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- JEE Main-11

Subject Topic Test – KAR Date

Basic Principles in Chemistry-1, Atomic JEE Main – 11 WT
Chemistry 1st Jul 2024
Structure-1 JM1120240701

Max. Marks: 60 Duration: 1 Hour

Useful Data
At. Wt.:
N = 14; O = 16; H = 1; S = 32; Cl = 35.5; Mn = 55; Na = 23; C = 12; Ag = 108; K = 39; Fe = 56; Pb = 207

Physical Constants:

h = 6.626  10−34 Js , N a = 6.022  1023 mol-1 , c = 2.998  108 m s-1 , me = 9.110−31 kg , R = 8.314 J mol-1 K -1

The OMR sheet for 200 questions is to be used

Answer all the questions. Each question carries 2 marks 30 x 2 = 60

1. Among the following pairs of compounds, the one that illustrates the law of multiple proportions is
(a) NH 3 and NCl3 (b) H 2 S and SO2 (c) CuO and Cu 2O (d) CS 2 and FeSO4

Sol: For the same amount of oxygen weight ratio of copper is 1: 2 therefore law of multiple
proportion.
Ans: (c)
2. 1 mol of CH 4 contains

(a) 6.02  10 23 atoms of H (b) 4 g atom of Hydrogen

(c) 1.81  10 23 molecules of CH 4 (d) 3.0 g of carbon

Sol: 1 mol of CH 4 contains 4 mol of hydrogen atom i.e. 4 g-atom of hydrogen.

Ans: (b)
3. One litre of a gas at STP weight 1.16 g it can possible be

(a) CH 4 (b) CO (c) O2 (d) C2 H 2

Sol: 1L of gas at S.T.P. weight 1.16 g

 22.4 L of gas at S.T.P. weight = 22.4 1.16 = 25.984  26

This molecular weight indicates that given compound is C2 H 2 .

Ans: (d)
4. The numbers of mol of BaCO3 which contain 1.5 mol of oxygen atoms is

(a) 0.5 (b) 1 (c) 3 (d) 6.02  10 23

Sol: 3 moles of oxygen is that in 1 mole of BaCO3

1 1
 1.5 moles of oxygen is that in mole of BaCO3 = 1.5 = = 0.5
3 2
Ans: (a)

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5. How many atoms are there in the sample of 1.4 mol of phosphorus trichloride ( PCl3 ) ?[ N A = 6  1023 ]

(a) 4 (b) 5.6 (c) 8.431 1023 (d) 3.36  10 24

Sol: No. of atoms in one molecule = 1.4  4  6  1023 = 3.36  1024

Ans: (d)
6. Which one of the following pairs of gases contains the same number of molecules?
(a) 16g of O2 and 14g of N 2 (b) 8g of O2 and 22g of CO2

(c) 28g of N 2 and 22g of CO2 (d) 32g of O2 and 32g of N 2

16 1
Sol: 16g O2 has no. of moles = =
32 2
14 1
14g N 2 has no. of moles = =
28 2
No. of moles are same, so no. of molecules are same.
Ans: (a)

7. 10 dm3 of N 2 gas and 10 dm3 of gas X at the same temperature contain the same number of molecules. The

gas X is
(a) CO (b) CO2 (c) H 2 (d) NO

Sol: If same volume is occupied by the gas, the no. of molecules are same, so no. of moles are same.
1 mol of N 2 gas = 2  14 = 28gm

1 mol of CO gas = 12 + 16 = 28gm

Ans: (a)
8. Average atomic mass of magnesium is 24.31 a.m.u. The relative abundance of this magnesium is
24 25 26 26
composed of 79 % of Mg and remaining 21 % of Mg and Mg . Calculate % of Mg .

(a) 15 (b) 11 (c) 10 (d) 16

26
Sol: Let % of Mg be x

( 21 − x ) 25 + x ( 26 ) + 79 ( 24 )
 = 24.31
100
x = 10%
Ans: (c)

9. An atom of an element X weighs 2  10−23 g . Calculate the number of atoms present in 30 grams of

the sample. [ N A = 6.0  1023 ]

(a) 3.1  10 22 (b) 6.6  10 22 (c) 1.8  1024 (d) 1.5  1024

Sol: The atomic mass of the element = 2  10−23  6.0  1023 = 12.0

30
The number of mol in 30 g of sample = = 2.5
12.0

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Number of atoms of element in 30 g = 2.5  6.0  1023 = 1.5  1024

