TEST

CLASS XII

OBJECTIVE QUESTIONS – (7) MM=25

1. What is the quantity of electricity in coulombs needed to reduce one mole of Cr2O72-
(1 F = 96500 C/mol)
2. What is the value of van’t hoff factor for ethanoic acid in benzene?
3. The standard emf of a galvanic cell involving 3 moles of electrons in a redox
reaction is 0.59 V. The equilibrium constant for the reaction of the cell is:
4. In comparison to a 0.01 M solution of glucose, the depression in freezing point of
a 0.01 M MgCl2 solution is_______________
5. Draw an enantiomer of :

6. Why is glycol and water mixture used in car radiators in cold countries?

7. Assertion (A) : Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene.

Reason (R) : —NO2 group is a m-directing group.
a) Both Assertion (A) and Reason (R) are correct statements, and Reason (R) is the
correct explanation of the Assertion (A).
b) Both Assertion (A) and Reason (R) are correct statements, but Reason (R) is not the
correct explanation of the Assertion (A).
c) Assertion (A) is correct, but Reason (R) is an incorrect statement.
d) Assertion (A) is incorrect, but Reason (R) is correct statement.

SUBJECTIVE QUESTIONS – (18)

1. Using the Eo values of X and Y, predict which is better for coating the surface
of iron to prevent rust? [1]

2. What are diasteromers? Give example? [1]

3. Give major products of : [1]

1
4. Predict all the alkenes that would be formed by dehydrohalogenation of the
following halides with sodium ethoxide in ethanol and identify the major
alkene. [1]
(i) 1-Bromo-1-methylcyclohexane
(ii) 2-Chloro-2-methylbutane
5. The vapour pressure of pure liquids A and B are 450- and 700-mm Hg
respectively. Find out the composition of the liquid mixture if the total vapour
pressure is 600 mm Hg. Also find the composition of the vapour phase. [2]
6. Write a short note on : [2]
a) Dow’s process
b) Finkelstein reaction
7. Calculate the freezing point of a solution when 3 g of CaCl2 (M = 111 g mol–1)
was dissolved in 100 g of water, assuming CaCl2 undergoes complete
ionisation. (Kf for water = 1.86 K kg mol–1)
8. Give reactions of discharging of lead storage battery? [2]
9. Convert : [2]
(i) Chlorobenzene to p-nitrophenol
(ii) Ethyl chloride to propanoic acid
10. 2 g of benzoic acid (C6H5COOH) dissolved in 25 g of benzene shows a
depression in freezing point equal to 1.62 K. Molal depression constant for
benzene is 4.9 K kg mol–1. What is the percentage association of acid if it forms
dimer in solution? [3]
11. Calculate e.m.f and ∆G for the following cell at 298 K: [3]