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2025-JEE Main - 3_Solutions_10 July
2025-JEE Main - 3_Solutions_10 July
2025-JEE Main - 3_Solutions_10 July
BD = BAC + BCB
The magnetic field is find out by using
0 I
B= sin(1) + sin(2 )
4r
2.(B) m1 = m2 = 10 A − m2
r = 1m
0 2m1
B = B12 + B12 B1 =
4 r 3
0 m2
B2 =
4 r 3
3.(B) = n( B dA cos )
3
= 20 0.1 0.2cos ( 90 − 60 ) = 20 0.1 0.2 = 0.346 Wb
2
4.(B) L = 0n2r 2l
5.(A) For the given R, L circuit the potential difference across AD = VBC as they are in parallel.
I1 = E / R1
I 2 = I0 (1 − e−t / ) where τ = L/R.
E 12
I 2 = I0 (1 − e−t /t ) But I 0 = = = 6A
R2 2
L 200 10−3 H
= = = 0.1 s I 2 = 6(1 − e−t /0.1)
R2 2
dl2
E (across BC) = L + R2 I 2
dt
Potential drop across L = E − R2 I 2 ; = 12 − 2 6(1 − e−t /0.1 ) = 12e−t /0.1 = 12e−10tV .
6.(A) The flux associated with coil of area A and magnetic induction B is :
1 1
= BA cos = Br 2 cos t A = r 2
2 2
Br 2
2
2
Charge flow = =
R R
I I I 0 I 0 I 0 I
7.(D) P → 0 − 0 = 0 [ − 1] Q→ + = ( + 2)
2r 2r 2r 2r 4r 4r
I I
R → 0 ( + 1) S→ 0
4r 4r
di
8.(D) Given, e1 = 25mV , 2 = 15 A/s
dt
Mdi2
The emf induced across coil 1, e1 = ; 25mV = M (15)
ldt
25
Mutual inductance across coil 1, M = mH ; Given, i1 = 3.6 A, flux linkage in coil 2, we get
15
25
2 = Mi1 ; 2 = mH (3.6) ; 2 = 6.00mWb
15
9.(A) ind = B1av − B2av
0 I 1 1 1 1
= −
−7
av = 2 10 − (0.1) (40) = 4 10−6 volts
2 x x + a 0.1 0.2
1
10.(D) emf. Developed is given by ; ind = BR 2 = 100 V
2
11.(B) F = I L B
L = 2 iˆ + 2 ˆj
12.(B) Let R be the radius of a long thin cylindrical shell.
To calculate the magnetic induction at a distance r (r < R) from the axis of
cylinder, a circular shell of radius r is shown. Since, no current is enclosed
in the circle, so from Ampere’s circuital law, magnetic induction is zero at
every point of circle. Hence, the magnetic induction at very point inside
the infinitely long straight thin walled tube (cylindrical) is zero.
13.(A) m = Ia2 square loop
2
3b
m' = I equilateral triangle
4
4a = 3b
14.(B) For charged particle in magnetic field, radius
mv 1 1 1
r= and q = 2q p rp rd r =
qB q p qP 2q p
r rp = rd
15.(A) B = 10 iˆ, u = 5iˆ + 4 ˆj ; Force will act on velocity component along y axis due to which particle will
move in circular path and due to x component of velocity, particle will move in helical path
m4
Radius =
qB
2m
Pitch = 5
qB
16.(C)
17.(A) As v of charged particle is remaining constant, it means force acting on charged particle is zero:
(
F = qE + q v B = 0 )
EB
So, (
q v B = − qE) v B =− E v=
B2
NI
18.(B) B0 = 0 ; L = N 2R
2R
0 NI N 2I
B0 = = 0 B N2
2
L L
N 2
0 I
19.(A) B0 = ( 2 − )
4R '
I
From B = 0 ()
4R '
2R
= (2 − ) ; 2R = ( 2 − ) R ' ; R' =
(2 − )
20.(A) M = 0n1N2r 2 = 410−7 800 100 (0.01)2 = 3.15 10−5 H
SECTION-2
N
1.(1) R = 0.01 , N = 400, l = 20 cm, r = 1.0 cm ; B = 0nI = 0 I
m l
3.(8) F = Il B
( )
Nm −2 2
4.(1) Spring constant, k = 10−8 ; N = 100, A = 1cm = 110
2
m2 = 110−4 m2 , B = 5T
rad
NBA 100 5 110−4
Si = = −
= 1106 rad V −1
kR 10 5
8
5.(3) ( )
B = 7iˆ − 3 ˆj 10−3T
F is perpendicular to B
F B = 0 Or aB = 0
(
So, emf is v B L)
7.(10) = B. A
dB
emf = A = 2 10 = 20V
dt
20
i= = 10 amp. From Lenz’s law direction of current will be anticlockwise.
