09-07-2023 Sr.star Co-sc(Model-b) Jee Main Ctm-46 Qp

Sec: Sr.
STAR SUPER CHAINA-MODEL-B Date: 09-07-2023

Time: 3 Hrs Max. Marks: 300
Name of the Student: ___________________ H.T. NO:

09-07-23_ Sr.IIT STAR_SUPER_CHAINA_MODEL-B _Jee-Main_CTM-46_Syllabus
MATHS:
PRESENTWEEK (60%): AREA:
Application of Definite integrals to find the area involving simple curves
PREVIOUS WEEK (20%):
Leibnitz Rule, Definite integrals, Inequation, Approximation, Definite integrals - Reduction formula
DESIGNATED TOPIC (20%) (6QS):
Continuity & Differentiability
PHYSICS
PRESENTWEEK (60%):
OPTICS-I : Complete Reflection (Plane mirrors + Spherical mirrors)
MAINS EXPERIMENTS:
The focal length of
(i) Convex mirror
(ii) Concave mirror, using the parallax method

AC : Alternating currents, peak and RMS value of alternating current/ voltage: reactance and
impedance: LCR circuit, resonance: Quality factor, power in AC circuits, wattless current. AC
generator and transformer.
COM & Collisions
CHEMISTRY
PRESENTWEEK (60%): Colour,
Magnetic properties, Catalytic properties, alloy and interstitial compounds formation, oxides
and oxoanions of metals, Preparation & Properties of Potassium dichromate & Potassium
permanganate
f-block Elements: Lanthanoid and actinoid contractions; oxidation states; general
characteristics.

d-Block elements : General Characteristics, electronic configuration, atomic & ionic size, density,
ionisation enthalpy, melting points, enthalpy of atomization, Oxidation states, Electrode potentials,
Chemical reactivity and E0 values, Nature of oxides
Chemical & Ionic equilibrium, Alkyl & Aryl Halides
Narayana IIT Academy 09-07-23_Sr.IIT *CO SC_MODEL-A&B_ JEE-MAIN_CTM-46_Q’P
PHYSICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
01. The images of clouds and trees in water are always less bright than in reality:
a) because water is making the image dirty
b) because there is an optical illusion due to which the image appears to be less bright
c) because only a portion of the incident light is reflected and quite a large portion goes into
the water
d) because air above the surface of water contains a lot of moisture.
02. A plane mirror is moving with velocity 4i  5 j  8k . A point object in front of the mirror
moves with a velocity 3i  4 j  5k . Here, k is along the normal to the plane mirror and
facing toward the object. The velocity of the image is
a) 3i  4 j  5k b) 3i  4 j  11k
c) 3i  4 j  11k d) 7i  9 j  11k

03. The position of an object u reflected from a concave mirror is varied, the position of the
image v also varies. By letting the object distance changes from 0 to +∞ the graph between
v versus u will be ( most possible graph)
a) b)
c) d)
SR.IIT_N-SC Page. No. 2

The important thing in life is not the triumph but the struggle.
04. Select correct statement
a) Two plane mirrors are inclined to each other at an angle of 750. If a ray of light incident
on the first mirror is parallel to the second mirror, it is reflected from the second mirror
parallel to the first mirror
b) The image formed by the first surface of a thick mirror is the brightest image
c) If a ray flying successivly from two plane mirrors inclined at a certain angle undergoes a
deviation of 3000, then the number of images observable is 11
d) A clock indicates a time 3:25. On seeing it in a plane mirror, the time appears 8:55.
05. A ray of light is incident on a plane mirror along a vector aiˆ  bjˆ  ckˆ . The normal at the
iˆ  ˆj
point of incidence is . Then the unit vector along the reflected ray is _______
2
(biˆ  ajˆ  ckˆ) (biˆ  ajˆ  ckˆ)

a) b)
a 2  b2  c2 a 2  b2  c 2
(biˆ  ajˆ  ckˆ) (biˆ  ajˆ  ckˆ)

