31-12-23

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A galvanometer of resistance 100  contains 100 division. It gives a deflection of one
division on passing a current of 104 A . Find the resistance to be connected to it, so that it
becomes a voltmeter of range 10V.

500 100
A)  B) 500  C)  D) 900 
9 9

2. If mass density of earth varies with distance ‘r’ from centre of earth as   k r and ‘R’ is
radius of earth, then find the orbital velocity of an object revolving around earth at a
distance ‘2R’ from its centre.

 kR3G  kR3G  kR3G

A) B) C) D)  kR 3G
4 2 8

3. A particle moves clockwise in a circle of radius 1 m with centre at ( x, y )  (1 m, 0) . It

starts at rest at the origin at time t  0 . Its speed increases at the constant rate of
  
  m / s . If the net acceleration at t  2sec is
2
2

2
1  N 
2
then what is the value of N ?

A) 2 B) 4 C) 1 D) 6

4. The rms speed of hydrogen molecules at a certain temperature is 300 m/s. If the
temperature is doubled and hydrogen gas dissociates into atomic hydrogen, the rms
speed will become

A) 100 m/s B) 300 m/s C) 600 m/s D) 300 2 m / s

5. The power of a lens (biconvex) is 1.25 m 1 in a particular medium. Refractive index of the
lens is 1.5 and radii of curvature are 20 cm and 40 cm respectively. The refractive index
of surrounding medium is

9 3 4
A) 1.0 B) C) D)
7 2 3
6. Let An be the area enclosed by the nth orbit in a hydrogen atom. The graph of n  An / A1 
against n(n)

A) will not pass through the origin

B) will have certain points lying on a straight line with slope 4

C) will be a monotonically increasing non linear curve

D) will be a circle

7. A screw gauge has 50 divisions on its circular scale. The circular scale is 4 units ahead
of the pitch scale marking, prior to use. Upon one complete rotation of the circular
scale, a displacement of 0.5mm is noticed on the pitch scale. The nature of zero error
involved and the least count of the screw gauge are respectively

A) Positive, 0.1  m B) Positive, 10  m C) Negative, 10  m D) Negative, 0.1  m

8. In an LC oscillator, if values of inductance and capacitance become twice and eight

times, respectively, then the resonant frequency of oscillator becomes ' x ' times its initial
resonance frequency 0 . The value of ' x ' is

1 1
A) B) 4 C) 16 D)
4 16

9. A closed organ pipe and an open pipe of same length produce 6 beats per sec when they
are set into vibrations simultaneously with their fundamental frequency. If the length of
each pipe is doubled, then the number of beats produced is

A) 4 B) 3 C) 5 D) 7

10. A closely wound solenoid of 1000 turns and area of cross – section 2.0  104 m 2 carries a
current of 2.0 A. It is placed with its axis horizontal in a uniform horizontal magnetic
field of 0.16 T. If the solenoid is free to turn about the vertical direction. The amount of
work (in J) needed to displace the solenoid from its stable orientation to its unstable
8x
orientation is . Find the value of x ?
250

A) 5 B) 4 C) 3 D) 2
11. The ratio of the KE and PE possessed by a body executing SHM when it is at a distance
of 1/n of its amplitude from the mean position is
1
A) n 2 B) C) n 2  1 D) n 2  1
n2

12. A fish rising vertically up towards the surface of water with speed 3 ms 1 observes a bird
diving vertically down towards it with speed 9 ms 1 . The actual velocity of bird is
4
(Given water  )
3

A) 4.5 ms 1 B) 5.4 ms 1 C) 3.0 ms 1 D) 3.4 ms 1

13. Electric potential on the surface of a uniformly charged solid sphere is V. Radius of the
sphere is R(=1m). Match the following two columns. ( ' r ' is the distance from the centre
of the sphere)
Column I Column II
R V
(A) Electric potential at r  (P)
2 4
V
(B) Electric potential at r  2R (Q)
2
3R 3V
(C) Electric field at r  (R)
4 4
11V
(D) Electric field at r  2R (S)
8
A) A – P; B – R; C – Q; D – S B) A – S; B – P; C – Q; D - R
C) A – S; B – Q; C – R; D – P D) A – R; B – Q; C – P; D – S
14. In the figure, potential difference between A and B is (Diode is ideal)

A) 5 V B) 10 V C) zero D) 15 V
15. In a photoelectric experiment, with light of wavelength  , the fastest electron has speed
3
v. If the exciting wavelength is changed to , the speed of the fastest emitted electron
4
will become
3 4 3 4
A) v B) v C) less than v D) greater than v
4 3 4 3
16. An insect is at the bottom of a hemispherical ditch of radius 1 m. It crawls, up the ditch
but starts slipping after it is at height ' h ' from the bottom. If the coefficient of friction
between the ground and the insect is 0.75, then ' h ' is ( g  10 ms 2 )

A) 0.80 m B) 0.60 m C) 0.45 m D) 0.20 m

17. For one mole of mono atomic ideal gas temperature (T in Kelvin) and Volume (V in m3 )
relate as shown in the graph. What is the change in internal energy from B to D?
 25 1 1 
 R  3 J mol K 

A) 1250 B) 1290 C) 1300 D) 1350

18. Statement 1 : A large soap bubble expands while a small bubble shrinks, when they are
connected to each other by a capillary tube

Statement 2 : The excess pressure inside bubble is inversely proportional to its radius

A) Statement–1 is True, Statement–2 is True; Statement–2 is a correct explanation for

Statement – 1.

B) Statement – 1 is True, Statement – 2 is True; Statement – 2 is not a correct

explanation for Statement – 1.

