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Exam
Name___________________________________
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
1) What is electricity? 1)
A) flow of protons B) flow of electrons
C) flow of neutrons D) flow of atoms
2) Which of the following does not have the same number of electrons when compared with the rest? 2)
A) O2- B) Mg 2+ C) F D) Ne
9) What is the oxidation state of the nitrogen atom in the compound NCl 3 ? 9)
A) 0 B) -3 C) +3 D) +5
10) What is the oxidation state of the carbon atom in the compound CO 2 ? 10)
A) +4 B) +2 C) +3 D) -2
11) Which atom(s) has a more positive oxidation state on the product side than the reactant side? 11)
Fe 2 O3 + 3CO → 2Fe + 3CO2
A) oxygen B) carbon
C) iron D) carbon and iron
12) Which atom(s) has a more negative oxidation state on the product side than the reactant side? 12)
Fe 2 O3 + 3CO → 2Fe + 3CO2
A) carbon B) iron
C) oxygen D) carbon and oxygen
1
13) In a chemical bond, which atom gets ownership the shared electrons? 13)
A) the more electronegative element B) the smaller element
C) the larger element D) the most electropositive element
14) In the water molecule, which atom holds the shared electrons between hydrogen and oxygen? 14)
A) hydrogen
B) both are shared equally
C) oxygen
D) One cannot say unless the state of water is known.
15) Which of the following elements may have more than one oxidation number? 15)
A) calcium B) hydrogen C) lithium D) sodium
16) Which of the following elements may have an oxidation number of +1 or -1? 16)
A) lithium B) potassium C) hydrogen D) sodium
17) Which of the following elements may have an oxidation number other than +2? 17)
A) iron B) magnesium C) calcium D) barium
18) Which of the following elements may not have an oxidation number of -1? 18)
A) fluorine B) chlorine C) hydrogen D) sodium
20) Which of the following elements may have a +3 charge when it becomes an ion? 20)
A) chlorine B) magnesium C) carbon D) aluminum
21) In which of the following is oxygen not at the -2 oxidation state? 21)
A) carbon dioxide B) methanol
C) hydrogen peroxide D) water
22) The only element that is more electronegative than oxygen is ________. 22)
A) nitrogen B) chlorine C) sulfur D) fluorine
24) What is the sum of the oxidation states in the following species H 2 SbO3 - ? 24)
A) -2 B) +2 C) 0 D) -1
25) The oxidation state of nitrogen in the ammonium ion is ________. 25)
A) -3 B) +1 C) -1 D) +3
26) The oxidation state of sulfur in the sulfate ion is ________. 26)
A) +7 B) +4 C) -2 D) +6
27) The oxidation state of chlorine in the perchlorate ion is ________. 27)
A) +8 B) -1 C) +6 D) +7
2
28) Identify the compound that contains bromine with a +3 oxidation state. 28)
A) NaBrO2 B) NaBrO 3 C) NaBrO4 D) NaBrO
31) Which of the following is true for the following reaction? 31)
Mg + O 2 → 2 MgO
A) Oxygen is reduced.
B) Magnesium is oxidized.
C) The oxidation state of magnesium in MgO is +2.
D) All of the above are true.
32) Which of the following is true for the following reaction? 32)
Cu + ZnCl 2 → CuCl2 + Zn
A) Cu is a reducing agent. B) Cu is oxidized.
C) Zn+2 is reduced. D) All of the above statements are correct.
33) Which of the following is true for the following reaction? 33)
Zn + CuCl2 → ZnCl 2 + Cu
A) The solution will turn blue.
B) The solution will turn from blue to light blue.
C) The gray zinc powder will disappear.
D) Both B and C are correct.
3
40) Identify the reducing agent in the following chemical process (a lead storage battery). 40)
Pb + PbO 2 + 2H + + 2HSO 4 - → 2PbSO4 + 2H 2 O
A) 2HSO 4 - B) PbO2 C) Pb D) H+
41) Identify the reduced species in the following chemical process (a lead storage battery). 41)
Pb + PbO 2 + 2H + + 2HSO 4 - → 2PbSO4 + 2H 2 O.
