® subscribe jee2neet for more books =e Balad Problems in Inorganic. — Chemistry JEE Main & Advance: dpoo Periodic Propertios 150, | Chemical Bonding (Basie) RTOS Chemical Bonding (Advanced) [104-178 Co-ordination Compounds (792248 Metallurgy x (247-277, s-Block Elements [278304 p-Bloek Elements (505379, d-Block Elements 80-407 Types of Reactions «OBST | Qualitative Inorganic Analysis Environmental Chemistry 34L Ostet @jee2neet Sodium bicarbonate has : {@) Ionic bond (b) Covalent bond (<) Hydrogen bond (4) All of these ‘Which of the following metal on burning in moist air does not give smell of ammonia ? (@) Mg (&) Ca ox @ bi For the alkali metals, which of the following increases with increasing atomic number? (a) First ionization energy (b) Electronegativity (c) Hydration energy of the univalent ion (4) Atomic radius ‘Among the carbonates of alkali metals which one has highest thermal stability? (a) Cs,CO, (©) Rb,CO, (© K,CO, (a) Na,CO; Which of the following is most soluble in water? (a) CsClO (b) Nacio, (© Kao, (a) uiao, ‘A solution of sodium in liquid ammonia is blue in colour due to : (a) the presence of ions Na* (©) the presence of ammontated elecrron (©) the formation of NaNH (@) the formation of sodium hydride ‘The basicity of the hydroxides of the following alkali metals is of the order (a) Li > Na > Rb > Cs (b) Na> Li > Rb > cs (©) Cs > Rb>Na>li (4) Rb > Cs > Na > Li ‘The mecallic lustre exhibited by sodium is explained by (a) diffusion of Na* ions (b) oscillation of loose electrons (c) excitation of free protons (4) existence of body.centered cubic lattice Soda lime is made from (a) Na+ Ca0+H,0 (b) CaO + NaoH(aq) (©) NaOH +Cacoy (@) NaHCO; + C2030. The compound called microcosmie salt is : (a) Na,HPO, 24,0 (0) Na(NH,)HPO, 44,0 (©) Na,NH,PO, 2H,0 (@ (NE,) HPO, 2H,0 11. Potassium when heated strongly in ‘oxygen, it forms. (@) K,0 ) KO, (9) K,0, @ WOy When @ concentrated solution of ammonia is saturated with sodium chloride in the presence of pieces of dry ice, a water cloud forms, ‘This is due to the : (a) precipitation of sodium carbonate from the reaction mixture () precipitation of sodium hydrogen carbonate from the reaction mixture (©) precipitation of ammonium hydrogen carbonate from the mixture (@ precipitation of ammonium carbonate 12. 38. The compound formed on heating sodium metal in a current of dry ammonia gas, is : (a) sodium imide (b) sodium nitrite (¢) sodium amide (4) sodium azide 14, Which of the following compounds is not obtained when the products obtained from the electrolysis of brine are mixed? (@ Nacl () Hy (©) Naoct @ a, 18. When dry emmonia gas is passed over heated sociium (in absence of air) the product formed (@) sodium hydride () sodium nitride (© sodamide (@) sodium cyanamide 16, Which of the following compounds liberate(s) oxygen on heating? @) 11,00, (®) Lion © NO, (@ NaH 17, Sodium peroxide is used to purify the ir in submarines and confined spaces because (@) it removes CO, and produces 0» (©) it decomposes to form Na,0 (©) it reacts with oxygea to form sodium superoxide (@) none of these 18. Which of the following salt is known as washing soda? (@) Na,CO, () Na,CO,H,0 (© Na,CO,10H,0 (@) Na,CO,5H,0 19. Which of the following compounds is formed when sodium bums in excess supply of air? (@) Sodium suboxide () Sodium oxide (©) Sodium peroxide (@) Sodiam superoxide 20. Glauber's salt is: (a) Na,S0, (0) Na,S0,H,0 (© Na,80,5H,0 (@) Na,0,.104,0 21, Sodium hydroxide is produced on a large scale (a) by the hydrolysis of NaxCO 0) by the electrolysis of an aqueous solution of NaCl (6) by adding water to sodium oxide (@) by reacting sodium with wateraa 22. Which of the following metal is used in flash bulbs? (@) Be (>) Mg Oca (@) Ba . 23. ‘The pairs of compounds which cannot exist together in aqueous solution are : () NaH,PO, and Na,HCO, (I) Na,CO, and NaHCO (Il) NaOH and NaH,PO, (IV) NaHCO, and NaOH @) 11,1 () mV OLN (@ um 124. Which one on reaction with NaOH solution gives inflammable gas? @s (b) Zn © NHC @L 25, In the reaction LiH{+ AIH —» LiAIH,, AIH, and LiH acts as : . @ Lewis acid and Lewis base (b) Lewis base and Lewis acid © Bronsted base and Bronsted acid (@) None of these 26. Which of the following is the most important factor in making lithium metal, the strongest reducing agent? {@) Tonisation energy (b) Hydration energy (c) Heat of sublimation (4) None of these 27. Which set of compounds in the following pair of ionie compounds has the higher lattice energy ? () KCl and Mgo (LiF end LiBe (ii), MggNaandNacl (@) KCl, LiBr, Mg zNo (b) MgO, LiBr, Mg 3N2 (© MgO, LiF, NeCl (a) MgO, Liz Mg ,N, 28, Sodium bicarbonate has: (a) ionic bond () covalent bond (©) hydrogen bond (2) all of these 29. Compound having lowest melting point: (@) Lic (©) csc © RbCl @ Kal 30. Incorrect statement is: (a) NaHCO, and KHCO, have same crystal structure (©) On heating LINO decomposes into Li,0 and NO, (© Among alkali metals, Li metal impart red colour to flame (d) Li,SO, does not form alum 31. The solubility of metal halides depends on their nature, lattice ‘i enthalpy of the individual ions. Amongst fluorides of alkali meal en ey ANd hydration in water is due to : Of alkali merals, the lowest solubility of LF (2) lonic nature of lithium fluoride ©) High lattice (© High hydration enthalpy of Wehum ion. (2) Low loneation eeecipy of lahium atm 32. The reducing power ofa metal depends on various factors. Suggest she sabveneeaniert ‘metal the strongest reducing agent in aqueous solution acta Shieh ake (@) Sublimation enthalpy (©) Ionisation enthal; (©) Hydration enthalpy @) Electron gain enthalpy33. Mg2Cy reacts with water forming propyne gas. C}- ions has : (@) two sigma and two pi bonds (© two sigma and one pi bond 34. The fluoride which is most soluble in water (@) CaF, (b) BaF, (©) Si, (@) Bers 35. ‘The highest occupied energy level of the group 2 elements radius is 7s”, which of these statements is likely to be incorrect? (a) The element will show an oxidation state of +11 in all its compounds (b) The element will decompose water, liberating hydrogen (6) Hydroxide of the element will he amphoteric (4) Metal carbonate is relative stable at higher temperature than calcium earbonate ‘Amongst the following hydroxides, the one which has the highest value of i, at ordinary temperature is : @ Mg(OH),, (©) Ca(OH), (© SOW)» (@ Ba(OH), Which of the following alkaline earth metal hydroxides is the least soluble in water? () B(OH), (&) Mg(OHD 9 © Ca(OH), (@) BaOH) 2 38, ‘The thermal stability of BaCOy,CaCO,SrCO, and MgCO, decreases in the order (@) BaCOs >SICO,>MgCO,>CaCO, ——_(b) CaCO, > S1CO >MgCO, > BaCOs (©) MgCO, >CaCO, >S1CO5>BaCO,,- (A) BaCO3 >S1C04 > CaCO5 > MgCOs 39. Magnesium cation has polarising power close to that of : (b) three sigma and one pi bond (@) two sigma and three pi bonds 37. (@) Liv ©) Nat OK @c 40. Which of the following salt does not impart colour to the flame? (a) Mgcl, (b) SiC, (© Bact, @) Lid 41, Mortar is mixture of : (a) Ca(OH), silica and water (B) CaCO, and SiO, (© CaO and silica (@) Caco, Sid, and water 42, When MgCl, -6H0 is strongly heated, then it forms : (@) MgO () Mg(OH), © Mg(OH)Cl @ Msc, 43. A piece of magnesium nbbon is heated to redfess in an atmosphere of nitrogen and on cooling with water, the evolved gas is (@) ammonia (b) hydrogen © nitrogen (@) oxygen 44. Plaster of Paris when mixed with the correct amount of warer sets into a solid mass due to the aso. 0) (€280,),-4,0 (©) CaSO, 24.0 @ cao 45. Plaster of Paris i (b) CaSO 4.7H,0 (a) caso, (© 20380 44,0 (@) CaS0,.2H,0ii oo | 46. Magnesium liberates H, on reaction with : (@) dil, HEL () dil. HO, (©) very dil. HNO, (@) all of these 47. At high temperature, nitrogen combines with CaC, to give (a) calcium cyanide (b) calcium cyanamide (©) calcium carbonate (@) calcium nitride 48. Calcium hydride on hydrolysis forms? (@) C20+H, (b) Ca(OH), only (© Ca(OH), +H, (@) only CaO ‘49. Magnesium wire is heated in the atmosphere of CO, because (@) magnesium acts as an oxidising agent (b) magnesium has two electrons in the outermost shell (©) magnesium acts as a reducing agent and removes oxygen from CO, (d) none of the above 50. MgO is used for lining furnaces because : (a) of high melting point of MgO (©) Mgo is a very good conductor of heat 2) MgO js an electrical insulator @ None of these 51. Amongst LiCl, RbCl, BeCl,,MgClz, the compounds with greatest and least ionic character respectively are : (@) LiCl and RbCL @) RBC! and Bec, (© RbCl