25-05-2024

1001CJA101017240002 JA

PART-1 : PHYSICS

SECTION-I

1) On a distinct planet, 'WOTI' is defined as product of work and time. On that planet , fundamental
physical quantities are force, velocity & acceleration. If WOTI = k(force)α(velocity)β(accelelation)γ,
where k is a dimensionless constant. Find value of 2α – β + γ2

(A) 1
(B) 2
(C) 3
(D) 4

2) Which of the following is correct regarding these four vectors?

(A)
(B)
(C)
(D)

3) Assertion : A body can have acceleration even if its velocity is zero at a given instant of time.
Reason : A body is momentarily at rest when it reverses its direction of motion.

(A) If both Assertion & Reason are True & the Reason is a correct explanation of the Assertion.
(B) If both Assertion & Reason are True but Reason is not a correct explanatilon of the Assertion.
(C) If Assertion is True but the Reason is False.
(D) If both Assertion & Reason are false.

4) Let us consider a system of unit in which units of length and force are dimensionless if mass has
dimension M which of the following is incorrect ? (Hint: power = force × velocity, angular
momentum = linear momentum × distance, linear momentum = mass × velocity)

(A) Dimension of velocity is .

(B) Dimension of acceleration is M–1.
(C) Dimension of power is .
(D) Angular momentum is dimensionless.
5) In a hypothetical set of units
1 star joule = 103 joule
1 star Newton = 104 Newton
1 star second = 10 second
Then one meter is equivalent to

(A) 100 star meter

(B) 1000 star meter
(C) 10 star meter

(D)
star meter

6) A force N. causes a displacement m. The work

done is 36 J. Find the value of C :-

(A) 4
(B) 5
(C) 7
(D) –2

7) A man travelling in car with a maximum constant speed of 20 m/s watches his friend start off at a
distance 100 m ahead on a motor cycle with constant acceleration ‘a’. The maximum value of ‘a’ for

which the man in the car can reach his friend is :

(A) 2 m/s2
(B) 1 m/s2
(C) 4 m/s2
(D) None of these

8) A particle is moving along a straight line whose velocity-displacement graph is as shown in the
figure. What is the magnitude of acceleration when displacement is 3m?

(A)
(B)
(C)

(D)
9) Particle is projected with initial velocity at an angle such that it grazes the top of two poles of
same height at time 2 and 6 sec. First pole is at distance 35 m from the point of projection. Then
match the list-I and List-II :-

List-I List-II
(P) Time of flight (in sec) (1) 80
(Q) Height of the pole (in m) (2) 70
(R) Maximum height reached by particle (in m) (3) 8
(S) Distance between two poles (in m) (4) 60
(A) P → 3; Q → 2; R → 4; S → 1
(B) P → 3; Q → 4; R → 2; S → 1
(C) P → 2; Q → 4; R → 1; S → 3
(D) P → 3; Q → 4; R → 1; S → 2

10) The velocity-time plot for a particle moving on a straight line is shown in the figure.

(A) Acceleration of particle for 0-10s is positive and for 10-30s is negative.
(B) The particle has never turned around.
(C) The particle has zero displacement in given time interval.
The average speed in the interval 0 to 10 s is the same as the average speed in interval 10s to
(D)
20 s.

11) The diagram shows the position–time graph for a particle moving in a straight line. The distance

covered by the particle in the time interval t = 0 to t = 4 s is

(A) 5m
(B) 25m
(C) 20m
(D) None of these
12) The velocity–time graph of a body moving in a straight line is shown in the figure. The
displacement and distance travelled by the body in 6sec respectively are :-

(A) 8m, 16m

(B) 16m, 8m
(C) 16m, 16m
(D) 8m, 8m

13) A shot is fired at an angle θ to the horizontal such that it strikes the hill while moving

horizontally. Find initial angle of projection θ.

(A)

(B)

(C)

(D) None of these

14) A particle moves in the x-y plane according to the scheme x = –8 sin πt and y = –2 cos2πt, where
t is time. Find the equation of path of the particle.

