Law and.
We are building machines
to undermine nature’s most
rigid rule, says physicist
Vlatko Vedral
FEW yearsago,thadan ideathat may
soundalitiecrazyIthought [ould sea
way tobuildan engine that works harder
thanthe awsof physiesaow.
You would bewithin yourrightstobaulk
atthis proposition. Afterall the efficiency
ofenginesis governed by thermodynamics the
‘most solid pillarof physic. This sone
st ofnaturallaws you dont mess with
Yeti leavemy ffice tthe University af
Oxford and strolldown the corridor. Ieannow
seeanengine that pays no heed tothese laws
Itisamachineof considerable powerand
intricacy, with green lasers and ions instead
foil and pistons. There sa longroad ahead,
bout believe contraptions ike this one will
shapethe future of technology. \ i
Better more efficient computers would
bejust the stat. The engineis also harbinger
ofanew erainscience. To build it, wehave
hhadto uncover afield called quantum
thermodynamics, onesettoretuneouridese
about why life, the universe-everything, in
factaretheway they are.
Thermodynamics isthetheory that describes
| ehe interplay between temperate, heat,
‘energy and work Assuch, it toucheson pretty 4
{much everything. ftom your braintoyour
muscles carenginesto kitchen blenders, stars
32 NewScientist 7 April2018
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.dsorder
to quasars. It provides abase from which we
can workout what sortsof things doand don’t
happen inthe universe. Ifyou eat a burger,
you must bur off the caloriesor get fatter.
Coffeeneverspontaneously warms up when
setonatable. Asthe universe expands, itcools,
heading unvwaveringly towards heat death in
the distant future. Allthese unavoidabletruths
spring from thermodynamics. In fact, they
come from itstwo main laws, uncreatively
named thefirst and the second laws.
‘These laws go back long way, and one
of my favourite episodes relating tothetr
creation involves Julius von Mayer, aGerman
doctor whose real passion was physics. The
story goes that in the 8405, Mayer got ajobas
a ship's surgeon ona voyage toakarta. During,
this, he noticed something curious: nearthe
‘tropics, the blood inthe sailors' veins wasn't
blue asi would be back home in Germany,
but deep red.
He hypothesised (wrongly, as it turns
‘out) that the redder blood was dueto less
food being used to keep the body warm in
the hotterclimate. But in thinking about
the giveand take between metabolism,
‘temperature and heat generation inthe
body, Mayerhad alighted on theessence
‘of the first law: energy can't be created or
destroyed, merely passed around.
‘What cameto be called the second law
had its genesis about 20 years before Mayer
boarded his ship. Atthis time, steam engines
were transforming Europe, their furnacesand
pistons driving the factories and mills ofthe
industrial evolution. Sadi Carnot, a French
engineer, wasdissatieied that no ane had a
rigorous understandingof how these engines
worked, and set out todevelopone.
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COVER STORY
His cructal insight was that, left to their
‘own devices, hot things always spread warmth
totheir surroundings When wateris heated
insteamengines, forexample, some ofthe
heat always leaks away to theairoutside,so
they are never perfectly efficient. In 1824, he
published his only book generalising the idea
toshow that noengine can exceed accertain,
limit,now known asthe Carnot efficiency.
‘Thisdependson the temperature difference
between theheat source (say, afire) and the
heatsink say, the outside air),
Inescapable entropy
Carnot died afew years later and hisbook was
ignored fordecades until German physicist
Rudolf Clausius ook notice. Carnot had
concelvedofhea sa weightloss substance
called calorie but Clustusknew twas actually
related to how fast atoms or molecules move
That enabled him to reformulate Carnot’
ideas in terms of a measure of disorderhe
called entropy. Imagine youhave hot box of
particlesthat are movingquickiy and acold
boxofslow-movingones. That isanorderiy
arrangement because alte pariceswith
similar energies are together, But the
universe doesn't ikelow entropy states, said
Clausius. if youopen the boxes, the particles
‘mix. Thisled him to thesecond lawas we
know it: entropy naturally increases unless
you put in some work to stop it.
Follow the logicof the two laws and you
end up with acast-iron description of what's
possiblein the universe. The astrophysicist
Arthur Eddington once said: "If your theory
Is found tobe against the second law of.
thermodynamics ican giveyounchope; >
7 April2018| New Scientist 133
+998 97 130 68 22thereis nothing fort but tocollapsein
deepest humiliation.”
