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YAKEEN-2.0

AIM NEET SERIES

[Practice Sheet-02]
1. The major product of the given 5. In which case SN2 Ar reaction is fastest ?
reaction is Cl Cl
NO2
product
(A) (B)

NO2
(A) Br Cl

NO2
(C) (D)
(B)

NO2 NO2

(C) EtONa
6. ⎯⎯⎯⎯→
(1 mol),

(D)
The product is

2. Which of the following carbocations is (A) (B)

expected to be least stable?

NO2
(A) (B)
(C) (D)
EtO Cl
Cl
(C) (D)

(CH ) NH
7. ⎯⎯⎯⎯⎯
3 2
→ The product is
3. Toluene and chromyl chloride reacts to Cu2O, 

produce
(A) Benzoic acid NMe2
(B) Benzaldehyde
(C) Chlorotoluene
(A) (B)
(D) Benzyl chloride

4. Ethylbenzene + Cl2 ⎯⎯⎯ Light

→ major NMe2
CN
product is
(A) o- & p-chloroethylbenzene NMe2
(B) 1-Phenyl ethane (C) (D)
(C) 2-Chloroethylbenzene
(D) m-Chloroethylbenzene F
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11. Aryl halides are less reactive towards

nucleophilic substitution reaction as
8. CH ONa
⎯⎯⎯⎯→
3 compared to alkyl halide due to

(A) The formation of less stable
carbonium ion
(B) Resonance stabilization
(A)
(C) Longer carbon-halogen bond
(D) The inductive effect

(B)

(C) 12.

The product is
(D)

(A)
9. The correct order of increasing reactivity
of C–Cl bond towards nucleophile
substitution reaction in the following
compounds is (B)
Cl Cl
NO2
I. II. (C)

NO2
Cl Cl
(D)
III. IV.
NO2 CHO 13. Identify the product in the following
(A) III < II < I < IV (B) I < IV < III < II reaction
(C) II < III < I < IV (D) IV < III < I < II
H O
⎯⎯⎯⎯
3
→

10. Product is
(A)

(B)
(A) (B)

(C)

(C) (D)
(D)
 3

(B) Benzene
14. ⎯⎯ ⎯⎯⎯⎯→
HNO3 / H2SO 4
100 C (C) 1, 4-Difiluorobenzene
Sn / HCl
(D) 1, 3–Difluorobenzene
Intermediate compound ⎯⎯ ⎯⎯→
Heat

19. Diazonium salts + Cu2Cl2 + HCl → ,

(A) (B)
the reaction is known as
(A) Chlorination
(B) Sandmeyer’s reaction
(C) (D) (C) Perkin reaction
(D) Carbyl amine reaction

20. In the reaction,

15. Electrophilic substitution of with

⎯⎯⎯→
(A)
(A) is
bromine water gives
(A) 2,3,4-Tribromo aniline
(B) 2, 4, 6-Tribromo aniline
(C) 4-Bromo aniline (A) H3PO2
(D) 3-Bromo aniline (B) Cu2Cl2
(C) HgSO4/H2SO4
16. Benzenediazonium chloride can be (D) H+ / H2O
converted into benzene on treatment with
(A) H3PO3 21. In the following reaction sequence, the
(B) H3PO4 compounds (X) and (Y) respectively are
(C) H3PO2
(D) HPO3
Excess Br
⎯⎯⎯⎯⎯
2
→ (X) ⎯⎯ ⎯ ⎯ ⎯⎯→ (Y)
(i ) NaNO 2 / HCl
H2O (ii) H3PO 2

HCN
17. CuCN product is
(A) and

(A) (B)
(B) and

(C) (D)
(C) and


18. ⎯⎯→ A is
(D) and
In the above process product A is
(A) Fluorobenzene
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22. Identify the final product in the following

sequence of reaction.
NH PO
⎯⎯⎯⎯ → ⎯⎯⎯ → ⎯⎯⎯ →
SOCl
2 3 2 5
H O
23. ⎯⎯⎯
3

⎯
→ [X]

(A)
Select the correct statement
(A) X gives effervescence of CO2 with
(B) NaHCO3
(B) X will produce alkane when treated
with Zn-Hg/HCl
(C)
(C) X will produce symmetrical diketone
when treated with sodalime
(D) (D) All of these
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ANSWERS

1. (D) 9. (B) 17. (B)

2. (C) 10. (A) 18. (A)
3. (B) 11. (B) 19. (B)
4. (B) 12. (A) 20. (A)
5. (B) 13. (C) 21. (B)
6. (A) 14. (A) 22. (C)
7. (B) 15. (B) 23. (B)
8. (A) 16. (C)

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