(A)

(B)

(C)

(D)

15) Assertion & Reason These questions contains, Statement I (assertion) and Statement II
(reason).

Statement–I : The initial velocity for ground to ground projectile is m/s. If range of
projectile is maximum then a = b.
Statement–II : In ground to ground projectile motion, angle of projection is equal to 45° for
maximum range condition.
(A) Statement–I is true, Statement–II is true ; Statement–II is correct explanation for Statement–I.
Statement–I is true, Statement–II is true ; Statement–II is NOT a correct explanation for
(B)
statement–I.
(C) Statement–I is true, Statement–II is false.
(D) Statement–I is false, Statement–II is true.

16) A particle is projected with a velocity m/s making an angle 45° with the horizontal.
Neglect the effect of air friction. Then after 1 seconds of projection. Take g =10 m/s2

(A) the height of the particle above the point of projection is 15 m.

(B) the height of the particle above the point of projection is 10 m.
(C) the horizontal distance of the particle from the point of projection is 10 m.
(D) the horizontal distance of the particle from the point of projection is 15 m.

17) A body starts from rest and moves for n second with uniform acceleration a, its velocity after n
seconds is v. The displacement of the body in last 3 seconds is :

(A)

(B)

(C)

(D)

18) A particle is projected with a speed 10 m/s as shown in figure. The particle strikes normally on

the inclined plane. Then angle θ is : (g = 10 m/s2)

(A) tan–1 1
(B) tan–1 3
(C) tan–1 2

(D)
tan–1

19) A projectile is launched from the origin at t = 0. Its position is given by at t = 2s.
If the projection was launched at an angle θ from the horizontal, then θ is (take g = 10 ms–2).

(A)

(B)
(C)

(D)

20) The final position of the particle if the particle starts from x = –15 m is :

(A) 10 m
(B) 5 m
(C) –5 m
(D) –15 m

SECTION-II

1) A student of TN batch forgot Newton's formula for speed of sound but the remember that there
were speed (v), pressure (p) and density (d) in the formula. He then start using dimensional analysis
to find the actual relation by assuming v ∝ pxdy. Find the value of x–y.

2) In an experiment to measure the velocity of water splash when a car passes over a water layer on
the road. It is found that the velocity depends on weight of car (in N), power delivered by its engine
and thickness of water layer. If velocity of splash was found to be 3 m/sec when a car weighing 1000
N passes over a layer of thickness 3 mm and its engine is supplying a power of 800 kW. Find the
velocity (in m/sec) of splash when car weighing 500 N passes over a layer of thickness 4mm & its
engine is supplying a power of just 400 kW.

3) Two forces and of magnitude N each are inclined at an angle of 1.8° to each other.
What is the magnitude (in N) of vector ? (Take π2 = 10.)

4) If a vector make angle α, β and γ respectively with the x, y and z axis. Then sin2α + sin2β + sin2γ
=

5) Force acting on a particle is given by then component of force along displacement

of particle is given by if displacement of particle is then value of is

__________.

6) A balloon rises from rest on the ground with constant acceleration g/3. A stone is dropped when
the balloon has rises to a height 60 metre. The time taken by the stone to reach the ground (in
second) is :-

7) Two particle A and B are moving in same direction on same straight line. A is ahead of B by 20m.
A has constant speed 5 m/sec and B has initial speed 30 m/sec and retardation of 10 m/sec2. Then if x
(in m) is total distance travelled by B as it meets A for second time. Then value of x will be.

8) A car travelling at 72 km/h decelerates uniformly at 2 m/s2. Calculate the distance it travels
during the third second:

9) A body moving in a straight line with constant acceleration of 10 m/s2 covers a distance of 40 m in
the 4th sec. How much distance will it cover in the 6th second

10) A particle moves along a straight path ABC with a uniform acceleration of 0.5 m/s2. While it
crosses A its velocity is found to be 5 m/s. It reaches C with a velocity 40 m/s, 30 seconds after it has
crosses B in its path. Find the distnace AB( in meter).

PART-2 : CHEMISTRY

SECTION-I

1) Assertion: N2O5 is acidic oxide of nitrogen.

