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Plasma Etching Processes for CMOS Device Realization
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Series Editor
Robert Baptist
Edited by
Nicolas Posseme
First published 2017 in Great Britain and the United States by ISTE Press Ltd and Elsevier Ltd
Apart from any fair dealing for the purposes of research or private study, or criticism or review, as
permitted under the Copyright, Designs and Patents Act 1988, this publication may only be reproduced,
stored or transmitted, in any form or by any means, with the prior permission in writing of the publishers,
or in the case of reprographic reproduction in accordance with the terms and licenses issued by the
CLA. Enquiries concerning reproduction outside these terms should be sent to the publishers at the
undermentioned address:
Notices
Knowledge and best practice in this field are constantly changing. As new research and experience
broaden our understanding, changes in research methods, professional practices, or medical treatment
may become necessary.
Practitioners and researchers must always rely on their own experience and knowledge in evaluating and
using any information, methods, compounds, or experiments described herein. In using such information
or methods they should be mindful of their own safety and the safety of others, including parties for
whom they have a professional responsibility.
To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, assume any
liability for any injury and/or damage to persons or property as a matter of products liability, negligence
or otherwise, or from any use or operation of any methods, products, instructions, or ideas contained in
the material herein.
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ix
Nicolas POSSEME
Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
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Preface
Now more than ever, plasma etch technology is used to push the limits of
semiconductor device fabrication into the nanoelectronics age. This will
require improvements in plasma technology (plasma sources, chamber
design, etc.), new chemistry methods (etch gases, flows, interactions with
substrates, etc.) as well as a compatibility with new patterning techniques
such as multiple patterning, EUV lithography, direct self-assembly (DSA),
e-beam lithography or nanoimprint lithography.
The goal of this book is to present these etch challenges and associated
solutions encountered through the years for transistor realization.
Nicolas POSSEME
October 2016
1
The basic principle of the solid state transistor was stated by Julius Edgar
Lilienfeld in 1925 who patented “a method and apparatus for controlling the
flow of an electric current between two terminals of an electrically
conducting solid by establishing a third potential between said terminals”
(Figure 1.1) [LIL 25].
which were a hair apart, and covered a triangle which was held in contact by
a spring.
The man who paved the way for the improvement was Gordon Teal, who
suspected that better grown materials of better quality could lead to better
performance. Teal thought transistors should be built from a single crystal,
as opposed to cutting a sliver from a larger ingot of many crystals. His
method was to take a tiny seed crystal and dip it into the melted germanium
then pull slowly as a crystal formed like an icicle below the
seed.
For several years, the Semiconductor Industry Association (SIA) gave the
responsibility of coordination to the United States, which led to the creation
of an American style roadmap, called the National Technology Roadmap for
Semiconductors (NTRS). The SIA produced its first technological roadmap
in 1993.
In 1998, the SIA came closer to its European, Japanese, Korean and
Taiwanese counterparts by creating the first global roadmap: the
International Technology Roadmap for Semiconductors (ITRS). This
international group has (as of the 2003 edition) 936 companies which were
affiliated to working groups within the ITRS. These companies agreed upon
the guidelines for device dimensions and specifications in order to provide
guidance to the whole industry [ITR 13].
Moore’s law states that each new generation of process technology was
expected to reduce minimum feature size by approximately 0.7x. A 0.7x
reduction in the linear features size was considered to be worthwhile for a
new process generation as it translated to about a 2x increase in transistor
density.
W × μ× Cox × (VG – VT ) 2
I dsat = [1.1]
2L
where W and L are the width and length of the MOSFET channel, μ is the
channel carrier effective mobility, Cox is the gate oxide capacitance, VG is the
gate voltage and VT is the threshold voltage.
Figure 1.3. NMOS band diagram with and without tensile strain. Tensile
strain induces a degeneracy splitting in the <001> valleys. As a result,
the electron concentration increases in the low effective mass subbands,
resulting in a lowered averaged conductivity mass (from S-I. Takagi [TAK 03])
Figure 1.5 shows how gate leakage becomes the main contributor to
leakage current when the equivalent oxide thickness was scaled down in the
1.5 nm range.
CMOS Devices Through the Years 9
Figure 1.5. Gate leakage as a function of gate voltage for SiO2 gate
oxide thicknesses ranging from 3.6 nm down to 1 nm. The threshold of
1 A/cm² was reached when gate oxide was below 2 nm for Vg = 1.5 V
(from Y. Taur and E.J. Nowak [TAU 97])
Bramah had an invincible dislike for sitting for his portrait and
consequently none exists. A death-mask was made by Sir Francis
Chantrey, who executed the Watt statue in Westminster Abbey, but it
was unfortunately destroyed by Lady Chantrey. The complete
catalog of the National Portrait Gallery in London[25] gives Bramah’s
name. The reference, however, directs one to Walker’s famous
engraving of the “Eminent Men of Science Living in 1807-1808,”
which shows about fifty distinguished scientists and engineers
grouped in the Library of the Royal Institution. This engraving is the
result of four years’ careful study. It was grouped by Sir John Gilbert,
drawn by John Skill, and finished by William Walker and his wife.
Bramah’s figure, No. 6, appears in this group, but with his back
turned, the only one in that position. It is a singular tribute to
Bramah’s influence among his generation of scientists that this
picture would have been considered incomplete without him. As no
portrait of him existed he was included, but with his face turned
away. The figure was drawn in accordance with a description
furnished by Bramah’s grandson, E. H. Bramah.
[25] Cust’s.
Figure 8. Eminent Men of Science Living in 1807-8
From Walker’s Engraving in the National Portrait Gallery, London
His son, Sir Isambard K. Brunel, was also one of the foremost
engineers of England, a bridge and ship builder, railway engineer
and rival of Robert Stephenson. At the age of twenty-seven he was
chief engineer of the Great Western Railway, and built the steamer
“Great Western” to run from Bristol to New York as an extension of
that railway system. This was the first large iron ship, the first regular
transatlantic liner, and the first large steamship using the screw
propeller. Its success led to the building of the “Great Eastern” from
his designs. This ship was about 700 feet long and for nearly fifty
years was the largest one built. She was a disastrous failure
financially and after a varied career, which included the laying of the
first transatlantic cable, she was finally broken up. Brunel was a
strong advocate of the broad gauge and built the Great Western
system with a 7-foot gauge, which was ultimately changed to
standard gauge. While a number of his undertakings were failures
financially, his chief fault seems to have been that he was in advance
of his generation.
CHAPTER IV
HENRY MAUDSLAY
We have mentioned Henry Maudslay frequently. In fact, it is hard
to go far in any historical study of machine tools without doing so.[31]
[31] For best accounts of Maudslay, see Smiles’ “Industrial Biography,”
Chap. XII, and “Autobiography of James Nasmyth.”