C) Statement -1 is True, Statement – 2 is False.

D) Statement – 1 is False, Statement – 2 is True.

19. Two identical billiard balls are in contact on a smooth table. A third identical ball
strikes them symmetrically and comes to rest after impact. The coefficient of restitution
is

2 1 1 3
A) B) C) D)
3 3 6 2
20. Three elephants A, B and C are moving along a straight line with constant speed in same
direction as shown in figure. Speed of A is 5 m/s and speed of C is 10 m/s. Initially
separation between A & B is ‘d’ and between B & C is also d. When ‘B’ catches ‘C’
separation between A & C becomes 3d. Find the speed of B (in m/s).

A) 15 B) 20 C) 5 D) 25

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. A beam of natural light falls on a system of 5 polaroids which are arranged in succession
such that the pass axis of each Polaroid is turned through 600 w.r.t. the preceding one.
1
The fraction of intensity of incident light that passes through the system is . Then
128 n

the value of n ?

22. A 60 pF capacitor is fully charged by a 20 V supply. It is then disconnected from the

supply and is connected to another uncharged 60 pF capacitor in parallel. The
electrostatic energy that is lost in this process by the time the charge is redistributed
between them is (in nJ) __________

23. A body of mass 2 kg moving with a speed of 4 ms 1 makes an elastic collision with
another body at rest and continues to move in the original direction but with one fourth
of its initial speed. The speed of the centre of mass of two body system after the collision
x
is ms 1 . Then the value of ' x ' is _________
10
24. In the LCR circuit shown, if RMS voltages across resistor, inductor and capacitor are
equal, the RMS value of voltage across resistor will be _________ volt.

25. In a cylinder piston arrangement, air is under a pressure P1 . A soap bubble of radius r
lies inside the cylinder. Soap bubble has surface tension T. The radius of bubble is to be
reduced to half. The pressure P2 to which air should be compressed isothermally is
BT
AP1  . Then the value of A  B is ________
r
26. A system of identical cylinders and plates is shown in figure. All the cylinders are
identical and there is no slipping at any contact. The velocity of lower and upper plates
are V and 2V, respectively, as shown in figure. Then the ratio of angular speeds of the
upper cylinders to lower cylinders is

27. The potential energy (in joule) of a body of mass 2kg moving in the x-y plane is given
by U  6 x  8 y . Where the position coordinates x and y are measured in metre. If the
body is at rest at point (6m, 4m) at time t = 0, it will cross the y-axis at time t equal to
28. An electromagnetic wave of frequency 1  1014 hertz is propagating along z-axis. The
amplitude of electric field is 4 V/m. If 0  8.8  1012 C 2 / N  m2 , then average energy
density of electric field will be N  1013 J / m3 .
29. The moment of inertia of a uniform circular disc about its diameter is 200 gm cm 2 . Then
its moment of inertia about an axis passing through its center and perpendicular to its
circular face is ______ gm cm2.
30. A light beam of wavelength 500 nm is incident on a metal having work function of 1.25
eV, placed in a magnetic field of intensity B. The electrons emitted perpendicular to the
magnetic field B, with maximum kinetic energy are bent into circular arc of radius 30
cm. The value of B is _____ 107 T . [Given hc  20 1026 J -m , mass of electron =
9  10 31 kg ]
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. In which of the following, mixing of 1N strong acid and 1N strongbaseresults in highest
increase in temperature.

A)20 ml acid + 30 ml alkali B)10 ml acid + 40 ml alkali

C)25 ml acid + 25 ml alkali D)35 ml acid + 15 ml alkali

32. Which of the following is an incorrect statement?

A)Half-life of second order reaction decreases with increase in concentration of reactant

B)Half-life of first order is independent of concentration of the reactant

C)The unit of rate constant of zero order is equal to unit of rate

D)The unit of frequency factor A in Arrhenius equation is the unit of half-life of the
reaction

33. A set of solution is prepared by using 180g of water as a solvent and 10g of different
non-volatile solutes A, B and C. The relative lowering of vapour pressure in the presence
of these solutes are in the order [Given, molar mass of A = 100 g mol1 ; B = 200 g mol1 ;
C = 10000 g mol1 ]

A)A > B > C B)A > C > B C)C > B > A D)B > C > A

34. Which of the following is an extensive property?

A)Heat capacity B)Refractive index

C)Specific volume D)Molarity

35. A certain metal when irradiated by light (  3.2  1016 Hz) emits photoelectrons with twice
kinetic energy than the photoelectrons emitted when the same metal is irradiated by
light (  2.0 1016 Hz) . Then 0 of metal is

A) 1.2 1014 Hz B) 8 1015 Hz (c)1.5 1016 Hz D) 4 1012 Hz

36. KMnO4 reacts with KI, in weakly basic medium to form I 2 and MnO2 . When 250 ml of

0.1 M KI solution reacts with 250 mL of 0.02 M KMnO4 in basic medium, what is the
number of moles of I2 formed?

A)0.015 B)0.0075 C)0.005 D)0.01

37. The term invert sugar refers to an equimolar mixture of

A)D-Glucose and D-Galactose B)D-Glucose and D-Fructose

C)D-Glucose and D-Mannose D)D-Glucose and D-ribose

38. Given below are two statements:

Statement-I: Pure Aniline and other arylamines are usually colourless

Statement-II:Arylamines get coloured on storage due to atmospheric reduction

In the light of the above statements, choose the most appropriate answer from the
options given below

