Eco-Friendly Corrosion Inhibitors :

Principles, Designing and Applications

Lei Guo
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Eco-Friendly Corrosion Inhibitors : Principles,

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 ECO-FRIENDLY
CORROSION INHIBITORS
 ECO-FRIENDLY
CORROSION
INHIBITORS
PRINCIPLES, DESIGNING AND
APPLICATIONS
Edited by

Lei Guo
School of Materials and Chemical Engineering, Tongren University, Tongren, China

Chandrabhan Verma
Interdisciplinary Research Center for Advanced Materials, King Fahd University of Petroleum and Minerals, Dhahran,
Saudi Arabia

Dawei Zhang
University of Science & Technology Beijing, Beijing, China
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 Contents

Contributors xi 3. Development process for eco-friendly

Preface xv corrosion inhibitors
MOHAMED RBAA, MOUHSINE GALAI, OMAR DAGDAG,
LEI GUO, BURAK TÜZÜN, ELYOR BERDIMURODOV,

Part 1 ABDELKADER ZARROUK, BRAHIM LAKHRISSI

Overview of industrial corrosion 3.1 Introduction 27

3.2 Process for development of eco-friendly synthesizing
and inhibition corrosion inhibitors 28
3.3 Process for development of eco-friendly extracting
1. General principles of industrial corrosion inhibitors 30
Conclusion 39
corrosion References 40
SHEERIN MASROOR

1.1
1.2
Introduction 3
Materials in industrial applications 3
Part 2
1.3 General principles or theories of industrial Industrial environments & corrosion
corrosion 4
1.4 Different types of corrosion in industries 5
inhibitors
1.5 Corrosion of metal in industries 10
References 12 4. Acidizing corrosion inhibitors
HAO LI, YUJIE QIANG, CHANDRABHAN VERMA
2. Corrosion prevention and
protection methods 4.1 Introduction of acidizing corrosion inhibitors 45
4.2 Acidizing inorganic corrosion inhibitor 46
SAMAN ZEHRA, MOHAMMAD MOBIN,
RUBY ASLAM 4.3 Acidizing organic corrosion inhibitor 46
4.4 New acidizing corrosion inhibitor 47
2.1 Introduction 13 Conclusion 52
2.2 Important considerations required for the corrosion References 53
prevention and control methods 14
2.3 Strategies of the corrosion prevention and control 5. Corrosion inhibitors used in alkaline
methods 18 environments
2.4 Methods of corrosion control 18 DAQUAN ZHANG, JUNYU YANG, PEI GAN, WENYUE ZHANG
Conclusion 25
Acknowledgment 26 5.1 Corrosion inhibitor used for alkaline metal-air
Useful books 26 battery 55
Useful websites 26 5.2 Corrosion inhibitors for rebar in concrete
References 26 reinforcement 64

v
vi Contents

5.3 Corrosion inhibitors in other alkaline media 65 8.5 Eco-friendly corrosion mitigation in the oil and
Summary and outlook 66 gas industry 116
Acknowledgments 67 8.6 Developing the corrosion inhibitor formulation 122
References 67 Conclusion 123
Useful links 124
6. Corrosion inhibitors in near neutral media References 124
K.R. ANSARI, AMBRISH SINGH, ABDULLAH K. ALANAZI,
M.A. QURAISHI 9. Vapor inhibitors for corrosion protection
K.R. ANSARI, AMBRISH SINGH,
6.1 Introduction 71 ABDULLAH K. ALANAZI, M.A. QURAISHI
6.2 Metals corrosion and their inhibition in a neutral
environment 72 9.1 Introduction 127
6.3 Heterocyclic corrosion inhibitors for neutral 9.2 Mechanism of VCI action 128
environments 72 9.3 Developed VCIs for ferrous and nonferrous
Acknowledgment 76 metals 130
References 76 9.4 Some important techniques used for corrosion
inhibition monitoring 133
7. Supramolecular corrosion inhibitors for 9.5 Advantages of VCIs 133
cooling water systems 9.6 Market growth 134
9.7 Methods of VCI application 134
BAOMIN FAN, HUA HAO
Acknowledgment 135
7.1 Introduction to supramolecular corrosion References 135
inhibitors 79
7.2 Preparation of supramolecular corrosion inhibitors 10. Inhibitors for microbiologically
via molecular recognition and self-assembly 82 influenced corrosion (MIC)
7.3 Assembly mechanism of the supramolecular LI FENG, HAILIN ZHU, XUEMEI MA, ZHIYONG HU,
corrosion inhibitor based on CDs 87 AMIR ZOMORODIAN
7.4 Characterizations of supramolecular corrosion
inhibitors 89 10.1 Introduction 137
7.5 Inhibition effect and mechanism of supramolecular 10.2 Microorganism species and MIC mechanism 138
corrosion inhibitors 99 10.3 MIC inhibitors 143
7.6 Supramolecular corrosion inhibitor used in Conclusion 149
industrial water treatment 105 References 150
Conclusions 109
Useful links 109 11. Corrosion inhibitors for Cu chemical
References 109 mechanical planarization (CMP)
BAIMEI TAN, LEI GUO, XINHUAN NIU, DA YIN, TENGDA
8. Corrosion inhibitors for oil and MA, SHIHAO ZHANG, CHENWEI WANG
gas systems
11.1 Benzotriazole (BTA) used for Cu CMP 155
BRAHIM EL IBRAHIMI
11.2 1,2,4-triazole (TAZ) used for Cu CMP 158
8.1 Well acidizing treatments in the oil and gas 11.3 2,2’-[[(methyl-1H-benzotriazol-1-yl) methyl]imino]
industry 111 diethanol (TT-LYK) used for Cu CMP 161
8.2 Materials used for well construction in the oil and 11.4 Other inhibitors used for Cu CMP 165
gas industry 112 11.5 The synergistic effects of mixed corrosion
8.3 Significance of corrosion and its associated agents inhibitor used for Cu CMP 165
in the oil and gas industry 113 Conclusions 167
8.4 Corrosion inhibitors and environmental Useful links 167
concerns 114 References 167
 Contents vii

