28-04-2024

1001CJA101017240001 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A bird flies from (2, 4, 6) m along , final position of bird is :

A. (6, 4, 2) m
B. (2, 6, 4) m
C. (8, 8, 8) m
D. (4, 0, –4) m

2) Angle between two vectors and shown in diagram is

A. 150°
B. 30°
C. 60°
D. 90°

3) Given that is a unit vector. What is the value of a ?

A.
B.
C.
D.

4) The period of a body under S.H.M. is represented by : T ∝ PaDbSc, where P is pressure, D is density
and S is surface tension, then the values of a, b, and c are :-

A.
B. –1, –2, 3

C.

D.

5) The pressure P is related to distance x, Boltzmann constant k (having dimension [M1L2T–2K–1]) and
temperature θ as: ; The dimensional formula of b is :

A. [M–1L–1T–1]
B. [MLT2]
0 0
C. [M L2T ]
0 0 0
D. [M L T ]

6) A particle with mass m and initial velocity v0 is subjected to a velocity dependent force of the form
bvn. Let stopping time t of particle depend on m, v0 and b as t ∝ mαbβv0γ Powers α, β and γ will be

A. α = 1, β = –1, γ = 1 – n
B. α = 2 – n, β = –1, γ = 2
C. α = 1, β = 1, γ = 1 – n
D. α = –1, β = –1, γ = 1 – n

SECTION-I (ii)

1) In a new system unit of force is 50N, unit of velocity is 5 m/s and unit of frequency is 2 Hz then
choose the correct statement(s):

A. Unit of time in this system is 0.5 s.

B. Unit of length in this system is 2.5 m.
C. Unit of mass in this system is 5 kg.
D. Unit of time in this system is 2 s.

2) Which of the arrangement of axes in figure. can be labelled “right-handed coordinate system” ? As

usual, each axis label indicates the positive side of the axis :
 A. (i), (ii)
B. (iii), (iv)
C. (vi)
D. (v)

3) The value of can be zero if :–

A.

B.

C.

D.

4) For the equation x = AC sin(Bt) + D e(BCt), where x and t represent position and time respectively,
which of the following is/are correct :-

A. Dimension of AC is LT–1
B. Dimension of B is T–1
C. Dimension of AC and D are same
D. Dimension of C is T–1

5) If the speed v of a particle of mass m as function of time t is given by v = ωA sin ,

where A has dimension of length.

A. The argument of trigonometric function must be a dimensionless quantity

B. Dimensional formula of ω is T–1
C. Dimensional formula of k is MLT–2

D. Dimensional formula of is T

6) If this equation is dimentionally correct where all the letters represent

physical quantities then choose the incorrect statement(s) : (none is dimensionless)
 A. Units of and are same.

B. Dimensional formulas of P and are same.

C. Dimensional formulas of P and are same.

D. Units of and X are same.

SECTION-II

1) The magnitude of scalar product of two vectors is 8 and that of vector product is for two
different angles between them. Find ratio of smaller angle to greater angle

2) Three forces of magnitudes 3 N, 4 N & 5 N act at corners of a cube along three sides as shown in

figure. Find the resultant of these forces in N.

3) A vector of magnitude 12 units makes angle 60° & 45° with x & y axis respectively then the
magnitude of it’s z component is :

4) Two forces P and Q are in ratio P : Q = 1 : 2. If magnitude of their resultant is and angle
between P and Q is X then value of cos (X) is.

5) Kinetic energy of a particle moving on a circle is given as, K.E. = maωbrc, where m = mass, ω =
angular speed, r = radius of circle then, |a + b + c| would be :

6) The time period of oscillation of a body is given by

T=
K : Represents the kinetic energy, m mass, g acceleration due to gravity and A is unknown.
If [A] = Mx Ly Tz
Then what is the value of (x + y + z).
 PART-2 : CHEMISTRY

SECTION-I (i)

1) Find the total number of possible sets of four quantum numbers for the 25th electron of Mn (Z =
25)

A. 5
B. 14
C. 10
D. 6

2) A certain negative ion A2– has 22 neutrons and 18 electrons. What is the mass number of an atom
of A?

