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PRODUCTION OF BLEACH SOLUTION AND

COMPARATIVE STUDY OF COMERCIALLY PRODUCED

BLEACH SOLUTION

BY

OZOR, HENRY OGECHI - STE/N2003/013


MICHAEL, CHIZARAM BLESSING - STE/N2003/014
MGBEKANNE, CHIGOZIE E. - STE/N2003/015

IN PARTIAL FULFILLMENT OF THE REQUIREMENT

FOR THE AWARD OF ORDINARY NATIONAL DIPLOMA

(OND)

IN THE DEPARTMENT OF SCIENCE TECHNOLOGY

INSTITUTE OF MANAGEMENT AND TECHNOLOGY

(IMT), ENUGU

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AUGUST 2005

TITLE PAGE

PRODUCTION OF BLEACH SOLUTION AND


COMPARATIVE STUDY OF COMERCIALLY PRODUCED
BLEACH SOLUTION

BY

OZOR, HENRY OGECHI - STE/N2003/013


MICHAEL, CHIZARAM BLESSING - STE/N2003/014
MGBEKANNE, CHIGOZIE E. - STE/N2003/015

IN PARTIAL FULFILLMENT OF THE REQUIREMENT

FOR THE AWARD OF ORDINARY NATIONAL DIPLOMA

(OND)

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IN THE DEPARTMENT OF SCIENCE TECHNOLOGY

INSTITUTE OF MANAGEMENT AND TECHNOLOGY

(IMT), ENUGU

AUGUST 2005

CERTIFICATION

The Project has been read and found worthy of submission to the

Department of Science Technology, Institute of Management and

Technology (IMT), Enugu.

BY

OZOR, HENRY OGECHI - STE/N2003/013

MICHAEL CHIZARAM BLESSING - STE/N2003/014

IMEGBEKANNE, CHIGOZIE E. - STE/N2003/015

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MRS. ADA IKEYI

SUPERVISOR DATE: _______________

HEAD OF DEPARTMENT DATE: _______________

EXTERNAL EXAMINER DATE: _______________

DEDICATION

This work is dedicated to Almighty God for His guidance and

protection throughout our stay in the polytechnic. And to our parents who

denied themselves of some pleasures in order to see us through.

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ACKNOWLEDGEMENT

The success of this research study is a combination of hard work,

determination and encouragement from our Supervisor, families and friends.

We are greatly indebted to our indefatigable Supervisor MRS. ADA

IKEYI, who in spite of her commitments devoted time to direct and guide us

throughout this study.

Our profound and sincere gratitude also go to our lecturers Mr.

Adebayo, Mr. Apkagu, Mr. Ugwuoke, Mr. J. N. Amuh, who is our Head of

Department and others too numerous to mention.

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We will even remain grateful to our parents who supported us morally

and financially throughout our stay in the polytechnic. We remain grateful

for your contributions.

ABSTRACT

Bleaching is the process in which net oral colouring matter is removed

from a fiber, yana or fabries. It ranges from simple to complex type

depending on the ingredeient moderal the bleach solution chosen in this

research work is oxochtorale: (i) acid solution (Hocl). The bleach was

produced when 100mls of hydrochloric acid was pound into the flask and

20g of potassium tetraozo magnate (vii) was also put into the round bottom

flask. The flask containing the Hcl was connected into one of the opening,

so that the Hcl ran into the round flask to make contact with the potassium

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tetraoxomaganate (vii) Kmno4. The chlorine gas was liberated and passed

on till the water became saturated form exochlorate (i) acid, which is the

bleach solution. This is an oxidative process. The equation is thus:

ch(g)+ H2O (L) Hoclca2)+ Hcl(og).

The oxochlorate (i) acid formed is an effective bleaching agent. The

bleach produced was compared with commercially produced bleach. The

control bleach used was Jik a product of PZ Nigeria plc. The result sowed

that there was significant difference between the laboratory produced bleach

and the commercially produced bleach solution.

