(6001CJA10102124001) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Main)

INTERNAL TEST
(Academic Session : 2024 - 2025)
30-04-2024

JEE(Main + Advanced) : ENTHUSIAST (PHASE : 1)

INTERNAL TEST - 01
ANSWER KEY
PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C D B B A A A A B B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D C C B D D A D B B
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 20.00 12.00 50.00 1.00 0.8 11.00 -12.00 120.00 100.00 1.20

CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10

A. D C D A D C C C C B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20

A. C B C D B C C C D D
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 3.00 2.00 6.00 281.00 3.00 6.00 4.00 6.00 4.00 3.00

MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. D B A C C D C D D B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. B A A D D D A C A B

Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 766.00 910.00 8.00 7.00 36.00 1.00 1.00 -3.00 5.00 6.00

HINT – SHEET

6001CJA10102124001 HS-1/9
 Target : IIT-JEE (M + A) 2024
PHYSICS 9. Ans ( B )
Vd μr
SECTION-I sin C = =
Vr μd
1. Ans ( C ) 10. Ans ( B )
1 x 0.2
tan 30 = = ⇒x=
√ 3 0.2 √3

11. Ans ( D )
fu b b
v= ; u1 = u − and u2 = u +
u−f 2 2
12. Ans ( C )
1 sin 45∘ = √2 sin r sin θ = √μ21 ∼ μ22
⇒ r = 30∘ 13. Ans ( C )
Angle of incidence on the 3rd interface is more μr μ3 μ1 sin θ
= = sin c ; =
than the critical angle. So, T.I.R. μd μ2 μair sin c
So the angle of deviation is 180°. 14. Ans ( B )
2. Ans ( D ) μ2 μ1 μ2 − μ1
− =
Upper section will behave like diverging lens v u R
and lower section will behave like a converging 15. Ans ( D )
v
lens. m=1−
f
c
3. Ans ( B ) ∴ f=
b
16. Ans ( D )
D = 2i – A
17. Ans ( A )
d = 180 − 2A = 2i − A
When ray appear to pass through centre of sin(90 − A
)
sin i 2 1
curvature of a convex mirror, it retraces its μ= = ;μ =
sin r sin A sin c
path. 2

18. Ans ( D )
5. Ans ( A ) dmin = 4f
Use displacement method. 19. Ans ( B )
A2object = A1 A2

7. Ans ( A )
μr C
= d = sin c
μd Cr
8. Ans ( A ) i > c ⇒ sin i > sin c
sin i 1 1
A μB = ⇒ > ⇒ μ > √2
sin r √2 μ

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20. Ans ( B ) 2. Ans ( C )
1 μl ens − 1 Oxidation state of Co is +3.
= μlens
f −1
μ liq 3. Ans ( D )
PHYSICS [Pt(en)2]+2
SECTION-II
'en' is neutral ligand
x + 2[O] = +2
1. Ans ( 20.00 ) x = +2
1 1 1
Apply = + 4. Ans ( A )
f v u
2. Ans ( 12.00 ) Oxidation state of both Cr and Co is +3.
1 1 1 5. Ans ( D )
= (μ − 1) ( − )
f R 1 R 2

3. Ans ( 50.00 )
1 6. Ans ( C )
L μg =
sin c [ Co(NH3 )5 (NO2 )] Cl2 + AgNO3
5. Ans ( 0.8 ) → [Co(NH3 )5 (NO2 )]
+2
+ 2AgCl ↓
w1 w2
+ =0
f1 f2 7. Ans ( C )
6. Ans ( 11.00 ) 3d9 and strong field ligand.
D = 360 − 2θ 8. Ans ( C )
360 Cr+2 (3d 4 ) , Mn+2 (3d 5 ).
n= −1
θ
7. Ans ( -12.00 ) 9. Ans ( C )
d0 and d10 do not show d − d transition colours.
Relative velocity = 2v
8. Ans ( 120.00 ) 10. Ans ( B )
1 1 1
Complexes in A, C, D have plane of symmetry.
= (μ − 1) ( − )
f R 1 R 2 12. Ans ( B )
9. Ans ( 100.00 ) No−1
2 is ambidentate.
μ2 μ1 μ2 − μ1
− = ; 14. Ans ( D )
v u R
1.5 1 1.5 − 1 Both Cis & trans isomers are symmetric.
− =
v (−100) (20) 15. Ans ( B )
10. Ans ( 1.20 ) Δ0 is calculated by complementary colors.
μl Cg
g μl = = 16. Ans ( C )
μg Cl
[Pt(NH3)4]+2 (square planar)
CHEMISTRY Pt+2 (all electrons paired)
SECTION-I μ = 0 B.M
−2
1. Ans ( D ) [NiCl4 ] (tetrahedral)
Conceptual Ni+2 (e4 t42 )
μ = √2 (2 + 2) = 2.84 B. M