2
8.(1) Just after switch is closed, inductor behave as infinite resistance, hence no current through it.
I
9.(1) Current density, J =
a 2
From Ampere’s circuital law, B . dI =0 . Ienclosed
For r < a
0 I r
B 2r = 0 J r 2 B=
a 2 2
a a 0 I
At r = , B1 =
3 2a 2 3
I
For r a B 2r =0 I B = 0
2r
I B1
At r = 3a, B2 = 0 =1
6a B2
1 1
CV 2 = 500 10−6 (100 )
2
10.(10) Net energy stored in capacitor when it is fully charged U c =
2 2
Uc = 2.5J
Max current happens in the circuit when energy stored in capacitor is fully transferred to inductor.
1 2 50 10−3 2
li = 2.5 ; i = 2.5 i = 10 A
2 2
CHEMISTRY
SECTION-1
1.(C) R = k[A]2
unit of R L
unit of k = k=
(unit of concentration) 2 mol − sec
2.(B) Use the formula:
2.303 V 1 V 1 25 mL log e 5
t= log 0 = ln 0 = − −
ln = min
k Vt k Vt 4.5 10 min
2 1 5 mL 4.5 10−2
2.303 A
3.(A) k= log 0
t At
2.303 1
k= log
1 3
1−
4
k = 1.386 hr −1
4.(A) At Equivalence point = 15 mL H2SO4 (from graph)
Using, mEq of acid = mEq of base
( 2 0.2 ) 15 = (1 M KOH ) 20 M KOH = 0.3M
5.(B) H2 + Br2 ⎯⎯
→ 2HBr
Slowest step is RDS
r = k1 H 2 B r ….(i)
Also,
2
B r
K eq =
Br2
B r = (K eq ) Br2
/2 1/2
Putting B r in equation (i), we get
r = k H 2 Br2
1/2
S1 P1
6.(A) = [Solubility of gas in the solution partial pressure of gas]
S 2 P2
6.56 10−2 1
−2
=
5 10 P2
P2 = 0.762bar
7.(D) A used = 2 75% = 1.5 mole
A remaining = 0.5 mol
Let B formed be 2x
Then C formed be 2(1.5 – x)
k1 [B]
=
k 2 [C]
1 2x
=
2 2(1.5 − x)
x = 0.5
[B] = 2 0.5 = 1mol
[C] = 2(1.5 − 0.5) = 2 mol
[A] + [B] + [C] = [0.5 + 1 + 2] mol = 3.5 mol
8.(D) H2O + C2H5OH forms an azeotrope with a boiling point of 351.15 K. CHCl3 + C2H5 OH forms
an azeotrope with a boiling point of 332.3K. HCl + H2O forms an azeotrope with a boiling point of
