Narayana IIT Academy 30-06-24_JR.

IIT_*CO-SC(MODEL-A)_JEE-MAIN_CTM-1_KEY&SOL

Sec: JR_*CO-SC(MODEL-A) CTM-1 Date: 30-06-24

Time: 3 Hrs JEE-MAIN Max. Marks: 300
KEY SHEET
PHYSICS
1 C 2 D 3 B 4 C 5 C
6 A 7 A 8 D 9 C 10 C
11 D 12 A 13 A 14 D 15 A
16 B 17 D 18 B 19 A 20 B
21 6 22 306 23 5 24 11 25 25
26 1 27 6 28 2 29 2 30 4

CHEMISTRY
31 B 32 B 33 D 34 A 35 B
36 A 37 D 38 C 39 C 40 A
41 A 42 A 43 A 44 B 45 D
46 D 47 C 48 B 49 B 50 B
51 4.3 52 4 53 539 54 5 55 9.04
56 3 57 3 58 1 59 20 60 40

MATHEMATICS
61 A 62 A 63 A 64 B 65 D
66 C 67 D 68 D 69 A 70 B
71 B 72 A 73 B 74 B 75 C
76 C 77 A 78 C 79 D 80 B
81 6 82 4 83 2 84 8 85 2
86 1 87 40 88 7 89 5 90 125

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Narayana IIT Academy 30-06-24_JR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_CTM-1_KEY&SOL
SOLUTIONS
PHYSICS
dy
1.  0  x  3x  6   0
dx
2. a v  g sin 2 
nv 1
3. t & H  gt 2  vt
g 2
1 1 3H
H  g  2t  & H  h  gt 2  h 
2
4.
2 2 4
2
 dv  mV
5. f  mg  m   & T 
 dt  R
6. 8t  4  vt sin  & vt  2sec 
7. F x 0 & F 4 0
8. mg sin   mg  mg cos 

 mg    ma 
2 2
9. T  ma
g mAg
10. a 
 mA  M  m
2
12. ma1  ma cos    m a sin  & t 
a1
V2
13. r
a
14. H  costant & R 1  R  H
g
15. a m  g    & a 2m    
2

19. 2t sin    mr2 &   2h
2
20. w  2ma
g
21. a B  a x2  a 2y & a x  a y 
4
22. T sin   m A g  f1 & f1    T cos  
24. T1 cos   mg  T2 cos 
5g 4g
25. a ij  & a ij 
6 5
2
26. t 1
& a 1  a 0 cos   g sin 
a
mg 
27. Fmin 
2  1
28. FNet  f  & blocks are at rest
2R
29. Varg 
t
 
30.  t & VA 
4 t

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Narayana IIT Academy 30-06-24_JR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_CTM-1_KEY&SOL
CHEMISTRY
31. Conceptual
n
32. C
V
33. Mole fraction of solute
number of moles of solute + number of moles of solvent
=
number of moles of solute
wSolute
nSolute MwSolute
 Solute  
nSolute  nSolute w w
Solute
 Solute
MwSolute MwSolute
Given, wSolute  wNaOH  8 g
MwSolute  MwNaOH  40 g mol 1
wSolvent  wH 2O  18 g ;
MwSolvent  18 g mol 1
8 / 40
  Solute   NaOH 
8 / 40  18 / 18
0.2 0.2
  0.167
0.2  1 1.2
moles of solute
Now, molality  m  
Mass of solvent (in kg)
wSolute
MwSolute
  100
wSolvent (in g )
8 / 40 0.2
 1000  1000
18 18
 11.11 mol kg 1
34. U  nCv T 
T2

 n   20  102 T   4700 J
T1

CP  nCP T  6362.8J
35. C3 H 8  g   O2  g   CO2  g   H 2O  g 
This reaction is not correct according to the law of conservation of mass, because it is not the
balanced chemical equation.
36. pV  constant at constant temperature. Higher curves corresponds to higher temperatue. Hence, the
correct order is T3  T2  T1
37. We know that,
w
No. of moles  n  
M
For O2 w  70.6 g , M  32 g mol 1
70.6 g
No. of moles of O2  n1    2.21 mol
32 g mol 1
For Ne, w  167.5 g , M  20 g mol 1