Part 3 15. Pharmaceutical drugs protecting metals

in aggressive environments
Modern environmentally friendly RUBY ASLAM, MOHAMMAD MOBIN, JEENAT ASLAM,
corrosion inhibitor systems AFROZ ASLAM

15.1 Introduction 229

12. Heterocyclic corrosion inhibitors with 15.2 Corrosion inhibitors 233
multianchoring groups 15.3 Drugs as corrosion inhibitor: Literature survey 234
15.4 Experimental validation 251
MOUHSINE GALAI, MOHAMED RBAA, K. DAHMANI,
BRAHIM LAKHRISSI, M. EBN TOUHAMI, LEI GUO 15.5 Limitations and future directions 252
Conclusions 257
12.1 Introduction 173 Acknowledgments 257
12.2 Corrosion inhibition review of quinoline Abbreviations 257
derivatives 175 Useful links 257
12.3 Example of a complete study on the use of two References 258
heterocyclic inhibitors 178
Conclusion 190 16. Plant extracts as environmentally
References 190 sustainable corrosion inhibitors I
XIN ZHANG, BOCHUAN TAN, WENPO LI
13. Pharmaceutical drugs as corrosion
inhibitors I 16.1 Preparation of plant extracts 263
HASSANE LGAZ, MUSTAFA R. AL-HADEETHI, RACHID SALGHI, 16.2 Experimental methods of plant extracts 265
HAN-SEUNG LEE 16.3 Mechanism of plant extracts 268
16.4 Recent advances of plant extracts 269
13.1 Introduction 195 16.5 Modification of plant extracts 274
13.2 General overview on drug synthesis and reuse 196 Summary and outlook 275
13.3 Application of drugs and expired drugs as References 277
corrosion inhibitors 199
Conclusions and future outlook 204 17. Plant extracts as environmentally
Acknowledgments 205 sustainable corrosion inhibitors II
References 205
ABHINAY THAKUR, HUMIRA ASSAD, SAVAŞ KAYA,
ASHISH KUMAR
14. Pharmaceutical drugs as corrosion
inhibitors II 17.1 Introduction 283
SHVETA SHARMA, RICHIKA GANJOO, 17.2 Prominent metrics for extract preparation 285
SHIMAA M. ELSAEED, ASHISH KUMAR 17.3 Plant extract as corrosion inhibitor 288
17.4 Mode of inhibitor adsorption on substrate 300
14.1 Introduction 211 17.5 Effect of temperature and concentration 301
14.2 Industrial applications of drugs as corrosion 17.6 Techniques to evaluate corrosion inhibition
inhibitors 211 efficiency 302
14.3 Experimental section 212 17.7 Advantage and disadvantages of green corrosion
Conclusion 222 inhibitors 305
Useful links 222 17.8 Future outlooks 305
References 223 Conclusion 306
Useful links 306
References 307
viii Contents

18. Amino acids and their derivatives as Conclusion 406

corrosion inhibitor Useful links 406
References 406
JEENAT ASLAM, RUBY ASLAM, AFROZ ASLAM