c) d)
a2  b2  c 2 a2  b2  c 2
06. A concave mirror of focal length 10 cm and another convex mirror of focal length 15 cm
are facing each other at a distance of separation 40 cm. A point object is placed at a distance
of 15 cm from the concave mirror. If the first reflection takes place at the concave mirror
and the second at convex mirror, the position of the image is
a) 16 cm behind the convex mirror
b) 6 cm in front of the concave mirror
c) 34 cm from the object towards convex mirror
d) 46 cm from the pole of concave
07. In front of a plane mirror a concave mirror of focal length 10 cm placed at a distance of 25
cm. A point object is placed on the principal axis at a distance of 15 cm in front of concave
mirror. The position of the image after three successive reflections taking the first reflection
on concave mirror is
a) At the pole of concave mirror
b) at the pole of plane mirror
c) At the center of curvature of concave mirror
d) at the focus of the concave mirror
08. A gun of mass m1 fires a bullet of mass m2 with a horizontal speed v0 . The gun is fitted
with a concave mirror of focal length ‘f’ facing towards the receding bullet. The speed of
separation of the bullet and its image is
m2
a) vr  (vg  v0 ) b) vr  2(1  )v0
m1
m2 m2
c) vr  2(1  )v0 d) vr  (1  )v0
m1 m1
09. For the given situation, the speed of the image as seen by object will be ( velocity of plane
mirror is towards right)
Vm  5ms 1
4ms 1
Object
a) 4ms 1 b) 2ms 1 c) 8ms 1 d) 14ms 1

10. For a plane mirror
p) When the object is real, image is always virtual
q) When the object is real, image is may be virtual
r) When the object is virtual, image is always real
s) When the object is real image is real
a) q, s are wrong b) p, q are wrong
c) q, s are correct d) p, s are wrong
11. The curve of a curved surface is represented by the equation y 2  2 x is placed so that the
polished surface is fading the negative x –axis and the origin is at the pole of the mirror. A
ray of light incident parallel to the X-axis at a point P(x, y) on the surface is reflected
parallel to the Y-axis. Choose the correct from the following values of (x,y)
a) (0, 0) b) (2,2) c) (1, 2 ) d) (0.5, 1)
12. There are four sources of energy losses in a transformer. They are
a) Joule heating loss in primary coil b) Joule heating loss in secondary coil
c) eddy currents loss d) hysteresis loss
Which of them are referred to as ‘iron losses’ ?

1) a, b 2) c, d 3) a, d 4) b, c
13. The core of a transformer is laminated so that
a) energy loss due to eddy currents is reduced
b) rusting of the core is prevented
c) change of flux is increased
d) ratio of voltage in the primary to that in the secondary is increased
14. Statement I: An alternating current i  i0 sin(2 / T )t passes through a resistor R. The rms
value of current from t = 0 to t= T/8 will be equal to that from time t = T/8 to t = T/4
Statement II : rms value of alternating current over a complete time period
can not be more than its peak value
a) Statemetn-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1
b) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for
Statement-1
c) Statement-1 is True, Statement-2 is False
d) Statement-1 is False, Statement-2 is True.
15. The peak voltage of 220 V a.c. mains is
a) 155.6 V b) 220.0 V c) 311 V d) 440 V
16. Below the resonance frequency, an L-C-R series behaves like
a) a resistor in series with a condenser b) a resistor in series with an inductor
c) a condenser in series with an inductor d) a resistor only
17. A uniform circular disc has a radius of 20 cm. A circular disc of radius 8 cm is cut
from edge (part of periphery coincide) from the original disc. The shift in centre of mass is
a) 1/ 7 cm b) 7/30 cm 3) 16/9 cm 4) 16 /7 cm
18. The coordinates of centre of mass of particles of masses 10 g, 20 g and 30 g are (1, 1, 1) cm,
( -2, 3, 1), and (1, -2, -2) respectively The position coordinates of mass 40 g which when
added to the system, the position of combined centre of mass be at (0, 0, 0), are
a) (3/2, 3/2, 3/2) b) (0, -0.25, 0.75)
c) (3/4, 3/4, 3/4) d) (-3/4, -3/4, -3/4)