A)Both statement-I and II are incorrect

B)Both statement-I and II are correct

C)Statement-I is correct but statement-II is incorrect

D)Statement-I is incorrect but statement-II is correct

39. Mark out the incorrect option regarding Cannizzaro reaction

A)The aldehyde, which doesn’t have enolisable hydrogen undergo Cannizzaro reaction

B)All types of Cannizzaro reaction e.g. inter, intra and crossed all can be said
disproportionation reaction

OH 
C)Reaction PhCHO  CD 2  O 
 PhCHD  OH  DCOO 

D)Reaction can be first order in base and 2nd order in substrate

40. Identify the alkyne in the following sequence of reactions

H Wacker
2
Alkyne  O3 / Zn
 A   B   H 2C  CH 2
Lindlar's Catalyst
H 2O
Only Process

A) CH3  C  C  CH3 B) CH3  CH 2  C  CH

C) CH2  CH  C  CH D) CH  C  CH2  C  CH

41. The IUPAC name of the following compound is

A)2-nitro-4-hydroxymethyl-5-amino benzaldehyde

B)3-amino-4-hydroxymethyl-5-nitrobenzaldehyde

C)5-amino-4-hydroxymethyl-2-nitrobenzaldehyde

D)4-amino-2-formyl-5-hydroxymethyl nitrobenzene

42. Lassaigne’s test for the detection of nitrogen fails in

A) NH2CONHNH2  HCl B) NH2 NH2  HCl
C) NH2CONH2 D) C6 H5 NHNH 2  HCl
43. Given below are two statements
Assertion (A): Cu 2 in water is more stable than Cu  .
Reason (R): Enthalpy of hydration for Cu 2 is much more negative than that of Cu  .
In the light of the above statements, choose the correct answer from the options given
below
A) Both A and R are correct and R is the correct explanation of A
B) A is correct but R is not correct
C) A is not correct but r is correct

D) Both A and R are correct but R is not the correct explanation of A

44. Which of the following statement is not correct?

A) B(OH)3 is acidic

B)Aqeous solution of Potash alum is acidic in nature

C)The decreasing order of acidic natureof BBr3 , BCl3 and BF3 is BBr3  BCl3  BF3

D) B2H6 contains B – B covalent bonds

45. Among the following, the correct statement is

A)Between NH3 and PH3 , NH3 is a better electron donor because the lone pair of
electrons occupies spherical ‘s’ orbital and is less directional

B)Between NH3 and PH3 , PH3 is a better electron donor because the lone pair of
electrons occupies sp3 orbital and is more directional

C)Between NH3 and PH3 , NH3 is a better electron donor because the lone pair of
electrons occupies sp3 orbital and is more directional

D)Between NH3 and PH3 , PH3 is a better electron donor because the lone pair of
electrons occupies spherical ‘s’ orbital and is less directional
46. Match the list-I with List-II
List-I (Cations) List-II (Group reaction)
(P) Pb 2 , Cu 2 (I) H2S gas in presence of dilute HCl
(Q) Al3 , Fe3 (II) (NH4 )2 CO3 in presence of NH4OH

(R) Co 2 , Ni 2 (III) NH4OH in presence of NH4Cl

(S) Ba 2 , Ca 2 (IV) H2S in presence of NH4OH .
A)P-I, Q-III, R-II, S-IV B)P-IV, Q-II, R-III, S-I
C)P-III, Q-I, R-IV, S-II D)P-I, Q-III, R-IV, S-II
47. Which of the following is correct stability order of oxides of 17th group elements is
A) Cl2  Br2  I2 B) I2  Br2  Cl2

C) I2  Cl2  Br2 (d) Cl2  I2  Br2

48. In the electrolysis of CuCl2 solution using Cu electrodes, the weight of Cu increased by 2
gram at cathode.At the anode:

A)0.2 mole of Cu 2 will go into solution

B)560 ml of O2 liberate

C)No loss in weight

D)2 gram of copper goes into solution as Cu 2

49. The major product of the following reaction is

A) B)

C) D)

50. The conductivity measurement of a coordination compound of Cobalt (III) shows that it
dissociates into 3 ions in solution. The compound is

A)Hexaamminecobalt(III) chloride

B)Pentaamminesulphatocobalt(III) chloride

C)Pentaamminechloridocobalt(III) sulphate
D)Pentaaminechloridocobalt (III) chloride
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51. In the following monobromination reaction, the number of possible chiral product(s)
is/are ____

52. The number of geometrical isomers possible for the complex

[Co L 2 Cl2 ] (L  H 2 NCH 2 CH 2 O  ) is

53. Consider the following reaction 6NaOH  3Cl 2 

 5NaCl  A  3H 2O . What is the
oxidation number of chlorine in “A”?
54. On complete combustion, 0.492g of an organic compound gave 0.792 g of CO2 . Then
the % of carbon in the organic compound is ____________ (Nearest Integer)
55. The number of d  p bonds in ClO4

56. The value of log10 K for a reaction A 

 B is (Given:  r H 0298K  54.07 kJ mol1 ,
 rS0298K  10 JK 1 mol1 and R  8.314 JK 1mol1 , 2.303  8.314  298  5705 )

57. A decapeptide (Molecular weight 796) on complete hydrolysis gives glycine (Molecular
weight 75), alanine and phenylalanine. Glycine contributes 47.0% to the total weight of
the hydrolyzed products. The number of glycine units present in the decapeptide is
58. The total number of cyclic isomers possible for a hydrocarbon with the molecular
formula C4 H 6 is
59. Consider the reaction: AB2 (g)  AB(g)  B(g) . If the initial pressure of AB2 is 500 torr
and equilibrium pressure is 600 torr, equilibrium constant K p in terms of torr is