18.1 Introduction 311 21. Applications of nanomaterials

18.2 Classification and properties of amino acids 314 in corrosion inhibitors
18.3 Corrosion inhibition mechanism by amino YUQIN TIAN, QI CHEN, XIAOYA SUN, JIAJIA ZHU,
acids 314 RENHUI ZHANG
18.4 Literature survey on amino acids and their
derivatives 316 21.1 Introduction 411
18.5 Challenges and recent progress 319 21.2 Nanomaterials and nanocomposites 411
Conclusions 326 21.3 Nanoparticles as corrosion inhibitors 415
Abbreviations 326 21.4 Important issues related with anticorrosive
Websites related to the topic 326 nanomaterials 421
References 326 References 421

19. Ionic liquids as green and sustainable

corrosion inhibitors I Part 4
ELYOR BERDIMURODOV, ABDUVALI KHOLIKOV, KHAMDAM
AKBAROV, LEI GUO, NURBEK UMIROV, DAKESHWAR KUMAR
Emerging trends in corrosion
VERMA, MOHAMED RBAA, OMAR DAGDAG, RAJESH inhibition
HALDHAR, SAVAŞ KAYA

19.1 ILs as environmental-friendly corrosion 22. Modern testing and analyzing techniques

inhibitors 331 in corrosion
19.2 ILs are corrosion inhibitors for steel materials 333 CHONG ZHU, ZHAOSEN ZHOU, YANG ZHOU, BIN XIANG
19.3 ILs are corrosion inhibitors for copper 369
19.4 ILs are corrosion inhibitors for magnesium 22.1 Traditional used corrosion testing techniques 429
materials 374 22.2 Potential corrosion detection approaches 443
19.5 ILs are corrosion inhibitors for other metallic Conclusions 447
materials 378 References 447
19.6 Inhibition mechanism of ILs 382
Conclusions 382 23. Development of high temperature
Abbreviations 383
corrosion inhibitors
References 383
ABDOLREZA FARHADIAN, LEI GUO