Ans: (d)
10. How many grams of MgSO4 are 1.25 mol of MgSO4 ? [Mol. Mass of MgSO4 =120]

(a) 250 (b) 140 (c) 30 (d) 150

Sol: Mass of MgSO4 = no.of moles  molecular weight =1.25  120 = 150g

Ans: (d)
11. Calculate the total number of electrons present in 22.4 g of N 2 gas. (At. no. N = 7 )

(a) 6.74  10 24 (b) 6.74 10 23 (c) 4.215  1023 (d) 4.8  10 22

Sol: Number of electrons in N 2 molecule = 14

22.4
Number of moles of N 2 = = 0.8
28

 Number of molecules of N 2 = 0.8  6.022  1023

 Number of electrons of N 2 = 14  0.8  6.022  1023 = 6.74  1024 electrons

Ans: (a)
12. Calculate the volume occupied by 4.0 mol of ethane at STP conditions
(a) 22.4 L (b) 89.6 L (c) 56 L (d) 44.8 L

Sol: Molar volume of any gas at STP = 22, 400 cc

The volume of 4 mol of ethane at STP = 4  22400 = 89600 cc .

Ans: (b)

13. How much coulomb charge is present on 1 g-ion of N 3−

(a) 5.2  106 coulomb (b) 2.894  105 coulomb

(c) 6.6  106 coulomb (d) 8.2  106 coulomb

Sol: One ion carries 3  1.6  10−19 coulomb

Then 1 gm ion N 3− (1 mole) carries

= 3  1.6 10−19  6.02  1023 = 2.89  105 coulomb

Ans: (b)
14. A Certain mass of a gas occupies 15 litre volume at 300 K and 1.5 atm pressure. Calculate the number
of mol present in it.
(a) 0.975 mol (b) 0.91mol (c) 0.7 3mol (d) 3.626 mol

Sol: The volume of the gas is 15 litre at 300 K and 1.5 atm pressure.

P  V  273 1.5 15  273

The volume of the same mass of gas at STP is given by, V0 = = = 20.475litres.
T 1 300

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20.475
The number of moles of the gas = = 0.91mol
22.4
Ans: (b)
15. Calculate the mass of NaCl which would contain same number of ions as 133.5 g of AlCl3 .

[At Mass Na=23, Al=27, Cl = 35.5]

(a) 100 g (b) 87.75 g (c) 117 g (d) 95 g

Sol: AlCl3 → Al 3+ + 3Cl −

1 mol = 133.5 gra ms → 4 mol ions

NaCl → Na + + Cl −
1 mol = 58.5 grams → 2 mol ions

4 mol ions is present in = 117 g

Ans: (c)
16. Which of the following statements is not correct regarding electromagnetic spectrum?
(a) The velocity of X − rays is same as that of microwaves
(b) Infra-red radiations have larger wavelength than cosmic rays
(c) The frequency of microwaves is more than that of ultra-violet rays
(d) X − rays have larger wave number than micro-waves.
Sol: The frequency of microwaves is less than that of ultra-violet rays
Ans: (c)
17. The ratio between the neutrons present in carbon and silicon with respect to mass number of 12 and
28 respectively are [At.no C=6,Si=14]
(a) 3: 4 (b) 7 : 3 (c) 3: 7 (d) 6 : 28
28
Sol: Carbon is 6 C12 and silicon is 14 Si

Ans: (c)
18. Which of the following has highest e/m ratio ?
2+ + + +
(a) He (b) H (c) He (d) Na
+
Sol: Mass of H is minimum
Ans: (b)
19. Bohr’s theory can also be applied to the ions like

(a) He+ (b) Li + (c) Be3+ (d) Both (a) & (c)

Sol: Bohr’s atomic theory is applicable to hydrogen and monoatomic ions like He + , Li 2+ , Be3+ , etc.

Ans: (d)
20. The limiting line in Brackett series corresponds to
(a) n1 = 4, n2 =  (b) n1 = 4, n2 = 4 (c) n1 = 2, n2 = 10 (d) n1 = 3, n2 = 

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Sol: The limiting line in Brackett series corresponds to n1 = 4, n2 = 

Ans: (a)
21. According to Bohr’s theory, the angular momentum of an electron in 4 th orbit is
(a) 10h /  (b) 2  5h /  (c) 2h /  (d) 1  0h / 
Sol: Angular momentum in the 4th orbit
= 4h / 2 = 2h / 
Ans: (c)
22. Calculate the number of spectral lines obtained in hydrogen spectrum when electrons from the

higher level ( n = 8 ) undergo transition to a lower energy level ( n = 2 ) .

