KEY & SOL

FILE NO. IIT-777/66 (31/01/09) CODE  VSSS.
(PAPER-II)
EXAM DATE;0202 09
PHYSICS CHEMISTRY MATHEMATICS
Q. No. Ans. Q. No. Ans. Q. No. Ans.
1 D 17 B 33 C
2 A 18 D 34 C
3 D 19 B 35 B
4 B 20 B 36 B
5 B 21 D 37 A
6 D 22 B 38 C
7 A,B,C 23 A 39 A,C,D
8 B,C 24 A,C 40 A,C,D
9 A,D 25 A,B,C 41 A,C,D
10 A 26 B 42 C
11 B 27 B 43 A
12 A 28 B 44 B
13 24120 29 9 45 3000
14 3100 30 333 46 1002
A-q; Aq,r
Ap,s B-p,r; Br
15 B – q,s 31 47
Cp,s C-p, q; Cq,s
D s
D-q,s Dp
16 Aq,r 32 A-prs; 48 Ar,s

B–s B – p,r,s; B – p,q
Cs C-q,s; Cs
Ds D-q,s Dp,q
Solutions _ Paper 2
1. [D]
On supplying a constant current of 10 amp in the circuit element, the potential difference across it is
increasing, therefore, it should be a capacitor because on supplying the current, charge on the
capacitor will increase. Hence, the potential difference across it will also increase.
The graph shows that initial potential difference across capacitor is equal to 2 volts and in 3
seconds, it increases through 6 volts. But charge supplied to the capacitor in 3 seconds is equal to 1
 3 = 3 coulombs. Hence, a charge of 3 coulombs increases the potential difference across the
capacitor through (8  2) = 6 volts. Hence its capacitance is
2. [A]
Suppose emf of the battery connected in the circuit is equal to E. Then the current at R = 0 will be
equal to Io = when R increases, current through the circuit decreases.
If R = Ro, then net resistance of the circuit will become equal to 2R.
Hence, current through the circuit will become
To reduce the current to Io/4, the net resistance of the circuit is to be increased to 4 times of its
original value Ro. Hence, R = 3Ro. Similarly, to reduce the current to Io/8, the resistance R must be
equal to 7Ro and to reduce the current to zero, R must be very large. Hence, (A) is correct.
3. [D]
Concept
4. [B]
Concept
5. [B]
6. [D]
7. [A, B, C]
When a stationary hydrogen atom emits a photon then energy of the emitted photon will be equal to
the difference of the energy of two levels involved in the transitions. Hence, energy of emitted
photon will be equal to (Em  En).
If a hydrogen atom is moving and photon is emitted by it along the same direction in which it is
moving to momentum of the emitted photon, the momentum of hydrogen atom will get decreased. It
means velocity of the hydrogen atom will get decreased or its K.E. will decrease. Therefore, energy
of the emitted photon will be equal to (Em  En + loss of K.E. of the hydrogen atom).
Hence, the frequency of the emitted photon will be greater than Fo. Hence, (B) is correct.
But if photon is emitted in a direction normal to the motion of the hydrogen atom then the frequency
of emitted photon will be equal to Fo.
Hence, (A) is correct. Obviously (D) is wrong.
If the photon is emitted by the hydrogen atom in the direction opposite to its motion, then frequency
of the emitted photon will be less than Fo.
Hence, (C) is correct.
8. [B, C]
If an object is at a distance x from a plane refracting surface and is viewed normally then it appears
at a distance x/ from the surface where  is refractive index of that medium (in which it is situated)
with respect to the medium in which observer is situated.
Suppose height of bird from water surface is x and depth of fish from the surface is y, then depth of
fish, observed by the bird, will be equal to
…………(1) ; where  is refractive index of water with respect to air
 r1 = 6.60 m
Hence (B) is correct
Height of bird, observed by fish, will be equal to
………. (2) ; where  is refractive index of air with respect to water.
 ; Hence, r2 = 8.80 m
Hence, (A) is wrong and (C) is correct.
9.
10.
11.
12.
13. Applying momentum conservation along the surface of inclined plane.

mvocos60o + 0 = (m + M)v
Where v is the velocity of bullet block system just after the collision.
Acceleration of block bullet + system along the incline
By v = u + at
 vo = (402)(60) = 24120 m/s
14. If subscript H is for hot side and C for cool side
Rate of heat flow =
Total heat in one day is,
 Quantity of ice melted,
15. A) The plot of power P consumed by variable resistor

of resistance R w.r.t R when connected across
a non-ideal cell is given by
B) At the instant ring has rotated by  = t ( = angular speed) in uniform and constant magnetic
field B, the magnetic flux through the ring is
or
Hence, for first half cycle, magnitude of emf first decreases and then increases.
C) As the lens is moved up, the projection of length of image on principal axis remains same, but its
slant with principal axis increases. This increase is due to the fact that lateral magnification of each
point of image of rod is different. Hence, as lens moves up the size of image increases and when it
moves down the size of image decreases.
D) As frequency of ac source increases, reactance of capacitor decreases. Therefore the bulb glows
more brighter.
16. A) Centre of mass lies in second quadrant.