20. Ionic liquids as green and sustainable 23.1 Introduction 451

corrosion inhibitors II 23.2 Plant extracts 452
RICHIKA GANJOO, SHVETA SHARMA, BHARMAL 23.3 Ionic liquids 461
A. SHABBIRBHAI, SHIMAA M. ELSAEED, 23.4 Amino acids 465
ASHISH KUMAR
23.5 Carbohydrates 466
23.6 Vegetable oils 472
20.1 Introduction 391
23.7 Miscellaneous 475
20.2 ILs as corrosion inhibitors 394
Conclusions 478
20.3 Techniques for conducting corrosion experiments
Useful links 478
and deciphering the mechanism of corrosion 398
References 478
20.4 Contact angle measurements of ionic liquids 405
20.5 Mechanism for the corrosion inhibitive property
of ionic liquids 405
 Contents
24. Smart corrosion inhibitor: Present status
and future scenario
XINGWEN ZHENG, LEI GUO, DAWEI ZHANG
24.1 Introduction 485
24.2 Controlled release inhibitor 486
24.3 pH-responsive inhibitor 489
24.4 Ion exchange inhibitor 497
24.5 Other smart inhibitor 501
Summary and future scenario 502
References 502
25. Controllable fabrication of carbon
dots based corrosion inhibitors with
fluorescence properties
YU ZHANG, BOCHUAN TAN, LEI GUO, MENGYUE ZHU
25.1 Corrosion inhibitor used for metal protection 505
25.2 Introduction of carbon dots 508
25.3 Synthetic strategies of CDs 511
25.4 Corrosion inhibition performance of CDs 514
Conclusions and outlook 521
Useful links 522
References 522
26. Computational methods used in
corrosion inhibition research
SAVAŞ KAYA, AKPAN N. IKOT, ASHISH KUMAR, SELÇUK
ŞIMŞEK, MENGYUE ZHU, LEI GUO
26.1 Introduction 527
26.2 Conceptual density functional theory
(CDFT) 529
ix
26.3 Some electronic structure principles and rules for
corrosion inhibition research 531
26.4 Molecular dynamics and Monte Carlo simulations
approaches in corrosion science 533
26.5 The application of first-principles calculation
approach 534
Conclusions 536
References 536
27. Corrosion inhibition strategy:
Synergistic effects
PENG HAN, JIAWEI FAN, LINGHUI KONG, BUYUN ZHANG,
ZHIXUAN CHANG
27.1 Problems and challenges in the study of synergistic
effect of corrosion inhibitors 539
27.2 Advances of synergistic effect 543
27.3 Advances in theoretical research on synergistic
effect of corrosion inhibitors 545
27.4 Significance and prospect of synergistic effect of
corrosion inhibitor 548
Abbreviations 549
References 549
Index 553
 Contributors
Khamdam Akbarov Faculty of Chemistry, National
University of Uzbekistan, Tashkent, Uzbekistan
Mustafa R. Al-Hadeethi Department of Chemistry,
College of Education, University of Kirkuk, Kirkuk,
Iraq
Abdullah K. Alanazi Department of Chemistry,
College of Science, Taif University, Taif, Saudi Arabia
K.R. Ansari Center of Research Excellence in Corro-
sion, Research Institute, King Fahd University of
Petroleum and Minerals, Dhahran, Saudi Arabia
Ruby Aslam Corrosion Research Laboratory, Depart-
ment of Applied Chemistry, Faculty of Engineering
and Technology,Aligarh Muslim University,Aligarh,
India
Jeenat Aslam Department of Chemistry, College of
Science, Taibah University, Yanbu, Al-Madina, Saudi
Arabia
Afroz Aslam Department of Chemistry, Faculty of
Science, Aligarh Muslim University, Aligarh, India
Humira Assad Department of Chemistry, Faculty of
Technology and Science, Lovely Professional Uni-
versity, Phagwara, Punjab, India
Elyor Berdimurodov Faculty of Chemistry, National
University of Uzbekistan, Tashkent, Uzbekistan
Zhixuan Chang Department of Materials Science
and Engineering, China University of Mining &
Technology (Beijing), Beijing, China
Qi Chen School of Materials Science and Engineer-
ing, East China JiaoTong University, Nanchang,
People’s Republic of China
Omar Dagdag Institute of Nanotechnology and
Water Sustainability, College of Science, Engineering
and Technology, University of South Africa, Johan-
nesburg, South Africa
K. Dahmani Laboratory of Organic, Inorganic Chem-
istry, Electrochemistry and Environment, Faculty of
Sciences, Ibn Tofaïl University, Kenitra, Morocco
xi
Brahim El Ibrahimi Department of Applied Chemis-
try, Faculty of Applied Sciences, Ibn Zohr University,
Aït Melloul, Morocco; Team of Physical Chemistry
and Environment, Faculty of Sciences, Ibn Zohr Uni-
versity, Agadir, Morocco
Shimaa M. Elsaeed Petroleum Applications Divi-
sion, Egyptian Petroleum Research Institute (EPRI),
Nasr City, Cairo, Egypt
Baomin Fan College of Chemistry and Materials
Engineering, Beijing Technology and Business Uni-
versity, Beijing, China
Jiawei Fan Department of Materials Science and
Engineering, China University of Mining & Technol-
ogy (Beijing), Beijing, China
Abdolreza Farhadian Department of Polymer &
Materials Chemistry, Faculty of Chemistry and Petro-
leum Science, Shahid Beheshti University, GC, Tehran,
Iran; Department of Petroleum Engineering, Kazan
Federal University, Kazan, Russian Federation
Li Feng School of Chemical Engineering and Tech-
nology, North University of China, Taiyuan,
China
Mouhsine Galai Advanced Materials and Process
Engineering, Faculty of Sciences, Ibn Tofaïl Univer-
sity, Kenitra, Morocco
Pei Gan School of Environmental and Chemical
Engineering, Shanghai University of Electric Power,
Shanghai, China
Richika Ganjoo Department of Chemistry, Faculty
of Technology and Science, Lovely Professional Uni-