Reason: Highest oxidation state of nitrogen in oxides is +5.

(A) Both Assertion and Reason are true and Reason is the correct explanation of Assertion.
(B) Both Assertion and Reason are true but Reason is not the correct explanation of Assertion.
(C) Assertion is true but Reason is false.
(D) Both Assertion and Reason are false.

2) Total number of orbitals possible having n + ℓ = 6 value.

(A) 9
(B) 6
(C) 3
(D) 18

3) Which process does not absorb energy

(A)
(B)

(C)
(D) Both (A) and (B)
4) Which one of the following order is not in accordance with the property stated against it ?

(A) Al2O3 < SiO2 < P2O5 < SO3 (Acidic strength)
(B) Al3+ < Mg2+ < Na+ < F – (Ionic size)
(C) B < C < N < O (IE1)
(D) I < Br < F < Cl (EA)

5) Select correct order.

(A) F– > Cl– (correct order of ionisation energy)

(B) O > Cl (correct order of electron affinity)
(C) O > F > N (correct order of 2nd ionisation energy)
(D) H– < Cl– (correct order of ionic size)

6) Which of the following species has maximum tendency to gain an electron ?

(A) H+
(B) He+
(C) Na+
(D) Cl+

7) Select correct order against property indicated –

(A)
(B) NaCl > MgCl2 > AlCl3 (L.E.)
(C) Li2O > Na2O > K2O (L.E.)
(D)

8) In the formation of X+2(g) from X+(g) , 4 eV energy is absorbed, which would be equal to :

(A)
+2
(B) IE of X (g)
(C) IE of X(g)
(D)

9) The electronic configuration of metal ‘M’ is 1s22s1 and of the non metal ‘X’ is 1s22s22p3 . When
these two elements combines, the formula of the compound will be :

(A) MX3
(B) M3X
(C) M2X3
(D) M3X2

10) According to the Lother Meyer's curve which of the following statements is incorrect?
(A) The element having similar properties will occupy the same position in the curve.
(B) Alkaline earth metals are at the peaks of the curve.
(C) Halogens are at ascending part of the curve.
(D) The atomic volume of the elements in a period initially decreases and then increases.

11) Element with atomic number 35 is present in ____ group and ____ period respectively

(A) 17, 5
(B) 17, 4
(C) 5, 5
(D) 15, 4

12) Which of the following statements is/are wrong

(A) Van der Waal’s radius of iodine is more than its covalent radius
(B) All isoelectronic ions belong to same period of the periodic table.
(C) I.E.1 of N is higher than that of O while I.E.2 of O is higher than that of N
(D) Number of lost or gain electrons during formation of ionic bond consider as electrovalency.

13) In given cycle

Calculate H.E. of B–2(g), if HE[A+3(g)] = –50J/mole,

Lattice energy A2B3(s) = 90 J/mole,
ΔHsolution [A2B3(s)] = –100 J/mole

(A) +30 J/mole

(B) –30 J/mole
(C) –140 J/mole
(D) +140 J/mole

0
14) atoms of X(g) are converted into X+(g) by absorbing E1 energy. 2N atoms of X(g) are
converted into X–(g) by releasing E2 energy. Calculate ionisation enthalpy and electron gain enthalpy
of X(g) per atom.

(A)

(B)

(C)

(D)
15) Which of the following is the INCORRECT match?

(A) ⇒ Isodiaphers
(B) ⇒ Isobars
(C) ⇒ Isotopes
(D) ⇒ Isoelectronic

16) The charge on the atom containing 17 protons, 18 neutrons and 18 electrons is :

(A) +1
(B) –2
(C) –1
(D) Zero

17) Match the list :-

List- I List- II
(Elements) (Properties)

(P) Ca (1) Belong to 2nd group

(Q) Ba (2) Belong to 1st group

(R) K (3) Has lower size than Cs

(S) Na (4) Have higher IE than Cs

The correct option is
(A) P → 1,3 Q → 2,3,4 R → 1,3,4 S → 2,3,4
(B) P → 1,3,4 Q → 1,3,4 R → 1,3 S → 2,4
(C) P → 1,3,4 Q → 1,3,4 R → 2,3,4 S → 2,3,4
(D) P → 1,3,4 Q → 1,3 R → 2,3 S → 1,4

18) Statement-I : Same value of σ, shielding constant for (Li+ , Be2+)

Statement-II : Oxidation number of sulphur is +6 in H2SO5

(A) Both Statement I and Statement II are correct.