A) H+ B) PbO2 C) Pb D) 2HSO 4 -
42) Identify the oxidizing agent in the following chemical process. 42)
Fe + Cu(NO3 )2 → Fe(NO3 )2 + Cu
A) Cu B) NO3 - C) Cu+2 D) Fe
43) Identify the oxidized species in the following chemical process. 43)
Fe + Cu(NO3 )2 → Fe(NO3 )2 + Cu
A) Fe B) NO3 - C) Cu D) Cu+2
44) Identify the reducing agent in the following chemical process. 44)
Cu + 2AgCl → CuC12 + 2Ag
A) Cl- B) Ag+ C) Cu D) Ag
45) Identify the reduced species in the following chemical process. 45)
Cu + 2AgCl → CuC12 + 2Ag
A) Ag+ B) Ag C) Cl- D) Cu
46) Identify the equation that has the greatest number of electrons transferred. 46)
A) NaClO → NaClO2 B) CuCl → CuCl2
C) NaClO 2 → NaClO4 D) 2 Mg + O 2 → 2 MgO
47) Identify the equation that has the least number of electrons transferred 47)
A) 2 Mg + O 2 → 2 MgO B) NaClO 2 → NaClO4
C) CuCl → CuCl2 D) NaClO → NaClO2
4
50) Identify the element that was oxidized. 50)
3 P + 5 HNO3 + 2 H2 O → 5 NO + 3 H3 PO4
A) phosphorus
B) oxygen
C) nitrogen
D) No elements were either oxidized or reduced.
53) A fuel cell is essentially a battery which uses the following reaction to produce electricity. What is 53)
happening at the cathode of such a fuel cell?
2H2 + O 2 → 2H 2 O
A) Oxygen is being oxidized. B) Oxygen is being reduced.
C) Hydrogen is being oxidized. D) Nothing at all is happening there.
54) What chemical process is happening at the anode of a fuel cell, which uses the following reaction 54)
to generate electricity?
2H2 + O 2 → 2H 2 O
A) Nothing at all is happening there. B) Oxygen is being oxidized.
C) Oxygen is being reduced. D) Hydrogen is being oxidized.
57) Consult the EMF activity series and predict which of the following changes will occur if an iron 57)
nail is placed in an aqueous solution containing the (Sn 2+ ) ion.
A) Nothing at all will happen (no reaction). B) Tin will be further oxidized.
C) Iron will be oxidized. D) Iron will be reduced.
58) Consult the EMF activity series and predict which of the following changes will occur if an 24K 58)
gold ring (pure gold) is placed in an aqueous solution containing hydrochloric acid.
A) Nothing at all will happen (no reaction). B) Gold will be reduced.
C) Gold will be oxidized. D) Hydrogen will be further oxidized.
5
60) Which of the following is the most easily reduced? 60)
A) Au+ B) Na+ C) Hg2+ D) K+
TRUE/FALSE. Write 'T' if the statement is true and 'F' if the statement is false.
67) In a chemical reaction the easiest electrons to be transferred are the core electrons (also called inner 67)
shell electrons).
68) When drawing dot structures, lone pairs of electrons are assigned completely to the atom on which 68)
they are drawn on the dot diagram.
69) In a chemical bond the less electronegative element gets complete ownership of both the shared 69)
electrons.
73) The oxidation state of an atom in its natural occurring elemental form is always equal to zero. 73)
75) All four halogens, F, Cl, Br and I, are diatomic in their free state. 75)
76) The oxygen anion almost always has the charge of -2. 76)
6
77) The sum of the oxidation states of all atoms in a formula must add up to the overall charge of the 77)
formula.
79) The highest oxidation state that sulfur can have is +6. 79)
80) The lowest oxidation state sulfur can have is in the sulfite form. 80)
81) The oxidation state of metals is almost always a positive number. 81)
82) The oxidation state of non-metals is almost always a negative number. 82)
87) More active metals lose electrons to ions of less active metals. 87)
88) Corrosion of a ship's hull can be inhibited if another metal that is more active is attached to the 88)
hull.
