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CIVIL ENGINEERING
MATERIALS
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WOODHEAD PUBLISHING
SERIES IN CIVIL AND
STRUCTURAL ENGINEERING
CIVIL ENGINEERING
MATERIALS
From Theory to Practice
QIANG YUAN
ZANQUN LIU
KEREN ZHENG
CONG MA
Elsevier
Radarweg 29, PO Box 211, 1000 AE Amsterdam, Netherlands
The Boulevard, Langford Lane, Kidlington, Oxford OX5 1GB, United Kingdom
50 Hampshire Street, 5th Floor, Cambridge, MA 02139, United States
Preface vii
1. Fundamentals of materials 1
1.1 Composition and structure 1
1.2 Physical properties 5
1.3 Mechanical properties 11
1.4 Durability 15
Exercises 16
4. Metal 205
4.1 Introduction 205
4.2 Structural steel 206
4.3 Standards and selection of building steel 220
4.4 Corrosion and prevention of steel 232
4.5 Nonferrous metals 234
Exercises 238
v
vi Contents
5. Wood 239
5.1 Introduction 239
5.2 Structure and composition 240
5.3 Engineering properties 241
5.4 Wood-based composites 250
5.5 Durability 257
Exercises 259
6. Polymers 261
6.1 Engineering plastics 263
6.2 Sealants 271
6.3 Adhesive 272
6.4 Fiber reinforced polymer 276
Exercises 284
7. Asphalt 287
7.1 Asphalt cement 287
7.2 Liquid asphalts 306
7.3 Asphalt concrete 308
Exercises 324
Index 377
Preface
vii
viii Preface
The authors of this book are from Central South University and
ShenZhen University in China. Qiang Yuan from Central South University
is responsible for the plan of this book and the writing of Chapter 3 and part
of Chapter 8. Keren Zheng from Central South University is responsible for
the writing of Chapters 1 and 2. Zanqun Liu from Central South University
is responsible for the writing of Chapters 4 and 5 and part of Chapter 8.
Cong Ma from ShenZhen University is responsible for Chapters 6 and 7.
Many masters and PhD students helped with the editing and figure
drawing of the manuscript during the preparation of this book. The authors
would like to acknowledge Ms. Yuman Wang, Mr. Shenghao Zuo,
Mr. Tsegaye Lakew Berihun, and Mr. Ghimire Prateek for their contribu-
tions to this book.
This book is intended for undergraduate and graduate students in civil
engineering or material science. It can also be used as a general reference
book for professional engineers and researchers, or a tool book for
professional engineers and researchers.
Qiang Yuan, Zanqun Liu
Keren Zheng, Cong Ma
CHAPTER 1
Fundamentals of materials
1.1.2 Structure
Generally, the term structure for materials refers to the arrangement of
internal components of materials. The structure of materials can be classified
by the general magnitude of various features being considered. The three
most common major classifications of structure are as follows: ①Atomic
structure, which includes features such as the types of bonding between the
atoms, and the way the atoms are arranged; ②Microstructure, which
includes features that can be seen using a microscope, but seldom with the
naked eye; ③Macrostructure, which includes features that can be seen with
the naked eye.
Actually, most properties are highly structure sensitive and the structure
virtually determines everything about a material: its properties, its potential
applications, and its performance within those applications. Therefore, it is
very important to understand the basis for the structure of materials to be
able to control the properties and reliability of engineering materials.
1.1.2.2 Microstructure
The term “microstructure” is used to describe the arrangement of phases
and defects within a material, the appearance of the material on the nme
mm length scale. A complete description of microstructures involves
describing the size, shape, and distribution of grains and second-phase
particles and their composition.
Microstructure can be observed using a range of microscopy techniques.
The microstructural features of a given material may vary greatly when
observed at different length scales. For this reason, it is crucial to consider
the length scale of the observations you are making when describing the
microstructure of a material.
Microstructures determine the mechanical, physical, and chemical
properties of materials. For example, the strength and hardness of materials
are determined by the number of phases and their grain sizes. The electrical
and magnetic properties and also the chemical behavior (corrosion) are
determined by the grain size and defects (vacancies, dislocations, grain
boundaries, etc.) presented in the material. As a consequence, the behavior
of such multiphase material is determined by the properties of the indi-
vidual phases and the fashion in which these phases interact. As a general
rule, the mechanical properties such as ductility, strength, resistance to creep
and fatigue of engineering materials are determined by their (micro)struc-
ture at different geometric scales.
Fundamentals of materials 5
Figure 1.2 The BSE and particles packing images of cement-based materials.
1.1.2.3 Macrostructure
Macrostructure describes the appearance of a material in the scale milli-
meters to meters, it is the structure of the material as seen with the naked
eye. The term macrostructure is sometimes used to refer to the largest
components of the internal structure. Grain flow, cracks, and porosity are
all examples of macrostructure features of materials. Macrostructure also
determines properties of materials, especially the mechanical properties.
7
8 Civil Engineering Materials
object by 9.8 m/s2 (the acceleration of gravity on the surface of the earth).
Since we are typically comparing things on the surface of the earth, the
weight of an object is commonly used rather than calculating its mass.
Specific gravity is the ratio of the density of a substance compared to the
density of freshwater at 4 C. At this temperature, the density of water is at
its greatest value and equals 1 g/cm3. Since specific gravity is a ratio, it has
no units. Specific gravity values for a few common substances are as follows:
Au, 19.3; mercury, 13.6; alcohol, 0.7893; benzene, 0.8786. Note that since
water has a density of 1 g/cm3, the specific gravity is the same as the density
of the material measured in g/cm3.
1.2.2 Fineness
Fineness indicates the fineness or coarseness degree of powdery materials. It
is often expressed as standard sieve percentage or specific surface area.
Fineness can also be expressed by percentage of particles of various sizes
or average value of unit weight material. The population of particles of
various sizes is termed as particle size distribution. D50 is usually used to
represent the particle size of group of particles, which characterizes the
median diameter or medium value of particle size distribution. For instance,
if D50 ¼ 5.8 mm, then 50% of the particles in the sample are larger than
5.8 mm and 50% smaller than 5.8 mm.
The specific surface area is the surface area of the powdery material per
unit weight. There are many methods to determine the specific surface
area, such as gas adsorption, organic molecular adsorption, and air perme-
ability. Blaine’s air permeability apparatus is commonly used for cementi-
tious materials, which consists essentially of a means of drawing a definite
quantity of air through a prepared bed of cement of definite porosity.
Fineness, PSD, and specific surface area are fundamental characteristics
of cementitious materials, they affect the properties of building materials in
many important ways. Taking cement for an example, the finesses affects its
hydration rate, water demand, workability of fresh concrete prepared with
the material.
C ¼m S (1.3)
where C is heat capacity; m is mass of material; S is specific heat.
Figure 1.4 Schematic illustration of contact angle of both hydrophobic surface and
hydrophilic surface.
Fundamentals of materials 11