FILE NO. IIT-777/66 (31/01/09) CODE  VSSS.

IIT JEE – 2009

GRAND TEST – 10
Key, Hints & Solutions
(PAPER-I) EXAM DATE:02  02  09

PHYSICS CHEMISTRY MATHEMATICS

Q. Ans. Q. Ans. Q. Ans.
No. No. No.
1 A 17 A 33 D
2 B 18 D 34 A
3 B 19 C 35 B
4 A 20 D 36 C
5 A 21 C 37 D
6 B 22 B 38 B
7 A,B 23 A,B 39 B,C,D
8 C,D 24 A,B,D 40 B,C
9 C 25 A,B,C 41 B,C,D
10 A 26 D 42 C
11 D 27 C 43 B
12 D 28 B 44 A
13 1350 29 449 45 2
14 227 30 325 46 4446
Ar,s A q A q
B r,s Br Bq
15 C- q,r 31 Cp,s 47
D p,r C p
D p
D p

Ap,s Ap,q,s A r
Bp,r Bp Bq
Cq,s 32 Cp,s
16 Dp,r 48 Cq,s
Dq,r,s
Dp,s
1.

 2x3 + 3x2  28 = 0
 2x2 (x  2) + 7x(x  2) + 14(x  2) = 0
x=2m

2. The distance of C.M from point of suspension

M.I of the system about

3.

4. When triangle moves, it cuts magnetic flux. Therefore, an emf is induced in it. In fact,
wires ac and abc are to be considered separately. Emf induced in each of these two
is equal to e = Blv and their resistances are equal to r 1 = l and r2 = ,
respectively. But these two cells are in parallel with each other, therefore, equivalent

emf will be equal to e = Blv and equivalent internal resistance will be .

Since, at left end, rails are connected by a resistance by wire and rails are also
resistanceless, therefore the cells is short circuited. Hence, a current will flow

through the circuit and thermal power will be generated in the cell.

Suppose force applied to pull the triangle with constant velocity is F then power
supplied by this force becomes FV, in fact, this is the power which converts into
electrical power.

 FV = 

5. Concept

6. Concept
7. Two containers contain different gases, therefore, they have different molar masses.
Since mass of each gas in two containers is same, therefore number of moles in two
containers are different from each other.
Let temperature of two gas be T,
then for first container : PAVA = nART
and for second container PBVB = nBRT
Since nA  nB.  (D) is wrong. It can be easily understood that (A) & (B) are possible
while (C) is impossible.

8. At distance r from left and of the conductor, its horizontal dimension is equal to

And vertical dimension is equal to

 area

If an elemental length dr is considered, its resistance

 =

Hence, (A) is wrong

Rate of generation of heat per unit length is equal to .

The rate of generation of heat per unit length is maximum where A is minimum.
For the given conductor, cross sectional area A is maximum at its middle section and
that is equal to
(1.5)x (1.5)y = 2.25xy
 rate of generation of heat is minimum
 (B) is wrong

Since, , drift velocity

 is minimum at middle section

 (C) is correct.

Electric field intensity in current carrying conductor is given by

The conductor is made of a uniform material, therefore  is constant.

A is same at two ends, therefore, electric field intensity is same at two ends of the
conductor.
  (D) is correct.

9. At wavelength  a dark fringe will be observed in spectrometer if destructive

interference takes place for that wavelength.
In case of transmitted light, the path difference is given by

Light rays are incident normally

 r = 0  cosr = 1
  = 2l ; for air  = 1
Since destructive interference takes place

 ; where n is integer

 (C) alone is correct.

10. Displacement of block in the time interval T is

 Wgravity =

11. The normal reaction acting on the block is M(g + b) in upward direction. The upward
displacement of the block is

 Wnormal =

12. According to observer B, the displacement of block is zero.

 Wg = 0 ; WN = 0 ; Wpseudo force = 0

13. Signal sent at time t by the source is received by the receiver.

Distance covered by the source in time t,

 Time elapsed by the sound pulse in reaching to detector =

Velocity of the source at t, v = at = 88 m/s

Thus,
14. Intensity of the source at the cross-section A

Power absorbed by the end A  80% of (I  r2)

Using Wien’s displacement law, to determine the temp at the end B.