and MgCl, (@) MgCl, and Bec, 52. Which of the following compounds does not have similarity in their structural aspect? (a) FeSO ,.7H,0 (©) Na,CO27H,0 (© Mgs0-7H,0 @ 2080, 74,0 83. By adding gypsum to cement : (@) Setcing time of cement becomes less (6) Setting time of cement increases (© Colour of cement becomes light (@ Shining surface is obtained 54. A compound (A) ls used in preperation of washing soda to recover ammonia in Solvay’ process, When CO, is bubbled through an aqueous solution of (A) the solution rence ite is used in white washing due to dsinfecant nature, What isthe chemical eee (@) CaHCO,) (0) C20 © caom, (@) Caco 55. Which isnot similar characterise) about the electronic configuration of Be, Mg, Ca? (a) All the atoms have a pair of selecrons in their outermost energy level " (all the atoms contain a pair of electrons in their outermost eeeray level (© All are alkaline earth metals (@) All are of second group of the periodic tableAi a Alkal 1 4 7 10. res Te KO, +C02+H,0 "2, ox}, 17) Products [X] and [Y] are ‘Tespectively > G@KCO5,02 (BY KHCOs,0, ——(@) KOH,K,CO, (4) KHCO5, H,0 ‘The correet order of increasing solubility in water (@) KE < NaF < LF (6) NaHCO, < KHCOs a", white pt Ais paramagnetic in nature and contains about 55% K. Thus, A is : (@) K.0 (©) K,0, (© KO, (@) K,80, 16. Baking powder used to make cake is a mixture of starch, Ne seceuctons i laHCO, and Ca(HPO,),. The (2) to show down the release of CO, gas (©) being acidic in nature and gives CO, when moistened with NaHCO, (© tw act as a filler (@) None of the above 17. To anacidified dichromate solution, a pinch ofNa0, is added and shaken, What s observed? (a) Blue colour (©) Orange colour chai te dire (©) Copious evolution of oxygen (@) Blishgreen precipitate ee 18. Which ofthe following comp. saaime) dh ‘i process) ouowing compounds s consumed during the preparation of Na CO, by Solvays (@) NH, CaCO, NaC () NH,, cicao, Nact Ge) G00. Nal (@) Ned NHWHCO, 19. Which of the following statements is incorrect? (@) Sodium and potassium are soft and silvery white metals (©) Sodium and potassium in alr get tarrished due to the formation ofa layer of onde ofLg SS Ee im burn in dry oxygen (excess) giving peroxides (@) Sodium and potassium are kept under kerosene to avoid the contact with air and moisture 20, Nitrogen dioxide cannot be obtained from : G@) CUNO). (6) HgCHO5)2 (0) NANOg (@) AgNOs ia op 21. ‘A'+H20 —+ NaOH; ‘A’ 3024 p NE, neoH+03 B is used for oxygenating in submarine. A and B ore : (@) Na,03 and Nao (b) NagOandNa,03 © No.0; and0, @ Na,OandO; 22. CaCl, is prefered over NaGi for clearing ice on ronds petiularyin very cold counties because : (a) CaCl is less soluble in HO than NaCl (b) CaCl, is hygroscopic but NaCl is not (¢) Eutectic mixture of CaCl,/H130 freezes at ~55°C while that of NaCV#H,0 freezes at 18°C (4) NaCl makes the road slipperty but CaCl, does not 23. A metal which does not react with nitrogen is @ Li @) K (Ca (@) Mg 24, ‘The pair of compounds which cannot exist together in aqueous solucion is = () NaH,PO, and NaHCO, (Ul) Na,CO, and NaHCO, (IM) NaOH and NaHPO > (WV) NaHCO, and NaOH (a) 1,1, (b) 11, © uv (a) only Vv Alkaline Earth Metals (gp.2 or 1A) 25. The incorrect order of solubility in water is : (a) Ca(OH), King) > Rbdag) > Cag Electrical conductance CANS) > MaBhay > Naieay: Hydrated size (2) Nagy A 23 a ES, ice fumes; Mera! at can be: @) Li, Mg (b) Li, Alor K (© Na, K or Mg (d) Li, Na or K 29. X and ¥ are two metals. When burnt in air, X forms only oxide while Y forms oxide and nitride, ‘The metals X and Y may be : (a) Ca and Mg (b) Na and Mg © Liand Na (a) Na ond Ko_o A) 30. Which is incorrect statement? : (@) The heats of hydration of the dipositive alkaline earth metal ions decrease with an increase in their ionie size (b) NaNOz forms Na0, on heating (©) Hydration of alkali metal ion is less than that of MA group (@) Alkaline earth metal ions, because of their much larger charge to size ratio, exert a much stronger electrostatic attraction on the oxygen of water molecule surrounding them 31, Which of the following statement is incorrect? (a) The atomic radius of Na is greater than that of Mg (b) Metallic bond of Mg is stronger than the metallic bond in Na (©) Melting and boiling points of Mg are greater than those of Ca (@) Mg and Ca are the most abundant elements amongst the alkaline earth metals 82, Thermal stability of MCO, is in order : (@) Bec, CH=CH (© Cac, +H,0 — chacH (©) Mg,C, +H,0 —+ CHy 37. Choose incorrect statement : (a) BeCOs is kept in the atmosphere of CO. since, its least thermally stable (b) Be dissolves in alkali forming (Be(OH) ,]*- (©) BeF; forms complex ion with NaF in which Be goes with cation (@) BeF,, forms complex ion with NaF in which Be goes with enion 38. ILA (alkaline earch metals) and If B (zinc family) resemble : (a) MgSO , :7H,0 is isomorphous with ZnSO, \7H,0 (b) ITA and 118 ations are not precipitated by #,$ in acidic medium (c) both (a) and (b) (@) none of the above 39. Select the correct statement : (a) Be and Al show diagonal relationship () Be forms tetrahedral complexes [Be(C,0 «))]* =cH @ Be,C+H,0 — cH,_. (©) Al forms AlE2*, an octahedral complex (a) All are correct statements 40, Calcium imide on hydrolysis gives gas (B) which on oxidation by bleaching powder gives gas (©). Gas (©) on reaction with magnesium give compound (D) which on hydrolysis gives again gas (B). Identify (8), (C) and (D). (a) NHy)N2,MgaNa (b) Ni, NH, MgNH (©) Na,N205,Mg(NO3), (d) NH3,NO2,Mg(NO2)2 41, Acompound X on heating gives a colourless gas. The residue is dissolved in water to obtain Y. Excess CO is bubbled through aqueous solution of Y and Z is formed, Z on gentle heating gives back X. The X is : (@) Caco, (b) Ca(HHCO 5), (©) Na,COs (@) NaHCO, 42. Which of the following statement is false? (@) The milk of magnesia used as antacid is chemically MgO + MgCl, ©) Stability of alkali metal peroxides increases with increase in atomic number (© Hydration energy of AgF is higher than its lattice energy @ Anhydrous MgCl, cannot be prepared by direct heating of MgCl, SHO 43, ‘The more commonly used baking powder contains about 30% NaHCO, 20% NeA\(SO,)2, 10% Ca(H1,PO 4), and 40% starch, Which of the following statements is/are correct? (@ Ca(H,PO ,)p is acidic and when moistened it reacts with NaHCO, evolving CO, gas () NaAl(S0,); slows down the decomposition reaction of NaHCO, so that CO, is evolved more slowly (© NaAl(S0,)s is acidic and when moistened it reacts with NaHCO , evolving CO, (@) Both (a) and (b) subscribe our youtube channel jee2neet for more amazing books pdfETITHS3 = rassace «1 ay Al alkali metals dissolve in anhydrous liquid ammonia to give blue colour solution. It is the ammoniated electron which is responsible for the blue colour of the solution, and the electrical conductivity is due to the ammonicted cation, (M(NH,),]” as well as the ammoniated electron, {e(NH), J", values of x and y depend on the extent of solvation by NH. Dilute solutions are paramagnetic due to free ammoniated electrons. 1. What happens if more alkali metals is allowed to react with concentrated liquid ammonia? (a) Paramagnetic character of solvated electrons is retained (b) Solvated electrons associate to form electron-pairs and paramagnetic character decreases (@) Reducing character is increased (@) Reducing character is not affected 2. Which of the following statement about solution of alkali metals in liquid ammonia is correct? (a) The solution have strong oxidizing properties (b) Both the dil. solutions as well as cone. solution are equally paramagnetic in nature (©) Charge transfer is responsible for the colour of the solution (@) None of these 3. Ammoniated solutions of alkali metals are reducing agents due to the presence of free ammoniated or solvated electrons that can reduce @ 02 t00F MD K .