19. Two particles, move towards each other from rest under a mutual force of attraction. At the
instant, when the speed of A is V, the speed of B is V/2. The speed of centre of mass of the
system is
a) zero b) V/2 c) 3V/2 d) 3V/4
20. Two point masses A and B of masses 1kg and 2 kg are separated by 2m. 1 kg travels with a
velocity 10 ms-1 collides with 2 kg. After the collision they travel at 450 with initial
direction of motion. Velocities after collision are _____, _____ & the Coefficient of
restitution is __________
10 5 1 5 5 1
a) , , b) , ,
2 2 2 2 2 2
10 10 1 10 5 1
c) , , d) , ,
2 2 2 2 2 4
SECTION-II
(Numerical Value Answer Type)
This section contains 10 questions. The answer to each question is a Numerical value. If the numerical value has
more than two decimal places, Truncate/Round-off the value of Two decimal places. Have to Answer
any 5 only out of 10 questions and question will be evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, 0 in all other cases.
21. When a plane mirror is placed horizontally on level ground distance of 60m from the foot of
a tower, the top of the tower and its image in the mirror subtend an angle of 900 at the eye.
The height of the tower in meter is:
22. A ray of light incident on a plane mirror at an angle 600 reached a screen arranged
perpendicular to the plane of the mirror. The distance of the screen from the point of
incidence is 3m. At t= 0 the mirror started rotating with an angular velocity 10 per second.
The speed of the spot on the screen at a time t = 15 S is 2 / 3v ms-1. Then v =
23. A thin rod of length f /3 is placed towards the pole along the principal axis of a concave
mirror of focal length f so that one end of the image coincides with the end of the rod. The
magnification of the image is M/2. Then M=
24. The sun subtends an angle 0.50 at the pole of a concave mirror of radius of curvature 1.5m.
Find the diameter of the image of the sun in 5 / N cm. then N =
25. In the path of converging rays a curved mirror such that the rays are obstructed 30 cm in
front of the point of convergence. The final image appears to be coming from a point at a
distance of 120 cm behind the mirror. The numerical value of the focal length of the mirror
in cm is
26. The focal length of a concave mirror is 30 cm. For an object approaching the mirror along
the principal axis with uniform speed 5 ms-1. The velocity of the image at the instant the
object is at a distance of 20 cm from the pole of the mirror is - 15V. Then V =
27. A series LRC circuit is connected to an a.c. source (1V, f). The voltage drop across R, L and
C respectively are 1V, 4 V and 4V. Find the reading shown in a.c. milliammeter.

28. In an a.c. circuit, E and I are given by E = 100sin(100t) volt and I = 1000sin  100t   mA.
 3
The power dissipated in the circuit in watt is _____

29. Three identical blocks each of length L and height h are kept one
above the other as shown in the diagram. The
L/3
maximum possible projection x shown is L / N. x
Then N =
30. Three particles A, B and C of equal masses move with equal speed v along the medians
towards center of gravity of a triangle. After collision A comes to rest. B retraces it path.
Then speed of C after collision is V/N. then N =

CHEMISTRY MAX.MARKS: 100
SECTION – I
31. The incorrect statement(s) among (1) – (3) is (are) :

1) W(VI) is more stable than Cr(VI)
2) in the presence of HCl , permanganate titrations provide satisfactory results.
3) Some lanthanoid oxides can be used as phosophorus
A) (2) and (3) only B) (1) and (2) only
C) (2) only D) (1) only
2 2 3
32. Consider the hydrated ions of Ti ,V ,Ti , and Sc 3 .
The correct order of their spin-only magnetic moments is :
A) V 2   Ti 2   Ti 3   Sc 3  B) Sc 3   Ti 3   Ti 2   V 2 
C) Ti 3   Ti 2   Sc 3   V 2  D) Sc 3   Ti 3   V 2   Ti 2 
33. Match the catalysts (Column I) with products (Column II).
Column I Column II
Catalyst Product
(A) V2O5 (i) Polyethylene
(B) TiCl4 / Al  Me3 (ii) ethanal
(C) PdCl2 (iii) H2SO4
(D) Iron Oxide (iv) NH3
A) (A)   iii  ;(B)   iv ;  C   i  ;  D   ii 
B) (A)   ii  ;(B)   iii  ;  C   i  ;  D   iv
C) (A)   iii  ;(B)   i  ;  C   ii  ;  D   iv
D) (A)   iv ;(B)   iii  ;  C   ii  ;  D   i 