versity, Phagwara, Punjab, India
Lei Guo School of Materials and Chemical Engineer-
ing, Tongren University, Tongren, China
Rajesh Haldhar School of Chemical Engineering,
Yeungnam University, Gyeongsan, South Korea
Peng Han Department of Materials Science and Engi-
neering, China University of Mining & Technology
(Beijing), Beijing, China
xii Contributors
Hua Hao Institute of Chemistry, Chinese Academy of
Sciences, Beijing, China
Zhiyong Hu School of Chemical Engineering and
Technology, North University of China, Taiyuan,
China
Akpan N. Ikot Theoretical Physics Group, Depart-
ment of Physics, University of Port Harcourt, Choba,
Nigeria
Savaş Kaya Sivas Cumhuriyet University, Health
Services Vocational School, Department of
Pharmacy, Sivas, Turkey
Abduvali Kholikov Faculty of Chemistry, National
University of Uzbekistan, Tashkent, Uzbekistan
Linghui Kong Department of Materials Science and
Engineering, China University of Mining & Technol-
ogy (Beijing), Beijing, China
Ashish Kumar Department of Chemistry, Faculty of
Technology and Science, Lovely Professional Uni-
versity, Phagwara, Punjab, India
Brahim Lakhrissi Laboratory of Organic Chemistry,
Catalysis and Environment, Faculty of Sciences, Ibn
Tofail University, Kenitra, Morocco
Han-Seung Lee Department of Architectural Engi-
neering, Hanyang University ERICA, Sangrok-gu,
Ansan, Korea
Hassane Lgaz Department of Architectural Engi-
neering, Hanyang University ERICA, Sangrok-gu,
Ansan, Korea
Hao Li National Center for Materials Service Safety,
University of Science and Technology Beijing,
Beijing, China; Key Laboratory of Marine Materials
and Related Technologies, Zhejiang Key Laboratory
of Marine Materials and Protective Technologies,
Ningbo Institute of Materials Technology and Engi-
neering, Chinese Academy of Sciences, Ningbo,
China
Wenpo Li School of Chemistry and Chemical Engi-
neering, Chongqing University, Chongqing, China
Xuemei Ma School of Chemical Engineering and
Technology, North University of China, Taiyuan,
China
Tengda Ma School of Electronics and Information
Engineering, Hebei University of Technology,
Tianjin, China
Sheerin Masroor Department of Chemistry, A.N.
College, Patliputra University, Patna, Bihar, India
Mohammad Mobin Corrosion Research Laboratory,
Department of Applied Chemistry, Faculty of Engi-
neering and Technology, Aligarh Muslim University,
Aligarh, India
Xinhuan Niu School of Electronics and Information
Engineering, Hebei University of Technology,
Tianjin, China
Yujie Qiang National Center for Materials Service
Safety, University of Science and Technology Beijing,
Beijing, China
M.A. Quraishi Center of Research Excellence in Cor-
rosion, Research Institute, King Fahd University of
Petroleum and Minerals, Dhahran, Saudi Arabia
Mohamed Rbaa Laboratory of Organic Chemistry,
Catalysis and Environment, Faculty of Sciences, Ibn
Tofail University, Kenitra, Morocco
Rachid Salghi Laboratory of Applied Chemistry and
Environment, ENSA, University Ibn Zohr, Agadir,
Morocco
Bharmal A. Shabbirbhai Department of Chemistry,
Faculty of Technology and Science, Lovely Profes-
sional University, Phagwara, Punjab, India
Shveta Sharma Department of Chemistry, Faculty of
Technology and Science, Lovely Professional Uni-
versity, Phagwara, Punjab, India
Ambrish Singh School of New Energy and Materi-
als, Southwest Petroleum University, Chengdu,
Sichuan, China
Xiaoya Sun School of Materials Science and Engi-
neering, East China JiaoTong University, Nanchang,
People’s Republic of China
Baimei Tan School of Electronics and Information
Engineering, Hebei University of Technology,
Tianjin, China
Bochuan Tan School of Chemistry and Chemical
Engineering, Chongqing University, Chongqing, China
Abhinay Thakur Department of Chemistry, Faculty
of Technology and Science, Lovely Professional Uni-
versity, Phagwara, Punjab, India
Yuqin Tian School of Materials Science and Engi-
neering, East China JiaoTong University, Nanchang,
People’s Republic of China
M. Ebn Touhami Advanced Materials and Process
Engineering, Faculty of Sciences, Ibn Tofaïl Univer-
sity, Kenitra, Morocco
 Contributors
Burak Tüzün Department of Chemistry, Faculty of
Science, Sivas Cumhuriyet University, Turkey
Nurbek Umirov Faculty of Natural Sciences, Karshi
State University, Karshi, Uzbekistan
Chandrabhan Verma Interdisciplinary Research
Center for Advanced Materials, King Fahd University
of Petroleum and Minerals, Dhahran, Saudi Arabia
Dakeshwar Kumar Verma Department of Chemis-
try, Government Digvijay Autonomous Postgradu-
ate College, Rajnandgaon, Chhattisgarh, India
Chenwei Wang School of Electronics and Informa-
tion Engineering, Hebei University of Technology,
Tianjin, China
Bin Xiang School of Chemistry and Chemical Engi-
neering, Chongqing University, Chongqing, China
Junyu Yang School of Environmental and Chemical
Engineering, Shanghai University of Electric Power,
Shanghai, China
Da Yin School of Electronics and Information Engineer-
ing, Hebei University of Technology, Tianjin, China
Abdelkader Zarrouk Laboratory of Materials, Nan-
otechnology and Environment, Mohammed V Uni-
versity, Faculty of Sciences, Rabat, Morocco
Saman Zehra Corrosion Research Laboratory,