SHORT ANSWER. Write the word or phrase that best completes each statement or answers the question.
91) Assign oxidation states to each of the atoms in the following chemical species: 91)
a) SiO2
b) NO-
c) TlCl
d) V2 O5
7
92) Assign oxidation states to each of the atoms in the following chemical species: 92)
a) H2 S
b) Cu2 S
c) HBrO2
d) KHCO3
93) Which of the reactions above are examples of electron transfer reactions? 93)
(a) Ba(OH)2 + H2 SO4 → 2H 2 O + BaSO4
(b) NaOH + HCl → NaCl + H2 O
(c) 2H2 + O 2 → 2H 2 O
(d) C2 H6 O + 3O2 → 2CO2 + 3H 2 O
94) For each reaction above that can be classified as an electron transfer reaction, state which 94)
element(s) gain, and which element(s) lose, electrons.
(a) Ba(OH)2 + H2 SO4 → 2H 2 O + BaSO4
(b) NaOH + HCl → NaCl + H2 O
(c) 2H2 + O 2 → 2H 2 O
(d) C2 H6 O + 3O2 → 2CO2 + 3H 2 O
95) Train tracks, iron rails,are difficult to weld. Large pieces of iron, like train tracks, can be 95)
"spot-welded" by placing a mixture of powdered aluminum and iron (III) oxide between
the two pieces of iron and adding to that a small amount of sulfuric acid to get a reaction
started.
a) Write a balanced chemical equation for the reaction of aluminum and iron (III) oxide
(ignore the role of sulfuric acid in this).
b) Identify the oxidizing and reducing agents.
c) Identify the oxidation and reduction products.
8
MATCHING. Choose the item in column 2 that best matches each item in column 1.
Match each element in every anion in the left column with its oxidation state that appears in the right column.
Match each cation in the left column with its corresponding number of electrons that appears in the right column.
9
115) potassium ion A) 54
115)
Match each element in the left column with its most likely oxidation state in the right column.
118) magnesium A) -3
118)
119) aluminum B) +1
119)
120) oxygen C) -1
120)
123) barium F) -2
123)
124) nitrogen G) +3
124)
125) sulfur H) +2
125)
126) fluorine
126)
127) strontium
127)
128) carbon
128)
129) arsenic
129)
Match each compound in the left column with the corresponding chlorine oxidation state that appears in the right column.
10
Match each compound in the left column with the corresponding sulfur oxidation state that appears in the right column.
139) sulfur, S8 E) -2
139)
Match each compound in the left column with the corresponding nitrogen oxidation state that appears in the right column.
Match each compound in the left column with the corresponding carbon oxidation state that appears in the right column.
148) Na2 CO 3 A) +2
148)
149) C60 B) 0
149)
150) C2 H2 C) -1
150)
151) CO D) +4
151)
152) CH4 E) -4
152)
11
Answer Key
Testname: UNTITLED10
1) B
2) C
3) C
4) B
5) B
6) C
7) D
8) C
9) C
10) A
11) B
12) B
13) A
14) C
15) B
16) C
17) A
18) D
19) A
20) D
21) C
22) D
23) B
24) D
25) A
26) D
27) D
28) A
29) D
30) A
31) D
32) D
33) D
34) D
35) D
36) B
37) D
38) C
39) A
40) C
41) B
42) C
43) A
44) C
45) A
46) C
47) C
48) D
49) D
50) A
12
Answer Key
Testname: UNTITLED10
51) A
52) B
53) B
54) D
55) B
56) B
57) C
58) A
59) A
60) A
61) C
62) A
63) C
64) D
65) B
66) TRUE
67) FALSE
68) TRUE
69) FALSE
70) TRUE
71) FALSE
72) TRUE
73) TRUE
74) FALSE
75) TRUE
76) TRUE
77) TRUE
78) FALSE
79) TRUE
80) FALSE
81) TRUE
82) FALSE
83) TRUE
84) FALSE
85) TRUE
86) TRUE
87) TRUE
88) TRUE
89) a) +7 (each)
b) +4
c) +2
d) +5
90) a) +2
b) +1
c) +4
d) +3
91) a) Si +4, O -2
b) N +1, O -2
c) Tl +1, Cl -1
d) V +5, O -2
13
Answer Key
Testname: UNTITLED10
92) a) H +1, S -2
b) Cu +1, S -2;
c) H +1, O -2, Br +3
d) K +1, H +1, O -2, C +4
93) both (c) and (d)
94) Reactions (a) and (b) cannot be classified as electron transfer reactions.