{Ni(CN) ,] to K ,[Ni(CN),) (I) Aromatic ring (IV) Non-terminal alkyne Choose the correct code : (a) Mt and WV (®) Wand tn ©LMMandv (@) Mand V passace 2 aM : Bia oO, $0; NagS/lq Ast /salt Na AS BS CES, p AEC 5 Ccompler) 1, The compound B and C are: (a) Na,CO;,Na,S0, (b) NaHCO ,,Na,S0, (6) Na,CO,,Na3S03 @ None of these 2. The compound D is : (a) Na,S0, (b) Na,8,0, (© Nay5,05 (€) Na,8,0, ‘8. Oxidation number of each 'S’ atom in compound D : (a) +2, 42 (b) +4,0 (© +6,-2 @ 45,4fissace’ 3 rr Metal + dil.ticl —y 4 N0#PO+, g cwhite poe.) HOF HoYg)| Heated Electrolysis in. “Preeece of act Met) 1. ‘The compound A is: (a) CaCl, 2H,0 (b) MgCl, 6H,0 (© Na,$0,10H,0 (a) cas0,.2H,0 2. The compound B is : (@) Mg(NH,4)PO, (b) Ca,(PO,),+NHy © Na(NH,)HPO, (d) both (a) and (b) 3. The compound C and metal M are : (a) NaCl, Na (b) CaClz,Ca (©) Mgcl, Mg. (d) BeC!,,Be vassnce 4 Calcium sulphate is found in nature in two forms, anhydrous calcium sulphate and hydrated ‘calcium sulphate. When anhydrous calcium sulphate is heated with coke, sulphur dioxide gas is obtained. When hydrated calcium sulphate is heated to 200°G, it forms anhydrous salt. 1. The anhydrous calcium sulphate is called : (@ gypsum (b) anhydrite (©) plaster of Peris (d) lime 2. When calcium sulphate is mixed with conc. HCl and the paste is formed. What colour is obtained when a pinch of this paste is brought near the flame? (@) golden yellow —_(b) brick red © crimson red (@) apple green 3. What is the product formed when hydrated CaSO, is heated to 125°C instead of 200°C? (@ (CaS0,),HJO (0) CaSO4 FH2O (©) CaSO4 (@ ca0+s0, Sodium sulphite (Na,S05) is added to meat as a preservative. The presence of Na,SO, can be detected by adding dil. H,S0, when the pungent smelling gas evolved turns the lime ‘water milky. The gas evolved was detected as sulphur dioxide. The SO 2 evolved was dissolved in water and it requires 1, solution in order to oxidize SO, to SO2 in titration. $0, +2H,0+1, —+ 4H +sod +ar In order to check the results of titration, excess barium chloride is added to the final solution. ‘The resulting precipitate is collected and weighed.1 50; and CO. both turns lime water milky: Which of the following reagent can be used to distinguish these two gases? © K,Cr,0,/H,$0, () KMn0,/H" (III) J, solution () 1, I, II correct (b) 1, Ml only correct © I, I only correct (4) MM only correct SO, gas is used as a bleaching agent. Its bleaching action is = (@) temporary and due to its oxidizing nature (b) temporary and due to its reducing action (© permanent and due to its oxidizing action (@) permanent and due to its reducing action Which of the following compounds is formed, when Na,SO, is bolled with sulphur (a) Na,SO, (b) Na,S,0, (c) NazS206 (@) Na,S,0 | ; (On treatment with cold water, an element (A) reacts readily liberating a colourless, odourless gas (B) and a solution (C). Lithium is reacted with (B) yielding a solid product (D) which ceffervesce with water to give a strongly basic solution (E). When CO 3 gas is bubbled through solution (C), a white ppt. (F) is formed but this redissolved forming solution (G) when more CO, is passed. Precipitate (F) effervesced when moistened with cone. HCI and give deep red colouration to a Bunsen burner flame. (F) on heating with excess of carbon at 2000°C give uo. ‘Answer the following questionsion the basis of'above passages. Metal (A) may be : (a) Be Ca © Mg @) Ba Solution (G) contains a salt which (i) causes permanent hardness of water (ii) can not be obtained in solid state (iil) causes temporary hardness of water (iv) can be obtained in solid state Select the correct statements : (a) @ and Gi ©) (@ and (iv) (© Gi) and Git) @ (id and (iv) Solid (#1) on hydrolysis gives a gas, which on passing through ammoniacal AgNO, solutiot» yields (a) white ppr () red ppt. (© no ppt. Cav beanapoRLithium only forms monoxide when heated i i in oxygen. Sodium forms monoxide and peroxide in excess of oxygen. Other alkali metals form superoxide with oxygen, ie, MOz. The abnormal behaviour of lithium is due to small ste. The larger sizeof higher alkali metals also decides the role in formation of superoxides, All the three anions abstract proton from water. ‘The three anions are related to each other as follows = i Fad ©, oF oF 205 hab (Oxide ion.) Peroxide ion Superoxide ion. Consider the following reaction : M +02 —> MO, (Mf = alkali metal) (stable superoxide) (a) M can not be Li and Na (b) M can not be Cs and Rb (c) M can not be Li and Rb- (@) None of these Which anion is stable towards water : fa) OF (b) OF © 0; (qd) None of these Which compound will berate oxygen when reacts with ice cold water? (a) Na,O2 (b) KO, (© Na,O @) G0, 4. In hydrolysis, the alkali metal oxides, peroxides and superoxides act as : (a) Bronsted acid (b) Bronsted base {6) Lewis acid (a) Lewis base , LT Most metal oxides are thermally stable at temperatures upto 000°C but the oxide of metals below hydrogen in the electrochemical series decompose fairly. easly Thus HO and Ag,0 | decompose on heating. 1. Which of the following salt does not give NO, gas on heating ? (a) Pb(NO.), (b) Zn(NOa)2 (©) AgNOs (@ KNO, Which of the following compound cannot be thermally decomposed even at high temperature? ia) GAC, () R{CO5, (0) LixC0, (4) (NH) ,004 3. Comect eode for following thermal decomposition reaction(s) evolving gas having equal number of ¢- and x~ bonds is: | 4 Beco, —_2> (ii) 2080, =o . _ re, (iv) (NH,)26r,0, 2+ Gi) FeSO, (2) Allof these @Lu (1, 1,1V (44, mt(Dont ov mone answers is/aRe connect 1, The correct statement(s) is/are: a (a) Thermal stability of alkaline earth metal chloride decreases with inereasing molecular ‘mass but reverse order is true for their melting point (b) Thermal stability of boron halides increases with decreasing molecular mass but reverse order is true for their melting point (€) Thermal stability of beryllium halides increases with decreasing molecular mass and same order is also true for their melting point | (A) Thermal stability of hydra acids of halogens increases with decreasing molecular mass bur reverse order is true for their melting point. 2. Consider the following rwo graphs between atomic number of clement and hydration enthalpies (at 25°C) of corresponding ion. (M = Alkali metal and x = halogens) ‘tome number of M— ane ae 07a tae a4 ‘SH ln Lino ‘dada in K/ mol) — o @ “Then according to the given information which of the following is/are correct relationship between enthalpy of solution (AM yiyuy,) OF 8 Salt 0X in water and difference of the enthalpies of hydration (AH yydiaion) of the constituent ion (M* andX~). -209=160 0 31007200 ~200-100. 0 9100 +200 aad Myamia = At yaa) Atte) ~ My™ 10, u. 12, @ none of these ~200 100-0 +100700 rgerten®)~ Aden OO) Which of the following metal(s) in liquid NH, with low cone. is not paramagnetic ? (a) Cs (b) Be OK @ Mg Which of the following substances can be used directly as fertilizer ? @NH,),80, —_(b) Cay(FO,)2 (©)Ca(HyPO,)2 —— (@) CCN, +C Which of the following will release CO, when heated to 100°C? @ KHCO, (@) Li,00, ©K,CO, (@) Poco, ‘Which of the following properties show a similar trend on moving from Li to Cs within the group? (2) Ionic mobility in aqueous solution _—_(b) Reactivity towards water (© Solubility of bromide salt (4) Thermal stability of carbonate salt ‘The alkali metals (@) form salt like ionic hydrides (b) possess low lonisation porential (©) have high affinity for non-metals (@ have low density On heating NaNO, gives : (@) 0, (b) NO, (© 0,+NO, (d) NaNO, Which of the following statements is/are true? {@) All alkali metals are soft and can be cut with knife (©) Alkeli metals do not occur in free state in nature (© Alkali metals are highly electropositive elements (@) Alkali metal hydrides are covalent in character Nitrogen dioxide cannot be obtained by heating = (@) KNO, (b) LINO, (2) PO(NOs)> (a) Nano, Select the incorrect statement(s) : G) Cs* is more hydrated than the other alkali metal ions @) Among the alkali metals Li, Na, K and Rb, lithium has the highest melting poine (© Ionic mobility of Li* is maximum among alkali metal cations (@) fonisation potential of Li is lower than that of Na tatement(s) A rn rn ef (b) Sodium can be prepared by electrolysing fused NaCl13, 14. 18. 16. 18. 19. 20. 21. 