‘What, then, of my ideaforan enginethat
bends the rules? It would seem like piein
the sky. Actually, we haveaname foran
engine that brushes aside thermodynamics.
We callita perpetual motion machine, a
byword forscientificcharlatanry. But the
‘machine down the corridors not oneof
those. It exploitsa sneaky but legitimate
loophole: quantum physics.
‘Thermodynamics predates quantum
theory; in fact, twas responsible for its birth.
1900, the German physicist Max Planck
ing to understand the properties ofa
hypothetical object called a black body that
absorbsall radiation fallingon itand then
emits it again. The best physicsof thetime
suggested there were an infinite number
cof wavelengths, sothe body would emit
aninfiniteamount of energy. That was
nonsensical Planck solved the problem by
supposingthat energy can only come in
chunks. He called them quanta,
‘That leap helped explain many nigeling,
questions in physics. But when we began.
studying objects that perform according to
the quantum playbook, we found they do
extraordinary things. One of the best-known
‘examples entanglement, whentwo particles
become intertwined so that interfering with
cone instantly changes theproperties ofthe
other. Another exampleis that an atom can
simultaneously exist in slow and high-energy
state, known as asuperposition.
‘These behaviours break allthe usual rules
of dynamics. Is there any reason to think
‘thermodynamics isexempt? Onlyin the past
five years oso have we had thetools to probe
‘this question. Take the work of Tobias Schaetz
atthe Freiburg Institute for Advanced Studies,
Germany. In2016, he described anexperiment
ooking ations inside crystal. He gave them
some energy and watched how they cooled
Unlike cupof coffee, which cools gradually,
the ions seemed to lose energy fora while, but
then the energy suddenly bounced back.It is
proof of what we had suspected: therales of
classicalthermodynamics don't always apply
inthe quantum word.
Unfortunately, itis tricky to pindown
what laws do apply. This is because there are
no obvious quantum equivalentsof classical
thermodynamic concepts like heat or entropy.
They arethe ultimate product of the motions
of many particles; sohhow do youbegin to
thinkof analogues when you aredealing with
Jjustone ortwo particles?
‘Well, never mind. thought Twoukl make «
34 | NewScientist 7 Apil2018
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quantum version ofa heat engineanyway.
Ilisrathera different enginefrom anything,
Carnot would have been familiar with, but
the principles are the same.The Idea wasto
set up pairs of organicmolecules and raise
‘themtoa high energy level by shining light
onthem.Leftalone,the molecules will return
‘toaslightly lowerenergy level, re-emitting.
light ofa different frequency as they doso,
“Here’stheimportant part. fwe set up
theexperiment just right, theemitted
light won't carry any information that
“Quantum thermodynamics
may mean time can tick
In two directions”
could tell us which ofthe two molecules
tcame from. According to quantum theory,
‘this forcesthem to become entangled, so
‘that when one dropsto the lower energy.
level,the other one automatically does
‘00, with both emitting light in unison in
«process called superradiance. fexpected
that this quantum engine would still be
subject toenergy leakages inthe manner
Carnot identified nearly 200 years ago.
But because of the superradianee,itshould
transfer energy faster, makingit more
au
BEEE
ane
Lt
Eaaee
efficient than a non-quantum engine.
‘Working with my two experimentalist
colleagues, Tristan Farrow and Robert Taylor,
completed acontrol experiment ast yearin,
which the molecules weren't entangled. But
just as we were putting the finishing touches
tothe interesting version, we were scooped.
In October 2017, my Oxford colleague
Ian Walmsley and his team described an
experiment similarto the one we had
envisaged. In this engine, it was not organic
‘molecules doing the absorbingand emitting,
but atoms trapped inside special cavities ina
diamond. The atoms weren't entangled, but
\wereina superposition of ahigh and low-
energy state. And sureenough, Walmsley and
this team saw that light was produced quicker
than theclassical rules of thermodynamics
predict
Itisn'tyet entirely clear why this isso. And
admittedly, the degree of violation istiny and
wouldn't be useful in practice, Nonetheless,
itis crucial first proof that quantum heat
engines can bend those eastiron rules.