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TABLE OF CONTENTS

Title page

Certification

Dedication

Acknowledgement

Abstract

Table of contents

CHAPTER ONE

1.0 Introduction

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1.1 Statement of the problem

1.2 Aims and objectives

1.3 Hypothesis

1.4 Limitation of the study

1.5 Significance of the study

CHAPTER TWO

2.1 BACKGROUND OF BLEACHING SOLUTION

2.2 OXIDIZING OR REDUCING BLEACHING AGENT

2.3 TYPES OF OXIDIZING BLEACHING AGENT

2.4 MECHANISM OF BLEACHING AGENT

CHAPTER THREE

3.0 MATERIALS AND METHODS

3.1 REAGENTS USED

3.2 APPARATUS/MATERIALS USED

3.3 METHOD OF PRODUCTION

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CHAPTER FOUR

4.0 RESULTS AND DISCUSSION

4.1 RESULTS

4.2 DISCUSSION

CHAPTER FIVE

5.0 CONCLUSION AND RECOMMENDATION

5.1 CONCLUSION

5.2 RECOMMENDATION

REFERENCES

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CHAPTER ONE

1.0 INTRODUCTION

Bleaching is a process in which natural colouring matter is removed

from a fiber to make it white. This process can be extended to other uses for

example, in yarn or fabrics or in pulp and paper industries where cellulose

used in making paper is bleached to white. Bleach solution can also be

defined as any solution that is capable of bleaching colouring matters.

Bleach solution ranges from simple to complex types in various trade names

like parazone, Jik etc. They completely depend on the makes up of the

ingredient materials.

1.1 STATEMENT OF THE PROBLEM

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There has been the problem of low quality production of bleach by

various producing firm in Nigeria. This study is set to assess the production

of bleach solution, self-empowerment of our young school leavers in

Nigeria.

“SUB PROBLEM 1”

The purpose of this study is to produce a bleach solution that will be

affordable to the common man in the society.

“SUB PROBLEM II”

The reason for this study is to produce a bleach solution that will be of

high quality compared to the commercially produced ones in the market.

1.2 AIMS AND OBJECTIVES

The aims and objectives of this project is to a large extent as

explained by the title – “Production of bleach solution comparatively to

commercially produced bleach solution. The research objectives are listed

below:

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1. To harness the available raw materials for the production of bleach

solution in the country.

2. To produce quality bleach, which will be affordable to the masses

comparatively to others produced and sold costly in the market.

3. To establish medium scale industries for employment of young school

leavers thus making them to become self-reliant.

1.3 HYPOTHESIS

Having stated the problems and the objectives of the study, the

researchers hereby make the following tentative statement. The following

hypothesis are being considered:

Ho : Bleach produced from project will be comparable to

commercially produced bleach sold in the market.

H1 : Bleach produced from project will not be comparable to

commercially produced bleach sold in the market.

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1.4 LIMITATIONS OF THE STUDY

This empirical study is concerned with the strategies for producing

bleach and making it to be of more quality compared to the commercially

produced ones already in the market.

In pursuance of a successful completion of this research work, certain

limitations posed some threats to the researchers. Among them we have:

1. FINANCE

Finance has been the major factor in any type of project. Lack of

adequate funds to meet the rising cost of undertaking a research work

was among the constraints.

2. TIME

The interval between choosing the project topic, the submission of the

project and preparation for the final examinations is very

infinitesimal, but these are logjam and hence the researchers were

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deprived of so many other activities to ensure the fulfillment of the

research work.

1.5 SIGNIFICANCE OF THE STUDY

For sometime now, there has been great public concern over the low

quality production of bleach solution.

The result of the findings will be of great importance to our society

because things like domestic work in our homes. For example, washing

clothes, removing of stubborn stains, cooking, cleaning and also in killing

germs will be done by the bleach solution produced.

Finally, this research work will be of immense importance to the

researchers, since it is a practical requirement for the award of Ordinary

National Diploma (OND) in Science Technology of the Institute of

Management and Technology (IMT), Enugu.

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CHAPTER TWO

2.0 LITERATURE REVIEW

2.1 BACKGROUND OF BLEACHING SOLUTION

In the history of bleach solution, evidence exists for the chemical

bleaching of cloth by archeologist prior to 300 BC.

According to Jeeves (2000), a United State based Professor said that

the Greek and Roman used this neutralization method until the mid –

eighteenth century. Firstly, soaking in an aqueous alkaline solution prepared

by digesting the seaweed cleans the material. After the alkaline treatment,

the cloth was treated with sour milk to remove any calcium salt and to

neutralize the alkaline solution. This neutralization process is called

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scorning. After scorning, the cloth was rinsed and laid in the sun for days at

a time to been bleached. This later process is called crafting.

By the 1800 century, there was a strong demand for bleached cloth.

The classical sequence of scour, some and bleach remained the only method

available. The first two steps in the sequence was later improved some what

by the use of alkali solution, in the scouring process and the replacement of

scour milk by oil of vitriol. GrownHill M. C. (1967).

USE OF LARGE TRACTS OF LANO

Due to the pressure existed by the decreasing availability of land, the

stage was set for the introduction of a chemical process for bleaching.

According to Frank B., Frank C. P., Seymann S. and Stanley M.