60. Reductive ozonolysis of a terpenoid of following structure gives how many

different products.
MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1
x 2 sin    2 x
 x
61. Let f x   1
then lim f x  x 0
 
1  x  x e

2 2 4 4
A) B) C) D)
e e e e

62. In a triangle ABC, BC= 3 and AC= 4 and circle with AB as diameter passes through the
centroid of a triangle, then AB is

5
A) 5 B) 5 C) 3 D)
2


2 x 1  sin x 
63. The value of definite integral  dx is:

1  cos 2 x

 2
A) B)  C)  2
D)
2 2

64. Let f  x   x3  x  1 and g  x  be its inverse then g   3  ___________.

1 1
A) B)  C) 4 D) –4
4 4

65. Let f  x  be a cubic polynomial on R which increases in the interval  , 0  and in 1,  

and decreases in the interval  0,1 . If f   2   6 and f  2   2 , then the value of

  3 
tan 1  f 1   tan 1  f     tan 1  f  0   is equal to:
  2 

A) tan 1 2 B) cot 1 2 C)  tan 1 2 D)  cot 1 2

66. Let the equations of two adjacent sides of a parallelogram ABCD be 2 x  3 y   23 and
5 x  4 y  23 . If the equation of its one diagonal AC is 3 x  7 y  23 and the distance of A
from the other diagonal is d, then 50d 2 is equal to__________

A) 501 B) 529 C) 468 D) 731

67. A survey of 500 television watchers produced the following information, 285 watch
football, 195 watch hockey, 115 watch basketball, 45 watch football and basketball, 70
watch football and hockey, 50 watch hockey and basketball, 50 do not watch any of the
three games. How many watch all the three games? How many watch exactly one of the
three games?

A) 190 B) 40 C) 25 D) 325

z i  
68. The mirror image of the curve arg    , i  1 in the line z  i  1  z 1  i   0 , in
 z 1  4

argand plane , is

z i   z 1 
A) arg   B) arg  
 z 1 4  z i  4

z i  z i 
C) arg  
 D) arg  

 z 1 4  z 1  4

69. If x  sin 1  sin10  and y  cos1  cos10  , then y  x is equal to:

A)  B) 0 C) 10 D) 7

70. Statement 1:Length of side of an equilateral triangle is 24. The mid points of the sides
are joined to form another triangle whose midpoints of sides are joined to form another
triangle and continue the process infinite number times. Then sum of perimeters of all
such triangles formed is 144.
Statement 2 : If log 2  a  b   log 2  c  d   4 then the minimum value of a+b+c+d is 8
A) Statements 1 & 2 both are correct
B) Statements 1 & 2 both are false
C) Statement 1 is true, statement 2 is false

D) Statement 1 is false, statement 2 is true

1  x x y
For each real x, -1<x<1. Let A(x) be the matrix 1  x  
1
71.  and z  . Then
 x 1 1  xy

A) A  z   A  x  A  y  B) A  z   A  x   A  y 

1
C) A  z   A  x   A  y  D) A  z   A  x   A  y 
72. If  ,  are the roots of the equation   x 2  x   x  5  0 . If 1 and 2 are two values of
  4  
 for which the roots  ,  are related by   , then the value of 1  2 , is
  5 2 1

A) 254 B) 200 C) 350 D) 154

73. Let A  1, 2,3, 4,5,6,7 . The number of surjective functions defined from A to A such that

f  i   i for atleast four values of i from i  1, 2,...., 7, is:

A) 7! B) 92 C) 126 D) 407

74. Let a line l pass through the origin and be perpendicular to the lines

    
   
l1 : r  iˆ  11 ˆj  7kˆ   iˆ  2 ˆj  3kˆ ,   R and l2 : r  iˆ  kˆ   2iˆ  2 ˆj  kˆ ,   R .

If P is the point of intersection of l and l1 , and Q  ,  ,   is the foot of perpendicular

from P on l2 , then       is ________

5 9 19 5
A) B) C) D)
9 5 5 3

75. ABCD and EFGC are squares and the curve y   x passes through the origin D and the
FG
points B and F. The ratio is (as shown in the figure).
BC

3 1 3 1 5 1 5 1
A) B) C) D)
4 2 4 2
2 4 
sin 2
sin 2 sin 2
76. The value of the expression 7  7  7 is equal to:
2  2 2 4
sin sin 2 sin
7 7 7

A) 3 B) 4 C) 5 D) 6
77. Two cards are drawn successively with replacement from a well shuffled deck of 52
cards, then the mean of the number of aces is
1 3 2 1
A) B) C) D)
13 13 13 2

STATEMENT-1: The integral part of  8  3 7  is an even integer.

20
78.

STATEMENT–2:  8  3 7    8  3 7  is an even integer.