A. 42
B. 38
C. 40
D. None of these

3) If spin only magnetic moment of Co+x is BM then value of x is :

A. 2
B. 3
C. 4
D. None of these

4) Which of the following satement is correct.

A. Total number of electrons in a subshell is (2ℓ +1)

B. pz, and orbitals are non axial.
C. Only s-orbital has directional properties while p, d and f-orbitals have non diractional
properties.
D. Spin multiplicity of N-atom is 4

5) Which of the following order of radii is correct?

A. Li < Be < Hg
B. H+ < Li+ < H–
C. O < F < Ne
D. Li < Na < K < Cs < Rb

6) Which transition involves maximum amount of energy? (M is an alkali metal)

A. M– (g) → M (g) + e⊖
B. M (g) → M+ (g) + e⊖
C. M+ (g) → M+2 (g) + e⊖
 D. M+2 (g) → M+3 (g) + e⊖

SECTION-I (ii)

1) Which of the following statements is/are correct ?

A. The second ionization enthalpy of oxygen element is greater than that of fluorine element.

B. The third ionization enthalpy of phosphorus is greater than that of aluminium.

C. The first ionization enthalpy of aluminium is slightly greater than that of gallium.
D. The second ionization enthalpy of boron is greater than that of carbon.

2) Which of the following is/are correct order/s of electron affinity.

A. N<C<O<F
B. P < Si < S < Cl
C. Si < P < S < Cl
D. C<N<O<F

3) Which of the following order is/are incorrect for Fe according to Slater's rule?

A. The Zeff experienced by 2s & 2p e– is equal.

B. The Zeff experienced by 3s, 3p & 3d e– is equal.
C. The Zeff experienced by 4s e– is greater than 3d e–
D. The Zeff experienced by 4s e– is less than 3d e–.

4) If Aufbau’s principle and Hund’s rule were not followed.

A. K would have been d–block element & paramagnetic.

B. Cu would have been s–block element.
C. Cr would have been diamagnetic
D. Fe+3 ion would have 5 unpaired electrons.

5) Out of the following statements which is/are correct :-

A. H is an element of minimum atomic radius

B. He is an element of highest I.P.
C. Cl is an element of highest EA
D. Li is an element of lowest I.P.

6) Which of the following is/are correct ?

A. For A(g) + e– —→ A¯ (g) ΔH may be negative

B. For A¯(g) + e– —→ A2– (g) ΔH may be negative
C. For A¯(g) + e– —→ A2– (g) ΔH must be positive
D. For Ne(g) + e– —→ Ne¯ (g) ΔH may be zero
 SECTION-II

1) Find out the total numbers of ions/atoms having greater radii than oxygen atom. H–, O+, S2–, O2–,
F–, Br–, I–, F, C

If your answer is 'x' then find the value of

2) Find ratio of number of elements in which last electron enters p-subshell to the number of
elements in which last electron enters s-subshell , upto atomic number 36. In long form of periodic
table.

3) Calculate :
where
x = Maximum number of degenerate orbitals in 2nd excited state of Li2+
y = Electronegativity value of most electronegative element on Pauling scale

4) If 'x' is the number of elements that can accomodate in 10th period of periodic table. Then find out

the value of .

5) The atomic number of element “Unnilquadium” is X. The value of is-

–
6) According to Slater's rule, calculate effective nuclear charge (Zeff) on last electron of F .

PART-3 : MATHEMATICS

SECTION-I (i)

1) If (x + y)(y + z)(z + x) = 11 and x + y + z = 11, then value of x3 + y3 + z3 is -

A. 1320
B. 1364
C. 1164
D. 1298

2) Product of all values of x satisying the equation

 A.
B. 3

C.

D.