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17. Ans ( C ) 5. Ans ( 3.00 )
1 Spectrochemical series
Δ0 α
λmax I – < Br− < S2 – < Cl – < NO−3 < F − < OH – <
1
λmax α EtOH < C2 O2−
Ligand strength 4 < H2O < EDTA < NH3 < en <
− –
NO2 < CN < CO
18. Ans ( C )
NO−2 , en and CN – are stronger ligand as
When Δo > P , pairing of electrons take place
compare to NH3
Δo < P , no pairing of electrons.
6. Ans ( 6.00 )
19. Ans ( D )
Δ 0 order: 5d > 4d > 3d.
20. Ans ( D )
Co+3 Primary valency = 3
Secondary valency = 6
CHEMISTRY
SECTION-II
1. Ans ( 3.00 )
Cis is optically active.
2. Ans ( 2.00 )
CN − is strongest ligand.

3. Ans ( 6.00 )
+2 O2
[ Co(H2 O)6 ] + 6NH3 −→ [Co(NH3 )6 ] + 3
CO+3 − t2g 6 eg o All given compounds show cis – Trans
isomerism.
4. Ans ( 281.00 )
Total Compunds = 6
Net stabilization energy of Fe2+ will CN –
ligands t2,2g2, 2 e0,g 0 = – 2.4 Δ 0 + 2P 9. Ans ( 4.00 )
= ( – 2.4 × 25000 + 2 × 15000) cm – 1 Paramagnetic species →
3+ 3−
= – 30000 cm – 1 [ Cr(H2 O)6 ] , [F e(CN)6 ]
2+ 3−
net stabilisation energy of Fe2+ ions with H2O [ Cu(NH3 )4 ] , [CoF6 ]
ligands t2,2g1, 1 e1,g 1 = – 0.4 Δ 0 Diamagnetic species → Cr(CO)6 , [ZnCl4 ]2−
= 4000 cm – 1 10. Ans ( 3.00 )
so required difference = 26000 cm – 1
= 26 × 105 m – 1
= 6 × 10 – 34 × 3 × 108 × 26 × 105 × 6 × 1023 ×
10 – 3 kJ/mole
= 2808 × 10 – 1 kJ/mole
= 281 kJ/mole
= 280.8 kJ/mol

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MATHEMATICS 4. Ans ( C )
SECTION-I
We know that,
sin2 x − sin2 y = sin(x + y) sin(x − y),
1. Ans ( D ) sin(π − θ) = sin θ, A + B + C = π
R1 → R1 − R2 \& R2 → R2 − R3
gives
∣ − sin(A−B)
∣
sin C sin(A − B) sin A sin B
0 ∣∣
∣ ∣
∣ − sin(B−C) ∣
∣ sin A sin(B − C) sin B sin C
0∣ = 0
∣ ∣
∣ ∣
∣ sin2 C cot C 1∣
2. Ans ( B ) on expanding
(aI2 + bA)2 = A
a b a b 0 1 5. Ans ( C )
[ ][ ] =[ ] since it is an identity, put a = b = c = 1
−b a −b a −1 0 ∣ 2 1 1∣
or a2 − b2 = 0 & 2ab = 1 ∣ ∣

1 1 1 1
∣
∣
1 2 1 ∣∣ = α
(a, b) = ( , ) or ( − ,− ) ∣ ∣
√ 2 √ 2 √ 2 √ 2 ∣1 1 2∣
3. Ans ( A ) or α = 4

6. Ans ( D )

6001CJA10102124001 HS-5/9
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7. Ans ( C ) 11. Ans ( B )