20 20

A) Statements 1 & 2 both are correct

B) Statements 1 & 2 both are false
C) Statement 1 is true, statement 2 is false

D) Statement 1 is false, statement 2 is true

79. If an unbiased die, marked with –2,–1,0,1,2,3 on its faces, is thrown five times, then the
probability that the product of the outcomes is positive, is:

881 521 440 27

A) B) C) D)
2592 2592 2592 288

80. The following data gives the distribution of height of students:

Height (in cm) 160 150 152 161 156 154 155

Number of students 12 8 4 4 3 3 7

The median of the distribution is

A) 154 B) 155 C) 160 D) 161

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. A function f : R  R satisfies the equation f  x  f  y   f  xy   x  y, x, y  R and f 1  0 ,

then f  2  f 1  2   ________

82. For y > 0 and x  R, ydx  y 2dy  xdy where y  f  x  . If f 1  1, then the value of f  3 is
83. Let f  x  be a polynomial of degree 3. If the curve y  f  x  has relative extrema at
2
x and passes through  0,0  and 1, 2  dividing the circle x2  y 2  4 in two parts,
3
k
then the area bounded by x2  y 2  4 and y  f  x  is . Find the value of k .
2

1  7 cos 2 x g  x
84. Suppose  sin 7 x cos2 xdx  sin 7 x  C , where C is an arbitrary constant of integration. The

find the value of g   0   g    .
4

85. The urns A,B and C contain 4 red, 6 black; 5 red, 5 black and  red, 4 black balls
respectively. One of the urns is selected at random and a ball is drawn. If the ball drawn
is red and the probability that it is drawn from urn C is 0.4 then   ___________.
86. ABCD is a parallelogram. L is point on BC which divides BC in the ratio 1:2 AL
intersects BD at P. M is a point on DC which divides DC in the ratio 1:2 and AM
BD
intersects BD in Q, then  _________.
PQ

87. From a given solid cone of height H, another inverted cone whose axis coincides with
the axis of the given cone, is carved whose height is h, such that it’s volume is
H
maximum, then the ratio = ___________.
h

88. The radius of the circle passing through the points of intersection of the ellipse
x2 y 2
  1 and x 2  y 2  0 is k, then [k] = _____________([.] is G.I.F)
16 9
89. Six X’s have to be placed in the squares of the figure below, such that each row contains
atleast one X. In how many different ways can this be done?

 x 3 2
90. Given the matrix A  1 y 4 . If xyz  60 , 8 x  4 y  3 z  20 and A  adjA is equal to kI ,
 2 2 z 

( k  R , I is identity matrices of order 3) then k = ______________

 Date: 31-12-23
Time: 3 HRS Max. Marks: 300
KEY SHEET
PHYSICS
1 D 2 B 3 B 4 C 5 B
6 B 7 B 8 A 9 B 10 B
11 D 12 A 13 C 14 B 15 D
16 D 17 A 18 A 19 A 20 A
21 4 22 6 23 25 24 141 25 32
26 3 27 2 28 352 29 400 30 125

CHEMISTRY
31 C 32 D 33 A 34 A 35 B
36 B 37 B 38 C 39 B 40 A
41 C 42 B 43 A 44 D 45 C
46 D 47 C 48 D 49 B 50 D
51 5 52 5 53 5 54 44 55 3
56 10 57 6 58 5 59 25 60 3

MATHEMATICS
61 D 62 A 63 C 64 A 65 D
66 B 67 D 68 C 69 A 70 A
71 A 72 A 73 B 74 A 75 D
76 C 77 C 78 D 79 B 80 B
81 3 82 3 83 4 84 5 85 6
86 2 87 3 88 3 89 26 90 68
 SOLUTIONS
PHYSICS
V  VG 10  1
1. IG   100  104   R  900 
R R
R
2. m    . 4 r 2 dr   KR 4
0

GM G   KR 4  KR3G
V0   
r 2R 2

3. a m / s2
2
Velocity after t  2
v  m/ s
V2 2
Then aN  
R 1
aN   m / s
2 2

2
 
So net according aT      2 
2

2
2
aT   4
4

aT  1  4 2
2
So N = 4
1
T Vrms T' M
4. Vrms  ,   2
M Vrms T M'
1  2  1 1  1.25  1.5   1 1 
5.     1      1   
f  1  R1 R2  100  1   20 40 
1.5 1 1.5 7 1.5  6 9
 1     1   .
1 6 1 6 7 7
6. An   r 2
An    r0 n 2 
2

An   r02 n 4
A
So n n  4 n n
A1
7. No.of divisions = 50
Pitch = 0.5 mm
0.5 mm
Least count   10  m
50
1
8. 
LC
 LC 1
 
0 8L 2C 4

 0 .
4
 V V V
9.  6  6
2 4 4
V V V
   3
4 8 8
  
10. For stable equilibrium, m is parallel to B (i.e.,   00 ) and for unstable equilibrium, m is

antiparallel to B (i.e,   1800 ).
 
PE in the unstable equilibrium, U 2  m.B  m B cos 00  m B
 (0.40 J / T )  0.16T   0.064 J
Amount of work done to displace the solenoid from its stable to unstable orientation, i.e.,
U 2  U f  0.064 J   0.064 J   0.128 J
K A2  x 2 1  1/ n 2
11.  2
 2
 n2  1
U x 1/ n
12. Vrel  VF   VB
4
 9  3  VB
3
 VB  4.5 m / s
KQ
13. A) V  3R 2  r 2 
3 
2R
R KQ  2 R 2  11KQ 11V
At r  , V   3R   
2 2R 3  4  8R 8
KQ V
B) V  
2R 2
KQ R KQ V
C) E  3  
R 2 2R 2 2
KQ V
D) E  
4R 2 4
14. Here the diode is in forward bias. So we replace it by a connecting wire,

30  VA 0  VA 0  VA
  0
10 10 10
3V
3 A
10
VA  10 V
15. In photoelectric experiment, speed of fastest emitted electron is given by
1 2 hc
mvmax  w
2 
1 hc
Case-I : mv 2  w ……… (i)
2 
1 hc
Case-II : mv '2  w
2 3 / 4
 1 4hc
mv '2  w ……. (ii)
2 3
From eqn. (i) & (ii)
4 w
v '2  v 2 
3 3
4
Hence v '  v
3
16. If the insect is not sliding, mg sin   f

mg sin    mg cos 
3
 tan    
4

The height h from the bottom

h  R  R cos 
4 R
h  R  R     0.20 m .
5 5
3
17.  U  nCv  T  1   8.314  100  1247.1 J
2
18. Conceptual
19. In x direction : Applying conservation of momentum
mu  2mv cos 30
u u
v 0