34. Strong reducing and oxidizing agents among the following respectively, are
A) Eu 2  and Ce 4  B) C e 3  and Ce 4  C) C e 4  and T b 4  D) C e 4  and Eu 2 
35. Which of the following factors may be regarded as the main cause of lanthanide
contraction?
A) Greater shielding of 5d electrons by 4f electrons
B) Poorer shielding of 5d electrons by 4f electrons
C) Effective shielding of one of the 4f electrons by another in the subshell
D) Poor shielding of one of the 4f electrons by another in the subshell
36. The incorrect statement is :
A) Manganate and permanganate ions are tetrahedral
B) In manganate and permanganate ions, the -bonding takes place by overlap of
p-orbitals of oxygen and d-orbitals of manganese
C) Manganate and permanganate ions are paramagnetic
D) Manganate ion is green in colour and permanganate
37. pick out the incorrect statement:
2
(A) MnO4 is quite strongly oxidizing and stable only in very strong alkalies. In dilute alkali,
neutral solutions, it disproportionates.

(B) In acidic solutions, MnO4 is reduced to Mn  2 and thus,
KMnO4 is widely used as
oxidizing agent
KMnO4 does not acts as oxidizing agent in alkaline medium.
(C)
KMnO4 is manufactured by the fusion of pyrolusite ore with KOH in presence of air or
(D)
KNO3 , followed by electrolytic oxidation in alkaline solution.
38. A  4
KOH ,O 2
  2B  2H 2 O
(Green )
B  4
HC l
  2C  M nO 2  2H 2 O
(Purple)
H 2 O ,KI
2C   2A  KOH  D
In the above sequence of reactions, A and D, respectively are :

A) KI and KMnO4 B) MnO2 and KIO3
C) KIO3 and MnO2 D) KI and K2MnO4

39.
Total number of 3 degree carbon atoms present in major product P is ….
A) 4 B) 6 C) 5 D) 3
40. The electronic configurations of bivalent europium and trivalent cerium are:
(atomic number: Xe  54, Ce  58, Eu  63 )
A)  Xe 4f 2 and  Xe 4f 7 B)  Xe 4f 7 and  Xe 4f 1
C)  Xe 4f 7 6s2 and  Xe 4f 2 6s2 D)  Xe 4f 4 and  Xe 4f 9
41. The number of unpaired electrons in Gadolinium  Z  64 is
A) 3 B) 8 C) 6 D) 2
42. In the Seveso disaster I Northern Italy in 1976, a large amount of highly toxic gas
(Q) was released when the reaction converting 1,2,4,5-tetrachlorobenzene into 2,4,5-
trichlorophenol was overheated. Then find out degree of unsaturation of Q is……
A) 6 B) 8 C) 9 D) 5
43. Which of the following statement is incorrect regarding following reaction scheme:
A) K and M are diasteromers

B) K is racemic mixture while M is mesoform
C) L and N are diastelroms
D) Stability of L is more than that of N

44. Pyrolusite in M nO2 is used to prepare K M nO 4 . Steps are
I
MnO2  MnO42 
II
MnO4
Here, I and II are
(A) fused with KOH / air, electrolytic oxidation
(B) fused with KOH / air, electrolytic reduction
(C) fuse with cone. HNO3 / air, electrolytic oxidation
(D) All are correct
45. The mechanism of SN I reaction is given as :

Y
R  X  R  X   R  X    R  Y  X
ion pair
Solvent
Separatedion
pair
A student writes general characterstics based on the given mechanism as :