Texpectthis machinecan be improved
‘upon and Iam excited about the future
of quantum heat engines. Thethingthat
first drew me into this game's my workon
{quantum computers. There i plenty of talk
about these futuristic machines, which
operate using quantum bits, orqubits, and
a
See
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+998 97 130 68 22should be able ocrackall sorts of intractable
calculations. But getting them to work
involves cooling the hardware toextremely
low temperatures, which demands vast
amounts of energy.
Descendants of Walmsley’s machine
could help. After all,aheat engine converts
heat into directed work, forexample to
moveasteam engine's piston. Ifyoureverse
that, youcan use directed work to pump
heat away. The result isa quantum fridge.
Gleb Maslennikovat the National University
of Singapore and his colleagues are already
experimenting with quantum fridges,
‘with promising indications that they too
tbe more efficient than their classical
counterparts
Ws not just quantum computers that
could benefit. Onemajorobstacle to further
‘miniaturising normal circuits isthat they
‘would overheat ifwe tried to cram components
any closer. Better refrigeration is exactly what
weneed,
Ifyouthink quantum fridges sound handy,
allow me tointroduce the quantum battery.
‘Aformer student of mine, Felix Binder, now
at Nanyang Technological University in
‘Singapore, has shown that quantum batteries
‘can charge more quickly than normalones.
Instead of movingionsaround, 3s
traditional batteries do, these devices would
ae
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have electronicbits akin toa computer bit
that can be cithercharged ornot. Under
classical thermodynamics, theamount of
energy used to charge the battery increases
linearly with the numberof bits. But Binder
has shown that if weentangletthe bits, the
amount of energy needed for afull charge
scales with the square root oftheir number.
‘This means that quantum battery with
million bits would be fully charged in the
time it would take to charge a1000-bit
classical battery. Vittorio Pellegrini at
the talian Institute of Technology in
Genoaisoneresearcher hopingto build
such a super-battery within afew years
The untidiest room
Butwe shouldn't think that quantum
thermodynamics is only about creating.
gizmos. Italso touches the most profound
distinction thereis:lifeand death. Living things
constantly strive against the second lawr
ofthermodynamics, sucking in energy to
‘maintain theorderwithin theircells. Powering
allthisareour bodies’ equivalent of heat
engines: mitochondria, So here's anintriguing
‘question: given that natural selection tends
toencourage efficiency, has biology evolved
‘quantum heat engines? There isa hot debate
about whether any quantum effects are
important in biology, but in my opinion it’s
not crazy tothink that evolution would
producethe most efficient engines possible.
Even the low oftime might be recast by
quantum thermodynamics. No physical law
provides aresson why any natural processes
can’t go backwards ~except the second law of
thermodynamics. Its insistence that entropy
IELTS’ ZONE
Rule breaker:
‘Adiamond-based
‘uantumheatengine
atthe University
of Oxford,
‘must increase leads many physicists to
suspect that time somehow arises from
entropy changes
Inclassicalterms,entropy makes
Intuitive sense. For example, classical
thermodynamics saysthe universe must
beatleast as disorderedas its partsare. This
islike sayingthat the overall messinessof
‘house, perhaps quantified asthe amount
of energy neededto tidy it up, can't beless
than the messiness of the untidiest roam,
‘Thepicture would be radically different
ifthe universe obeysthe laws of quantum
thermodynamics. True, wedon'tknow exactly
what these are yet. But wedo know from the
‘equations of quantum theory that the overall
amount of disorder intheuniverse must
remain constant. What's more, quantum,
"uncertainty forbids us from gaining fll
Information about the states of individual
partsofthe universe, meaning that some
partscan be more disordered than the whole,
‘This could mean that if you look atthe
universeas whole, entropy doesn’t change
and sotheres notime. But lookat small
patches where entropy is changingand time
startsticking Because things don’thavetoadd
up everywhere, allthetime, its even possible
that the arrowsof time flow indifferent
directionsin different parts of the universe.
Itisonly by carefully probingthequantum
foundationsof thermodynamicsthat we will
discern whether any of thisisan accurate
picture of reality. That's why quantum heat
engines are so interesting, [can't wait to put
minethrough its paces.
‘Viatko Veoral spiysistat he Unversity ot
(Orford, UK. and the Nationa Uriversity of Singapore
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