(1978), Benthlef applied chlorine after his discovery in 1974 in a

commercial bleaching. Benthlef attempted at first to use water solution of

chlorine, but he found out that this weakened the cloth excessively. He later

discovered that chlorine could be assorted by a caustic potash solution to

form potassium hypochlorine. This process of bleaching then became the

fully accepted chemical bleaching process with lime and soda ash being used

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for the scour, oil of vitriol for the scour and potassium hypochlorine for the

bleach.

According to Clugston M. J., Fraze, M. J., Akkins, P. L., Jones R.

(1988), labarraque replaced the expensive potassium solution with caustic

soda and by the turn of the century, labarraque solution has completely

replaced potassium hypochlorine and simultaneously eliminated the need for

crafting.

Other chlorine base methods of bleaching were also being

investigated at the beginning of the nineteenth century.

Also according to Ababid O. (1984), p. 282, the development of

bleaching powder was of great importance since this solid form of chlorine

bleach could be transported easily.

This development eliminated the need for onsite chlorine generating

plants adjacent to the textile mills. For the next century, bleaching powder

remained the chief source of textile bleach and has the impetus for much of

the early chemical and chemical engineering investigations.

Thus, materials could be bleached either with an oxidizing a reducing agent.

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2.2 OXIDIZING OR REDUCING BLEACHING AGENT

Scoring generally removes all impurities except the natural colouring

matters, which have to be broken down by bleaching, either with an

oxidizing a reducing agent.

Oxidizing bleaching agent are used to a far greater extent than

reducing agent Ababid (1984). Almost invariably the oxidizing agent gives

a more permanent white than the reducing agent. When the colour is acted

upon by a reducing agent, there is always the possibility that the oxygen in

the air re-oxidize it to its original state.

Due to this reason, oxidizing bleaching agent is preferred to reducing

bleaching agent. The traditional oxidizing bleaching agent for cellulosic

fibers was bleaching powder, which is more convenient to handle and more

constant in composition Jeeves (1998).

The cheapest and most abundant oxidizing agent is atmospheric

oxygen Ababid (1984), p. 165 and the method of bleaching was to lay the

methnal out in a field where it was exposed to the sun and air. This was

known as “dew bleaching”. But the generally accepted oxidizing bleach

solutions are oxochlorate (i) acid and sodium hypochlorite.

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Sulphur dioxide has been used as a reducing bleaching agent, which

has the disadvantages of forming sulphuric acid after bleaching. Sodium

dothionatic has been the most popular reducing bleach used in the textile

industry. Also, sodium biohydcide is being considered as reducing bleach,

unlike most of the metal hydrides. It can dissolve in cold water, and thus

used in aqueous reductions.

Oxidizing bleaching agent will now be reviewed under the following

categories of bleaching materials; chlorine, hypochlutes, chloramines,

hydrogen peroxide, perborales, chlorine dioxide etc. Ababid (1984), p. 165.

2.3 TYPES OF OXIDSIZING BLEACHING AGENT

There are eight types of oxidizing bleaching agents. They include

i. Chlorine,

ii. Chloramines

iii. Hydrogen Peroxide

iv. Chlorinated trisodium Phosphate

v. Perborales

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vi Chlorine dioxide

vii. Calcium hypochlorine

viii. Sodium hypochlorite

a) CHLORINE

Chlorine is generally used in bleaching operations as an agent for the

preparation of hypochlorine. It is strong and serves for many

purposes, however, chlorination is employed as the first stage bleach

in the preparation of wood pulp because of the high content of

reactive impurities, Ababid (1984), p. 279.

b) CHLORAMINE

The first chloramines used extensively against bleach was 1, 3, -

dichlorine 5, 5 – dimethy chydantion. The first chlorine comes off

with a hydiolysis constant of 2.5 x 10 -4 and the second ax 1.1 x 10 -4.

These values gives sufficient hypochlorous acid at usual laundry

concentration for appreciable bleaching, although not as good as

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bleach that would be obtained with the same concentration of

available chlorine present in a hypochlonite solution.

c) HYDROGEN PEROXIDE

This is the most universal of all commercial bleaches, despite its

higher cost compared to chlorine. It is used mainly in bleaching of

cotton and silk. Ababid (1984), p. 300.

d) CHLORINATED TRISODIUM PHOSPHATE

It is useful in some operations such as cleaning the pipelines used in

transporting milk. For bleaching and sanitation, however, it is less

effective than hyppochlorite preparations, which are not as strongly

alkaline. Ababid (1984).

e) PERBORALES

Perborales are widely used in Europe, where it is a common practice

to bring the wash water to boil or temperatures approaching boiling.