In reaction (c), H's lose electrons, gained by O's.
In reaction (d), carbon is oxidized by oxygen (reduced).
95) a) 2Al + Fe2 O3 → Al2 O3 + 2Fe
b) Al is the reducing agent; Fe (III) is the oxidizing agent.
c) Fe is the reduction product; Al (III) is the oxidation product.
96) H
97) J
98) F
99) I
100) G
101) G
102) E
103) D
104) A
105) I
106) C
107) I
108) B
109) F
110) A
111) B
112) A
113) C
114) A
115) B
116) A
117) A
118) H
119) G
120) F
121) C
122) B
123) H
124) A
125) F
126) C
127) H
128) E
129) D
130) D
131) B
132) A
133) C
134) E
14
Answer Key
Testname: UNTITLED10
135) A
136) D
137) E
138) A
139) B
140) C
141) C
142) D
143) B
144) E
145) F
146) D
147) A
148) D
149) B
150) C
151) A
152) E
15
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American aeronautic skill.
Stagger, she had, and dihedral, and retreat, mystic technicalities
of wing construction which came very near to realizing the dreamer’s
goal of automatic stability. Control wires had a safety factor of eight.
There was a dashboard before each of the dual control yokes dotted
with a maze of glass-dialed instruments.
The two seats were tandem, with telephonic communication so
that the occupants could converse above the roar of the engine.
Nothing, in fact, which might contribute to speed and safety and
accuracy had been omitted. And now—she was going out into the
approaching night beyond her capacity of return, like a swimmer who
swims out to sea beyond the limit of his strength. No wonder that the
owner swore at his old Uncle Sam even while he made his gift.
On the beach, where the great machine floated like some
graceful, swift storm petrel, Jim suddenly pushed Rankin to the rear
seat.
“What’s the matter?” asked Rankin hurriedly. “Aren’t you going to
fly her?”
“Nope,” said Jim with determination. “’S your job. You’re a better
flier anyway. Me for the instruments. I’ve been boning up a lot on this
new dope about wave crest length and wind ratio and bomb
dropping and all. Kinder hoped to get a commission myself—once;
but—hell! Hop in and make your tests. If I’m in on this funeral I’m
going to phone good-by to the girl.”
Then for the first time did Rankin remember his girl, and her trust,
and his promise, and what it meant between him and her.
He hesitated a moment; he, too, would have liked to telephone.
For he was very human and just then some mysterious providence
or other which looks after those who strive with a great purpose
flashed to him a vague realization of his own weakness.
Telephoning, the voice on the wire, with its note of appeal from the
purely personal view point of the woman who waited, might
undermine that high resolve. He set his teeth and climbed into the
seat ready for action.
With lips hard pinched, he tested his controls to see that
everything was running smoothly. He tested the Christensen self-
starter. With an explosive whir the propeller caught up the ignition.
He ran the engine at idling speed, watching his oil pressure and
water gages for free feeding. Everything ran with the smoothness of
a fine watch.
Jim came running.
“Give her the gun!” he shouted, hurling himself into his seat.
Rankin pulled back the throttle lever. With a roar the propeller took
up its speed; the tachometer dial jumped to fifteen thousand
revolutions; and the beautiful great bird glided out from the shore,
trusting to fate to attain its purpose.
Rankin pulled tentatively on the elevator control. The machine
answered beautifully; lifted at once to its planing angle and skimmed
the surface. Rankin hauled back, on the control.
“How does she climb?” he asked into the telephone mouthpiece
which rose from his chest.