3) If the expression N = (2 + 1) (22 + 1)(24 + 1) (28 + 1) .... (21024 + 1) is equal to 2n – 1 then n is

equal to

A. 1023
B. 4096
C. 2048
D. 2047

4) Factors of (x + 2) (x + 4) (x + 6) (x + 8) + 12 is :

A. (x2 + 10x – 7) (x2 + 10x + 5)

B. (x2 + 10x + 22) (x2 + 10x + 18)
C. (x2 + 5x + 4) (x2 + 5x – 7)
D. (x2 + 5x + 9) (x2 + 5x + 3)

5) ≤0

A. (–1, 1] ∪ [2, 3] ∪ [4, ∞)

B. (–∞, –1] ∪ [1, 2] ∪ [3, 4]
C. (–1, 1] ∪ [3, ∞] ∪ {2}
D. None

6) Consider the following diagrams (Where 'O' is centre of circle)

then (θ + α + γ) is :

A. 290°
B. 150°
C. 210°
D. 300°

SECTION-I (ii)
1) A survey shows that 63% of the Indian like apples whereas 76% like oranges. If x% of the Indian
like both apples & oranges then

A. minimum value of x is 39
B. maximum value of x is 63
C. one possible value of x is 51
D. one possible value of is 59

2) If n(U) = 700, n(A) = 200, n(B) = 300, n(A ∩ B) = 100, then,

A. n(A' ∪ B') = 400

B. n(A'∩ B') = 300
C. n(A' ∪ B') = 300
D. n(A ∪ B) = 400

3) Values of expression
E = x2 + y2 – 4x – 6y + 15, x, y ∈ R can take is (are)

A. 1
B. 2
C. 3
D. π

4) Choose the correct option/s :-

A. Sum of solutions of the equation ||x – 1| – 2| = 0 is equal to 2

B. , for x, y ∈ R
C. Greatest number among is
D. a4 + a2 + 1 = (a2 – a + 1) (a2 + a + 1)

5) In a survery, it was found that 21 persons liked product A, 26 liked product B and 29 liked
product C. If 14 persons liked products A and B, 12 liked products C and A, 13 persons liked
products B and C and 8 liked all the three products then which of the following is (are) true ?

A. The number of persons who liked the product C only = 12

B. The number of persons who like the products A and B but not C = 6
C. The number of persons who liked the product C only = 6
D. The number of persons who like the products A and B but not C = 12

6) Let (where a, b ∈ N), then

A. ab = 30
B. a2 – b2 = 31
C. a + b = 11
D. a2 + b2 = 41
 SECTION-II

1) is equal to

2) An algebraic polynomial P(x) is such that P(2) = 4 and P(1) = 1. If the remainder when P(x) is
divided by x2 – 3x + 2 is Q(x) then find Q(10) ?

3) Sum of value(s) of x satisfying 52x – 6.5x + 5 = 0 is

4) xy = 12, yz = 15, zx = 20 find x + y + z ; x, y, z ϵ R+

5) If , then the value of

is

6) Find the largest solution of equation

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. [2] [1] [2] [0] [2] [0]

SECTION-I (ii)
Q. 7 8 9 10 11 12
A. [["true","true","true","false"]] [["true","true","true","false"]] [["false","true","false","true"]] [["false","true","true","false"]] [["true","true","false","false"]] [["true","false","false","false"]]

SECTION-II

Q. 13 14 15 16 17 18
A. 0.50 7.05-7.07 6.00 0.75 5.00 3.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. [2] [1] [1] [3] [1] [3]

SECTION-I (ii)
Q. 25 26 27 28 29 30
A. [["true","true","false","true"]] [["true","true","false","false"]] [["false","true","true","false"]] [["true","true","true","false"]] [["true","true","true","false"]] [["true","false","true","false"]]

SECTION-II

Q. 31 32 33 34 35 36
A. 4.37 2.25 6.50 7.20 3.33 4.85

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. [3] [3] [2] [1] [2] [0]

SECTION-I (ii)
Q. 43 44 45 46 47 48
A. [["true","true","true","true"]] [["false","true","false","true"]] [["false","true","true","true"]] [["true","false","false","true"]] [["true","true","false","false"]] [["true","false","true","false"]]