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Narayana IIT Academy 30-06-24_JR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_CTM-1_KEY&SOL
167.5 g
No. of moles of Ne  n2    8.375 mol
20 gmol 1
n1
Mole fraction of O2  1  
n1  n2
2.21
  0.21
2.21  8.375
Mole fraction of Ne   2   1  1
1  0.21   2  1  1 
 2  0.79
Partial pressure of a gas  Mole fraction  total pressure
Partial pressure of O2  0.21  25  5.25 bar
Partial pressure of Ne  0.79  25  19.75 bar
w
38. Number of moles of A, nA  A
MA
0.50
  0.0083
60
w 0.20
Number of moles of B, nB  B   0.0044
MB 45
Total pressure  PT   750 mm of Hg
PA  mole fraction of A   A   total pressure  pT 
nA
Mole fraction of A,   A    pT
n A  nB
0.0083
  750  490 mm
0.0083  0.0044
p B  750  490  260 mm
39. Conceptual
40. Given, V2  375 mL , V1  50 mL , n  0.04 mol
T  310 K , q  208 J
 The process is isothermal expansion, hence
q  W and E  0
V
Now, W  2.303n RT log 2
V1
375
 2.303  0.04  8.314  310  log
50
 208 J
 q  208 J ,
W  208J (expansion work)
41. Key concept Relation between heat of reaction   r H  and bond energies (BE) of reactions and
products is given by,
 r H   BERe ac tan ts   BEPr oducts
The reaction of formation for XY is given as,
1 1
X 2  g   Y2  g   XY  g  ; H  200kJmol 1
2 2

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Given, the bond dissociation energies of X 2 , Y2 and XY are in the ratio 1: 05 :1 . Let the bond
dissociation energies of X 2 ,Y2 and XY are a kJ mol 1 , 0.5a kJmol 1 and a kJ mol 1 , respectively.
  r H   BERe ac tan ts  BEPr oducts
1 1 
200    a   0.5a   1 a 
2 2 
a a
  a
2 4
2a  a  4a  a
200  
4 4
1
a  800 kJ mol
 The bond dissociation energy of X 2 will be
X 2  akJ mol 1
 800 kJ mol 1
42. The conversion of 1 kg of ice at 273 K into water vapours at 383 K takes place as follows

H Fusion 334kJkg 1
S1    1.22kJ kg 1 K 1
TFusion 273K
T  373K 
S 2  C ln 2  4.2kJ K 1 kg 1 ln  
T1  273K 
 4.2  2.303  log 373  log 273  kJ K 1 Kg 1
 4.2  2.303  2.572  2.436   1.31 kJ K 1 Kg 1
H vap 2491 kj kg 1
S3    6.67 kJ kg 1 K 1
Tvap 373 K
T2  383K 
S 4  C ln  2 kJ K 1 kg 1 ln  
T1  373K 
 2  2.303  log 383  log 373 kJ K 1 kg 1
 2  2.303  2.583  2.572  kJ K 1 kg 1
 0.05 kJK 1 kg 1
 STotal   S1   S 2   S 3   S 4
 1.22  1.31  6.67  0.05
 9.26 kJ kg 1 K 1
43. Required equation for the formation of 1 mole of methane,  CH 4  is given by
Given, C  g   2 H 2  g  
 CH 4  g  ;  f H   ?
i  The enthalpy of combustion of 1 mole of methane is
CH 4  g   2O2  g  
 CO2  g   2 H 2O  l  ; H  890.3 kJ mol 1

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 ii  The enthalpy of combustion of 1 mole of graphite is
C  s   O2  g   CO2  g  ; H  393.5 kJ mol 1
 iii  The enthalpy of combustion of 1 mole of dihydrogen is
1
H 2  g   O2  g    H 2O  l  ; H  285.8kJ mol 1
2
Multiplying Eq.  iii  by 2, we get
 iv  2 H 2  g   O2  g  
 2 H 2O  l  ; H  571.6kJ mol 1
Adding Eqs. (ii) and (iv), we get
 v C  s   2 H 2  g   2O2  g    CO2  g   2 H 2  l  ; H  965.1 kJ mol 1
Reversing Eq. (i) we get,
 vi  CO2  g   2 H 2O  l    CH 4  g   2O2  g  ; H  890.3 kJ mol 1
Adding Eq. (v) and (vi) , we get required equation
C  s   2 H 2  g    CH 4  g  ; H  74.8 kJ mol 1

Add
44. External energy (U) is a state function as it depends only upon the state of the system (i.e. initial and
final states) and does not depend on path.
Moreover, temperature (T) is an intensive property as it does not depend on the quantity Thus, both
A and R are correct but R is not the correct explanation of A.
45. No solutions
46. No solutiosn
47.
A  2 B  2C  D
Intial moles 1.1 2.2 0 0
Moles at equil. 1.0 2.0 0.2 0.1