“’Bout six hundred,” came the muffled reply from the observer’s
seat in front. “Let her go.”
V.
Here was one test of the born aviator. Presence of mind. Rankin
did not hold wildly on to everything within reach to save himself from
falling; his first instinct was to fling himself clear from the entangling
brace wires. Though he was under water and half smothered, he
kept in mind the most open way out, and within the half minute he
struggled out onto the limp wreckage of what had once been a lower
wing plane. Jim was already crawling up onto an upper surface.
“Hell!” was his greeting. “Guess I’ll earn no more toward that three
thousand out of her. Come on up, the view is fine. This side isn’t
smashed up so terribly, and there’s air enough in the camber spaces
to keep her afloat for a long while yet.”
Rankin climbed up and joined him on his sagging raft, careful not
to put his foot through the fabric. The whale was gone utterly! So
were all the shark fins. At least, they could see none from their
rocking perch. The dominant thought that had impelled him for so
long was still uppermost in Rankin’s mind.
“Good stuff!” he kept muttering. “Great! Now’s her time to get
away. Why don’t she turn and make a blue streak?”
Their own plight remained in the background of his mind, to be
taken out and dealt with after other more important matters had been
settled.
But the United States Destroyer Woodruff was showing no desire
to get away. Instead, she rushed back and forth and up and down
like a questing terrier and every now and then she barked viciously
as one gun crew or another fired at anything which appeared to them
to have the remotest chance of being a shark’s fin.
For a full half hour she hunted, and then at slower speed she
steamed for the soggy, slowly sinking raft. With navy smartness a
boat hit the water long before the ship had lost her way, and in a few
more minutes the two fanatics, nearly normal now, stood on the
heaving deck which rolled thirty degrees each way and felt to them
as solid as a city sidewalk.
At the gangway a petty officer saluted them.
“Cap’n’s compliments, sir. Waiting for you in his cabin, sir.”
Rankin was surprised. He had looked for surprise from the other
side, but they seemed to have been expecting him.
Lieutenant Commander Evans stood in his holy of holies, the
captain’s cabin. Ensign Rankin was quite normal by this time. That is
to say, he did not know exactly what navy etiquette demanded for
the occasion. He drew himself up stiffly, dripping sea water all over
the carpet, and saluted.
“Report on board for duty, sir.”
His commander gasped at the amazing young man. For the first
time in all his navy experience he did not know himself exactly what
such an occasion demanded. For a few minutes he said nothing;
then, with a dry smile:
“H-m, yes; we heard all about you. Managed to pick up a wireless;
but I’m hanged if we ever expected to see you.” He broke into a grim
laugh. “Yes, we were surprised enough; but you must have looked
like the premeditated malice of the devil to those submersibles. It
was great work my boy, great. We’ll be sorry to lose you now.”
“Lose me?” wondered Rankin.
“Well,” Commander Evans spoke with slow deliberation. “I
suppose you’ll be reassigned to aviation after this. It’s not every day
that one saves a United States destroyer, you know.”
Rankin’s heart jumped and he felt his color rising; and since it is
not seemly for an aviator to display emotion he saluted hastily and
turned to go. The deliberate voice stopped him.
“Better put in a claim for that machine. Since she’s been in active
service I guess the navy’ll take her over.”
“Thank you, sir.” Again Rankin turned with his hand on the door-
knob lest his face should betray the double exultation in his soul.
Once again that exasperating recall.
“Oh, by the way; there was another wireless; private, for you; a
most insistent person.”
Rankin wheeled in a flash. There is a limit to emotional
suppression. His commanding officer was holding out a long
envelope to him. Rankin took it with a haste which amounted almost
to a rudeness and tore it open with fingers that trembled unmanfully.
The first thing he looked for was the signature—Eileen! It loomed as
big as a theater advertisement.
“Bully for both of you,” it read. “I know you’ll succeed.”
Rankin waved it wildly over his head and whooped like a
hysterical Indian. It was a shameful display of emotion for an aviator,
and a most improper action for an ensign in his commander’s private
cabin. But Lieutenant Commander Evans only smiled.
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