(B) Statement I is correct but Statement II is incorrect.
(C) Both Statement I and Statement II are incorrect.
(D) Statement I is incorrect but Statement II is correct.

19) Which of the following configuration shows second excitation state of Iodine :

(A)

(B)

(C)
(D)

20) A sigma bond is formed by the overlapping of:-

(A) s-s orbital alone

(B) s and p orbitals alone
(C) s-s, s-p or p-p orbitals along internuclear axis
(D) p-p orbital along the sides

SECTION-II

1) Calculate the magnetic moment of Fe3+ :

2) Find maximum number of electrons in ‘Al’ in which . [At. no. of Al = 13]

3) Bond length of A – A bond is 124 Å and bond length of B – B bond is 174 Å. The bond length (in
pm) of A – B bond in AB molecule if percent of ionic character of A – B bond is 19.5% is ___________.

4) Consider the ground state electronic configuration of an element with atomic number 29 and find
the multiplication of X and Y.
Here X = Number of electrons present in non directional orbital
Y = Number of filled orbitals with |mℓ| = 1

5) Ratio of number of nodal plane in 6dxy orbital to 3dxz is :

6) Find total number of orbitals in which electron density is observed along any of the axis (x, y or z).
s, px, py, pz, dxy, dxz, dyz, ,

7) A first row transition metal in its +2 oxidation state has a spin-only magnetic moment value of
3.86 BM. The minimum atomic number of the metal is :

8) Given 4 different Lattice energies values of Halides of Lithium (in kJ/mol) (not necessarily in
order)
1035.12, 760.05, 810.00, 859.61
The value of Lattice energy for LiF will be.

9) Consider the following compounds :

HNO3, ZnO, Al(OH)3, SO2(OH)2, Pb(OH)2, Mg(OH)2, BeO, B(OH)3, SnO2, BaO
If,
X = number of amphoteric compounds
Y = number of only acidic compounds
Z = number of only basic compounds
then find the value of .

10) x = Number of anions which have greater size than F– among Se2–, N3–, O2–, I–, Cs+, Al3+
y = Maximum number of elements which can be present in 7th period if 3e– can be accomodated in
each orbital.

Find the value of

PART-3 : MATHEMATICS

SECTION-I

1) The number of positive integer solution of ≤ 0 is

(A) Four
(B) Three
(C) Two
(D) Only one

2) Which of the following is true for the given graph. If y = ax2 + bx + c :–

(A) a > 0
(B) b < 0
(C) c > 0
(D) b2 = 4ac

3) Assertion (A) : If roots of the equation x2 – bx + c = 0 are two consecutive integers, then b2 – 4c
= 1.
Reason (R) : If a, b, c are odd integer then the roots of the equation 4b x2 + (b2 – 4ac)x – b = 0 are
real and distinct.

(A) A is True, R is True; R is a correct explanation for A.

(B) A is True, R is True; R is not a correct explanation for A.
(C) A is True, R is False
(D) A is False, R is True.

4) Number of real roots of the equation

x2 –3|x |+ 2 = 0 is

(A) 1
(B) 2
(C) 3
(D) 4

5) If the quadratic equation x2 – 3ax + a2 – 9 = 0 has roots of opposite sign, then complete set of
values of 'a' is -

(A) (–3, 3)
(B) (0, 4)
(C) R
(D) (0, 3)

6) If α, β are the roots of ax2 + bx + c = 0, then the roots of equation ax2 – bx(x – 1) + c(x – 1)2 = 0
are :-

(A)

(B)

(C)

(D) α, β

7) If roots of the equation ax2 + bx + c = 0 are imaginary then roots of the equation
(4c + 2b + a) x2 – 2 (a + b) x + a = 0 are :-