Equilibrium constant for the reaction 

 C   D
2

 A B 2
K 
 0.2 / V   0.1/ V 
2

 0.001
1/ V  2 / V 2
Ea

48. K  A.e RT
49. Molar mass of NH 4 SH  18  33  51g mol 1
Number of moles of NH 4 SH introduced in the
Weight 5.1
vessel =   0.1 mol
Molar mass 51

 NH 3  H 2 S   0.01 0.01  104 molL1 2

KC 
 NH 4 HS  s   1
 

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 K p  K C  RT 
ng

 where, Δn g =  n product - n reactant   2  0  2

 K p  K C  RT 
2

 104  0.082   273  327   atm2

2

 0.242 atm 2
50. Given G  2494.2 J
1 1
 A  ;  B   2; C  
2 2
R  8.314 J / K mol
For the reaction, 2A  B  C
1
2 
Q
 B C   2 4
 A2
1/ 2 2
 We know that,
G  G  RT ln Q
 2494.2  8.314  300 ln 4
 5951.89J  ve value 
Also, we have G  RT ln Q / K ,
If G is positive Q / K C
Therefore, reaction shifts in reverse direction.
M M
51. 75mL HCl  25mL NaOH
5 5
M 1
Milliequivalent of HCl  75mL of HCl   75  15
5 5
M 1
Milliequivalent of NaOH  25mL of NaOH   25  5
5 5
 Milliequivalent of HCl left unused  15  5  10
Volume of solution  100 mL
10 1
 Molarity of  H  in the resulting mixture 


100 10
1
 pH  log  log 10   1
H  
 
52. PbCl2   Pb 2  2Cl 
S S 2S

 
3
K sp  S  2 S   4 S 3  4  102
2
 4 106

In 0.1M NaCl , Cl    0.1  2 102  0.1M

As 0.1MPbCl2  0.02M Cl 
2
 Pb 2  Cl    K sp
  
Or  Pb   0.10   4 106
2 2

Or  Pb2   4 104 M

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53. AgCl  s   Ag   aq   Cl   aq 
K sp of AgCl   Ag   Cl    1.8 1010 .....  i 

Now,  Ag  NH 3 2   aq   Ag   aq   2 NH 3  aq 
 Ag    NH 3 2
 KC   

 6.2  108 ....  ii 
 Ag  NH 3 2 
From eq. (i) and (ii) , we get
KC

 NH 3  2

....  iii 
Lsp  Ag  NH    Cl  
 3 2  

AgCl  2 NH 3   Ag  NH 3  2   Cl 
1 0 0
1 a a a
Thus, on substituting the values in eq. (iii), we get
6.2  10 8 1
10
 2 or, a  0.0539M
1.8  10 a

54. Given, pH of Ba  OH 2  12
pOH  14  pH  14  12  2
We know that, pOH   log OH   2   log OH    OH    102
Ba  OH 2 dissolve in water as
Ba  OH 2  Ba 2  2OH 
S 2S
Smol L1

OH    2S  102
 
10  2 2

K sp   Ba  OH   10
2  2
 2
 
2
6 7
 0.5  10  5  10
2
55. Given that, K sp Mg  OH  2   Mg 2  OH  
2
1.2 1011   0.1 OH  
2
OH    1.2 1010
 
OH    1.0954 105 M
 

pOH   log 1.0954 105  4.96 
pH  14  4.96  9.04
Thus, at 9.04 pH, precipitation will not take place.
K Ea  T2  T1 
60. log 2   
K1 2.303R  T1  T2 
0.693
K
t1/ 2

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MATHS
62. a  c  2b........(1)
a,b,c forms a triangle then a  b  c, b  c  a,a  b  c
 3b  2c and 2c  b
2 b
  2
3 c
63. For the equation to have four distinct real roots, the line y = k must intersect
y x 2  bx  c at four distinct points.
 b 2  4c 
 b  4c  0 and k   0,
2

