Sec: JR.

IIT_*COSC(MODEL-A) WAT-12 Date: 30-06-24

Time: 3 Hrs 2017_P1 Max. Marks: 183
KEY SHEET
MATHEMATICS
1 AD 2 ACD 3 ACD 4 ABC 5 C
6 ABC 7 ABD 8 8 9 1 10 9
11 3 12 2 13 C 14 A 15 D

16 D 17 A 18 C

PHYSICS
19 ABCD 20 ABCD 21 ACD 22 BCD 23 BC
24 ABD 25 BD 26 1 27 4 28 8
29 0 30 5 31 B 32 C 33 A

34 B 35 A 36 D

CHEMISTRY
37 BC 38 ABCD 39 BD 40 AB 41 BC

42 BCD 43 AB 44 8 45 2 46 3

47 5 48 3 49 C 50 A 51 A

52 B 53 A 54 B
Narayana IIT Academy 30-06-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-12_KEY&SOL
SOLUTIONS
MATHEMATICS
n 1
1. G. E    cos 2  cos 2      cos 2   2   ...... n terms 
2 2

where  
n
n 1 n
G . E    0   which is independent of 
2 2 2

2. u 2  a 2  b2  2 a 2
cos 2   b 2 sin2   a 2 sin 2   b2 cos2  
 a 2  b2  2 a 4
 b 4  sin2  cos 2   a 2b 2  cos 4   sin4  

 a 2  b2  2 a 4
 b 4  sin2  cos 2   a 2b 2 1  2 sin2  cos 2  

 a 2  b2  2 a 2b 2   a 2  b 2  sin2  cos2 
2

a  b2 
2 2

 a b 2 a b
2 2 2 2
 sin2 2
4
3. A)  
f  4  x   sin   4  x  
2 
    
 sin   4   x    sin  2   x  
2   2 
 
 sin   x    f  x 
 2 
B) sin2 x  cos 2 x  sin2 x  1  sin2 x 
2

 sin 2 x  1  sin4 x  2 sin2 x

 1  sin 4 x  sin2 x  cos 2 x  sin 4 x
h  x   1 x

C) g  x  is periodic with period 2

D)   x   sin   x    x   1  x
  x   0  1   x  1   x
  x  is periodic with period 1

4. Maximum value of
f  x  c   ab   b 2 1  a 2   c  b
2

Maximum value of f  x  c  b
5. cos ecx  1  1 if cos ecx  2

tan x  1 if x 
4

2 sin 3x  1 if x 
18
but sin x  4  3, 5

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Narayana IIT Academy 30-06-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-12_KEY&SOL
6.
f n     cos   cos 2    cos 2  cos 3    cos 3  cos 4   ......   cos n  cos  n  1 
 cos   cos  n  1 
sin x cos x tan x cot x
7. f  x    
sin x cos x tan x cot x
 4, x  1st Quadrant
 2 x  2nd Quadrant

f  x  
0 x  3rd Quadrant
2 x  4th Quadrant
0
P 4 tan1 4 tan 20 4 tan 30 4 tan100
8.     .......
R 1  tan2 10 1  tan2 20 1  tan2 30 1  tan2 100
 2. tan 20  2 tan 40  2 tan 60  ......  2 tan 200  210.Q
P  210 QR ,   210
 x x
sin    1  x 2  2 x   2  sin    1   x   
2
9.
2 2
LHS  0 and RHS  0
Then solution is obtained if LHS=RHS=0 and x  satisfies both.
10. Let    x   then
f1  x   sin  
 12 
   x  24     x   24 
f1  x  24   sin    sin  
 12   12 
   x     x 
 sin  2    sin    f1  x 
 12   12 
f1  x  is periodic with period 24

Similarly tan    x   is periodic with period 3

 
 3 
   x   is periodic with period 8
cos  
 4 
 period of f  x  is 24.
11. cos2 1  sin2  2  .....  sin2 10
By cauchy schwartz inequality
sin  2  sin 3  ......  sin 10  
1   .... 1 sin2  2  .......  sin2 10
1
9 times

  sin  2  ........ sin10   9  sin2  2  .......  sin2 10 

2

 sin2  .......  sin10 

2

sin  2  sin 3  .......  sin

2 2 2
10 
9
sin  2  .....  sin 10
cos 1 
3
sin 1  sin  3 ......  sin10
similarly cos  2 
3
sin 1  .....  sin 9
cos 10  .........
3

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Narayana IIT Academy 30-06-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-12_KEY&SOL
1
cos 1  .....  cos 10 
3
9  sin1  .....  sin10 
cos 1  cos  2  .....  cos 10
 3
sin1  s i n  2  .....  sin 10
2
  x    x  
12. f  x    2 cos2     2 cos  2 
 4  2 
2
 