381.65 K. Benzene + Toluene forms an ideal solution and hence does not form an azeotrope.
− Ea
9.(A) k = Ae RT
k 2 = 6k1
Ea 1 1
−
k2 R T1 T2
=e
k1
Ea 1 1
−
R 350 400
6=e
Ea = 41.8 kJ mol−1
10.(C) Cu 2+ + 2e− ⎯⎯
→ Cu
If 2F charge ⎯⎯
→ 63.5 g Cu deposited
63.5
1F charge ⎯⎯
→ g Cu deposited
2F
63.5 0.72F
Then 0.72 F charge ⎯⎯ → g Cu deposited = 22.86g
2F
11.(B) Given
Observed pressure = 70 torr
According to Raoult’s law,
5
pA = x A p0A = 64 = 21.33 torr
15
10
pB = x B p0B = 76 = 50.67 torr
15
Code A | Page 6 | Solutions JEE Main - 3 | JEE-2025
Vidyamandir Classes: Innovating For Your Success
and A0 = A at time t = 0
Then from Ist order equation
A0 = At ek1t or At = A0e−k1t
k [CH3 ]2 10−4 mole
15.(D) K eq = f
kb
[C2H6 ]
CH3 = 10 L
= 10−5 M
10 mole
C2 H 6 = 10 L
= 1M
( )
pHanode = − log 2 10−2 = 2 − 0.3 = 1.7
1 2atm 1
= 0.059 1.7 − 1 + log = 0.059 0.7 + log 2
2 1atm 2
1
= 0.059 0.7 + 0.3 = 0.059(0.7 + 0.15) = 0.059 0.85 0.06 0.85 = 0.05V
2
2.303 r 2.303 3 108
17.(A) k= log 1 = log = 0.1min −1
t2 − tl r2 23.03 3 107
dN / N 1 −1
k= = 0.1 min −1 = s
dt 600
18.(A) During discharging:
Anode: Pb(s) + SO24− ⎯⎯
→ PbSO4 (s) + 2e−
Cathode: PbO2 + SO24− + 4H+ + 2e− ⎯⎯
→ PbSO4 + 2H2O
During charging:
→ PbO2 + SO42− + 4H+ + 2e−
Anode: PbSO4 + 2H2O ⎯⎯
K sp of AgCl = Ag Cl−
10−10 = Ag 0.1
Ag = 10−9
a
For concentration cell, E0 = 0
Ag
0.06 a
E=− log
1 Ag
c
10−9
−0.06log
10−1
−0.06 (−8) = 0.48
a = 48
3.(10) Let the vapour pressure of pure A be = p0A ; and the vapour pressure of pure B be = p0B .
Total vapour pressure of solution (1 mole A + 3 mole B)
= x A p0A + x B p0B [xA is mole fraction of A and xB is mole fraction of B]
1 0 3 0
550 = pA + pB
4 4
or 2200 = p0A + 3p0B …..(i)
Total vapour pressure of solution (1 mole A + 4 mole B)
1 4
= p0A + p0B
5 5
1 4
560 = p0A + p0B
5 5
or 2800 = p0A + 4p0B …..(ii)
Solving equation (i) and (ii),
p0B = 600mm of Hg = vapour pressure of pure B
p0A = 400mm of Hg = vapour pressure of pure A
p0A + p0B = 1000 mm of Hg a = 10
E 0.0006 −1
4.(17) S = nF = 3 96500 − = −17.37 J K = 17 (nearest integer)
P
T 10
5.(13) Aqueous NaCl solution on electrolysis gives Cl2(g) at anode and H2(g) at cathode and OH− ions in
the solution.
1F = 1 equivalent of H2(g) = 1 equivalent of Cl2(g) = 1 Equivalent of OH− ions
Equivalent 1
OH− = = = 10−1 N
Volume of solution in L 10 L
( )
pOH = − log 10−1 = 1
pH = 14 − 1 = 13
1 0.224
6.(24) n HCl = 0.01mol
0.082 298
NaOH + HCl ⎯⎯
→ NaCl
n NaCl = 0.01
→ Na + + Cl−
NaCl ⎯⎯
Van’t Hoff factor (i) = 2
Relative lowering of vapour pressure,
Po − Ps n NaCl
= i
P o n H2O + n NaCl
For dilute solution, n NaCl n H2O
Po − Ps n NaCl
Then
o
= i
P n H2O
n NaCl 24 2 0.01
P = Po i = = 0.24 = 24 10−2 mm Hg
n H2O 36 /18
cm 3.907
7.(4) = = = 0.01
om 390.7
CH3COOH CH3COO− + H +
Initial conc c 0 0
Final conc c(1 − ) c c
[H + ] = c = 0.01 0.01 = 10−4 M
pH = − log (10−4 ) = 4
8.(350) t1/2 = 245days
To find the disintegration of any radioactive element, average life is given as:
1 t1/2
So, = = = 350 days