(A) Real and equal

(B) Imaginary
(C) Real and unequal
(D) None

8) If 8, 2 are the roots of x2 + ax + β = 0, and 3, 3 are the roots of x2 + αx + b = 0 then the roots of
x2 + ax + b = 0 are :-

(A) 8, –1
(B) –9, 2
(C) –8, –2
(D) 9, 1

9) The values of k ∈ R for which

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II
 sum of roots of x2 + (2 – k – k2)x – k2 = 0
(A) (I) –4
is zero

The roots of x2 + (2k – 1)x + k2 + 2 = 0

(B) (II) 1
are in ratio 1 : 2

Sum of the square of the roots of

(C) (III)
x2 – (k – 2)x – k – 1 = 0 assume the least value

kx2 – (k + 1)x + 2k – 1 = 0
(D) (IV) –2
has equal roots
(A) A–II, B–IV, C–I, D–II
(B) A–I, B–III, C–II, D–IV
(C) A–IV, B–I, C–II, D–III
(D) A–II, B–IV, C–I, D–III

10) If the equation 4x2 – x + 1 = 0 and 3x2 + (λ + µ)x + λ – µ = 0 have a common root then the value
of λµ is (where λ, µ are rational)

(A) 0

(B)

(C)

(D)

11) Set of all values of 'x' satisfying inequality, ≥ 0 is :-

(A) (–∞, –2) ∪ [1, 3] ∪ (5, ∞)

(B) (–∞, –2) ∪ [0, 1] ∪ (2, 3] ∪ [5, ∞)
(C) (–∞, –2) ∪ [1, 3] ∪ (5, ∞) ∪ {0}
(D) (–∞, –2) ∪ [1, 2) ∪ (2, 3] ∪ (5, ∞) ∪ {0}

12) The value of p for which one root of the equation x2 – 30x + p = 0 is the square of the other, are
:-

(A) 125 only

(B) 125 and –216
(C) 125 and 215
(D) 216 only

13) The number of integers 'x' satisfying the equation (x2 – x – 1)x+2 = 1 is-

(A) 2
(B) 3
(C) 4
(D) 5

14) The sum of the values of m for which the quadratic polynomial P(x) = x2 + (m + 5)x + (5m + 1) is
a perfect square (m ∈ R) is

(A) 3
(B) 7
(C) 8
(D) 10

15) Statement I : The equation x2 + 3x + 1 = 0 has an irrational root. Statement II : If is

one root of equation x2 + ax + b = 0, where a, b ∈ R then b = 1.

(A) Both statements are correct

(B) Both statements are incorrect
(C) Statement I is incorrect and statement II is correct
(D) Statement I is correct and statement II is incorrect

16) If x is real, then maximum value of y = is :-

(A) 1
(B) 5
(C) 3
(D) 2

17) The expression is equal to

(A)
(B)
(C)
(D)

18) Which of the following statement is true :

(A)
(B)
(C)
(D)

19) If x2 + 4y2 + z2 - 2xy – 2yz – zx = 0 then x : y : z equals

(A) 1:2 :1
(B) 2 :1 :2
(C) 1:2 :3
(D) 1:1: 2

20) Find the value of

(A)
(B)
(C)
(D)

SECTION-II

1) If α, β are the roots of the equation x2 – 3x – 15 = 0, and f(n) = αn + βn then is

equal to

2) Minimum value of , x ∈ R – {0} is equal to

3) If and then the value of (x – y)2 equals to

4) Value of + is :

5) If , then value of is

6) Value of x satisfying the equation + |x2 + 4x – 12| = 0 is

7) The number of possible ordered pairs (x,y) (where x and y are integers) which satisfy xy – 2x – y –
4 = 0 is

8) Remainder when x100 – 3x99 + 2x98 + 3x – 2 is divided by x – 2 is equal to

9) Two finite sets have m and n elements. The number of subsets of first set is 112 more than that of
the second set. Then value of m + n is equal to

10) If A = { x : x satisfy x2 – 3x + 2 ≤ 0 and x ∈ I } then number of proper subsets of set A is