2 cos 30 3
v u 2
Also e  0
 
u cos 30 3u 3
2
 e
3

d d
20. 
s u  10
u  10  s  u  1 s m / s
4
I I 1 I
I  0 cos 2 60  0     0
4
21.
2 2  4  512
1 CC 
22. Loss   1 2  V 2
2  C1  C2 
1
  30  1012  (20) 2  6  109 J
2
23. Conservation of linear momentum, pi  pf
2  4  2  1  m2  v2
m2 v2  6 ….. (1)
v v
The coefficient of restitution, e  2 1
u1  u2
v v
1  2 1  v2  5 ms 1
u1  u2
By (1), m2  5  6
 m2  1.2 kg
m v  m2 v2 2  1  1.2  5 8 25
vcm  1 1   
m1  m2 2  1.2 3.2 10
x  25
24. VL  VC  0
200
VR 
2
3
 4T  3  4T   r 
25.  P1   r   P2   
 r   r/22
 4T  8T
  P1   8  P2 
 r  r
T
 P2  8P1  24
r
v v
26. up  rel and down  rel
2R 2R

U ˆ U ˆ
27. F  i j  6iˆ  8 ˆj
dx dy
 a  3iˆ  4 ˆj
 ax  3
s x  6
2 6
t  2s
3
2
1 2 1  4 
28. u  0 Erms   8.8  1012     352  10
13

2 2  2 
29. Conceptual
hc
30. By photoelectric equation,    K max
2
1240
K max   1.25  1.25
500
2mK
r
eB
2mK
B  125  107 T .
er
 CHEMISTRY
31. Highest amount of heat will be released when equivalents of acid and base are equal i.e., complete
neutralization takes place.
1
32. For second order reactions t1/ 2 
K[A]0
 Half-life decrease with increase in concentration of reactants.
ln 2
For 1st order, t1/ 2  and is independent of concentration
k
dx
For zero order,  K (both are same)
dt
10 10 10
 P  100   P  200  P  10000
33.  0   10 180 ;  0   10 180 ;  0   10
 P A  P B  P C 180
  
100 18 200 18 10000 18
 P   P   P 
 0   0   0 
 P  A  P  B  P C
P
Relative lowering of V.P. = 0  Xsolute .
P
35. (KE)1  hv1  hv0
(KE)2  hv 2  hv0
As (KE)1  2  (KE)2
 hv1  hv0  2(hv2  hv0 )
or hv0  2hv2  hv1
or v0  2v1  v1 .
= 2  (2  1016 )  (3.2  1016 ) = 0.8 1016 Hz  8 1015 Hz .
36. Number of milli equivalents of
MnO 4  0.02  3  250  15
Number of milli equivalent of
I2  0.11 250  25
Thus, here MnO 4 is limiting reagent
 Number of milli equivalents of I 2 formed = Number of milli equivalent of MnO 4
15
= 15 or number of equivalent of I 2 formed =  0.015
1000
0.015
 Number of moles of I 2 formed =  0.0075 .
2
38. Statement-I is correct: Pure aniline is colourless liquid
Statement-II is incorrect: Aniline becomes dark brown due to action of air and light (oxidation)
39. Cross Cannizzaro is simply redox process.
41.

5-amino-4-hydroxymethyl-2-nitrobenzaldehyde
43. 2Cu   Cu 2  Cu
The stability of Cu 2 (aq) rather than Cu  (aq) , is due to the much more negative  hyd H of
Cu 2 (aq) then Cu  (aq) , which more than compensates for the second ionization enthalpy of Cu.
48. During electrolysis of CuSO4 solution using Cu electrodes, the cell reaction is
 Cu   2e
Anode: Cu(S) 
Cathode: Cu  (aq)  2e   Cu(s)
The loss in weight of anode is equal to gain in weight of cathode.
50. Pentaamine chloride cobalt (III) chloride
[Co(NH 3 )5 Cl]Cl 2 [Co(NH3 )5 5Cl  ]2  2Cl 
Gives 3 ions in aqueous solution.
51. Given compound undergoes free radical bromination under given conditions, replacing H by Br.
C is chiral carbon.

(III) has two chiral centres and can have two structures.

(IV) has also two chiral centres and can have two structures.

It has plane of symmetry thus, achiral,

Thus, chiral compounds are five, I, IIIA, IIIB, IVB and V
54. Weight of C in 0.792 gm CO2
12
=  0.792  0.216 .
44
0.216
% of C in compound = 100  43.90%  44 .
0.492
56. G 0  H0  TS0  54.07 103 J  298 10 J = 57.05 103 J
Also, G 0  2.303RT log K .
G 0 57.05 103
 log K  =  10 .
2.303 RT 5705
57. A decapeptide has nine peptide (amide) linkage as

Therefore, on hydrolysis, it will absorb nine water molecules.

Hence, total mass of hydrolysis product = 796  18  9  958
958  47
 Mass of glycine in hydrolysis product =  450 .
100
450
 Number of glycine molecule in one molecule of decapeptide=  6.
75
58.