SECTION-II
Q. 49 50 51 52 53 54
A. 1.66 28.00 1.00 12.00 0.00 2.00
 SOLUTIONS

PART-1 : PHYSICS

1) =

2) θ + 150° = 180°
θ = 30°

3) 0.22 + 0.62 + a2 = 1

4) T = [ML–1T–2]a [ML–3]b [MT–2]c

0 0
Ma+b+c L–a–3bT–2a–2c = M L T1
a+b+c=0
a + 3b = 0
2a + 2c = –1

;
c=1

5)

6)

t ∝ mαbβv0γ

0 0

M L T1 =
= Mα[MLT–2]β[LT–1]γ–nβ
α+β=0 ...(A)
β + γ – nβ = 0 ...(B)
–2β – (γ – nβ) = 1 ...(C)
–β = 1
β = –1
From (B) γ + n – 1 = 0
γ=1–n.
 7)

Let’s assume units of mass, length and time in new system is M1, L1, T1

So,

And
M1 = 5kg

8)

Only (v) option is not a right handed coordinate system.

9) Sum of 3 sides must be ≥ fourth side.

10) Bt = 1
[B] = T–1
BCT = 1
C=1
D=L
AC = L
A=L

11)

Plane angle is dimensionless

[ωA] = [v]
[ω]L = LT–1
[ω] = T–1

=1

k= = MT–2

⇒ = T–1

12)
 13) AB cosθ = 8
AB sinθ =

θ = 60°; 120°

14)

= 5 ×1.414
= 7.07

15)

cos2α + cos2β + cos2γ = 1

⇒ cos2 60 + cos2 45 + cos2γ = 1

cos γ = ±

Acosγ = 12 ×
AZ = ±6
Magnitude = 6.00

16) R =
R2 = 5P2 + 4P2cosθ
Since R2 = 8P2, ∴ 8P2 = 5P2 + 4P2cosθ

17)

Applying dimension
ML2T–2 = MaT–bLc
a=1
b=2
c=2
So a + b + c = 5
 18) [T] = = =

=
0
⇒ [A] = M L T2
x = 0, y = 1, T = 2
x+y+z=3

PART-2 : CHEMISTRY

19)

25thelectron enters '3d' subshell

20) A2– = n =22, e– = 18,

∴ p = 16
⇒ Mass number = n + p = 22 + 16 = 38

21)

Refer notes

22)

N = 1s2 2s2 2p3

Total spin = 3 ×

spin multiplicily is

23) (A) Li > Be < Hg

(B) H+ < Li+ < H–1
(C) Ne > O > F
(D) Li < Na < K < Rb < Cs

24)
Higher the positive charge on ion, higher will be its ionisation energy.

25)

(A) As removal of second electron takes place from half filled valence shell electron
configuration of O+ i.e. 2s22p3.
(B) I.E(III) of 13Al is 2744 kJ mol–1 where as that of 15P is 2910 kJ mol–1. This is because of higher
nuclear charge in phosphorus.
(C) I.E(I) of Al is 577 kJ mol –1 and that of Ga is 579 kJ mol –1. This may be because of their
similar sizes i.e. 1.25 Å in both.
(D) 5B+ = 1s22s2; 6C+ = 1s22s22p1; As s-sub shell electron has high penetration power than p-sub
shell electron. In addition B+ has completely filled 2s sub shell. So I.E (II) of B is 2427 and that
of C is 2354 kJ mol–1.

26) Electron affinity is the tendency is attract shared pair of electron towards itself. Its value
decreases in a group and increases in a period.

27)

Incorrect statements :-
Fe ⇒ Z = 26
According to slater's rule :-

Incorrect are :- B, C

28)

Fe3+ ion will have = One unpaired electron.

29)

Element having lowest IP is Cs.

30) is generally negative but always positive

31) H–, S2–, O2–, F–, Br–, I–, C

32)

s-Block : H, He, Li, Na, K, Be, Mg, Ca (8)

p-Block : B, C, N, O, F, Ne, Al, Si, P, S, Cl, As
Ga, Ge, As, Se, Br, Kr (18)
so ratio

34)

10s2 , 6h22 , 7g18 , 8f14 , 9d10 , 10p6

so total electron or elements = 72

so Ans.

