3]
V RT
Now consider 1 m3 of humid air. The partial pressure of the dry air in that
mixture at the total pressure P is P (1 − y V ) , and the mass of dry air present
is:
M G P (1 − y V )
mG = = ρG (1 − y V )
RT
⎛ Y ⎞ B (1 + Y )
ρGH = m G (1 + Y ) = ρG ⎜ 1 − ⎟ (1 + Y ) = ρ G [1.4]
⎝ B+Y⎠ B+Y
However:
B MG 0.622 × 29 1
= =
R 8314 461
Humid Air Water Cooling Towers 5
M G P (1 + Y ) B P (1 + Y )
ρ GH = = [1.5a]
RT ( B + Y ) T × 461 ( B + Y )
B (1 + Y )
M GH = M G [1.5b]
(B + Y)
The volume VGH of humid air corresponding to 1 kg of dry air is:
1 + Y 461
VGH = = ( 0.622 + Y ) T
ρ GH P
⎡ 17.0057 t ⎤
π ( t ) = exp ⎢ 6.4145 +
⎣ 233.08 + t ⎥⎦
Cμ
Remember that the Prandtl number Pr is
λ
μ
The Schmidt number Sc is
ρD
The Prandtl number and the Schmidt number are dimensionless, as is the
Pr CρD
Lewis number, which is the ratio = .
Sc λ
Let us now consider operation in the turbulent regime. The heat transfer
coefficient is of the form:
λ
α= j( Re ) Pr1/3
δ
D
β= j( Re ) Sc1/3
δ
δ: reference length: m.
If, as is the case for the water–air system, the Lewis number is equal to 1,
λ α
= Cρ and = Cρ = CGH ρGH [1.6]
D β
Let us write that the cooling of the gas serves to vaporize the water in the
sleeve surrounding the wet-bulb thermometer.
α ( t G − t H ) = βΛ ( C H − CGH )
Let us set:
0 = α ( t GH − t H ) + βΛ ( CGH − CH )
⎛ YGH YH ⎞
= βCGH ρGH ( t GH − t H ) + βLρG B ⎜ − ⎟
⎝ B + YGH B + YH ⎠
(1 + YGH ) B
ρ GH = ρ G
( B + YGH )
Finally:
⎡ 1 + YGH ⎛ YGH YH ⎞ ⎤
0 = βρ G B ⎢ C GH ( t GH − t H ) + L ⎜ − ⎟⎥ [1.7]
⎣⎢ B + YGH ⎝ B + YGH B + YH ⎠ ⎥⎦
1) Lines ε = const.
PV
We know that ε =
π(t)
Conversely: t H = t ( π ) = f ( PV / ε )
However,
PY
PV =
B+Y
Thus:
⎛ PY ⎞
t H = f ⎜⎜ ⎟⎟
⎝ ε (B + Y) ⎠
2) Lines PV = const.
PY
PV =
B+ Y
3) Lines t = const.
The enthalpy of the humid air expressed in relation to the dry air is
written, in accordance with equation [1.2]:
HGH = HG + YHV
These lines are therefore straight lines whose ordinate at the origin is HG
and whose slope is HV. As the enthalpy of the vapor includes its latent heat,
that slope is steep.
10 Adsorption – Dryers for Divided Solids
P (1 + Y )
t GH = × − 273
ρ GH x 0.622 ( 0.622 + Y )
The temperature decreases slightly when Y rises from zero. Apart from
this restriction, the curves ρGH = const. are similar to the lines t = const.
The wet-bulb thermometer equation (see equations [1.7] and [1.8]) can be
used to calculate tGH if we know tH and YGH:
L tH
t GH = t H + σ ( YH − YGH ) [1.9]
CGH
−1o −1
C GH : specific heat capacity of the humid air: J.kg C
dHGH
CGH =
dt
The lines tH = const. are curves with a slight positive slope. Indeed, we
can write approximately:
We can clearly see that the coefficient of YGH is low, because σ is nearly
equal to 1 for the air–water system.
As the enthalpies HG and HGH and the humidity Y are relative to the unit
mass of dry air, the mixing law applies, provided that each component is
weighted by its mass of dry air. In the diagram, the mixture is the barycenter
of the images of the components. This property is useful in performing the
calculations for a dryer where the air is recycled.
σL
t GH − t H = (YH − YGH )
CP
12 Adsorption – Dryers for Divided Solids
Remember that:
B yH π
; y H = H ; σ = ( Lu )
2/3
YH =
1 − yH P
Lu: Luikov number. This number is very close to 1 for water vapor in air.
The Luikov number is none other than the Lewis number.