At such temperature, the peroxide released from the perborales

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becomes effective bleach, at temperature lower than 170 o. It is less

successful, and below 140o it becomes markedly inferior to bleach in

its ability to remove stains and to whiten garments.

f) CHLORINE DIOXIDE

Chlorine dioxide has a very important bleaching agent particularly in

the pulp industry in the past decade. The principal processes used to

generate chlorine dioxide employ sulphur dioxide or methanol to

reduce sodium chlorate in strongly acidic solution. However, the

overall reaction may be whiten as follows:

2NaClo3 + So2 + H2So4 2CLo2 + 2NaHSo4

g) CALCIUM HYPOCHLORITE

Calcium hypochlorine is the stable form in which hypochlorines can

be stained. It contains 35 – 37% available chlorine, 10 – 15% water

and several percent free calcium hydioxide. Good calcium

hypochlorine is not seriously hygroscopic if kept under 105of during

manufacture. Ababid (1984), p. 440.

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h) SODIUM HYPOCHLORITE

The solution contains 14 to 15 percent of available chlorine. This is


the oxidizing power of the solution measured by its ability to liberate
iodine from an acidified iodide solution. Among all the bleaching
agents mentioned above. It is only oxochlonate (i) acid that will be
treated in details (Ababid, 1984). But before going into the processes
involved in bleaching solution, one has to look into the mechanism of
bleaching solution.

2.4 MECHANISM OF BLEACHING SOLUTION

Bleaching is the process in which natural colour matter is removed

from a fiber to make it white. Many coloured materials contain a conjugated

chain that is a double bond, which alternate with single bonds. If one of the

double bonds in a conjugated chain is broken, the colour is usually

destroyed; therefore any agent, which will remove a double bond linkage,

may be effective as bleach. A bleaching agent may also act on the groups at

the end of the chain, Lambert J., Mirow T. (1965).

Generally, bleaching reactions are not reversible and especially not if

a double bond has been destroyed. In some instances in which colours can

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be restored, the action is probably mild and limited to the terminal

groupings.

Each class of bleaching agent has a different attach, therefore a

succession of bleaching treatments may be more effective than a single

treatments. If some colour materials remains after a chlorine dioxide

treatment as in case of calcium hypochlorine, a light treatment with peroxide

may remove the remaining colour. Sodium hypochlorine has the widest

range of attack and may be used up to the point where it attacks the fiber.

During the process of bleaching with sodium hypochlorine in water

solution, hydrolysis occurs with the production of hypochlorous acid. This

is represented by the reaction.

NaDCL + HOH HCLO + Nacl

This acid is very instable and breaks down releasing nascent oxygen

as shown by the reaction.

HCLO HCL + (O)

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Excess NaOH and the PH condition control the nascent oxygen release

and thus the ultimate whitening.

For bleaching, sodium hypochlorine is delieved to give a solution

containing between 1 and 3glc of available chlorine. As one gallon per

hundred gallons of water will yield of the other of 1.45glc this will fall

comfortably within the range of 1 to 3glc. Bleaching with calcium

hypochlorine is never free from the risk of tendering due to the formation of

oxycellulose.

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CHAPTER THREE

3.0 MATERIALS AND METHODS

3.1 REAGENTS USED

1. Potassium tetraoxomanganate (vii)

2. Hydrochloric acid

3. Water

3.2 APPARATUS/MATERIALS USED

1) Round bottom flask (with two openings)

2) Connecting tube

3) Beaker

4) Cork

5) Three retort stand

6) Flask with tap

7) Spatula

8) Weighing disc

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9) Weighing balance

3.3 METHOD OF PRODUCTION

The apparatus was set up as shown below:


Concentrated
Hydro Acid (HCL)

Retor
t
stand

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DISTILLED WATER Potassium

Tetraoxomanganate

(VII)

CHLORINE Crystals

(Kmno4)

OXOCHLORATE ACID

H2O + CL2 HOCL + HCL

FIG. 3.1: PRODUCTION OF OXOCHLORATE (I) ACID BLEACH

SOLUTION.

100mls of hydrochloric acid was poured into the flask with tap and

clamped with a retort stand. 20g of potassium tetraoxomaganate (vii) were

also put into the round bottom flask with two openings. The flask

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containing the HCL was connected into one of the openings of the round

bottom flask with the help of a cork. The tap was turned on so that the HCL

ran into the round bottom flask to make contact with the potassium

tetraoxomaganate (vii) lcmno4.