35)

= 3.33

36) 9F – → 1s2 2s2 2p6

(1s)2 (2s, 2p)8
Zeff on last electron on F –
=Z–σ
= 9 – (2 × 0.85 + 7 × 0.35)
= 4.85

PART-3 : MATHEMATICS

37)

Use : (x + y + z)3
= x3 + y3 + z3 + 3(x + y)(y + z)(z + x)
(11)3 = x3 + y3 + z3 + 3(11)
∴ x3 + y3 + z3 = 1298

38)

⇒
2
5x – 14x – 3 = 0

39) N = (2 + 1) (22 + 1) (24 + 1) (28 + 1)....(21024 + 1)

 ⇒ n = 2048

40)

(x2 + 10x + 16) (x2 + 10x + 24) + 12

Let x2 + 10x + 16 = t
t(t + 8) + 12
= (t + 6) (t + 2)
= (x2 + 10x + 22) (x2 + 10x + 18)

41)

x ∈ (–1, 1] ∪ [3, ∞) ∪ {2}

42)

θ = 120°, α = 120°, γ = 50°

43)

n(A ∪ B) = n(A) + n(B) – n(A ∩ B) = 63 + 76 – n(A ∩ B) = 139 – n(A ∩ B)

n(A ∪ B) ≤ 100 ∴ 139 – n(A ∩ B) ≤ 100 ⇒ n(A ∩ B) ≥ 39 ...(A)
Now A ∩ B ⊆ A & A ∩ B ⊆ B ⇒ n(A ∩ B) ≤ 63 & n(A ∩ B) ≤ 76
∴ n(A ∩ B) ≤ 63 ∴ 39 ≤ n(A ∩ B) ≤ 63

44)

n(A' ∩ B') = n(A ∪ B)'

= n(U) – n(A ∪ B)
= 700 – n(A ∪ B)
Now n(A ∪ B) = n(A) + n(B)– n(A ∩ B)
= 200 + 300 – 100 = 400
Hence, n(A' ∩ B') = n(A ∪ B)' = n(U) – n(A ∪ B)
= 700 – 400 = 300

45)

E = (x – 2)2 + (y – 3)2 + 2
E≥2

46)
(A)
|x – 1| = 2
x = +3, –1

(B) only when x, y > 0

(C) LCM (3, 4, 6) = 12

is greatest
(D) a + a2 + 1 = a4 + 2a2 + 1 – a2
4

= (a2 + 1)2 – (a)2

= (a2 + 1 – a) (a2 + 1 + a)

47)

n(A) = 21, n(B) = 26, n(C) = 29

n(A ∩ B) = 14, n(A ∩ C) = 12, m(B ∩ C) = 13, n(A ∩ B ∩ C) = 8
n(C ∩ A' ∩ B') = n(C ∩ ) = n(C) – n((C ∩ A) ∪ (C ∩ B))
n(C) – [n(C ∩ A) + n(C ∩ B) – n(A ∩ B ∩ C)]
29 – [12 + 13 – 8] = 12
n(A ∩ B ∩ C') = n(A ∩ B) – n(A ∩ B ∩ C) = 14 – 8 = 6

48)

Let

⇒ x2 – x – 1 = 0

Let

⇒ y2 – y – 31 = 0

∴
⇒ a = 6, b = 5

49) = =

50) P(x) = (x – 1)(x – 2)Q(x) + (ax + b)

 P(2) = 2a + b = 4
P(1) = a + b = 1
a = 3, b = –2
Q(10) = 3 × 10 – 2 = 28

51)

Let 5x = t
t2 – 6t + 5 = 0
(t – 1) (t – 5) = 0
0
5x = 5 or 5x = 51
x = 0 or x = 1
sum = 1

52)

(xyz)2 = (60)2
xyz = 60
x= 5, y= 4, z= 3

53)

⇒ b + c = 0 ⇒ b = –c

and
⇒ a2 + a (b + c) + bc = 0
⇒ (a + b)(a + c) = 0
a = – b or a = – c

⇒0

54)

Put ⇒
t2 – 22t + 1 = 0

t=
t=
t=
t=