 4 
cos 2q sin 2n q
64. 1  Tan 2 q  and cos q and cos 2q cos 22 q …… cos 2 n 1 q  n
cos q 2 sin q

a1  a 3 a  a4 a  a 2012 a a
65. a2  ;a 3  2 , a1  2 ;.......a 2012  2011 1
2 2 2 2
a 2  a 4  ....  a 2012  3018 - (1)
2a 2  2a 4  .....  2a 2012  6036
a 1  a 3  a 3  a 5  .....  a 2011  a 1  6036
2  a1  a 3  .....  a 2011   6036
a 1  a 3  .....  a 2011  3018 -(2)
(1)  (2)  a1  a 2  .....  a 2011  6036
1 1 1 1 1
66. 1     ...  
2 3 4 199 200
 1 1 1 1  1 1 1 
  1     ....    2    ...  
 2 3 4 200   2 4 200 
 1 1 1 1  1 1 1 1 1 
  1     ....    2   1     ...  
 2 3 4 200  2 2 3 4 100 
1 1 1 1
    .....   M  200
101 102 103 200
69. Let x1 , x 2 , x 3 , x 4 , x 5 , x 6 are roots of the equations then their
AM  2
GM  2  roots are equational
 x1  x 2  ......  x 6  2
f  x    x  2   x 6  12x 5  ax 4  bx 3  cx 2  d
6

a  60, b  160,c  240,d  192

a  b  c  d  140  192  52
70. By C-S-inequality
4a  1  4b  1  4c  1

 4 a  b  c  3 1  1  1
24  3 3
3 3  b  9
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Narayana IIT Academy 30-06-24_JR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_CTM-1_KEY&SOL
71. D1  p 2  12q; D2  r 2  4q; D3  s 2  8q
Case-I: If q < 0 then D1  0, D3  0 and D2 may or may not be +ve
Case-II: If q > 0 then D2  0 and D1 , D3 may or may not be +ve
So, given equations has at least two real roots.
n 1
72. M of 1,2,3,…. n 
2
If k, k + 1 are removed then
n  n  1   2k  1
AM =
n2
n  1 n  n  1  2  2k  1
1   n  k 1
2 2  n  2
  360
p 360  1 n 1  n 360
 1 1 
73.       
   
q n 1  n n  1 n  n  1  n 1 n n  1  n  1  n  n 1  n n 1 

 1   1 1   1 1  1 18
 1      ....      1  19  19
 2  2 3  360 360 
 p  q 1
 5 1
74. 4cos 36  4   5 1
 4 
 3 1
1  
 1  1  cos 15   2 2 
cos  7      6 3 2 4
 2  sin15 3 1
2 2
75. log 3 sin x  log 3 cos x  log 3 1  tan x   log 3 1  tan x   1
 tan x  tan x 1 2
log 3    1    tan 2 x 
 1  tan x  1  tan x 3 3
2 2

76. As the difference of roots of f  x   0 and g  x   0 are equal

D1 D2
Then 
a1 a2
Now minimum value of
D1   p  4q 
2
1
f  x    
4a1 4 4
4s  r 2
1
    r 2  4 s  1.... 1
4 4
Least value of g  x  occurs at
b2 r 7
x  
2 a2 2 2
 s  12  g  x   x 2  7 x  12  0
 x  3, 4

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Narayana IIT Academy 30-06-24_JR.IIT_*CO-SC(MODEL-A)_JEE-MAIN_CTM-1_KEY&SOL
 s  12  g  x   x 2  7 x  12  0
8 8
 tan  r  1 A  tan  rA  tan A  tan 9 A  9 tan A
78.  tan  rA  tan  r  1 A   
r 1  tan A

tan A
 10
r 1 
x 1
80. tan   
z 3
y 1
tan   
z 2
tan   tan  
tan      1   
1  tan  tan  4
4sin 2    Sin   Sin  
2
83.
And 4Cos 2   4Cos  Cos 
Adding these equations, we get the result
 ac  b  ab  c    bc  a 
2 2 2 2
84.
a 2bc  ac 3  ab 3  b 2 c 2  b 2 c 2  a 4  2a 2bc
a 3  b3  c3  3abc
a 2 b2 c2 a 3  b 3  c3
 
2 bc ca ab
2 abc
 23  8

85. Let log 2x  y  y 2  y  y 2  1  2 y 2  y  1  0

1
y   ,1
2
Since log 2x  0, log 2x  1  x  2
88. x 2
 5 x  10  x 2  5 x  2   12  0
  x 2  5 x  10  x 2  5 x  10  8   12  0
  x 2  5 x  10   8  x 2  5 x  10   12  0
2

x 2  5 x  10  2,6
1 1 1 1 4
Required sum =    
2 2 6 6 3
x1  2 x2  3x3  4 x4  5 x5 1

89.   x1.x22 .x33 .x44 .x55 15

15
 x1  x2  x3  x4  x5  1
90.  1  12  48  64
 125  

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