Department of Applied Chemistry, Faculty of Engi-
neering and Technology, Aligarh Muslim University,
Aligarh, India
Daquan Zhang School of Environmental and Chemi-
cal Engineering, Shanghai University of Electric
Power, Shanghai, China
Wenyue Zhang School of Environmental and Chemi-
cal Engineering, Shanghai University of Electric
Power, Shanghai, China
Shihao Zhang School of Electronics and Information
Engineering, Hebei University of Technology,
Tianjin, China
Xin Zhang School of Chemistry and Chemical Engi-
neering, Chongqing University, Chongqing, China
xiii
Renhui Zhang School of Materials Science and Engi-
neering, East China JiaoTong University, Nanchang,
People’s Republic of China
Dawei Zhang University of Science & Technology
Beijing, Beijing, China
Yu Zhang School of Chemistry and Chemical Engi-
neering, Chongqing University, Chongqing, China
Buyun Zhang Department of Materials Science and
Engineering, China University of Mining & Technol-
ogy (Beijing), Beijing, China
Xingwen Zheng School of Chemical and Environ-
mental Engineering, Sichuan University of Science &
Engineering, Zigong, China
Zhaosen Zhou Analytical and Testing Centre of
Chongqing University, Chongqing University,
Chongqing, China; Henan Chemical Technician
College, Henan, China
Yang Zhou Analytical and Testing Centre of Chongq-
ing University, Chongqing University, Chongqing,
China
Hailin Zhu School of Chemical Engineering and
Technology, North University of China, Taiyuan,
China
Jiajia Zhu School of Materials Science and Engineer-
ing, East China JiaoTong University, Nanchang,
People’s Republic of China
Chong Zhu School of Chemistry and Chemical
Engineering, Chongqing University, Chongqing,
China
Mengyue Zhu School of Materials Science and Engi-
neering, East China Jiaotong University, Nanchang,
China
Amir Zomorodian Department of Engineering,
University of Cambridge, Cambridge, United
Kingdom
Selçuk Şimşek Sivas Cumhuriyet University,
Faculty of Science, Department of Chemistry, Sivas,
Turkey
 Preface
It is well-known that corrosion has a huge eco-
nomic, environmental, and sustainability
impact on virtually all facets of metallic materi-
als, including power facilities, integrated cir-
cuits, chemical industries, desalination, bridges,
oil and gas pipeline, etc. Annual costs of corro-
sion and its consequences are estimated in the
region of 3–5% of GDP for industrialized coun-
tries of the world. Most of all, the disposal and
further substitution of the damaged elements
involve an additional consumption of energy
and resources. To face and solve this challenge,
an increasing number of studies have focused
on environmentally friendly, renewable, and
efficient corrosion inhibitors, which are promis-
ing alternatives to toxic corrosion inhibitors, in
order to control corrosion damage in diverse
corrosive environments. These materials range
from plant extracts to amino acids, expired
drugs, ionic liquids, carbohydrate polymers,
and zero-dimensional carbon quantum dots.
Although the subject of corrosion inhibition has
been a conventional research topic over the past
few decades, more advanced knowledge is still
required to win the battle. A comprehensive
understanding of this phenomenon will guar-
antee an improved design to reduce the dra-
matic consequences.
In this regard, the present book aims to shed
more light on the recent progress and advances
on the usage of green and sustainable inhibitors
to protect metallic materials against corrosion
in different corrosive conditions, such as acidic,
neutral, alkaline, and sweet/sour environ-
ments. A wide range of ecofriendly corrosion
xv
inhibitors have been presented and their poten-
tial applications in various industrial fields
were also discussed.
The book is divided into different parts,
where each part contains multiple chapters.
Part 1 “Overview of industrial corrosion and
inhibition” covers topics such as general prin-
ciples of industrial corrosion, corrosion preven-
tion, and protection methods, and the
development process for ecofriendly corrosion
inhibitors. Part 2 “Industrial environments &
corrosion inhibitors” entirely focuses on the
application of corrosion inhibitor in acidizing,
alkaline, and near neutral media, as well as the
inhibitors for cooling water systems, oil and gas
systems, and chemical mechanical planariza-
tion. Part 3 “Modern environmentally friendly
corrosion inhibitor systems” is specific about
the corrosion inhibitors based on pharmaceuti-
cal drugs, plant extracts, amino acids, ionic
liquids, nanomaterials, and synthetic com-
pounds. Part 4 “Emerging trends in corrosion
inhibition” gives a description of modern
testing and analyzing techniques in corrosion,
the smart and high temperature corrosion
inhibitors, the synergistic inhibition strategy,
and computational methods used in corrosion
inhibition research.
Overall, this book is written via a scientific
summary of modern corrosion inhibitors, and
is prepared for graduate students, researchers,
as well as practitioners in multiple industries
who require comprehensive knowledge of this
aspect. The editors and contributors are well-
known scientists with many years of research
xvi Preface