(Note : I is set of integers)
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C B A D C A A A D D C A C A A C A B C C

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 1 3 1 2 7 6 50 15 60 600

PART-2 : CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. A A B C C B C D B B B B B A A C C A C C

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 6 9 149 42 1 6 23 1035 4 12

PART-3 : MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B C B D A B B D C A D B C D D B B B B B

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 8 4 2 6 110 2 8 4 11 3
 SOLUTIONS

PART-1 : PHYSICS

1)

[ML2T–1] = [MLT–2]α[LT–1]β[LT–2]γ
α=1
α+β+γ=2
2α + β + 2γ = 1
α = 1, β = 3, γ = –2

2)

(according to polygon law)

4)
0 0
[F] = [M1L1T–2], [F ] = [M1L T–2]
⇒ M1T–2 = 1 ⇒ T =
(A) [V] = [L1T–1],

(B) [a] = [LT–2],

(C) [P] = [M1L2T–3],

(D) [L] = [M1L2T–1],

5)

L EaFbTc
L = (ML2T–2)a (M1L1T–2)bTc
L = Ma+b L2a+b T–2a–2b+c
a+b=0
2a + b = 1
–2a – 2b + c = 0
2a – a = 1
a=1
b = –1
L = EaFbTc = E1F–1 or length = energy/force
(1 star meter) = (1 star joule)1 (1 star N)–1
= (103) (104)–1 [(Joule)1 (N)–1]
1 star meter = 10–1 m
1 m = 10 star meter
 6)

W=
36 = 3C + 8 + C2
solving we get, C = 4

7)

400 > 2a(100)

a<2

9)
Time of flight
= TOA + TAB + TBC
= 2 + 4 + 2 = 8 sec
height is equal at t = 2 & t = 6 sec

y = vy × 2 – g × 2 2 = v y × 6 – g × 62
180 – 20 = 4vy
160 = 4 vy

vy = 40; vx =

R = 140
distance between poles
ΔE = 140 – 70 = 70 m
Height of pole

= 80 – 20 = 60 m

10)
 11)

12)

15)

In projectile motion, angle of projection is equal to 45° for maximum range condition and when
angle of projection is 45° then horizontal and vertical components of initial velocity will be same.

18)

t = 1 sec.

v sin θ = 6
–v cos θ = 8 – 10 (1)
tan θ = 3

19)

u sin θ... 2 –
t = 2 sec u sinθ = 35 .........(ii)
ucosθ × 2 = 40
ucosθ = 20 .....(i)
equation i and ii

⇒θ=

20) xf = – 15 + Area

= – 15 + 2 +
= –15 + 10 = – 5m

21)

by comparing power of M, L and T

x + y = 0, – x – 3y = 1, –2x = – 1

⇒x= ,

y=–

22)

From dimensional analysis,

v = kFaPbtc
⇒ LT–1 = (MLT–2)a(ML2T–3)bLc
∴ a+b=0
a + 2b + c = 1
–2a – 3b = –1
∴ a = –1, b = 1 & c = 0

∴ ⇒ v2 =

23)

25)
Component of force along

26)

Velocity of balloon after rising 60m

v2 = 2g/3 × 60
v = 20 m/s
when stone released, it acquires velocity of balloon
y = – 60

– 60 = (20 t) – gt2

5t2 – 20t – 60 = 0
t2 – 4t – 12 = 0
t = 6 sec.

28)

u = 72 km/h = 20 m/s
a = –2 m/s2

S3 = 20 + (–2) (2 × 3 –1) = 15

29)
PART-2 : CHEMISTRY

31)

+5 highest oxidation state results in more acidic nature.