59.
AB2  AB(g)  B(g)
500  
500  x x x
Require = 600 torr = 500 – x + x + x, x = 100 torr
P  P 100 100
K p  AB B   25 torr .
PAB2 400
60.
 MATHS
1
x 2 sin    2 x
 x x
61. lim .
1  x   e
1/ x
x 0 x
 1  x  2 4
 lim  x sin    2    0  2     
x 0
  x   e 1  x  11 x 2  ....  e  e e
 2 24 
62.

Median CD = 3r
1
2  3   2  4    2r 
2 2 2
3r 
2
36 r 2  18  32  4 r 2  40 r 2  50
5 5
r2  r
4 2
Diameter AB = 2r  5

2 x 1  sin x 
63. I  dx

1  cos 2 x

2 x 1  sin x   2   x 1  sin x  
x sin x
Using King and add 2I  

1  cos x 2
dx  4 

1  cos 2 x
dx
 
x sin x
I  2  f  x dx  I  4 dx
 0
1  cos 2 x

sin x
Using Kind and add 2 I  4  dx
0
1  cos 2 x
Put cos x  t
1
dt 
2 I  4   I  4  2.
1
1 t2 4
64.  f 1  3  g  3  1
 Point   3,1
1 1 1
g f  x    g  3   
f x  f  1  4
1
 Tangent  y  1   x  3  x  4 y  1  0 .
4
65.  f   x   ax  x  1  f   2  6  a3
3x2
f   x   3  x2  x   f  x   x3  C
2
  3
f x   x2  x  
 2
f  2  2  C  0 .
66.

Point A be the intersection of AC & AB i.e.  4,5  & B be the intersection of AB & BC i.e.  3, 2 
 1 7
Mid–point of AC will be   , 
 2 2
7
7  1
Equation of diagonal BD is y   2  x    7 x  y  0
2   1 2
2
23 2  ax  by1  c1 
Distance of A from diagonal BD  d   50d 2   23   d  1 
50  a 2  b2 
50 d 2  529 .

67. Let F, H and B be the sets of television watchers who watch football, Hockey and Basketball
respectively.
Then, according to the problem, we have
n U   500, n  F   285, n  H   195,
n  B   115, n  F  B   45,
n  F  H   70, n  H  B   50,
And n  F   H   B   50,
Where U is the set of all the television watchers.
Since, n  F   H   B   n U   n  F  H  B 
 50  500  n  F  H  B   n  F  H  B   450
We know that,
n  F  H  B  n  F   n  H   n  B  n  F  H   n  H  B  n  B  F   n  F  H  B
 450  285  195  115  70  50  45  n  F  H  B 
 n  F  H  B   20
Which is the number of those who watch all the three games. Also, number of persons who watch
football only  n  f  H   B 
 n  F   n  F  H   n  F  B  n  F  H  B
 285  70  45  20  190
The number of persons who watch hockey only
 n  H  F   B
 n  H   n  H  F   n  H  B   n  H  F  B   195  70  50  20  95
And the number of persons who watch basketball only
 n  B  H   F 
 n  B   n  B  H   n  B  F   n  H  F  B   115  50  45  20  40
Hence, required number of those who watch exactly one of the three games
 190  95  40  325 .
68.  The image of ‘z’ in the line y  x is i z .
i z i  
 The image of the given curve is arg  
 i z 1  4
 z 1 
 arg  
 z i  4
z 1  
  arg    arg  z    arg  z  
 z i  4
 z i     z1   z2  
 arg    arg     arg    .
 z 1  4   z2   z1  
69. x  sin 1  sin10   3  10
y  cos 1  cos10   4  10
 yx .
70. I ) Sum of perimeters = 3  24  12  6      
 
 1 1   1 
72 1   ........   72   144
 2 4  1
 1 
 2
II) log 2  a  b  c  d   4
  a  b  c  d   24
abcd 4
   a  b  c  d   a  b  c  d  8 .
4
1 1  x  1  y 
A  x  A  y   1  x  1  y  
1
71.  
  x 1   y 1 
1 1  xy  ( x  y 
 1  xy  ( x  y )   
( x  y) 1  xy 
 x y 
1 
1  xy 
1
 x y 
 1      A z 
 1  xy    x  y 1 

 1  xy
 
72. The given equation can be written as
 x 2     1 x  5  0
  ,  are the roots of this equation.
 1 5
    and  
 
  4
But, given  
  5
2  2 4
 
 5
   1
2
10

   
2
 2 4  2
 4
  
 5 5 5

    1
2
 10 4
    2  12  1  4
5 5
   16   1  0
2

It is a quadratic in  , let roots be 1 and 2 , then 1  2  16 and 12  1

1 2 12  22  1  2   212 16   2 1
2 2

      254 .
2 1 12 12 1
73. A  1, 2,3, 4,5,6,7
Case–I: When exactly 4 values follows f  i   i
7 1 1
C4  3!    70
 2! 3! 
Case–II: When exactly 5 values follows f  i   i
7
C 5  1  21
Case–III: When all 7 values follows f  i   i
Number of function = 1
Total functions = 70 + 21 + 1 = 92.
74.     
Let l  0iˆ  0 ˆj  0kˆ   aiˆ  bjˆ  ckˆ   aiˆ  bjˆ  ckˆ 
iˆ ˆj kˆ
 aiˆ  bjˆ  ckˆ  1 2 3  4iˆ  5 ˆj  2kˆ
2 2 1


 l   4iˆ  5 ˆj  2kˆ and 
l1 1    iˆ   11  2  ˆj   7  3  kˆ
P is intersection of l and l1
 4  1   , 5   1  2 , 2   7  3
By solving there equation   1, P  4, 5, 2 
Let Q  1  2 , 2 ,1   
Then, PQ   5  2 , 5  2 ,1   