22, (©) Sodium is « strong oxidising agent @) Sodium is soluble in liquid ammonia Identify the correct statement(s) : () Sodium carbonate on heating evolves carbon dioxide (b) Sodium nitrate on heating evolves nitrogen dioxide (©) Sodium hydroxide does not decompose on heating (@) Sodium bicarbonate on heating evolve carbon dioxide Which statements are false? (@ Manufacture of NaOH is done by Solvay process (b) Manufacture of K ,CO, is done by Solvay process (© Manufacture of NaOH is done by Castner Kellner process (@ Manufacture of NaHCO, is done by Solvay process ‘Sulphates salt gives metal oxide and SO, (or $0; +402) on heating : (a) K,80, @) C280, () Mgso, (€) (NH,),S0, ‘The correct statements about sodium and its compounds would include that : (a) Sodium forms an ionic hydride NaH (b) Sodium nitrate decomposes to the nitrite on heating (c) Sodium is a hard metal (d) Sodium carbonate decomposes readily on heating NaH reacts with water to give > (a) alkaline solution (b) acidic solution (c) neutral solution (@) hydrogen gas ‘Which of the following statement(s) is/are incorrect? (a) Magnesium may be extracted by self reduction method (b) Down's cell process is used to extract magnesium from sea water (©) Magnalium is an alloy of magnesium (d) Formula of Epsom salt is MgSO, 61,0 Identify the incorrect statement(s) : (a) Density of Mg is less than Ca (b) The atomic radius of Mg is greater than that of Ca © Mg alloys are used in the construction of air crafts (@ Mg is used as a reducing agent Which of the following properties of the clements of group I (alkaline earth metal) rease(s) with increasing atomic number? (a) Stability of carbonate @) Solubility of byte (©) Reactivity with water (@) First ionization energy Select the wrong statement(s) : (@) Caf, is soluble in water (4) 2450, 1 slut 1 (©) Ba(OH), is soluble in water (¢) Mgso, is soluble in wearer Which of the following statements about the elements, Mj eit compounds is true? Ig, Ca, Sr and Ba and tht (a) Solubility of the hydroxides in water increases with increasing atomic myguber:4 26. 27. a1. 32, (b) Thermal stability of the carbonat ith i 7 eases with ine atomic number ( All given elements react with water or eae ner (2) Metal chores ae liu et foom temperate Which of the following does/do not impart characteristic colour to the flame? (a) MgSO, (b) CaCl, (©) Sr(NO4)2 (d) Bech, ‘Which statement is correct regardi ae 15 be ant egy ata aga eo aoa he ls Be (b) Both carbide on hydroles 7 (¢) Both ean form conpeg oats Hae Bak (@) Both have nearly close m.p, Which of the following metals on treatment with alkali will liberate H ga3? (a) Be () sn (© Ga @ in Choose the correct statement(s) : (@) BeCO, is kept in the atmosphere of CO since, itis least thermally stable {b) Be dissolves in an alkali solution forming (Be(OH) 4] (©) BeF, forms complex ion with NaF in which Be goes with cation (@) BeF, forms complex ion with NaF in which Be goes with anion Select the incorrect statement(s) (a) Magnesium can be burnt in the atmosphere of CO, and SO, (D) Magnesium reacts with alk! halides to form Grignard's reagent (c) Out of Mg and Ga, only Mg reacts with N to form magnesium nitride (@) Calcium is less reactive than magnesium ‘Which of the following statement(s) is/are correct? (a) Sodium bicarbonate is more soluble than sodium carbonate () Sodium hydroxide is known as caustic soda (©) Sodium bicarbonate is used as antacid (@) Sodium nitrate is used in the manufacture of soaps Select the incorrect statement(s) : (a) KOH is a weaker base than NaOH (b) Milk of magnesia is an aqueous solution of Mg(OH) (c) Mg? ions are precipitated with the addition of NHOH in the presence of NH ,Cl (@) CaO is less stable than MgO. Which ofthe following statement regarding the oxides of alkali and alkaline metals is correct? (a) The reactivity of K 0 towards water is more than that of Na,O () The oxides of alkaline earth metals are mare basic than those of alkali metals (o Mgo is used as a refracory material for lining of electic Furnaces (@ The mili of lime and lime water are two different solutions The pair of compounds which can not exist together in aqueous solution is : (@) Na,CO, and NaHCO; (b) NaHCO, and NaOH (©) NaOH and NaH{,PO, (@) NoOH+Na,HPO, Which of the following are soluble in water? () Na aoe oon (b) BaC 04 (© Mgco, (2) catNo,),=e RG, 33, Which of the following salts exist(s) as decahycirated crystals? (a) Washing soda (b) Glaubers sal (c) Epsom salt GD Geremin.sslt 34, Which of the statements are true? (a) NaHCO, and KHCO, have same crystal structure (b) On heating LigCO, gives Li,0 and CO, (©) Among alkali metals, Li metal has high LE. and impart no colour to flame @ Li,S0, does not form alum 35. Saturated hydrocarbon gas is evolved by carbide(s) is/are + (@) Cac, ) ALC, © Mg2C3 (d) Be xe [MATCH THE COLUMN Entries of Golumn-I are to be matched with entries of Column-II. Each entry of Column-I may have the matching with one or more than one entries of Column-Il. (A) Yellow flame colour (P) Ca (B) Most reactive with water {Q) Mg (C) Gives carbide with ‘C” (R) Na (D) Mecal nitrate 5 metal oxide +NO, (8) Li +02 2 (a esitinaar! (A) Product in Solvay process "®) Nact suit (B) Evolve CO, 7 on heating (Q) Na,0, (© ag. soln. is neutral towards litmus!“ (R) NaHCO, (©) Oxone (Na;02) (S) Na,co, 2 TA CRG (A) Metal sulphate —*+ metal oxide ®) Ba " +80, +0, (B) Metal cation+ K ,CrO, —+yellowppt. (Q) Sr (© Metal + NH, “8%, piue solution) Ne (@) MCL, + cone. H504—rarbite pet. (S) Mg.(B) Ag “salt —+ soluble complex (©) Fe* —+ Fe(OH), (D) FeCl; —+ Fecl, (A) Most negative standard electrode Potential an element in the periodic table Lei PES ae Eerees ®) Na,8,05 (Q) NaOH (R) KOH S) Na,S0; 2 Golumntt (®) Solvated electrons @) Alkali_metal carbonate which (Q) MgsCs decomposes on heating (© Na/liq. NH, is blue colour solution (R) Al,C which conducts electricity (D) Metal carbide which gives methane on (S) Magnesium hydrolysis (E) Metal carbide which on hydrolysis gives (I) Li,CO, Propyne (P) Metal used in flash bulbs (U) Lithium 6. ~~ Colamnt Bee @ Column-Hee ss Ee (Compounds) vane an (Use of compounds)... (A) Magnesium hydroxide (P) Asa purgative (B) Barium sulphate (Q) Asa fertilizer (© Magnesium sulphate (D) Calcium cyanamide cesar ee a (A) BeP < BaF < StF, RS BOS; Assertion-Reason Type Questions 10 20 30 408 8A 60 7A BO 44. (A) 12, B) 13. A) 14 (CP 18. (A) 18. (C) 7. A) Subjective Problems 13 (e) a) © ia ©) m (9), 4 (acc) 8 bad) 6. (dd) T.dad) 8. (ad) (x) 16. (ad) (ad) 24, (@b0) @e) 32 A) Fos ©) 1 0)Hints and Solutions” Level 1 Rao. ees 2 (© In group only Li form nite and all! group metals form nitride. Mg +Na—> Mg," gion), +NHy (Ca-4N, + CayNy M28, Ca(OH), NH U4, + Ligh 22 on any K Hg no reaction ‘4. (a) Itis due to more ionic character of 5,605, 29. (a) In general order of meking point. Uk < Cex NaNO, >ENO, 1,60, ) NaOH! ‘being deliquescent absorb water from atmosphere therefore strength of solution will decrease. below L 20. nano, +1o, (Nano, 2% +} RAP Bee ae ppepsaaneiss CutIO,), A cx0 + 280,74 Lost Hg(NO,), 4 Hg l+2no,t+0,+ AgNO, 4s ag +NO.T+ fort 22. (©) Due to much lower freezing point of eureede mixture of CaCly,0, 26. (a) Only bicarbonate salt of alkali metals are Found in solid stare, 27. © (2) Ca < Kt <* Kiagy > Rbfug) > Cig Elecerical conductance (4) Krag < Briagy < Cling) < Flag): Fonic mobilityCet) +24, —+ CaCO), + NHACG) o 2NH, + 3Ca0Cl, —+ Nils) + 3CeCl, +3H,0° @ © Na)+3Mg —> Mg © oO MBN, + 6H, —+ SMg(OH), + 2NHy @ @ 42, (a) Milk of magnesia isa suspension of MgO + HO. tevel3 Passage-1 2, (@) All are wrong. The solution has strong reducing nature and coloured due to emmoniaed electron. 3. (0) Ms) +N) —+ MONE), « FON), "Ammoniated@ responsible for blue colour and reducing character. 4f conc. of solution is increased, then association of solvated electrons get started hence, ‘paramagnetism decreases and solution changes to bronze colour. Passage-6 1. 6° ca 422s Hy +CaCOHD,fan, 2! + C200, BEE ca 2", aco, HE, Cac, (a) a © oO a) w oo (60, (Excess) | u HO, LoH+H,t — CatHeos), © @ 12, (© It is CaHIOO>, which can nor be obtained in solid state and causes temporary hardness. 8, (@) It is acetylene gas and gives white ppt. of silver acerylide Passage-7 11, (@) Liand Na do not form stable superonide. 2. (@) all he three O™, OF and OF are unsta'le in presence of water and abstract proton from water. 3. (b) All superoxides liberate oxygen with water 20; + 28,00) —> 208"(ag) HD +0x68) “4. (B) All abstract proton from water so they are Bronsted base, One or More Answers is/are Correct 1 bo (@) > Thermal stability of Hydra acids HF > HCL> HBr > Hi= Melting point tion energy and metalic lattice energy Be and Mg do not dissolve into liquid NH; ‘in liquid NH is not paramagnetic. 3t soluble in water hence itis of no use for plants. > HF > HBr> HL 3. 4) ‘Due to high ionizat hence their solution 4 @od ast tesa erry phosphate and no19. (ab) Magnesium is more dense than calcium. ‘Magnalium is an alloy of magnesium which is used in the construction of air crafts. 25, (a,b,c) Be, Sa and Ga are amphoteric metals. 26. (abd) Bef +2NaF —> NagBeF,J Assertion and Reason Type Questions 41. (ClAmong sulphate salt of alkali metals only i804 does not forms alurn, as Li” has very small size. 2uL+NH(@) 2+ LiNH+ Hat 2. (DYBECL, can be easly hycrlysed due to its deficient nature BeCl; + 2H,0 —+ Be(OH), +2HAT ‘3. (A)onic radius of NH} is almost equal to ionic radius of K”. 