B), C) and D) centre of mass lies on y-axis and below x-axis.
17. B
Decarboxylation in presence of soda lime proceeds through carbanion mechanism. p - d makes

Cl3C− most stable.
18. D
As the ion in the counter ion part is Fe3+ it gives a reddish brown precipitate of Fe(OH)3
19. B
Let x be the volume of water gas used
Vol of H2 in it = 0.5 x; vo of CO = 0.45 x
CO + H2O  CO2 + H2
0.45 x excess 0.05x 0.5x
0 - 0.05x+0.45x 0.5x+0.45x
Therefore vol of H2 produced is 0.5x + 0.45x = 50 L
x = 52.63 L
20. B
In FCC octahedral voids are at body centre as well as edge centres while octahedral voids are at
the centers of the eight small cubes contained in the unit cell.
P1 contains only octahedral voids
P2 contains both octahedral and tetrahedral voids
P3 contains only tetrahedral voids.
21. D
Ni2+ has d8 configuration.
Cl- does not cause pairing and hence hybridization is sp3 and the shape is tetrahedral.
PPh3 causes pairing and hence the hybridization is dsp2 and the shape is square planar.
22. B
α-hydroxy ketones also give Tollen’s test
Formic acid gives Tollen’s test.
23. A
24. A, C
Na2S3 + O2 Na2S2O3 + S
25. A,B,C
26. B
27. B
When pOH decreases by two units concentration of OH- increases by 100 times and hence the
rate increases 100 times.
28. B
As concentration of B is in excess the reaction is just first order with respect to A.
r = 10k[A] = k’[A]
half life time =
29. 9
30.
A is [Cr(H2O)6]Cl3
B is Cr[(H2O)4Cl2]Cl.2H2O
C is Cr[H2O)5Cl]Cl2.H2O
Number of moles of Cl- from A , x = 13 = 3
Number of moles of Cl- from B, y =3  1 = 3
Number of moles of Cl- from C, z = 1.5  2 = 3
xyz = 333
31. A-q; B-p,r; C-p, q; D-q,s

Sb3++H2O SbO+ + 2H+
2CrO42- + 2H+ Cr2O72- + H2O
B4O72- + 7H2O 2B(OH)3 + 2[B(OH)4]-
2[B(OH)4]-- + 2H3O + 2B(OH)3 + 4H2O
6XeF4 +12H2O 4Xe + 2XeO3 + 24 HF + 3O2
32. A-prs; B – p,r,s; C-q,s; D-q,s
33. [C]
N = 2000C1 + 2.2000C2 + ……..+ 2000.2000C2000 = 2000.21999 = 22003.53
No.of divisors = (2004)(4) = 8016.
34. [D]
Using characteristic equation  20   + 2 + 21 = 0
 2   + 1 = 0
 A2  A + I = 0
 A3 = I
So, = (I)160 (AI) = AI
= I
35. [B]
If it is columnwise orthogonal then take
Prefactor matrix will become inverse of A if 1st row is divided by 3, 2nd by 6, 3rd by 2.
36. [B]
Using multinomial theorem,
The given expansion will have rational term if x1, x2, x3 are multiple of 6 as well as sum is 10.
 possibilities are x1 = 4, x2 = 6, x3 = 0
x1 = 10, x2 = 0, x3 = 0
x1 = 4, x2 = 0, x3 = 6
so three rational terms.
37. [A]
Number of ways to give one fruit to first person = n
“ to second person = n
“ “ “
“ “ “
“ rth person = n
Total no.of ways = n2
38. [C]
f(x) = cos2x + cos22x + cos23x