 
PQ. 2iˆ  2 ˆj  kˆ  0  2  4  4  1    0
1  7 2 10 
  Q , , 
9  9 9 9 
7 2 10 5
                y  .
 9 9 9  9
75. Let DC  CB  BA  AD  k
 Coordinates of B are  k , k  ,
Which lie on y x
 k  k
 k  2
 BC  k   2
Also, let CG  GF  FE  EC  k1
 Coordinates of F are   2  k1 , k1  ,
 Which lie on y x
Then k1    2
 k1 
 k12   4   2 k1
Or k12   2 k1   4  0

2   4
 4 4  k1 1  5
 k1  Or 
2 2 2
FG 5 1
Or 
BC 2
2 4  2 4 8
sin 2 sin 2 sin 2 sin 2 sin 2 sin 2
76. S 7  7  7  S 7  7  7
2  2 2 2 4 2  2 2 2 4
sin sin sin sin sin sin
7 7 7 7 7 7
  2 4    2 4 
S  4  cos 2  cos 2  cos 2   4  1  2 cos  cos  cos 
 7 7 7   7 7 7 
 1
 4 1  2    5 .
 8
4 1
77. Let X denote the number of aces. Probability of selecting an ace, P  
52 13
1 12
Probability of not selecting an ace, q  1  
13 13
 1   12  24
P  X  1  2       
 13   13  169
1 1 1
P  X  2   
13 13 169
24 2 2
Mean  Pi X i    .
169 169 13
 
20
78. Let 8  3 7  I  f, where f = fractional part and I = integral part

 
20
Also let 8  3 7  g then 0  g  I

   8  3 7  
 2 820  20 C2.818. 3 7    
20 20 2 20
Here I  f  g  8  3 7  ......  20 C20 3 7
 
 I  f  g = even integer
But 0  f  g  2
So, I  1  even Integer  f  g  1
 I  odd Integer
79. Possible favourable outcomes will be getting by, either all outcomes are positive or any two are
negative.
3 1
Now, p  P  All positive   
6 2
2 1
q  p  both negative   
6 3
So, required probability
5 2 3 4 1
1 1 1 1 1 521
 5C5    5C2      5C4      .
2
  3 2
    3 2
    2592
80. Arranging the data in ascending order of magnitude, we obtain
Height (in 150 152 154 155 156 160 161
cm)
Number of 8 4 3 7 3 12 4
students
Cumulative 8 12 15 22 25 37 41
frequency
Here, total number of items is 41, which is an odd number.
th
41  1
Hence, the median is  21st item.
2
From cumulative frequency table, we find that median i.e., 21st item is 155.
81. Putting x = y = 1, we get f 1  2
Putting y = 1, f  x   x  1
 f 1  x   x  1
 f  x  f 1  x    x 2  1  f  2  f 1  2   22  1  3
xdy  ydx
82.  dy
y2
x
   d     dy
 y
x
   yc
y
At x  1, y  1  c  2 .
3
x  3   y  2
y
y2  2 y  3  0
 y2  3y  y  3  0
 y  y  3   1  y  3  0
  y  1 y  3  0
 y3  y  0 .
 4  x3 4 x 
83. f   x   a  x 2    f  x   a     b passes through  0,0  and 1, 2 
 3 3 3 

-2 O
2

 b  0, a  2
2x 2
f  x 
3
 x  4
  2
2

Required area   2  4 k 4.
2 2
 1  7 cos 2 x sec 2 x 1
84. We have  sin 7 x cos 2 x  sin 7 x dx  7  sin 7 x dx
dx 

I    sin x   sec2 x  dx  7   cos ecx  dx integrating by parts

7 7

    
I II

tan x cos x dx
  7 tan xdx  7 
 sin x   sin x   sin x 
7 8 7

tan x cos x dx tan x

  7  7  C
 sin x   sin x   sin x   sin x 
7 7 7 7

Hence, g  x   tan x
So, g   x   sec2 x
And g   x   2sec2 x tan x

 g   0   1 and g     4
4
 
Hence, g   0   g     1  4  5 .
4
85. Given

R
P C  P  
C  C 
Now, P   
 R  P A P R   P B P R   P C P R 
           
 A B C 
1 

3   4
 0.4   6
1 4 1 5 1 
   
3 10 3 10 3    4 
86. Let P divides AL in the ratio  :1
P divides DB in the  :1
  
Let AB  a , BC  b

 b 
a   
 3    a   b  
 1  1
   3;   3

BD 4
  2
PQ 2
87.
H h H
  r
 H  h R
r R H
r h
2
R 2
h  H  h
2
 V   2
3 3H

dV  R 2     R  H  h  H  3h 
2
   
2
 H  h  2 h H  h
dh 3 H 2   3H 2
H H
 Vmax when h    3 .
3 h
88. Required circle
x2 y2

 1   x2  y 2  0
16 9

Using x2 coefficient  y 2 coefficient.
1 1 7
     
16 9 288
288
Required circle x 2  y 2  .
25
89. In the given figure there are 8 squares and we have to place 6X’s this can be done in
8 8.7
C6  8C2   28 ways
1.2
But these include the possibility that either headed row or lowest row may not have any X. These
two possibilities are to be excluded.
 Required number of ways = 28 – 2 = 26.

90. Now, A  adjA  A I

x 3 2
Now, A1 y 4
2 2 z
 x  yz  8  3  z  8   2  2  2 y 
 xyz   8 x  4 y  3z   28
 60  20  28  68
From equation (i), A  adjA   68I .