4, (B)Alums are Mi(SO,) MASO,),-24H,0 ‘These are soluble in water. Theiraqueous solution are acidic in nature both the statements are truc but it is not the correct explanation, 5. (A)2Mg +O: —* 2Mg0+C Mg isa strong reducing agent and have great affinity for O, at high temperarure. 6. (D)Mg?" + zn +50 —> Mg* +80 +2n* (no reaction) 8. (C)Be( OH), is amphoteric in nature. ‘Subjective Problems #0 a> NaOH + H,0, o @ 1. Nag Wimer Met NaOH + Opt + HO oO © Bond order of (0-0) in, ~20 Bond order of 0-01 in 0, =2.0 Sum of bond order between same bonded azoms in Qand R compounds =142.0 =3.0Setar eer 1. Anhydrous aluminium chr is x stig olan hore (Al (1 1 eovalene compound and voile In wener ings (b) [AIGH,O) «1° and Cl” ions (©) [AICL,(H,0),]* and [AICl,(H_,0) ,]" ions (@ none of the above 2. AL4Cs is an ionic carbide, named as: (a) Acetylide (b) Mechanide (©) Allylide (@) Alloy 3. Which of the following compounds is formed by addition of mineral acid solution of borax? pene es (@) Boron oxide () Onthoborie acid (©) Metaboriec acid (€) Pytoborie acid 4. AICI, on hydrolysis gives: (@) Al,0,11,0 (0) AI(OH)5 (9 A103 (@) AlCl, 64,0 5. Alumina is insoluble in water because: (a) Itis a covalent compound @) It has high lattice energy and low heat of hydration (© Ichas low latice energy and high heat of hydration (@) Al? and O™ ions are not excessively hydrated 6. Which of the following is an electron deficient molecule? @) Lin (D) BaHs (© LiBH, (@) ByN3Hym oy 10. 1. ‘Anhydrous aluminium chloride fumes in moist air owing to the formation of: (a) gaseous aluminium chloride (b) chlorine (©) chlorine dioxide (@) hydrogen chloride Colour of the bead in borax bead test is mainly due to the formation of: (a) metal oxides (b) boron oxide (© metal metaborates (@) elemental boron ‘The possible oxidation state of TI are: (a) Hand +2 (&) +2and+3 (© Hand -1 (@ +and +3 ‘Which of the following sublimes on heating? (@) Al,0, (& AOR), (©) (Al), @ (Ald,), ‘The gaseous product(s) expected at room temperature by reaction of sodium borohydride and boron trifluoride under anhydrous conditions is/are: G@) H, () BiH, and, (© Bats (@ BH,F and H, I ee ee eT 12. 13, 14, 18. 16. 17. 18. Silicate having one monovalent comer oxygen atom in each tetrahedron unit is : (a) sheet silicate ©) cyclic silicate (©) single ehain silicate (@ double chain silicate PbI, does not exist because: (2) lodine is not a reactive (b) Pb) is oxidizing and I” is strong reducing agent (© Pb(IV) is less stable than Pb) (@) Pb" is not easily formed ‘The silicate anion in the mineral kinoite is a chain of three SiO, tetrahedra, that share comers with adjacent tetrahedra, The change of the silicate anion is: @-4 @) -8 © 6 @2 ‘The gaseous product of the reaction between Sn and conc. H,S0, is: @H, ©) s0, (© SaH, @ so, ‘The dehydration of malonic acid CH (COOH) with P,Oyy gives: (a) carbon monoxide (b) carbon suboxide (©) carbon dioxide (a) all three Which of the following structural features of graphite best accoum (a) Delocalized eleccrons (b) Strong covalent bonds between carbon atoms (©) van der Waals' forces between layers (@) limited three covalency of carbon Which of the following is sparingly soluble in cold water (@) Pb(NO5), ®) Poa, (©) PdsO, @) PeGrO, ts for its use as a lubricant? ‘and fairly soluble in hot water?The structural of sili i : 39, Te structural of slleon GV) oxide belongs tothe type (®) macromolecular, with a layer structure (c) molecular lattice, with van der Weals forces among the molecules @ macromolecular, with a non-layer structure ‘\ 20. ‘Silicon dissolves in excess of HF due to formation of: (@) Sik @) sit, © H,SiF. @ HS, 21. Which of the following halides does not hydrolyse at room temperature? (@) PDCl, ©) sic, © cl, @ Snel, 22, SICl, on hydrolysis gives: (@) silica licic (0 ane (0 site 23. Which substance is having molecular solid: © graphite ©) Cw (©) gold @ €a,(P04), 24. A cyclic skeleton of silicon and oxygen can constructed by the silicate ion composition: (@) Si,0¢ (b) si,0F (© sioe @) siot 25. Which of the following is an organo silicon polymer? (a) Silica (®) Silicone (©) Silicon carbide 26. SnCly acts as a reducing agent because: {@) SnCl, can accept eleccrons readily (©) Sn is more stable than Sn** (©) Sn** is more stable than Sn (@) Sn can be easily converted to metallic tin 27. The correct order of decreasing ionic nature of lead dihalides is: @ Silicie acid (a) PbF, > PbCl, > PbBr, > Pbly () PbE, >PBr, > PbCl, > Pbl, (c) PbF2 PbBr2 0) —> ©)33. 34, 37. 39. a. A.B,CandE are: (@) CO,,CO,H,0, HCONH, (b) CO,CO,,COC1,, HCONH; © €0,COz,H,0,NH,CONH, (@ CO,CO2,Hz0, COC Si,0$- anion is obtained when: (@) no oxygen of a SiO, tetrahedron is shared with another SiO, tetrahedron (b) one oxygen of a SiO, tetrahedron is shared with another SiO. tetrahedron (© two oxygen of a SiO, tetrahedron are shared with another SiO tetrahedron (q) three or all four oxygen of a tetrahedron are shared with other SIO4 tetrahedron Peck ‘Tisilyamine (Sif) Nis: mpounds (15 (2) srigonal pyramidal and acidie (>) trigonal pyramidal and basic (© tigonel pyramidal and neutral (@) trigonal planar and weakly basic ‘The mixed anhydride of nitrogen is: G@) N,0; (2NO) (©) N04 @NO,) © N05 (@) N,05 ‘Among NH3,PHs, Asi, and SbHiy whieh one is a stronger reducing agent? (a) NH, () PH, (© AsHs (@) SbH, When 2ine reacts with very dilute HNO, the oxidation state of nitrogen changes from: (@) Sto +1 (0) 45t0-3 © +5104 (@) 15043 Which of the following orders regarding thermal stability of hydrides ME, of group 15 is correct? (@) NH, >PH, > ASH, (b) NH PH, < ASH; (@ NH, AsH, ‘The products formed by complete hytiroiysis of PCI, are: (@) HPO, and HCL (b) POCI, and HCI (© HPO, and HCL (@ H,P,0, and Hct When a sample of NO; is placed in a container, this equilibrium is rapidly established. 2NO.(3) = N20,(g) If this equilibrium mixture isa darker colour at high temperatures and at low pressure , which of these statements about the reaction is true? (@) The reaction is exothermic and NO, is darker in colour than NO, (b) The reaction is exothermic and NO, is darker in colour than NO (©) The reaction is endothermic and NO, is darker in colour than N04 (@) The reaction is endothermic and N,0 is darker in colour than NO, Heating of ammonium dichromate produces: (@) NH, Cr,0; and H,0 () N,,Cr,03 and H,0 (© NO,CrO, and H,0 () NjO,CrO, and H,0 Which of the following halide undergoes in hydrolysis via S,, reaction ? @ Bd, (&) NF, (© NCly () AsCly42. Which of the following compound does not give oxjaeid of central atom on hydoiys @sicl, Na, (Ord; (d) PCls 43. In which process does the nitrogen undergo oxidation? (@QN— 2NHy ©) N04 > 2NOg (QNO5-4N205 (d) NOz + NO3 44. For which element would XH, be a stable species : @c si OP @s xygen Family and th ior 45. S—O bond length is maximum in (a) SOBr, @ soci, {¢) SOF, (@) SO(CH,)2 46. In case of hydride of oxygen family, which of the following physical property change regularly on moving down the group. (a) Melting point (b) Thermal stability (© Boiling point (@) Critical temperature 47. When KHSO , is added into a concentrated solution of H,S0,, the acidity of the solution: (@) increases () decreases (© remains constant (can't be predicted 48, Hydrolysis of one mole of peroxodi-sulphurie acid produces: (2) two moles of sulphuric acid (b) two moles of peroxomono-sulphuric acid (© one mole of sulphuric acid, one mole of petoxomono-sulphuric acid G) one mole of sulphuric acid, onle mole of peroxomono-sulphuric acid and one mole of hydrogen peroxide 49. In trimer form of sulphur trioxide, each sulphur atom is bonded with: (@) four oxygen atoms (D) three oxygen atoms (©) two oxygen atoms (@) two sulphur atoms 50. Sodium thiosulphate Is formed when: (@) $0, is boiled into NazS (b) Na,SO> is boiled with elemental sulphur (©) H,S,05 is neutralised by NaOH (@) Na;SO, is reduced by zine dust 51, Kg[Fo(CN)g] reacts with ozone to give (a) Fe.03 @) Fe(or, (©) Ks[Fe(CN) 6] @ ENO, 52. The dipole moment of 1,07 is more than that of #,0 butH,0, is nota good solvent because: {a) Ie has a very high dielectric constant 20 that ionic compounds cannot be dissolved init (b) tt does not act as an oxidising agent (©) Ieacis as a reducing agent @ it dissociates easily and acts as an oxidising agent in chemical reactions 53. The correct increasing order of acidity is: (6) CO, >H,02 7 H20 @) H,0C02 (@) H,0,>€0,>H,0aS TM ae RA a ane ao Dea 54. 