8. Ans ( D )
1 1 1
Taking , & common from
log x log y log z
R1 , R2 & R3 respectively, we get
∣ log x log y log z ∣
∣ ∣
1 ∣ ∣
log x log y log z ∣ = 0
log x log y log z ∣
∣ ∣
∣ log x log y log z ∣
since R1 = R2 = R3
9. Ans ( D )
Apply R1 → R1 + R2 + R3 , all the elements of
R1 become 0.
12. Ans ( A )
10. Ans ( B )

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13. Ans ( A ) 16. Ans ( D )
P TP = I
∴ Q2 = P A2 P T , Q3 = P A3 P T .......
Q2015 = P A2015 P T
1 2015
∴ P T Q2015 P = A2015 = [ ]

0 1
FInd A2, A3, A4 yourself & observe the pattern
17. Ans ( A )
then infinite −4 −1
solutions A=[ ] ⇒ |A| = −1
3 1
Hence −4 −1 −4 −1 13 3
λ can be any real numbe A2 = [ ] [ ] =[ ]

3 1 3 1 −9 −2
14. Ans ( D ) ∣A
∣
2016
− 2A 2015 2014 ∣
−A ∣
C1 → C1 − C2 , C2 → C2 − C3 2014 ∣ 2 ∣ 2
= |A| ∣A − 2A − I ∣ = ∣∣A − 2A − I ∣∣
∣ 1 0 sin2 x ∣

∣ ∣
Simplify this expression yourself.
∣ ∣
∣
−1 1 cos2 x ∣
=0
∣ ∣
∣ 0−1 1 + 4 sin 2x ∣
18. Ans ( C )
R2 → R2 + R3
∣ 1 0 sin2 x ∣
∣ ∣
∣ ∣
−1 0 cos2 x + 1 + 4 sin 2x =0
∣
∣
∣
∣
on solving, |A| = 5e−t ≠ 0 ∀t ∈ R
∣ 0 −1 1 + 4 sin 2x ∣
19. Ans ( A )
Expanding from C2, we get
p2 + p2 + 0 = 1
1 7π 11π
sin 2x = − ⇒ 2x = ,
2 6 6 20. Ans ( B )
15. Ans ( D )

6001CJA10102124001 HS-7/9
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MATHEMATICS 3. Ans ( 8.00 )
SECTION-II

1. Ans ( 766.00 )

4. Ans ( 7.00 )

2. Ans ( 910.00 ) 5. Ans ( 36.00 )

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6. Ans ( 1.00 ) 9. Ans ( 5.00 )
2 4 2 0 0
A=[ ] ⇒A = [ ]
−1−2 0 0
|I + 2A + 3A2 + ... + 101A100| = |I + 2A|
1 0
(I + 2A) = [ ]
0 1
4 8 5 8
+[ ] = [ ]
−2 −4 −2 −3
|I + 2A| = 1
7. Ans ( 1.00 )
2
|adjA| = |A|
|5A| = 53 |A|
|adjB| |adj (adj A) | |A|4 |A|3
= = =
|C| |5A| 53 |A| 125
|A| = 5
8. Ans ( -3.00 )
⎛
3 4 1⎞
⎜ ⎟
(p q r) ⎜
⎜
3 2 3⎟
⎟
= (3 0 1)
⎜ ⎟

⎝
2 0 2⎠
[3p + 3q + 2r 4p + 2q p + 3q + 2r] = [3 0 1]
3p + 3q + 2r = 3 → (i)
4p + 2q = 0 → (ii)
p + 3q + 2r = 1 → (iii)
from eq. (iii)
3q + 2r = 1 – p
put the value of 3q + 2r in eq. (i)
we get
3p + 1 – p = 3
2p = 2 10. Ans ( 6.00 )
p=1
Put the value of P in equation (ii)
4(1) + 2q = 0
2q = – 4
q=–2
Put the value of P and Q in equation (i)
3(1) + 3 ( – 2) + 2r = 3
3 – 6 + 2r = 3
– 6 = – 2r
r=3
find = 2p + q – r
= 2(1) – 2 – 3
=–3
6001CJA10102124001 HS-9/9