Effervescence occurred and chlorine gas was liberated which passed

through the other opening into the connecting tube and into a beaker

containing distilled water. The chlorine gas passed on till the water became

saturated to form oxochlonate (i) acid,which is the bleach solution when the

water in the beaker turned yellow, the reaction was stopped. The equation is

thus:

Kmno4 + 2HCL kmno3 + H2O + CL2

CL2(g) + H2O(c) HOCC (Q) + HCL.

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CHAPTER FOUR

4.0 RESULTS AND DISCUSSION

4.1 RESULTS

The table below shows the time taken to saturate 50mls of beaker of

water with chlorine.

TABLE I

Time taken to saturate 50mls of water with chlorine.

SAMPLE TIME TAKEN (MINUTES)

I 10

II 15

III 20

The table shows the cleansing ability of the different samples and the

commercially produced product and laboratory-produced product.

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TABLE II

A) CLEANSING ABILITY OF THE LABORATORY BLEACH

SAMPLE CLEANSING ABILITY

I Effective

II More Effective

III Most Effective

B) CLEANSING ABILITY OF THE COMMERCIALLY PRODUCED BLEACH

SAMPLE CLEANSING ABILITY

I Not Effective

II Effective

III Effective

The table below shows the Irritability test of the laboratory produced

bleach solution and commercially produced bleach solution.

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TABLE III

A) IRRITABILITY TEST FOR LABORATORY PRODUCED

BLEACH SOLUTION

SAMPLE IRRTATION

I Non Irritable

II Non Irritable

III Irritable

B) IRRITABILITY TEST FOR COMMERCIALLY PRODUCED

BLEACH SOLUTION

SAMPLE IRRTATION

I Irritable

II Irritable

III Irritable

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4.2 DISCUSSION

TIME OF SATURATION

The experiment shows that the longer the time last to saturate the

water, the more concentrated the solution becomes and the more bleaching

effect.

CLEANSING ABILITY

The cleansing ability of the laboratory produced bleach solution was

effective in sample (I) than the commercially produced bleach solution also

shows that the laboratory produced bleach solution of sample II was more

effective while the commercially produced bleach solution was only

effective. The laboratory produced bleach solution of sample III became

most effective while commercially produced bleach remain effective. All

these were done on the same timing after 10, 15, 20 minutes each.

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IRRITABILITY TEST

The Irritability test on the laboratory produced bleach solution shows

that there was no irritation because these were moderate concentration of

chlorine. But the irritability test for commercially produced bleach solution

shows that there were irritations on the samples due to excessive chlorine

concentration.

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CHAPTER FIVE

5.0 CONCLUSION AND RECOMMENDATION

5.1 CONCLUSION

CLEANSING ABILITY

Due to the experiment carried out and with the help of the results, the

researchers were able to conclude that sample III, which was most

concentrated, was the most effective of all the bleach samples.

However, because of its unpleasant smell and possible reaction to the

user, the level of chlorine advocated by Federal Development Agriculture

(FEDA), and Standard Organization of Nigeria (SON) should be maintained

in the production of bleach solution.

Generally, for a 50mls of water sample saturated for about 10

minutes, yields an acceptable bleach solution capable of removing any stain

after washing for about 5 minutes. At this, concentration, the smell was

acceptable and appealing to the end user and non irritating and hence will

make a better market.

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5.2 RECOMMENDATION

It is therefore recommended that further work be done on the aspect of

bleach solution to see if acceptable smell is produced.

And also, we should encourage laboratory production of bleach, so

that the small-scale industries can grow and chlorine produced will not be

wasted.

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REFERENCES

Ababid Osei Yam (1984): New School Chemistry Published by

Africana, Fep Publishers Limited. Pages 159 –


440.
Clugston, M. J. Fraze M. J., Atkins P.hl and Jones R. A. Y. (1988):
Chemistry Principles and Applications. Page 350.
Frank, B., Frank C. P., Seymoul, S. and Stanley, M. (1978): Chemistry.
A Modern Introduction, W. B. Saunder, Company
Philandelphia; London, Toronto (2nd edition);
page 624.
Gram-Hill M. C. (1967): McGraw-Hill Encyclopedia of Science and
Technology (Volume 6th edition); pages 612 – 614.

Holidays, A. K. and C. Chambers (1982): Inorganic Chemistry

Butterworth Scientific. Page. 302.

Jeeves, J. (2000): World Wide Web (WWW. ask.com) on History of

Bleach Solution and Detergent.

Lambert, J. and Mior T. A. (1965): Practical Chemistry Heinemaun

Educational Books Limited; London (2nd edition);

pages 121 – 123.

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