55. 56. 57. 59. 60. o. 62. 6s. In which case, the order of acidic strength is not correct ? @ HI> HBr> Hel (@) HIO, > HBrO, > HCIO, (@ HCO, > HCIO, > HClO, (@) HF>H,0>NH3 Concentrated nitric acid reacts with iodine to give: (a) HOL (b) HI (2) HOIO, (@) HOIO, Thermally most stable compound is: (@) HOCIo, (») HOO, (©) Hod (@ HOdIO ‘Which of the following halogen axide is used for estimation of carbon monoxide in automobile exhaust gases? (@) €1,0, (b) 105 @ Co, (@ Bro, The interhalogen which does not exist is: (a) IFS (>) CIF; (c) BrCl (d) Ich, Which of the following halogen disproportionates in water? (a) Fy ) cl, OL, (d) All three Which of the following is correct statement? (@) F, has higher dissociation energy than Clz (b) F has higher electron affinity than Cl (© HP is stronger acid than HCl (@) Boiling point increases down the group in halogens Only fodine forms hepraluride IF, but chorine and bromine give penta‘Muordes. The reason for this i: (a) low electron affinity of iodine (b) unusual pentagonal bipyramidal structure of IF, (©) thatthe larger iodine atom can accommodate more number of smaller fhirine atom around it (4) low chemical reactivity of IF, Acid used for making permanent marking on the glass surface is (a) HNO, (@) HF (© HIO; @ HS0, The unfavourable electrochemical reaction among the following is: (@) Zn+H,S0, —+ ZnSO, +H, ©) Ki+cl, — kel+1, (©) KCL+1, —> KI+ICl @ Al+3Ha —4 Alcs +3, Which anion can undergo both oxidation and reduction? (a) Cr,0F (b) NO} (© ocr (@) s> In the series HCl, HBr and Hl, the boiling point increases in the order HCI < HBr< Hl. This is due to: (a) Hl is the strongest acid among the series (b) Hi is the strongest reducing agent among the series (©) higher van der waals' forces of attraction in HI (@) intermolecular H-bonding in HIEoExcre EREECIeu kena woes) 66. nics factor is most responsible for the increase in boiling points of noble gases from He to _ (@) Decrease in 1.8, (b) Monoatomic nature (© Decrease in polarisabilty (4) Increase in polarisability 67. ‘The compound that cannot be formed by xenon is: © XeOg (b) Xer, © Xecl, (@) XeOsFy 68. The noble gases can be separated by: () passing them through suitable solution () electrolysis of their fluorides (© adsorprion and desorption on charcoal (@) adsorption and desorption on activated hydrogen 69. Which of the following xenon compound has the same number of lone pairs as in 13? (a) XeO, () XeF, (©) Xe @ Xe03 Cece la) 70. Incorrectly matched characteristic is: (a) 89: Covalent lattice (b) Py: Tetrahedron (©) S#: Zig-Zag (@ SiO 4: Covalent lattice 71. Which is wrong statement? (a) The decreasing order of thermal stability is CsOH> ROH > KOH > NaOH {b) The decreasing order of bond angle is BF, > PF; > CFs (c) The deereasing order of bond dissociation energy is Cla > Br >F, >1, (a) The decreasing order of melting point is NH > (CH,),NH > CH NH, > (CH,)5N 72. Which of the following has been arranged in order of decreasing bond dissociation energy: (a P—o>cl—0>s—O @) P—0>s—0>c_—0 (9s—o>cl—0>P—O @cl—0>s—0>P—0i nn Pim2 Pema acne Rca ee ee 1, BY; + NH, ©5, BX, -NH, + Hear of adduct formation (SH) ‘The numerical value of AH is found to be maximum for : (@) BF, ©) Ba; (© Bers @ Bl; 2. Which of the following properties describes the diagonal relationship between boron and silicon? (@) BC, is nor hydrolysed while SiCl, can be hydrolysed (b) Both form oxides B 0, is amphoteric and SiO, is acidic (© Both metals dissolve in cold and dilute nitric acid (@) Silicide and boride salts are hyerolysed by water 3. Anhydrous AICI, is covalent however, when iris dissolved in water hydrated ionic species are formed. This transformation is owing to: (@) the trivalent state of Al (b) the large hydration energy of Al> (©) the low hydration energy of AI* @ the polar nature of water 4. Borax in its crystal possess: (a) 3 tetrahedral unit (b) 2 tetrahedral and 2 planar triangular units (© 3 tetrahedral and 2 planar iangular units @ all etrahedral units S. Consider the following statements for diborane: 1. Boron is approximately sp° hybridized 2. BIB angle is 180° 3. There are rwo terminal B—H bonds for each boron atom 4. There are only 12 bonding electrons available Of these statements: (@) 1, 3 and 4 are correct (b) 1, 2 and 3 are correct (©) 2, 3 and 4 are comect @ 1,2 and 4 are correct 6. Aluminium vessels should not be washed with materials containing washing (@) washing soda reacts with aluminium to form soluble aluminate a (b) washing soda is expensive (©) washing soda is easily decomposed (@) washing soda reacts with aluminium to form insoluble aluminium oxide 7. Which of the following statements about anhydrous aluminium chloride is correct? (a) It can exist as AICL, molecule in vapour (b) Ik is # strong Lewis base (©) It sublimes at 180°C under vacuum (d) It is not easily hydrolysed10. n. 12. 13, 4. 18. 16. Na,B 407 10H,0 HS, x 4 Ng30,4H,0, X+6r0, y Green coloured) X and are @) Na,B0, andcr(B0,), (b) Na,8,0, and Cr(BO,)y (©) B20 and Cr(B0,.), (d) 8,0, and CrBO, Borax is converted into crystalline boron by the following steps: é torr 4,90, *y 2,0, 2s 8 X and ¥ are respectively: (a) HCl, Mg @) Hale (0 Gal (@) HCL, AL The dissolution of AI(OH), by a solution of NaOH resuits in the formation of (a) [AICE,0) ,(08),]* () [ALCH,0) (0H) 3] (©) (ANCHO) (08) «1 (@ (AGO) «(OH 3) ‘Choose the correct sequence for the geometry of the given molecules Borazone, Borazole, BOF , FeCl, trimer of FCN. CP stands for planar and ‘NP’ stands for non-planar] (@ NB, NRNR RP () RENE NRE (©) NB NE NBR NP (@ NRBRNBP Which is not true about borax? (@) Itis a useful primary standard for titrating against acids ©) One mole of borax contains 4B —O —B bonds (© Aqueous solution of borax can be used as buffer (@) itis made up of two triangular BO, units and two tetrahedral BO, units B(OH) + NaOH —> NaBO, +Na[B(OH) ,]+H,0 How can this reaction is made to proceed in forward direction? (@) addition of cis1,2 diol (©) addition of borax: (© addition of rransi,2 diol @ addition of Na3t1PO, Which of the following cation can not give borex bead test 7 G@) cr* ) Co™ © Ag* (@) Mn® Hcl» x + Gas'P a meat LBaotny y + Gas’ ‘The incorrect statement regarding above reactions is : (@) Al shows amphoteric character (b) Gas‘ and 'Q' are different (© Both Xand ¥ are water soluble (@) Ges Q is inflammable ‘The incorrect statement regarding 'X’n given reaction is BF, + LiAIH, 8" 4(X) + LIF + ALF (a) Twelve electrons are involved in bonding (©) Four, two centre-two electron bondsii Cs (©) Two, three centre-two electron bonds (@) X does not react with NH, 17. The incorrect stability order of +3 and +1 states of 13th group “ements (boron family) is (@) Ga* 71" © Gat cn’ ctr (d) Ga >Ga* Eee Ree ater ee Geer 18. Consider the following route of reactions: R,SIC1, + Water —> (a) stain, (gy ‘Compound(B) in above reaction is : @) Dimer silicone (b) Linear silicone (© Gross linked silicone (d) Polymerisation of (A) does not occur 19. The most basic oxide of elements in group 14 of the periodic cable is: @) SiO, ©) Gro (©) 8202 (d) PbO 20. (Si,0,)2~ anion is obtained when: 2) no oxygen of a SiO cetrahedron is shared with another SiO} tetrahedron (©) one oxygen of a SiO$- tetrahedron is shared with another SiO{- tetrahedron (© two oxygen of a SiO} tetrahedron are shared with another SiO tetrahedron (@) three oxygen of a SiO} tetrahedron are shared with another SiO} tetrahedron 21. Amphibole silicate structure has ‘x’ number of comer shared per tetrahedron. The value of is: 1 @2 M25 ©3 @ 4 22. The silicate anion in the mineral kinoite is a chain of three SiO, tetrahedra that share comers with adjacent tetrahedra. The mineral also containsCa** ions, Cu ions, and water molecules ina 1:1: 1 ratio mineral is represented as: (a) CaGuSi,0y9:H,0 (b) CaCusi,0 i924 ,0 (© Ca,Cu,$i,09°2H,0 (@) none of these 23. Choose the correct order of G — G bond length in the given compounds: (@) Acetylene < ethylene < graphite < benzene < ethane (®) Acetylene < ethylene < benzene < graphite < ethane () Acetylene < graphite < ethylene < benzene < ethane (@) Acetylene < benzene < graphite < ethylene < ethane 24, Silicate having one monovalent comer oxygen atom in each tetrahedron unit is: (a) sheet silicate (b) cyclic silicate (© single chain silicate (@ double chain silicare 25. In which of the following silicates, only two corners per tetrahedron are shared ? (@ Pyro