A) The reaction is favoured by weak nucleophiles
B) R  would be easily formed if the substituents are bulky
C) The reaction is accompanied by racemization
D) The reaction is favoured by non-polar solvents
Which observations are correct?
A) (1) and (2) B) (1) and (3)
C) (1) (2) and (3) D) (2) and (4)
46. Identify correct reactivity order for ArSN reaction
A) i  ii  iii B) ii  iii  i C) i  iii  ii D) iii  i  ii

47. which of the following statements about the interstitial compounds is incorrect?
A) They retain metallic conductivity
B) They are chemically reactive
C) They are much harder than the pure metal
D) They have higher melting points than the pure metal
48. Identify correct reactivity order for SN2 reaction
A) i  ii  iii B) ii  iii  i C) i  iii  ii D) iii  i  ii

49. (i) Chlorobenzene is mono-nitrated to M
(ii) Nitrobenzene is mono-chlorinated to N
(iii) Anisole is mono-nitrated to P
(iv) 2-Nitrochlorobenzene is mono-nitrated to Q
Out of M, N, P and Q the compound that undergoes reaction with aq.NaoH fastest is
A) M B) N C) P D) Q
50. Balance the following reaction.
FeC2O4  KMnO4  H2SO4  Fe2 SO4 3  CO2  MnSO4  K2SO4  H2O
A) 10FeC2O4  6KMnO4  2H2SO4  5Fe2  SO4 3  20CO2  6MnSO4  3K2SO4  24H2O
B) 5FeC2O4  4KMnO4 12H2SO4  7Fe2  SO4 3  20CO2  6MnSO4  3K2SO4  24H2 O
C) 10FeC2O4  4KMnO4  24H2SO4  6Fe2  SO4 3  20CO2  6MnSO4  3K2SO4  24H2O
D) None of these

SECTION-II
51. In the chemical reaction between stoichiometric quantities of KMnO4 and KI in weekly
basic solution, what is the number of moles of I2 released for 4 moles of
KMnO4 consumed?
52. Total number of species that can be oxidized by acidic permanganate ion  MnO 4  / H  
I ,Fe2 ,CO2 ,C2O42 ,S2 ,SO32 , NO2 ,PO43 ,SO42
53. The spin - only magnetic moment value of M 3 ion (in gaseous state) from the pairs
Cr3 / Cr2 ,
Mn3 / Mn2, Fe 3  / Fe 2  and Co 3  / Co 2  that has negative standard electrode potential is B.M
[Nearest integer]
54. Find total number of ions whose aqueous solution is coloured.
Sc3 ,Ti3 ,V3,Cr3,Mn2 ,Fe2,Co2,Ni2,Cu2 ,Zn2
55. The number of moles of F eC 2 O 4 that reduces three moles of K M nO 4 in acidic medium
are
56. An acidified solution of potassium chromate was layered with an equal volume of amyl
alcohol. When it was shaken after the addition of 1 ML of 3% H2O2 ,a blue alcohol layer
was obtained. The blue color is due to the formation of a chromium (VI) compound
' X ' .what is the number of oxygen atoms bonded to chromium through only single bonds
in a molecule of X ?
57. The degree of dissociation of 0.1M weak acid is 10 2 and the degree of dissociation of
the same acid in 0.025M concentration is ‘x’. then find 100x____
58. KSP of M (OH)x is 27x10-12 and its solubility in water is 10 3 mole litre 1 . Find the value
of x.
59. Solubility products of ACO3, BSO4 and ASO4 are 4x10-10 , 6x10-10 and 8x10-10 respectively.
The solubility product of BCO3 is x  10 10 . What is x.