0.7
l
9.(400) R = 210ohm, = 0.84 cm −1
a
1 1
k= G* = 0.84 = 4 10−3 ohm−1 cm−1 or S cm−1
R 210
k 1000 4 10−3 1000
eq = = = 400 S cm2 eq −1
N 0.01
10.(232) We know that,
w B 1000
Tf = K f
mB w A
Where, Tf = Depression in freezing point
Kf = Molal depression constant of benzene
wB = Mass of solute
mB = Molecular mass of solute
wA = Mass of solvent
1.4 1000
Case-I: (278.4 − 277.12) = Kf
58 100
14
1.28 = Kf ….(i)
58
2.8 1000
Case-II: (278.4 − 277.76) = Kf (m(A) = molecular mass of solute)
m(A) 100
28
0.64 = Kf ….(ii)
m(A)
Dividing equation (i) by equation (ii), we get m (A) = 232
MATHEMATICS
SECTION-1
ln x − 1 1 1 1
1.(B) lim lim = k=
x→e x − e x→e x e e
2.(C) f ( x) = | x | sin x + |( x − ) ( x + )|cos x points to be checked x = 0, , − at x = 0 function is
differentiable and not differentiable at x = , −
3.(B) f '( x) = x 2 − (m − 3) x + m 0
D0
(m − 3)2 − 4m 0
m [1, 9]
x
4.(C) g ( x) = 3 f + f (3 − x) and f "( x) 0x (0, 3) f '( x) is increasing function
3
1 x x
g '( x) = 3 f ' − f '(3 − x) = f ' − f '(3 − x)
3 3 3
If g is decreasing in (0, )
g '( x) 0
x
f ' − f '(3 − x) 0
3
x
f ' f '(3 − x)
3
x 9
3− x x
3 4
9
Therefore =
4
9
Then 8 = 8 = 18
4
sin x x
5.(A) & are even functions
x tan x
For x0 sin x x tan x
sin x x
1 & 1
x tan x
3sin x 4x
lim = 2 & lim =3
x→0 x x→0 tan x
1
6.(C) y = 2 = x 2 x = 1, y = 1
x
dy 2 dy
m1 = = − 3 = −2 ; m2 = = 2x = 2
dx x dx
m1 − m2 4
tan = =
1 + m1m2 3
1 1 x
f ( x) = 2 − + − 1
1 + x2
1 + x2 − x 1+ x
2
1 1
f ( x) = 2 − −
1 + x2 1 + x2
f ( x) 0 x R
8.(D) Let f ( x) = 1 + 3 x 2 + 32 x 4 + .......... + 330 x 60
f ( x) = x(6 + 4.32 x 2 + .......... + 60.360 x58 )
f '( x) = 0 x=0
( ) (
f "( x) = 1 6 + 4.32 x 2 + .........x60 .330 x58 + x 4.32.2 x + 60.330.58 x57 )
f "(0) = 6 0
f ( x) has minimum at x = 0 only.
9.(B) f '( x) = −(k − 3) (k − 4)sin x + 2(k − 4)
= (k − 4) −(k − 3) sin x + 2
f ( x) does not have critical points therefore f '( x) = 0 does not have any solution in R
k 4,
2 − (k − 3)sin x 0
2
sin x
k −3
2
So, 1 | k − 3 | 2
k −3
k (1, 5) − {4}
dl
10.(A) l1 + l2 = 20 2 = −1
dl1
2 2
l l
A1 = 1 and A2 = 2
4 2
2 2
l 3l
Let S = 2 A1 + 3 A2 = 1 + 2
8 4
dS 2l 6l dl
=0 1 + 2 2 =0
dl 8 4 dl1
l1 6l2 l1
= =6
4 4 l2
11.(A) (A) ( )
f ( x) = log x 2 + ab − log ( a + b ) − log x
2x 1
f ( x) is continuous in [a, b] and f '( x) = − which clearly exists in (a, b)
x + ab
2 x
Also, f (a) = f (b) so Rolle’s Theorem is satisfied.
(B) f (1) f (3) Rolle’s theorem is not satisfied.
2
(C) f '( x) = . Clearly f '(1) does not exist Rolle’s theorem not satisfied
3( x − 1)1/3
1
(D) f ( x) = cos is continuous at x = 0 Rolle’s theorem not satisfied.
x
12.(A) f ( x) = x 2 − 5 x + 6 − 3x + 2
x − 8x + 8 ; x [−1, 2]
2
f ( x) =
− x + 2 x − 4 ; x [2, 3]
2
4R ; n = 2R
13.(D) f ( x) = 4 R − 2 ; n = 4 R − 1
2R − 1 ; n = 4R − 3
(R N )
Note that for any element, it will fall into exactly. One of these sets
y : y = 4r ; y N y : y = 2r − 1 ; y N
Corresponding to that y, we will get exactly one value of n. Thus, f is one – one & onto.