2
  x    x  
2  
 1  cos     2 cos   2 cos 2   1  cos 2 
 2  2 
2
 
 x  
 1  cos2  
 2
2

Period of 
f  x   2 3
 1 
 2
 2 
13, 14, 15
I) f x  7  6t  t where t  tan x
2
 
1 t2
7  6t  t 2
y
1 t2
y  yt 2  7  6t  t 2   y  1 t 2  6t  y  7  0
0
 36  4  y  1 y  7   0  y 2  6 y  16  0
  y  8  y  2   0  y   2, 8
II)
   13 3 3
f  x   5 cos x  3  cos x cos  sin x sin   3  cos x  sin x
 3 3 2 2
169 27
f max  3    10
4 4
169 27
fmin  3    4
4 4
III)
f  x   3 sin x 
2
 2.3 sin x.5  25
 3 sin x  5  5  3 sin x
f max  8 f min  2
IV)
f  x   3 sin x  10    4 cos x   25 sin2 x  60 sin x  84
2 2

 5 sin x   2  5 sin x  .6  36  48   5 sin x  6 

2 2
  48

 5  1  6 
2
f max   48  13

 5 1  6 
2
f min   48  7

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Narayana IIT Academy 30-06-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-12_KEY&SOL
16, 17, 18.
4
x 
I) Period of ecos is 1

 
Period of x  x is 1
Period of cos 2  x is   1

II) Period of 2 x is 1
2
 
III) Fundamental period of cos sin  x  sin x  is 2

IV) Period of  x x
cos5    sin5   is 2  
2 2 1
2
PHYSICS
6mg 3mg
19. Slipping will first start between A – B & C – O at & between hand and A will occur at
 2
20. If there is friction & rope is massless
dT  dN
& dN  Td
T  gy
21. a  2r  
r
2 2  w  
w 2R  2Rw      5R
5 5 5 
 6w 2

2s
22. To minimize time, maximize the avg acc.

23. acc. Of p wrt A & B will be same. Use the concept of rotating frame.
24.

26. Angle rotated by velocity vector in dt time is same as that at centre of curvature in dt time
dv
Ft  m
dt
v 2 mv 2
Fn  m  d
R vdt
Ft dv

Fn vd

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T
27.  .1a
2
T
1  .1a
2

29. VB  VA tan 
d
a B  a A tan   VA sec2 
dt
d VA

dt R cos 
Putting the values.
aB  0
30.

V
V1  (  x)

dV1 vd  1  x 
Tangential acceleration of P    
dt dt   
v 2 Rx
at  3

31-33.

v sin 60
w Po 
r
Normal component of acc. = wv
34-36.

Check for static or kinetic friction.

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Narayana IIT Academy 30-06-24_JR.STAR CO-SC(MODEL-B)_JEE-ADV_WAT-12_KEY&SOL
CHEMISTRY
37. Conceptual
1  d  NH 3  1 d  H 2O 
38. A)  
4 dt 6 dt
1 1 d  H 2O  d  H 2O 
 3.6  103     5.4  103 M S 1
4 6 dt dt
 Ea / RT
C) K  Ae T  K  A
K 2
D) 1  i.e K1  K 2
K2 1
 Ea / RT
K  Ae
If K is high, Ea is low. E2  E1
2.303 a
39. Use initial rate law method, let the reaction be first order, So, k  log
t ax
2.303  0.4 
b. At t=20 s, k1  log  
20  0.2 
2.303  0.4 
and at t  40 s, k2  log  
40  0.2 
 Assumption is correct  k1  k2 
0.693
Rate at 20 s  k  A   0.2
20
 0.0063  7 103 Ms 1
Clearly, half life t1/2  20 s
60
d. In 60 s, number of life  3
20
  B  at 60 s
3
1
 0.4  0.4    0.35
2
40.
41. rate determining step is the slowest step. H Of reaction   ve
A t t
d [ A]
42.  1/2
 k  dt (for integrated form)
A0
[ A ] t 0
A0 /2 t t1/ 2
d [ A]
 
A0
[ A]1/2
k 
t 0
dt (for half-life)

dCB 1 dnB 1 d (CB .V )

43. rB   
dt V dt V dt
V dCB CB dV dCB CB dV
   
V dt V dt dt Vdt

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dy
 k 0.6
2
44.
dx
0.09  k 0.6
2

k  0.25
r  k 0.8  0.16
2

0.693
45. r1  a
T
1
r 2  a
2

aT
46. Let order with respect to NO be “x” and that of H 2 be “y”
x y
 dp  1.5  360  1.6  300 
r    ;    x  2;    y  1.
 dt  0.25  150  0.8  150 
Over all order of reaction = 3
47. 
 3B
A 

At t  0 a -
At t  t a-x 3x
At time ' t ' (a-x)  3x
 a  4x
2.303 4x 0.693 2.303 4
K log  log
t 3x t1/2 t 3
t1/2  4.82 min
 t1/2  5.0min
(i) Addition of NaOH will decrease  H 3O  .

48.
(ii) Addition of water will decrease the concentration of both.
(iii) Acetic acid is a weak acid and hence,  H 3O  will decrease.


(iv) Increase in temperature increases the reaction rate.

49. Conceptual
50. Conceptual
51. Conceptual
52. Conceptual
53. Conceptual
54. Conceptual

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