(a) 15 (b) 21 (c) 10 (d) 8

Sol: n2 = 8 and n1 = 2

(n2 − n1 )(n2 − n1 + 1)
The number of spectral lines =
2
(8 − 2)(8 − 2 + 1) 6  7
The number of spectral lines = = = 21
2 2
Ans: (b)
23. The electronic transition from n = 2 to n = 1 will produce shortest wavelength in

(a) H-atom (b) Li 2+ ion (c) He+ ion (d) both (b) and (c)

Sol: E for Li 2+ = E2 − E1 is maximum as E = EnH  Z 2

nLi 2 +

1
E  Z 2  
Z2
Ans: (b)
24. The shortest and longest wave number in H spectrum of Lyman series is (R = Rydberg constant)

3 1 4 4 3
(a) R, R (b) , R (c) R, R (d) R, R
4 R 3 3 4
__
Sol: Shortest v means shortest E and vice versa.
When, n = 1, n2 = 2

__ 1 1  3
v = R −  = R
 12 22  4
__
Longest v means longest E
When n1 = 1, n2 = 

__ 1 1 
v = R − =R
 12  2 
Ans: (a)

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25. Threshold wavelength depends upon :

(a) frequency of incident radiation (b) velocity of electrons
(c) work function (d) None of these
hc
Sol: Work function = w 0 = (Threshold wavelength)  it only depends on work function.
0
Ans: (c)

26. A bulb emits light of wavelength 6000 A , which can provide 30 J of energy. How many photons are

emitted by the bulb per second? [ h =6.6×10-34 Js ]

(a) 9.1  10 21 (b) 3.01  1019 (c) 3.01  10 20 (d) 9.1  1019

Sol:  = 6000 Å = 6.0  10−7 m

hc 6.6 10−34  3 108

E= = = 3.3 10−19 J
 −7
6.0 10
Ebulb 30
Number of photons emitted per second = = = 9.1 1019
Ephoton 3.3 10−19

Ans: (d)

27. If the second Bohr orbit of H − atom has a radius of 2.21 10−10 m . What is the radius of the 3rd Bohr
orbit H − atom?

(a) 1.989  10−9 m (b) 1.38  10−9 m (c) 4.97  10−10 m (d) None of these

Sol: rn = a0  n 2

r2 22 4 9
= = ; r3 = r2 
r3 32 9 4

9
r3 = 2.2110−10  = 4.97  10−10 m
4
Ans: (c)
28. What is the of the velocity of electron in 5th Bohr’s orbit of H − atom.

(a) 0.358  106 ms-1 (b) 3.12  105 ms-1 (c) 3.48  107 ms-1 (d) 4.38  105 ms-1

1 1
Sol: Velocity of electron in H − atom = 2.19  106  = 2.19 106  = 4.38 105 ms-1
n 5
Ans: (d)

29. Calculate the energy of an electron in the 2nd Bohr orbit of Li 2+ ion

(a) −2.18  10−18 J (b) −2.25  10−18 J (c) −4.9 10−18 J (d) −6.54  10−18 J

Sol: For lithium Z = 3 and for the second orbit n = 2

Z2
En = −2.18 10−18  J
n2

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32
E3 = −2.18  10−18  = − 4.9  10−18 J
2
2
Ans: (c)

30. The threshold frequency of a metal is 8.0  1014 s −1 . Calculate the kinetic energy of an electron

emitted when the radiation of frequency 1.0  1015 s −1 strikes the metal surface. [Given

h = 6.625  10−34 Js ]

(a) 1.9875  10−19 J (b) 1.2625  10−18 J (c) 1.325  10−19 J (d) 9.821 10−17 J

Sol: The kinetic energy of photoelectrons is given by,

KE = h( − 0 )

(
KE = 6.625 10−34  1.0 1015 − 8.0 1014 )
KE = 6.625  10−34  2.0  1014

KE = 1.325 10−19 J

Ans: (c)

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Key Answers:

1. c 2. b 3. d 4. a 5. d 6. a 7. a 8. c 9. d 10. d
11. a 12. b 13. b 14. b 15. c 16. c 17. c 18. b 19. d 20. a
21. c 22. b 23. b 24. a 25. c 26. d 27. c 28. d 29. c 30. c