14.(B) f ( x) = ( x + 1)1/3 − ( x − 1)1/3
1 1
f '( x) = ( x + 1)−2/3 − ( x − 1)−2/3
3 3
f '( x) = 0 where x + 1 = 1 − x
x=0
f (0) = 2
f (1) = 21/3
Greatest value = 2
ax + b
15.(C) y=
( x − 4) ( x − 1)
dy a( x − 4) ( x − 1) − (ax + b) (2 x − 5)
=
dx ( x − 4)2 ( x − 1) 2
dy
For an extremum = 0 a( x − 4) ( x − 1) − (ax + b)(2 x − 5) = 0
dx
Or a(−2)(1) − (2a + b)(4 − 5) = 0 b = 0
2a + b
Also, −1 = 2a + b = 2 a = 1
(2 − 4) (2 − 1)
5
f − f
f '(c) = 6
6
16.(B)
2
1 log1/ 2 − log1/ 2
cos c =
sin c /2
cos c = 0
c=
2
17.(D) Let n I
f ( x) = 0
lim f ( x) = lim
x→n− x→n−
( x − x ) = (n −1) − (n
2 2 2 2
− 1) = 2 − 2n
f ( x) = lim ( x − x ) = n − n = 0
2 2 2 2
lim
x→n+ x→n+
Thus, lim f ( x) = f (0) = 0 and lim f ( x) = 2(1 − n) = 0 only at n = 1
x →n + x →n −
So f ( x) is continuous at n = 1, discontinuous at all other integral points
3x + 3h
f ( x + h) − f ( x)
f − f ( x) f (3x) + f (3h) − 3 f ( x)
18.(C)
f ( x) = lim = lim 3
= lim
h→ 0 h h→ 0 h h→ 0 3h
f (3h)
= lim [ x = 0, y = 3x gives f (3x) = 3 f ( x) ]
h→ 0 3h
f (3h) − f (0)
= lim = f (0) = 3
h→ 0 3h
f (3x) = 3 f ( x) = 3 x + k f ( x) will be a linear function
dx 3t t
19.(B) = 2cos t − 2cos 2t = 2 2sin sin
dt 2 2
dy 3t t
= −2sin t + 2sin 2t = 2 sin cos
dt 2 2
dy t d2y 1 t dt 1 t 1
= cot and 2 = − cosec2 = − cosec2
dx 2 dx 2 2 dx 2 2 4sin 3t sin t
2 2
20.(C) f ( x) will be increasing only if sin x + cos x is an increasing function so,
cos x − sin x 0
cos x sin x
x − ,
4 4
SECTION-2
1.(0) f ( x) = f (1 − x)
f '( x) = − f '(1 − x)
1
At x=
2
1 1
f ' = − f ' 1 −
2 2
1 1
f ' = − f '
2 2
1
f ' = 0 ……(i)
2
1
At x=
4
1 1
f ' = − f ' 1 −
4 4
1 3
f ' = − f '
4 4
1 3
f ' + f ' = 0 ……(ii)
4 4
2.(3) It is clear the graph that there are three points where there is sharp comer. Hence there are three
points where function is not differentiable.
f (3) − f (2)
3.(5) = f '()
3− 2
f (3) 5 ….(i)
f (5) − f (3)
= f '()
5−3
f (3) 5 ….(ii)
Hence f (3) = 5
x2 x2
4.(1) lim
(
9 −1
) (
3 − 1 cos x − e x
x
x
)
= ln 9 ln 3 lim
1
2!
− + ........... −
1 + x +
2!
+ ..........
x→0 x x 2 n −1 x→0 2 n −1
x x
exist if n = 1
ke x = x ….(i)
ke x = 1 ….(ii)
x =1
1
k=
e
x
3/5
x 1
8.(3) f ( x) =
−( x − 2) x 1
3
3 −2/5
x x 1
f '( x) = 5
−3( x − 2)2 x 1
Critical points where f '( x) = 0 x=2
Non differentiable at x = 0, 1
Number of critical points = 3
2 −3 x −2
1 −2 x −1
0 −1 x 0
9.(4) f ( x) =
0 0 x 1
1 1 x 2
2 2 x 3
Which is discontinuous at x = −2, − 1, 1, 2