silicate (i) Cyclic silicate (ii) Double chain silicate Gv) Single chain silicate (W) 3D silicate (vi) Sheet silicate (@ @, Gi) and (v) (b) (iv) and (vi) only(©) (i) and (vi) only (@) Gi) and (iy) only 26. The correct code for stability, of oxidation states for given cations is @ Pee > PY mW <1 Gi Bi* Pb, BI > Bie Gy) TI Sn" (v) Sn™ pp (wi) Sn® 6) —“? > 2) Identify [2] gas : (a) Nz @) NH, (202 @H, 30. Which of the following oxyacid contains both P—H and P—P bond simultaneously ? (@) HP.05 (©) HPO, (0 H4P.06 (@) None 81. Among the following statement which one is true? (a) NH, is less soluble than PH, in water (b) NH Is stronger base and stronger reducing agent than PH {e) NH, has higher boiling point than PH and has lower melting point than PH (G) bit is stronger reducing agent than NH, and ithaslower eitcal temperarure than NH, 982, Which of the following statements regarding NO, is mot correct? (a) ft is a planar molecule . (b) Iris used as non-aqueous solvent (6) It involves N--N bond which i larger than the N—N bond in hydrazine {(@) Ammonium nitrate in N04 acts as a base 183. Which of the following on heating produces NO;? (a) NaNO i) AND GB NBNOs @ NH,NO, 34, Which of the following equation is incorrectly written? +20NO, + 4H,0 (a) P,+20HNOs —+ 4H3P0s (tee 1OHNO, —> 2H10, + 10NOs + 4H,0 fo) Sr 6HINO, —? Hs804+6NOs +2H20 (a) None of the above=~ Se) 85, ‘The cyclotrimetaphosphoric acid is: (a) (HPO), and contains 9o-bonds (b) HPO, and contains 12 -bonds : (©) (HPO), and contains 1S0-bonds (@) HyP,Oy and contains 18 0-bonds 96, A+H,O —> B+HCl B+H,O —. C+HCl ‘Compound (A), (B) and (C) will be respectively: (@) PCls, POCL,, HyPO, (®) Pls, POCIs, HPO, (© SOCz,POCs,H3PO, (€) PCly, POG; HsPO. ‘37, It is recommended that liquor ammonia bottle should be opened after cooling it in ice for sometime. This is because liquor ammonia: {@) brings tears in the eyes (©) is corrosive liquid (© is a mild explosive (@) generates high vapour pressure ‘38. Which of the following statements are correct about the reaction between the copper metal and dilute HNO? The principal redueing product is NO gas (1) Cu metal is oxidised to Cu* (aq. ion which is blue in colour {lD NO is paramagnetic and has one unpaired electron in antibonding molecular orbital (IV) NO reacts with 0, to produce NO. which is linear in shape ‘Choose the correct statements: @ 1,1, ) 401 © nv @ All the above 189. In which of the following acids, PP bonds is present? (a) Tetra poly phosphoric acid (P4019) (b) Pyrophosphoric acid (H ,P,0,) (©) Hypophosphoric acid (H4P:0 5) (4) Polymecaphosphoric acid (HPO 5), 40. 8,40, Ps Ati; A+0, — B B+0,+H,0 —+C A.BandC are: (@) N,0,NO, and HNO (©) NO,NO, and HNO, (© NO, NO and HNO3 (@) N,0,NO and HNO, 41. The formation of PH is difficult compared to NHI, because: (@) lone pair of phosphorus is optically inert (b) lone pair of phosphorus resides in almost pure p-orbital (©) lone pair of phosphorus resides at sp* orbital (2) lone pair of phosphorus resides in almost pure s-orbital‘42. Nitrogen(1) oxide is produced by: (a) thermal decomposition of sodium nitrite at low temperature (b) thermal decomposition of ammonium nitrite (©) disproportionetion of NO, @ interaction of hydroxyl amine and nitrous acid 43, Amongst the following compounds @) HPs (1) HeP, 5 (UD HP.0,5 GV) H,P,0;5 non-cyclic phosphates are: @ 4m winm OLY @ 10, mv 44. Match List with List-I and select the correct answer using the codes given below the lists: List-l (Compounds) List-II (used in) (®)_ BaSO, +2nS @) Explosive @) My @) _Oxidiser in rocket propellants © N,0, G) Space capsule ©) KO, ) Pigment a ® © ©! ao ® © ® @ 3 1 het se Bi © 4 i 2 3 © 3 4 1 2 @ 4 3 2 1 48. Which is the correct sequence in the following jroperties? For the correct order mark () and for the incorrect order mark (F). i (0) tenis oiity onder: Ss < Sis SbH > AsH > PE (© Boiling point: NE > SbH, > AsH, >PH, (@ Dipole moment order: NH >SbH; > Asif >PH, G@) FTFT (b) TEIF © FIT (@ FFF 46, An orange solid (X) on heating gives a colourless gas (¥) and only a green residue (Z).Gas(¥3 on teatasent with Mg produces # white solid substance: ne @ Mg3N2 @) MgO © Mg,05 (© Mga, 47. Calcium imide on hydrolysis wil give gas (B) which on oxidation by bleaching powder given gas (©). Gas (C) on reaction with magnesium gives compound (D). (D) on hydrolysis gives again gas (). (B), (©) and (D) are: (@) NH3,N3,MgaNo (b) Na,NH3,MgNH (©) N3,N,05,Mg(NOa)2 (@) NH5,NO2,Mg(NO,), 48. Among the following compounds, which on heating do not produce N ,? (@) (NH4)201.07 () NH,Cl+ Nano, (©) NH,Ci+ C20 © Baw)._ ae 49. In which of the following compounds hydrolysis takes place through S,, and S,,: mechanism respective? (a) NF3, NCI; (©) PyOjo, SiCL, (SF, Tee @ sil, sir, ‘50. Incorrect statement about PH is : (@) Its produced by hydrolysis of CaP, (©) It gives black ppt. (CugP,) with CuSO, solution (©) Spontaneously burns in presence of PH, (@) It does not react with BH, 51. Which of the folowing compound does not produce oxyacid of central atom on hydrolysis? (@) BE, Nd, (© SE, @Pa; ‘52. The incorrect statement regarding 15" group hydrides (EH3). [E=N, P, As, Sb, Bil (a) NH, >PH, > AsH > SbH, > BiH: Thermal stability (b) N—H > PH > As_H > Sb_H'> BiH: EH bond dissociation enthalpy (©) NH, >PH, > ASH, > SbH, > BiH: Reducing character (@) NH, >PH, > AsH, >SbH, > BiH: Basicity Calculate x + y +2 for HPO, acid, where x is number of lone pairs, y is number of o-bonds and 2 is number of r-bonds : @s @) 14 () 13 (¢@) 12 54. A non-metal M forms MCl;, M0, and Mg,M, but does not form Mt,. Then incorrect statement regarding non-metal M is (a) M can form multiple bond (b) M Is of second period element (©) Atomicity of non-metal is 4 (d) The range of oxidation number for M is +5 to -3 5. The incorrect orcer is : (a) Thermal stability : HF > HCl > HBr (©) % p-character : NO! >NOS >NH{ 53. (©) Lewis basic character: PR; PH > AsH, Oxygen Family and their Compounds (16 gp.) 56. The correct order of S—S bond length in following oxyanions is : s,07 a so} ay $07 @t>m>m I> O21 @m>u>1 @M>1>1 57. In which of the folowing reaction product does not contain ‘Peroxy' linkage? (a 20n Destin 20 0) H,P,0, "2, (d) None of these ‘58. Consider the following statements in respect of oxides of sulphur (2) In gas phase SO, molecule is V-shape. excess Og (© 2Na61. 2) In gas phase SO, molecule is planar (3) ¥-SO, 18 cyclic trimer, Which of the above statements are correct ? (@ 1 and 2 onty. (b) 2 and 9 only (© Yand 3 only A 2and 9 Gas that can not be collected over water is: m0, (503 omy In thiosulphuric acid: (@ each sulphur atom is in identical oxidation state ()) there is a S=S linkage present (©) one $ atom is in +2 and other sulphur atom is in +4 oxidation state (@) there is only one replaceable hyulrogen atom One gas bleaches the colour of flowers by redution, while the other by oxidation, the (wo _gases respectively are: (a) CO and Cl (b) H,Sand Bry (©) NH; and S04 (@) SO, and ly Which of the following halides cannot be hydrolysed at room temperature? @ Ter, @) SE, aut) Nel, VY) NF, Choose the correct code: (@) Mand W (b) 1, Hand ti © 1wana (a) Mond V By which of the following methods, HO, can't be synthesised? (@) Lewis addition of ice cold H3S0, on BAO, (b) Addition of ice cold H,S0, on PLO, (© Aerial oxidation of 2-cthyl anthraguinol (@) Electrolysis of (NH,.)2S0, at a high current density, Give the correct order of initials T or F for following statements. Use Tif statement is true and F if its false. @) Number of S—S bonds in H,8,0¢ are (n +1) (a) When F, reacts with water gives HE,O, and O, (it) LNO, and BaCl; compounds are used in fire works {v) Be and Mg hydrides are ionic and polymeric (a) FITE () FITT (© THT ore Which of the following parent oxy acid does not have its hypo acid ? (a) H;S0z () HNO, HPO, (@) CIO, ‘Which pair of elements can from multiple bond with itself and oxygen? EN @) N.C NP @Nc Consider the following reactions : (i) PCL, +3H,0 — HsPOs + 3HCL Gi SP, +3H,0 —+ 1,80, + 4HF Gi) BCL, + 34,0 — H;BO, +3HCl Gv) Xe, +310 — Xe0, + 6HF ‘Then according to given information the Incorrect statement is:rh @ During the (@ reaction the hybridisation of 15th group element does not chan {}) During the (iD reaction the hybridisation of 16th group element has been changed {e) During the (i) reaction the hybridisation of 13th group element does not change (a) During the (Gv) reaction the hybridisation of 18:h group element does nor change 68. Consider the oxy acids