experience in corrosion inhibitors. Thank all the cal support for future research and innovation
hard-working project managers and acquisi- in the field of corrosion inhibition.
tions editor of this book for their enthusiasm
and help in the publishing process. We would Lei Guo
like to thank Elsevier for publishing this book, Chandrabhan Verma
which can provide theoretical basis and techni- Dawei Zhang
 P A R T 1

Overview of industrial corrosion

and inhibition
1 General principles of industrial corrosion 3
2 Corrosion prevention and protection methods 13
3 Development process for eco-friendly corrosion inhibitors 27
 C H A P T E R

1
General principles of industrial
corrosion
Sheerin Masroor
Department of Chemistry, A.N. College, Patliputra University, Patna, Bihar, India

1.1 Introduction warming and greenhouse emissions, all inter-

The economic development of any region,
state or country, depends not only on its natural
resources and productive activities, but also on
the infrastructure that account for the exploita-
tion, processing, and marketing of goods. Irriga-
tion systems, roads, bridges, airports, maritime,
land and air transport, school buildings, offices
and housing, industrial installations are affected
by corrosion and therefore susceptible to dete-
rioration and degradation processes.
Corrosion is a worldwide crucial problem
that strongly affects natural and industrial envi-
ronments. Today, it is generally accepted that
corrosion and pollution are interrelated harmful
processes since many pollutants accelerate cor-
rosion and corrosion products, such as rust, also
pollute water bodies. Both are pernicious pro-
cesses that impair the quality of the environ-
ment, the efficiency of the industry and the
durability of the infrastructure assets. Therefore,
it is essential to develop and apply corrosion
engineering control methods and techniques.
Other critical problems, that impact on infra-
structure and industry are climate change, global
related phenomena. This chapter presents
important aspects of corrosion in industrial
infrastructure, its causes, impacts, control, pro-
tection and prevention methods.
1.2 Materials in industrial applications
Earthly materials always keep an important
point which is for good development of any
economy we are living, that further be sustained
globally. The usage of metal depends upon the
characteristic properties it is having and its
important applications that it may be having in
society. Few were summarized below:
In the line of any metal production from its
ore, multiple processes applied are mineral
mining, manufacturing with application along
with production of various solids, liquids, and
gases that are having great impact on the society
and environment.
For specific industrial progress, in general the
metal and materials are produced in such a way
that they will not affect the environment at
greater level [1–7]. The metals or materials can

Eco-Friendly Corrosion Inhibitors

DOI: https://doi.org/10.1016/B978-0-323-91176-4.00013-1 3 Copyright © 2022 Elsevier Inc. All rights reserved.
Another random document with
no related content on Scribd:
Mrs. Pepper didn’t!
She thought that they were frumps!
Who thought that French men were polite?
Mrs. Pepper didn’t!
She thought that they were boors!
So she wrote to Tom, in New York.
And to Dick, in New York.
And to Harry, in New York.
And she said, “I hate Paris!”
In the morning, she walked—alone.
Mile after mile.
In the afternoon, she drove—alone.
Hour after hour.
In the evening, she dined—alone.
Course after course.
But what was the good of anything?
Nothing!
She met a Count.
But he was a Frenchman.
And a puppet.
She met a Baron.
But he was a Russian.
And a savage.
Then she met—a Man.
He was an American.
And a gentleman.
She met him in the Bois de Boulogne.
It was in the morning.
She was walking.
So was he.
She was walking up.
He was walking down.
They met.
He looked at her.
She looked at him.
They passed.
He looked around.
So did she.
She walked on.
He followed her.
She knew when he was behind her.
She knew when he was beside her.
And then he spoke.
“I beg your pardon!” said the Man.
“What is it?” said the Woman.
“Please do not misunderstand me,” said the Man.
“I will try not to,” said the Woman.
“I am an American,” said the Man.
“Yes,” said the Woman.
“I am here alone,” said the Man.
“Well?” said the Woman.
“And I am—lonely,” said the Man.
“What has this to do with me?” said the Woman.
“That is what I want to know,” said the Man.
“Indeed?” said the Woman.
“You are an American,” said the Man.
“Yes,” said the Woman.
“You are here alone,” said the Man.
“I am,” said the Woman.
“And you are—lonely,” said the Man.
“I am—not,” said the Woman.
“Oh, I thought you were!” said the Man.
“Well, you have made a mistake!” said the Woman.
“You have misunderstood me!” said the Man.
“No,” said the Woman, “you have misunderstood me!”
She walked away.
He stood still.