60. The equivalent weight of Potassium dichromate in acidic medium is __________

MATHEMATICS MAX.MARKS: 100

SECTION – I
61. Area bounded between two successive points of intersections of y  sin x, y  cos x is
A) 2 B) 2 C) 2 2 D) 8
62. f(x) is an increasing function such that f (x) > 0  x  R; f(0) = 0; if f(1) = 1,
1
 f  x  dx  K
1
then area bounded by f(x) and f–1(x) can be
0
A) 2K – 2 B) 2K – 1 C) 1 – 2K D) K
2
63. Area of the region bounded by the curve  y  x   x 3 and x  1 is
1 2 3 4
A) B) C) D)
5 5 5 5
64. The area bounded by the curve (y – arc sinx)2 = x – x2, is
  
A) B) C)  D)
4 2 3
65. The area of the figure bounded by y  x 2  2 x  3 and the line tangent to it at M  2,3 and
y  axis is
1
A) B) 8 / 3 C) 2 D) 4
3
66. Let f(x) be a positive continuous function such that the area bounded by the curve y =
a2 a   
f(x), the x-axis and the two ordinates x = 0 and x = a is  sin a  cos a ,then f   is
2 2 2 2
1 2   1 2 
A) B)  C) D) 
2 8 4 2 8 4
x2
67. The circle x 2  y 2  8 is divided into two parts by the parabola y  then area of the
2
smaller part is
4 4 8 16
A)   B) 2  C) 2  D) 2 
3 3 3 3

68. The area bounded by the curves y  2 | x 1| , y  sin x ; x  0 and x  2 is

A) 1  2cos2 1 B) 2  sin 2 1 C) D) 1  log 2
2
69. The area of the region enclosed by the curve 5x2 + 6xy + 2y2 + 7x + 6y + 6 = 0 is
  
A) sq. unit B) sq. unit C)  sq. unit D) sq. unit
4 2 3
70. Area bounded by the curve x 2/ 3  y 2 / 3  a 2 / 3 is
 a2 3 a 2 3 a 2 3 a 2
A) B) C) D)
3 5 8 4
1
71. Find the area enclosed between the curves y  ln  x  e  , x  ln   and x-axis
y  
A) 1 sq units B) 2 sq units C) 3 sq units D) 4 sq units
1 1 2 2
72. If I1   2 x 2 dx, I 2   2 x 3dx, I 3   2 x 2 dx and I 4   2 x 3dx, , then
0 0 1 1
A) I3 > I4 B) I3 = I4 C) I1 > I2 D) I2 > I1
73.   xdx    a  4 , then

0
a
A) 0  a  4 B) 2  a  4 C) 2  a  0 D) a  2 or a  4
1
n In 
74. Let I n   1  x a  dx and if  1  then  equals
0
I n1 a
1 1
A) n B) n+1 C) D)
n n 1
 /2
75. If U n   x n sin x dx , then the value of u10  90 u8 is:
0
8 9 9 9
   
A) 9   B)   C) 10   D) 9  
2 2 2 2
(1  3x)5/3x , x  0
76. f(x)   .If f(x) is continuous at x = 0, then k =
 k, x 0
A) e2 B) e4 C) e5 D) e3
 n 1
 x sin   x  0
77. If f  x     x is continuous but not differentiable at x=0 then
 0 x0

A) n  (-1,0) B) n  (0,2] C) n  (0,1] D) n  (1,2)
2n
78. Let f(x) = limsin
n 
x , then number of point(s) where f(x) is discontinuous is
A) 0 B) 1 C) 2 D) infinitely many
79. The area defined by 1  x  2  y  1  2 in square units is
A) 2 B) 4 C) 6 D) 8
80. The area between the curves y  2 x 4  x 2 , the x-axis and the ordinates of two minima of
the curve is in square units.
7 5 7 7
A) B) C) D)
120 127 127 60
SECTION-II
81. Area bounded by  x    y   3 is (where [.] denotes G.I.F.)
82. Area of the figure bounded by y  x  1 , y  3  x is
83. If the area of the region bounded by y  x  x 2 and y  mx is equal to 9/2 then positive
value of ‘m’ is
84. Area of the region bounded by x 2 y 2  a 2  y 2  x 2  and x   a . is  a 2 then   ____
85. Let f ( x )  x 2  6 x  1 and S denotes the set of points (x, y) in the coordinate plane such that
f ( x )  f ( y )  0 and f ( x )  f ( y )  0 The area of S is k then k =……
x
86. Let f :  0,    R and F  x    f  t  dt. If F  x 2   x 2 1  x  , then f ( 4 ) equals
0