HCIO, series, here value of n is 1 10 4, Then incorrect statement regarding these oxy acids is {@) Acidic character of oxy acids increases with increasing value of r. (D) oxidising power of oxy acids increases with decreasing value of n. (© Thermal stability of oxy acids decreases with increasing value of n. (@ CO bond order decreases with decreasing value of = 69. The correct statement regarding CIO; molecular ion is = (@) On decreasing value of 1’, ‘C-O" bond order increases (©) On incressing value of 7, LO" bond length increases (©) On increasing value of n, oxidation number of central atom increases (¢) On increasing value of n, hybrid orbitals on central atom increase 10,0) -HF— P+ IFH™ of acid HF attaches with Q. then correct option for hybridization of Cl-atom and Z0C!)0 in the P and Q ions = (@) Ps sp*s> 120° ©) Qsp?; 10928" {c) P:sp5;< 109928" (@) Q:sp*;> 109°28" 71. Bromine is commercially prepared from sea water by displacement reaction Cl; + 2Br- (oq) —> 2C1"(aq) + Br Br, gas thus formed is dissolved into solution of NaCO, and then pure Br. is obtained by ‘treatment of the solution with : (@) Ca(OH); (b) NaOH (H,80, wn 7. Which of the following properties of halogens increase with increasing atomic number? (Ionization energy onic radius (Ul) Bond energy of the X, molecule (IV) Enthalpy of vaporisation (a) 1, 0, Wl ® Lm oun @ Vv 73. Predict the corect product when Gls passed through H—O—O—H solution (a) H® +C1> +0, (both oxygen having 18) ° (b) HOCLand HCIO, (all oxygen having 18) (© HCO, and HCI (all oxygen having 18) (4) 1,0 and H,0 (all oxygen having 18) 74. Cx(g) + Ba(OH), —> X(aq.) +BaCl + H,0 X+HS0, —+ ¥ +850, vate £140,Yond Z are respectively (@) HClO,,clo, © Hcio,,clo, (© HCIO;, Clog @ HCO,, c1,0, 75. Auto-oxidation of bleaching powder gives: (@) only caleium chlorate (@) only calcium chloride (©) only caletum hypochlorite (4) both (@) and (6) 76. Which is incorrectly marched? (@) 4,0) = 1 +3105 () 1,0, = 10" +103 (© GsBry A Ost + Bry (@) None of these 77. The three elements X,Y and Z with electronic configurations shown below all form hydrides: Element Electronic configuration x astastap? Y s%2s22p*3s! Zz 1s?2st2p*3s*3p°3d'?4s74p° Which set of properties match correctly with properties of the hydrides of these elements: Hydride of X Hydride of ¥ Hydride of Z (@) Colourless gas insoluble Silver/grey solid reacts Colourless gas, forms a inH,0 with H,0 toform an alkali strong acid in HzO (4) Colourless liquid, m0 Silver/grey solid formsH., Tonic solid with formula reaction with H20 and H,0 ZH (© Nonpolar compound Silver/grey ionic solkd Forms when water is reacts with Cl, in light with formula YH, added to phosphorus and ‘elemental Z, (4) colourless gas which Silver/grey solid which Colourless, corrosive burns with air reacts violently with acids liquid at STP 78, ‘The incorrect order is : (@) HF < HCl < HBr < HT: Acidic strength (b) HE > HCl > HBr > HI: Thermal stability (©) HF > HCl > HBr > HI: Boiling point | (a) HF > HCl > HBr > HI : Bond dissociation enthalpy Tee rene Chr Reem ee) 79, ‘The correct statement regarding perxenate fon (XeOS") is ¢ (a) It is polar species (b) It is a planar species (e) Xe—OF bond order is 1.33 {@) Molecular fon has only one ype of bond angle 80. XeF, and XeF, are separately hydrolysed then: (@ both give out 02 (b) XePs gives O, and XeF, does not (© XeF; alone gives O2 (€) Neither of them gives HF322 82. 83. 84. 85. 86. 87. 89. MF +XeP, —» ‘A’ (M~ = Alkali metal cation) ‘The state of hybridisation of the central atom in ‘A and shape of the species are: (a) spd, TBP @&) sp°d?, distorted octahedral © sp%d°, pentagonal planar (@) No compound formed at all Xenon tetrafluoride, XeF', is: (a) tetrahedral and acts as a fluoride donor with SbFs (b) square planar and acts as a fluoride donor with PFs (c) square planar and acts as fluoride donor with NaF (d) see-saw shape and acts as @ fluoride donor with As, XeF, dissolves in anhydrous HF to give a good conducting solution which contains: (a) H* and XeF> ion (b) HF and XeFé ions (©) HXeF} and F~ ions (d) none of these Which of the following is nor true about helium? (a) It has the lowest boiling point (b) It bas the highest first ionization energy (©) It can diffuse through rubber and plastic material (@) It can form clathrate compounds SbF, reacts with XeF, to form an adduct. The shapes of cation and anion in the adduct are respectively: (@) square planar, trigonal bipyramidal (b) T-shaped, octahedral (©) square pyramidal, octahedral (@) square planar, octahedral Consider the following transformations: (D) Xer, +NaF —> Na*[Xer, 7" OD 2PC1,() —+ [Palg)* Pag” (al) [AIGH,0),}** +H,0 —» [AI(H,0),0H]** +H,0* Possible transformations are: @ 41,1 ©) 1m un @) um Which of the following is an uncommon hydrolysis product of XeF, and XeR,? (@) Xe (b) XeOs, OHF (@o, Incorrect statement regarding following reactions is : FEICESHO ey yp XeFe— L220 yy up (a) 'X'is explosive (b) ‘Y's an oxyacid of xenon (©) Both are example of non-redox reaction (@) XeF, can undergo partial hydrolysis Which of the following noble gas does not form clathrate compound? (a) Kr (b) Ne (Xe @) ar90. Correct order of bond angle in given species is : (a) SIOf” > PCly > NCL, > SbH, >H,Te (b) SIOf” >NCly > PCI > SbH, > HzTe {¢) SiOD >H,Te> SbH, > PCI; > NCly (d) NCI; > PC; > SIO4” > Sb, > HzTe 91. ‘The incorrect order is (a) N > P > As: Strength of r-bond with oxygen atom () SiP, > SiCl, > SiBr, > Sil, : Thermal stability (©) HzS>H,Se>H,Te: Arrhenious acid character (@) CaBr, > MgBr, > BeBr, : Mekting point 92, Among the following, cyclic species are : HPO. (U) [B,0;(0H)s]* (IN HPs OY) PaNaCls @ 1, ut 1, m,1V On, u,v @1n 0, 98. The substance that has the lowest boiling point is @ Hel ) HS (© PHs @ Sit, 94. Which of the following molecule can show Lewis acidisy? @ co, ) Br (uD sacl, @) HE ) NMe, @ m1 ©) L100 © Lu, (@ u,m,Vv 95. Molecule having non-polar as well as polar bonds but the molecule as a whole is polar = (a) (SCN). (b) C105 (© BC, @LOs 96. Which of the following order is incorrect ? (a) Lewis basic character : NH >PH, > AsH > SbHs (b) Bond dissociation energy + ‘HF >HC! > HBr > HI (c) Thermal stability : H,0 > H,S>H,Se>H,Te (@ Bond angle : CH, > Sift, > GeH, > Sok, 97. Which of the following does not undergo Lewis acid-base reaction ? (@) co, +H,0 @) AG, +cr (© SF. + BPs (@) BOOM), +H,0Each oxy-acid contains at least one X—OH unit (Cis non-metal). The H-atom of A—OH unit {sonable and the numberof —OH groups directly stach ‘non-metal decides the basicity oxy-acid. Which of the following oxy-acid does not have its peroxy form having two central atoms? (a) H,S0, (b) HNO, (©) H;PO, (¢) None ‘Which of the following hypoform of oxy-acid can exhibit tautomerism ? (a) HaN 302 @) H,?,0, (©) H,S,0¢ @) HPO, ‘Which of the Following oxyanion of Pyro acid has different oxidation state of central atom? (a) 807° ©) Si,0$ (©) 8,02" (@ None vase 2a” eo Formation of a bridge bond is best explained by molecular orbital theory. Acoording to which a bridge bond is formed by filing electrons into molecular orbital which spread over three ‘nuclei hence such bonds are specified a5 three centered bond. Z In which of the following dimer empty atomic orbital of central atom of monomer does 101 involve in hybridization: @ Ga,H, () AL Beg (© Be, (@c,0, In which of the following compound hybridization of bridging atom is different from hybridisation of central atom : @AL(NH Ds )1,Cl, (© Solid BeCl, @ ACOH), Which of che following compound is having maximum number of atoms in same plane ? (a) Al;Meg ©) BH, (©) BesHa @ CH,(Passage > | " , Question No. 1 to 3 (8 quer @ P+ (carbon) +ci, ab ascot Gi) BNF HO —s R+NH,t Gv) Q+ LIAL, —> S+Licl+alcl, @) S+H, —+ Rvn,t () $+NaH — T @ QR, Sand T do not represent their chemical symbols) 1, Compound Q has: (© zero dipole moment (D an electron deficient compound Choose the correct code: @Lv OLtW Lam @ 10,0, 2, Compound T is used as a/an: (a) oxidising agent (b) complexing agent (¢) bleaching agent (4) reducing agent 3. Compound S is: (@ an odd-e~ compound ID (2c =3e) compound (WU) a electron deficient compound (WV) a sp? hybridized compound Choose the correct code: @ m (b) ©1mv @ Luv | OO © aH © © . Yellow ppt. Gives blue colour Brown Gi) Q4+H,0 —+ R+HCI (QD a planar trigonal structure GY) a Lewis base yey to the flame Ges cdo FeS0y | ius +H,80, OoA™=O0+O0 © Black ppt. Were i) onal 1, Compound (D) +1" +H” —> Gas gos is similar to Sarcat (b) Gas-G (© Gast @) None