That afternoon, when she drove, she saw the Man and he saw her.
That night, when she dined, she saw the Man and he saw her.
The next morning, when she walked, she saw the Man and he saw
her.
And so it went—morning, noon and night.
Day after day.
He never spoke.
He never made a sign.
And neither did she.
But he was always—there.

Now he was a Man.

And she was a Woman.
He was an American.
And so was she.
So at last—one evening, in the foyer of the hotel, she bowed to him.
He came over to her.
She held out her hand.
He took it.
He looked into her eyes.
She looked into his.
“You are lonely!” said the Man.
“No,” said the Woman, “not any more!”

Mrs. Pepper wrote to Tom, in New York.

And to Dick, in New York.
And to Harry, in New York.
And she said, “I love Paris!”
 MOON-MADNESS
It was noontime.
Noontime in Bombay.
Nana Lalla fared forth through the town.
The streets were narrow and winding.
They were lined with shops.
Goldsmiths and silversmiths.
Fruit-shops and sweet-shops.
Merchants and money changers.
Before these booths people stopped and stared.
Bargained and bartered.
Went in, or went on.
Great throngs tramped up and down.
To and fro.
Shoulder to shoulder.
Some in flowing robes.
Some in scanty rags.
Dogs trotted at one’s side.
Bullocks pushed at one’s back.
And all the time the sun shone in the sky.
Shone like a ball of fire.
It burned the world with its blazing beams.
Nana Lalla hated the day.
And she loathed the sun.
She did not look to the left.
Nor to the right.
She looked straight before her.
And she went her way.

It was midnight.
Midnight in Bombay.
Nana Lalla was in her room.
She lay on her couch.
Her eyes were open.
But she was dreaming.
Dreaming of sweet-smelling flowers.
And soft-splashing fountains.
And bright-beaming eyes.
Of such things the poets prated.
Of such things the singers sang.
And Nana Lalla had read the poets’ rhymes.
And Nana Lalla had heard the singers’ melodies.
She delighted in these things.
Delighted in them exceedingly.
She tossed and she turned.
She sighed and she sobbed.
And then she arose.
She went to the window.
She looked through the lattice.
The moon shone in the sky.
Shone like a pool of silver.
It bathed the world in liquid light.
Nana Lalla loved the night.
And she worshipped the moon.

Nana Lalla wound a scarf about her body.

Draped a shawl over her head.
And slipped sandals on her feet.
She stole out of her room.
She slipped out of the house.
And once again she fared forth through the town.

Never had Nana Lalla known such a night.

Never had Nana Lalla seen such a moon.
So soft, and so silver.
So gentle, and so gracious.
And yet with all, so—maddening.
Nana Lalla’s eyes sparkled.
Nana Lalla’s hands trembled.
And Nana Lalla’s heart beat high.
Oh, could she only flee away from the city!
Could she only flee away to the country!
Could she only flee away—by the light of the moon!
Or else—could only something happen!
Something strange.
Something sweet.
If only—
Someone stood before her.
Someone spoke to her.
Someone touched her arm.
It was a man.
And yes—his eyes were sparkling too.
His hands were trembling also.
And his heart was beating as wildly as was hers.
She could see.
She could tell.
She could feel.
He and she were alone.
Alone at midnight.
And the moon was shining.
How she loved the moon!
And perhaps he loved it too.
Nana Lalla was not afraid.
Instead, she was full of hope.
He must love the moon—even as did she!
So, when he touched her, she did not shrink away.
When he took her in his arms, she yielded herself.
And when he kissed her—she responded....
The Man always remembered Nana Lalla.
He had loved her.
And he thought that she had loved him.
But Nana Lalla soon forgot the Man.
She had not loved him.
She had only loved—the Moon....
THE END
 Transcriber’s Notes:
On page 60, spang has been changed to sprang.
All other spelling has been retained as typeset.
 *** END OF THE PROJECT GUTENBERG EBOOK MOON-
MADNESS, AND OTHER FANTASIES ***

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