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Full download Elastomer Blends and Composites: Principles, Characterization, Advances, and Applications Sanjay Mavinkere Rangappa file pdf all chapter on 2024
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Elastomer Blends and
Composites
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Elastomer Blends and
Composites
Principles, Characterization, Advances,
and Applications
Edited by
Jyotishkumar Parameswaranpillai
Associate Professor, Department of Science, Faculty of Science & Technology,
Alliance University, Bengaluru, Karnataka, India
Suchart Siengchin
President, King Mongkut’s University of Technology,
North Bangkok (KMUTNB), Thailand
Togay Ozbakkaloglu
Professor, Ingram School of Engineering, Texas State University,
San Marcos, TX, United States
Elsevier
Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands
The Boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, United Kingdom
50 Hampshire Street, 5th Floor, Cambridge, MA 02139, United States
1. Introduction to elastomers 1
Jyotishkumar Parameswaranpillai, C.D. Midhun Dominic, Sanjay Mavinkere
Rangappa, Suchart Siengchin and Togay Ozbakkaloglu
1.1 Introduction 1
1.2 Vulcanization/cross-linking in elastomers 2
1.3 Elastomeric composites and blends 2
1.4 Recent developments in elastomeric blends and composites 3
1.5 Conclusion 6
Acknowledgments 7
References 7
2.1 Introduction 11
2.2 Preparation techniques 13
2.3 Conclusion 29
References 29
3. Elastomer-based blends 33
Aswathy Jayakumar, Sabarish Radoor, Jyotishkumar Parameswaranpillai, E.K.
Radhakrishnan, Indu C. Nair and Suchart Siengchin
3.1 Introduction 33
3.2 Compatibilization of elastomer-based blends 34
v
vi Contents
4.1 Introduction 45
4.2 Preparation and properties of fillers 46
4.3 Conclusions and perspectives 52
References 53
5.1 Introduction 57
5.2 Elastomer blends and composites processing methods 58
5.3 Elastomer blends and composites engineering applications 62
5.4 Conclusion 76
Acknowledgments 77
References 77
6.1 Introduction 83
6.2 Basic aspects of rheology 84
6.3 Basic key terms 85
Contents vii
Index 405
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Contributors
Jitha S. Jayan Department of Chemistry, School of Arts and Sciences, Amrita Vishwa
Vidyapeetham, Amritapuri, Kollam, Kerala, India
xiii
xiv Contributors
Kam Sheng Lau Bioresource & Biorefinery Research Group, Department of Applied
Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, Bangi,
Selangor, Malaysia
Gopika Venu Department of Chemistry, School of Arts and Sciences, Amrita Vishwa
Vidyapeetham, Amritapuri, Kollam, Kerala, India
Elastomers are also called rubbers and have many specific features such as elasticity, good
strength, and high toughness. Some of the examples of elastomers are natural rubber,
polyurethane, ethyleneepropylene rubber, silicone rubbers, etc. The performance of the
elastomer depends on the cross-link density, molecular weight, and type of elastomer. The
elastomer as such possesses poor thermomechanical properties. Therefore, cross-linking of
elastomers is essential for improving their performance. Sulfur or no-sulfur compounds are
used for cross-linking elastomers. The cross-link density or vulcanization can be controlled by
changing the cross-linking agents, varying the amount of fillers, etc. Generally cross-linking
improves the performance of the elastomer.
In recent years, blends and composites of elastomers are formulated for improved
performance. Some of the potential applications of elastomeric blends and composites are in
the oil and gas industry, automobile, conveyer belts, adhesive, and sealants, etc. This book
comprises all the important areas of elastomeric blends and composites and their charac-
teristic properties such as structural, thermomechanical, morphology, rheology, and
modeling. The recycling and potential applications of elastomeric blends and composites are
also discussed. We hope this important book will benefit students, scientists, industrialists,
and those who are interested in rubber-based materials. The editors thank all the authors for
their contributions.
Acknowledgments
This work was supported by King Mongkut’s University of Technology North Bangkok has
received funding support from the National Science, Research and Innovation Fund (NSRF)
with Grant No of KMUTNB-FF-65-19.
Editors
Sanjay Mavinkere Rangappa (Thailand)
Jyotishkumar Parameswaranpillai (India)
Suchart Siengchin (Thailand)
Togay Ozbakkaloglu (USA)
xvii
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1
Introduction to elastomers
1.1 Introduction
Elastomers are viscoelastic polymers, showing both viscous and elastic properties. The
elastomer possesses long polymer chains held together with weak intermolecular forces.
These weak forces make them flexible and sticky, with high elongation upon the
application of stress. Once the stress is released, it could come back to the original shape
and hence called elastomer. Most of these polymers are having 100% recoverability,
thanks to their low degree of cross-links. The low degree of cross-links in the elastomer
makes it amorphous; however, once it is stretched, crystalline sites can be observed. The
elastomer retains its original shape because of these cross-links. In order words, cross-
linking within the elastomer provides a better shape and stiffness. The other features
of elastomers are low glass transition temperature, hydrophobicity, good adhesion, good
breaking resistance, tear strength, abrasion resistance, resistant to gas, water, and steam,
and are excellent insulators. It finds application in adhesives, sealing applications, and
insulations [1]. Elastomers are of natural and synthetic origin. The synthetic elastomers
are petroleum-based, while natural rubbers are of plant origin. Examples for elastomers
are natural rubber, EPDM rubber, silicone rubber, olefin thermoplastic elastomer, etc.
The properties of a pure elastomer such as elasticity, strength, hardness, and resilience
are poor, which restricts its use in advanced applications. Therefore, cross-linking is
necessary. The properties and performance of the elastomer can be dramatically
enhanced with vulcanization/cross-linking [2].