32) n + = 6
6 0 = 6 = 6s = 1 orbital
5 1 = 6 = 5p = 3 orbital
4 2 = 6 = 4d = 5 orbital

33) (A) ΔH = +ve

(B) ΔH = –ve
(C) ΔH = +ve

34)

Acidity of the oxides of non-metals increases with the electronegativity and oxidation number of the
element.
(Al2O3 < SiO2 < P2O3 < SO3)
B < C < O < N (IE1)

35) Correct of I.E. (F– > Cl–)

Correct order of E.A. (O < Cl)
Correct order of ionic size (H– > Cl–)

37)
Li2O Na2O k2O
⇒ charge on cation ⇒ +1
charge on Anion ⇒ –2
size of cation ⇒ Li+ < Na+ < k+
size of cation LE ↓
∴ Li2O > Na2O > K2O

38)
|ΔHeg| of X+2 = I.E. of X+ = 4ev

39) Valency of M = 1.
Valency of X = 8 – 5 = 3
 Therefore, Using Criss-Cross method M3X.

40) Alkaline earth metals are at the descending part of the curve.

41)

Z = 35 = The element is Bromine

It is present 17th group and 4th period

42)

In the isoelectronic species, all isoelectronic anions belong to the same period and cations to the
next period.

43)

–100 = 90 – 2(50) + 3x
–100 = 90 – 100 + 3x
x = –30 J/mole

44)

IE of atoms = E1

1 atms =
x(g) + eΘ → xΘ(g) :- E2
Electron gain enthalpy of 2NO atoms = –E2

For an atom =

45)
(A-2Z) 2, O, O
So not isodiaphers

46)

Cl– have 17 proton, 18 neutron and 18 electron.

47)

(P) Ca
Belongs to 2nd group
Has lower size than Cs (across the period size decreases)
Have higher IE than Cs (as zeff increases across the period)
(P) → 1, 3, 4
(Q) Ba
Belong to 2nd group
Has lower size than Cs (across the period size decreases) have higher IE than Cs(as zeff increases
accross the period)
(Q) → 1, 3, 4
(R) K
Belong to 1st group.
Has lower size than cs (Top to bottom size increases )
Have higher IE than cs (top to bottom IE decreases.
(R) → 2, 3, 4
(S) Na
Belong to 1st group
Has lower size than Cs (Top to bottom size increases)
Have higher IE than cs (Top to bottom IE decreases
(S) → 2, 3, 4

49)

50)

51) Refer to notes

55) Nodal plane = given by l

6dxy l = 2 (2 Nodal planes)
3dxz l = 2 (2 Nodal planes)
Ratio = 1

56)

57)

Minimum atomic number is 23 (V+2)

= 3.86
Number of unpaired electron = 3
So, V2+ =[Ar] 3d3
So, Minimum atomic number is 23

58)

Lattice energy ∝ q1 q2

59)

Amphoteric (X) : ZnO, Al(OH)3, Pb(OH)2, SnO2, BeO

Acidic (Y) : HNO3, SO2(OH)2, B(OH)3
Basic : Mg(OH)2, BaO

So

60) X = 4
Se2–, N–3, O–2, I– ⇒ these anions have greater size than F–
7th period, 3e– in each orbital
7s 5f 6d 7p
↓ ↓ ↓ ↓
3e 7×3 e 5×3 e 3 × 3 e–
– – –

No of elements in 7th Period = 3 + 21 + 15 + 9

= 48
Y = 48

= 12

PART-3 : MATHEMATICS

61)

Zeroes x = 0 , 4/3, 2
Poles x = 5, 7/2

x∈
+ ve integer satisfying are x = {2,3,4}
No. of + ve integer = 3

62)

for given graph y = ax2 + bx + c = f(x)

(i) a < 0

(ii) – >0 ⇒ ⇒ b>0

(iii) f(0) > 0 ⇒
(iv) D > 0 ⇒ b2 > 4ac

63)

Assertion:

x2 – bx + c =
Difference of roots = 1

⇒ b2 – 4C = 1
Reason:
D = (b2 – 4ac)2 + 4b2
D>0

64)

Let |x| = t
t2 – 3t + 2 = 0
⇒ t = 1 or t = 2
|x| = 1 or |x| = 2
⇒ x = ±1, x = ± 2 No of sol. = 4

65)

ƒ(0) < 0
a2 – 9 < 0
a ∈ (–3,3)

66)

=α
x = α – αx
x = (1 + α) = α

x=

67)

b2 – 4ac < 0.
Now (4c + 2b + a) x2 – 2(a + b) x + a = 0
∴ D = 4(a + b)2 – 4a (4c + 2b + a)
= 4b2 – 16ac
= 4 (b2 – 4ac) < 0
So roots are imaginary.