For conduction through the rod


 TA = 500 K

15. A) Because the magnetic field is parallel to x-axis, the forces on wire parallel to x-axis
is zero. The force on each wire parallel to y-axis is . Hence, net force on loop is
Boil. Since force on each wire parallel to y-axis passes through centre of the loop net
torque about centre of the loop is zero.
B) Because the magnetic field is parallel to y-axis, the forces on wire parallel to y-axis
is zero. The force on each wire parallel to x-axis is . Hence, net force on loop is
Boil. Since force on each wire parallel to x-axis passes through centre of the loop, net
torque about centre of the loop is zero.
C) Since net displacement of current from entry point in the loop to exit point in the
loop is along the diagonal of the loop. The direction of external uniform magnetic field
is also along the same diagonal. Hence, net force on the loop is zero. Since force on
each wire on the loop passes through centre of the loop net torque about centre of
the loop is zero.
D) The net displacement of current from entry point in the loop to exit point in the
loop is along the diagonal (of length ) of the loop. The direction of external
 uniform magnetic field is also perpendicular to the same diagonal. Hence magnitude
of net force on the loop is . Since force on each wire on the loop passes
through centre of the loop net torque about centre of the loop is zero.

16. A) The rate of change of heat energy of thin shell of mass m, specific heat C, radius
R and width dR is given by

is independent of S = 4R2 and decreases with time as temp of shell T decreases

with time.
B) The potential outside bubble can be found by simply concentrating net charge on
bubble at its centre. Hence potential at fixed point outside is constant and
independent of S.
C) The magnitude of force exerted by liquid of density  escaping with speed v is
Sv2. Hence, this force depends on S and decreases with time as amount of liquid in
container decreases resulting in continuous decrease of v.
D) The magnitude flux through surface S of closed cylinder is zero. Hence it is
constant and independent of S.

17. A
ΔS = nF = 2 x 96500  3.4  10-4 = 65.62 J K-1 mol-1
18. D
Vapour pressure of depends on temperature as well as the nature of a liquid.
19. C
The central atoms in all I3−, ClF3 & SF4 have five pairs (lp + bp) of electrons and
hence are sp3d hybridized.
20. D
NaCN is added as a depressant which forms a soluble complex with ZnS and
hence facilitates the preferential wetting of PbS by froth.
21. C

22. B
H2/Ni does not reduce carboxylic acids to alcohol. Among metal catalysts only H2/
Ru-C and H2/Cu-Ba-Cr oxide can reduce carboxylic acids to alcohols.

23. A, B
SiO2 + CaO → CaSiO3
PbO + SiO2 → PbSiO3
PbSiO3 + CaO → PbO + CaSiO3
24. A, B, D
H = Cp ΔT = 7  75 = 525 cal mol-1
 S =

S =
25. A, B, C
All these compounds A, B and C have a group that can react with the formed
Grignard reagent readily.
26. D
Major product of the following reaction is

27. C
-NO is a +R group and hence decides the orientation.
28. B
Friedel Craft’s reaction fails with compounds having strongly deactivating groups.
29. 449

Ionic product of BaF2 = [Ba2+][F-]2 =

As ionic product is less than solubility product no precipitation takes place.

[Ba2+] = 0.01 = 0.004 M

[Cl-]= 0.012 = 0.008 M

[Na+] = [F-] = 0.01 = 0.006 M

Total concentration of solute particles is 0.024 M

Osmotic Pressure =CRT = 0.024  0.082  300  760 Torr = 449 Torr
30. 325
 ________________________

= 820kJ

…..(c)

(a)-(b) = (c)

=1470

= 820kJ
_____________________________
(-) - 2Heg = 650 Heg = -325 kJmol-1.

31. A – q, B-r, C-p,s, D-p

32. A-p, q, s; B-p, C-p,s, D-q,r,s

33. (D)

34. (A)

Required probability

35. (B)
36. Total number of ways of giving 10 gifts to 5 students so that each get atleast one and a
particular student gets atleast 5 gifts.

37. (D)
S=

=
 =

38. (B)
Let =

= as

39. (B), (C), (D) (A) False, e.g. f(x) =

(B) True, from I.V.T.

(C) True as

 not defined
(D) True, as the line passes through the centre of the circle
40. (B), (C)
41. (B), (C), (D)
P= =

42. (C)

 =0

Since  A, B, D are wrong

43. (B)

 ; ; ; p+q+r=2
44. (A) As are non-coplanar
 are also non-coplanar

Hence,
  , ,

Hence,

=  (A)

45. and

Now p is a root of
And r is a root of
Adding those two

Also
From

46.

Where

But
From and