1
87. The value of Lt  tan  t sin x dx equals
t 0 t
0
88. Let f  x   cos x  sin x  , 0  x  2 , where [.] denotes G.I.F. Then number of points of
discontinuity of f(x) is
89. The function f  x    x 2  1 x 2  3x  2  cos  x  is not differentiable at x=_____
 3
90. Let f : 0,  R be a function defined by f(x) = max sin x,cos x,  , then number of points
 2   4
where f(x) is non differentiable is


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Sec: Sr.

STAR SUPER CHAINA-MODEL-B Date: 09-07-2023

Name of the Student: ___________________ H.T. NO:

PREVIOUS WEEK (20%):

PREVIOUS WEEK (20%):

c) 3i  4 j  11k d) 7i  9 j  11k

SR.IIT_N-SC Page. No. 2

(biˆ  ajˆ  ckˆ) (biˆ  ajˆ  ckˆ)

(biˆ  ajˆ  ckˆ) (biˆ  ajˆ  ckˆ)

a) 4ms 1 b) 2ms 1 c) 8ms 1 d) 14ms 1

SR.IIT_N-SC Page. No. 4

SR.IIT_N-SC Page. No. 5

The power dissipated in the circuit in watt is _____

SR.IIT_N-SC Page. No. 7

31. The incorrect statement(s) among (1) – (3) is (are) :

(B) TiCl4 / Al  Me3 (ii) ethanal

(C) PdCl2 (iii) H2SO4

(D) Iron Oxide (iv) NH3

A) (A)   iii  ;(B)   iv ;  C   i  ;  D   ii 

B) (A)   ii  ;(B)   iii  ;  C   i  ;  D   iv

C) (A)   iii  ;(B)   i  ;  C   ii  ;  D   iv

D) (A)   iv ;(B)   iii  ;  C   ii  ;  D   i 

SR.IIT_N-SC Page. No. 8

In the above sequence of reactions, A and D, respectively are :

C) KIO3 and MnO2 D) KI and K2MnO4

Total number of 3 degree carbon atoms present in major product P is ….

A)  Xe 4f 2 and  Xe 4f 7 B)  Xe 4f 7 and  Xe 4f 1

C)  Xe 4f 7 6s2 and  Xe 4f 2 6s2 D)  Xe 4f 4 and  Xe 4f 9

41. The number of unpaired electrons in Gadolinium  Z  64 is

A) K and M are diasteromers

SR.IIT_N-SC Page. No. 10

A student writes general characterstics based on the given mechanism as :

A) i  ii  iii B) ii  iii  i C) i  iii  ii D) iii  i  ii

SR.IIT_N-SC Page. No. 11

48. Identify correct reactivity order for SN2 reaction

A) i  ii  iii B) ii  iii  i C) i  iii  ii D) iii  i  ii

A) 10FeC2O4  6KMnO4  2H2SO4  5Fe2  SO4 3  20CO2  6MnSO4  3K2SO4  24H2O

B) 5FeC2O4  4KMnO4 12H2SO4  7Fe2  SO4 3  20CO2  6MnSO4  3K2SO4  24H2 O

C) 10FeC2O4  4KMnO4  24H2SO4  6Fe2  SO4 3  20CO2  6MnSO4  3K2SO4  24H2O

SR.IIT_N-SC Page. No. 12

The solubility product of BCO3 is x  10 10 . What is x.

SR.IIT_N-SC Page. No. 13

MATHEMATICS MAX.MARKS: 100

SR.IIT_N-SC Page. No. 14

A) I3 > I4 B) I3 = I4 C) I1 > I2 D) I2 > I1

73.   xdx    a  4 , then

82. Area of the figure bounded by y  x  1 , y  3  x is

where f(x) is non differentiable is

SR.IIT_N-SC Page. No. 16

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