= 1 + cos2x + cos22x +  sin23x
= 1 + cos2x + cos5x.cosx
= 1 + cosx(cosx + cos5x)
= cosx.cos2x.cos3x = 0
 or or
 no.of values of x = 5
39. A, C, D
graph of always increasing
also and has no critical point
40. A, C, D
…….. (1) and ………. (2)
From equation (2), ……..(3)
Substituting the result of (3) in (1)
We get
 ……… (4)
From (1) and (4); we get , hence, n = 4
G.P. is
t1 + t2 = 9
41. A, C, D
(B) tanA = 300  A < 90o triangle is always possible
secB = 450  B < 90o “ ”
(D) A, B  90o (as in this case cosecA cosB cannot be equal to 3)
If C = 90o, then B = 90o  A
 cosecA.cos(90oA) = 1
 not possible
42. [C]
No.of sample space =
Number of number divisible by 6
Case-I : when digits are 0, 1, 2, 3, 6
0 0 0 0 0
4! 0  24 + 18 + 18 = 60
4!  3! 2
4!  3! 6
Case-II : when digits are 0, 1, 3, 6, 5
0 0 0 0 0
4! 0  24 + 18 = 42
4!  3! 6
The total no.of numbers divisible by 6 = 60 + 42 = 102
Required probability =
43. [A]
Number divisible by 5
0 0 0 0 0
0  120 + 96 = 216
Number divisible by 4
0 0 0 0 0
4! 20  24 + 24 = 48
4! 60
Number divisible by 5 but not by 4 = 216  48 = 168
Required probability =
44. [B]
Number divisible by 6 as in Q.42 is = 102
Number divisible by 4 is
Case-I :
0 0 0 0 0
3! 60
3! 20
3!  2! 32  6 + 6 + 4 + 4 + 4 + 4 = 28
3!  2! 16
3!  2! 16
3!  2! 36
Case-II :
0 0 0 0 0
3!  2! 56
3! 60
3!  2! 36  4 + 6 + 4 + 4 = 18
3!  2! 16
Total no. divisible by 4 is 46
Required probability = .
45. Dividend = divisor  quotient + remainder
Dividend  Remainder = divisor  quotient
f(x)  (x + a) = x4  6x3 + 16x2  25x + 10  x  a
= x4  6x3 + 16x2  26x + 10  a
This should be divisible by x2  2x + k
x4  6x3 + 16x2  26x + 10  a  x2  2x + k
 x(10 + 2k) + 10  a  8k + k2 = 0
 This should be zero for all x
 10 + 2k = 0  k = 5 and 10  a  8k + k2 = 0  a = 5
So, 500  5  100  (5) = 3000
46. Let
Coefficient of is
48. (i)
range of is (two interger)
is also odd and non periodic
is also one  one function
graph of is
(ii)
contain only two integers 0 and 1.
is periodic with period 1 many – one
range contain only positive value neither odd nor even function
graph of
(iii)
graph shows is odd, range contain only two integer which is , non one  one and non periodic
(iv)
is periodic with period many one
neither odd nor even function
must lie between 0 to 1
range of
Which contain only two integer 0 and 1.


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FILE NO. IIT-777/66 (31/01/09) CODE  VSSS.

Q. No. Ans. Q. No. Ans. Q. No. Ans.

8 B,C 24 A,C 40 A,C,D

9 A,D 25 A,B,C 41 A,C,D

14 3100 30 333 46 1002

16 Aq,r 32 A-prs; 48 Ar,s

Ds D-q,s Dp,q

equal to Io = when R increases, current through the circuit decreases.

Hence, current through the circuit will become

…………(1) ; where  is refractive index of water with respect to air

………. (2) ; where  is refractive index of air with respect to water.

Hence, (A) is wrong and (C) is correct.

13. Applying momentum conservation along the surface of inclined plane.

 vo = (402)(60) = 24120 m/s

14. If subscript H is for hot side and C for cool side

Rate of heat flow =

Total heat in one day is,

 Quantity of ice melted,

15. A) The plot of power P consumed by variable resistor

16. A) Centre of mass lies in second quadrant.

Decarboxylation in presence of soda lime proceeds through carbanion mechanism. p - d makes

Let x be the volume of water gas used

Vol of H2 in it = 0.5 x; vo of CO = 0.45 x

0.45 x excess 0.05x 0.5x

Therefore vol of H2 produced is 0.5x + 0.45x = 50 L

P1 contains only octahedral voids

P2 contains both octahedral and tetrahedral voids

P3 contains only tetrahedral voids.

Ni2+ has d8 configuration.

α-hydroxy ketones also give Tollen’s test

Formic acid gives Tollen’s test.

half life time =

31. A-q; B-p,r; C-p, q; D-q,s

2CrO42- + 2H+ Cr2O72- + H2O

B4O72- + 7H2O 2B(OH)3 + 2[B(OH)4]-

2[B(OH)4]-- + 2H3O + 2B(OH)3 + 4H2O

6XeF4 +12H2O 4Xe + 2XeO3 + 24 HF + 3O2

32. A-prs; B – p,r,s; C-q,s; D-q,s

N = 2000C1 + 2.2000C2 + ……..+ 2000.2000C2000 = 2000.21999 = 22003.53

No.of divisors = (2004)(4) = 8016.

Using characteristic equation  20   + 2 + 21 = 0

So, = (I)160 (AI) = AI

If it is columnwise orthogonal then take

Using multinomial theorem,

so three rational terms.

Number of ways to give one fruit to first person = n

Total no.of ways = n2

f(x) = cos2x + cos22x + cos23x

graph of always increasing

also and has no critical point

…….. (1) and ………. (2)

From equation (2), ……..(3)

Substituting the result of (3) in (1)

From (1) and (4); we get , hence, n = 4

(B) tanA = 300  A < 90o triangle is always possible

secB = 450  B < 90o “ ”

(D) A, B  90o (as in this case cosecA cosB cannot be equal to 3)

If C = 90o, then B = 90o  A

No.of sample space =

Number of number divisible by 6

Case-I : when digits are 0, 1, 2, 3, 6

Case-II : when digits are 0, 1, 3, 6, 5

The total no.of numbers divisible by 6 = 60 + 42 = 102

Number divisible by 5 but not by 4 = 216  48 = 168

KEY & SOL

KEY & SOL