68)

8 + 2 = –a ⇒ a = –10
3⋅3 = b ⇒ b = 9
Now x2 + ax + b = x2 – 10x + 9 = 0
i.e. x = 9, 1

69)

(A) 2 – k – k2 = 0 ⇒ k = 1, – 2
(B) α + 2α = –(2k – 1)
α(2α) = k2+ 2

(C) α2 + β2 = (k – 2)2 + 2(k +1)

= k2 – 2k + 6 = (k – 1)2 + 5
so for k= 1 it assume least value
(D) (k + 1)2 – 4k(2k – 1) = 0
7k2 – 6k – 1 = 0 ⇒ (7k + 1) (k – 1) = 0

70)

∴ and

71)

x ∈ (–∞, –2) ∪ [1, 2) ∪ (2, 3] ∪ (5, ∞) ∪ {0}

72)

Let α and α2 are roots

α + α2 = 30 ; α⋅α2 = p
α2 + α – 30 = 0
(α + 6) (α – 5) = 0
α = –6, α = 5
Now p = (–6)3 or (5)3
p = –216 or 125

73)

Case-1 : x + 2 = 0 ∴ x = –2
Case-2 : x2 – x – 1 = 1
x2 – x – 2 = 0
(x – 2)(x + 1) = 0
x = 2, x = –1
Case-2 : x2 – x – 1 = –1 and x + 2 must be even
x2 – x = 0
x = 0, x = 1
For x = 0, x + 2 is even, for x = 1, x + 2 is odd.
∴x=0
∴ x = –2, 0, –1, 2

74)

D=0
(m + 5)2 – 4(1)(5m + 1) = 0
 m2 + 25 + 10m – 20m – 4 = 0
m2 – 10m + 21 = 0
m1 + m2 = 10

75)

Roots of x2 + 3x + 1 = 0 are

, both are irrational

∵ a, b ∉ Q
So b can take any value.

76)
Case-I :
y≠1

(y – 1)2 – 4(y – 1)(y – 4) ≥ 0

(y – 1) (y – 5) ≤ 0
1<y≤5
⇒ y ∈ (1, 5]
maximum value of y = 5

77)

78) Do yourself

79) 2 × (x2 + 4y2 + z2 – 2xy – 2yz – zx) = 0

⇒ x2 + 4y2 – 4xy + 4y2 + z2 – 4yz + x2 + z2 – 2zx = 0
⇒ (x – 2y)2 + (2y – z)2 + (z – x)2 = 0
⇒ x = 2y = z ⇒ x : y : z = 2y : y : 2y = 2 : 1 : 2.

80)

⇒
 ⇒ x2 + 2x – 1 = 0

81)

α2 – 3α – 15 = 0 ⇒ α2 – 3α = 15 .... (1)
β2 – 3β – 15 = 0 ⇒ β2 – 3β = 15 .... (2)
f(8) = α8 + β8
3f(7) = 3α7 + 3β7
f(6) = α6 + β6

= =8

82)

Using AM ≥ GM

83)

∴ (x – y)2 = x2 + y2 – 2xy

84)
=6

85)

∴ = (5)3 – 3 × 5 = 110

86)
 87)

xy – 2x – y – 4 = 0

∴ x – 1 = –1,1,–2,2,–3,3,–6,6
Thus number of possible ordered pairs is 8.

88)

Let ƒ(x) = x100 – 3x99 + 2x98 + 3x – 2

remainder = ƒ(2) = 2100 – 3.299 + 2.298 + 3.2 – 2
= 2.299 – 3.299 + 299 + 6 – 2
=4

89)

2m – 2n = 112
m = 7 and n = 4

90)

x2 – 3x + 2 < 0
(x – 1) (x – 2) < 0 ∴ x ∈ [1,2]
or possible integers are 1,2
∴ A = {1,2}
Number of porper subsets = 22 –1 = 3