Narayana IIT Academy 30-06-24_SR.

IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL
44.
O
OH O
NH

Y= Z=
X=

Sec: SR.IIT_*CO-SC(MODEL-A) REVIEW TEST-1 Date: 30-06-24

45. Time: 3HRS 2023_P2 Max. Marks: 180
NHCOMe NHCOMe
NO 2 NHCOMe
KEY SHEET
P= Q= R= S= MATHEMATICS
1 C 2 D 3 D 4 B 5 ABD
NH2 OH

a 6 ABCD 7 AD 8 127 9 0 10 3
 a  0.05   25   31.25 atm L2 mol1
2
46.  0.05 
V 2
11 63 12 2 13 4048 14 7 15 9
V  b  RT   b  V  RT  25  0.08  300 1L mol 1
1.16 TO
a 31.25 3125 16 17 0.33
TB     390.625 1.17
bR 1  0.08 8
47. Tf  1   / 2   K f  m
7.52
7  1   / 2   14   10
94
 PHYSICS
1   0.625   0.75
2 18 C 19 D 20 B 21 A 22 BC
48. p p 5
OH K b

1 23 ABCD 24 ABCD 25 19 26 4 27 5
p H  7  p K  log C b

2 0.15
p K  log C  3.7
b
28 400 29 1260 30 60 31 1.25 32 to
C = 0.05 mol /L 0.17
0.1  V 1  V = 50 mL 2.50 12.50

 50  V  20 33 TO 34 TO
0.5 0.1  50 500 3.50 13.50
 M  100 g / mol
M 1000 5
49. 10 5  0.1  2   102

  0m CHEMISTRY
m
 m  10  400  4 K  1000  4
2
K = 0.04 Sm -1 35 C 36 A 37 B 38 B 39 AB
0.1
50. P4  10SO 2Cl 2 
 4PCl5  10SO 2 40 D 41 ACD 42 480 43 3 44 64
0.04 mol 0.16 mol 389
PCl5  2Ag 
 2AgCl  PCl3 45 2 46 TO 47 75 48 100 49 0.04
0.08 mol 0.16 mol 392
w AgCl  0.16  143.5  22.96 50 22.96 51 10.44
51. 2PCl5  Sn 
 SnCl4  2PCl3
0.08 0.04
w SnCl  0.04  261  10.44
4

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Narayana IIT Academy 30-06-24_SR.IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL Narayana IIT Academy 30-06-24_SR.IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL
SOLUTIONS CHEMISTRY
MATHS 35.
OH
1. sinx+x+1 is increasing
OH
 sinx+x+1  (-2.17, 4.14) O
OH
Not differentiable at x = -2, -1, 0, 1, 2, 3, 4 OH
OH O
 S = 7, n = 7 O OH
2 OH
2. Clearly f ' 1  0 , f ' 1  3x  6  a  2  x  3a
OH
f ' 1  0  3  6  a  2   3a  0
2  a  2   a  0 36. Based on hybridization of ‘N’ and resonance.
–
O
2  4  a  0 O
O P H -
5=a Cl O
37. H
 f  x   x 3  9x 2  15x  7
(c, d) point of curve where tangent crosses it. 3a 8r
38. Z = 8 8r  a
 f ''  c   0 f '  x   3x 2  18x  15 4 3
4 3
f ''  x   6x  18 Packing efficiency = 8  3 r
3  100  35%
 C  3 d  33  81  45  7  2  8r 
2
 
 3
3. x  y  2a must be tangent to  x  1  y 2  1
39.
OH OH OH
2a  1 2 1
 1 a  CHO COOH
2 2 P= Q= R=
 2a  1 
  a  1, , f a   7 40. Brownian motion depends on size of solution and viscosity of solution.
 2 
Tyndall effect is observed when the size of solution particle is NOT much smaller than wavelength
4. O, Z1 , Z 2 are collinear maximum perpendicular distance from “1” to the line joining Z1 & Z 2 is 1. of light used
1 The process of precipitating colloidal solution by an electrolyte is called coagulation.
 maximum area =  1  4 KI  AgI : I  : K 
 AgNO3 
2 ex
1 2 3 1  41.  2CuCl  s 
Cu  CuCl 2 
S
  
5. 0 P  4 0 0  Pb3O 4  HNO3   PbO 2  Pb  NO3 2  H 2O
 0 
0 3  q  1 3r  1 SO  Fe3  H O 
2 2
 Fe 2  SO 24  H 
A) for P = 4, q = 1 r = 1 / 3, planes will coincide 
Cl 2 O  NaOH   NaCl  NaClO 3  H 2 O
B) for P = 4, q = 1 r = 1, 3rd plane will be parallel to 1st and 2nd planes
C) for P  4, q = 1 r = 1/3, 1st & 3rd will coincide & will have line of intersection with 2nd plane 42.
O O OH OH
excess CH 2O -
D) for P  4, q  1 r = 1/3 , (1, 0, 0) is the only common point Ph H Ph H + HCOO
NaOH +
7. n = 5 as 3 common tangents as well as y =1 & y = 1 also satisfy the condition (i) H3O
 L1 : y  1 L 2 : y  1 , L 3 : x  2 HO OH
(ii) [Ag(NH 3)2]OH
x2 x2 H2CrO4, 
L4 : y   5 ; L5 :  5
5  5 Ag(s)
O
1 1 (silver mirror)
  2m    4m2  1  m  
m 5 Ph CH3
x = 4 ; y = 120
 n  5 and vertices are  3,0  ,  5  3, 1 ,
 5  3,  1 ,  2, 1 &  2,  1
 2 
43. MnO 4 ,  FeCl 4  - tetrahedral and paramagnetic
3
P4 ,SiO 44 ,  CuCN 4  - tetrahedral and diamagnetic
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Narayana IIT Academy 30-06-24_SR.IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL Narayana IIT Academy 30-06-24_SR.IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL
28. 1. Moment of Inertia of the Disk a b 
I disk 
1 1
MR 2  (4 kg)(1 m)2  2 kg·m 2 8. M 
2 2 c d 
2. Moment of Inertia of the Sphere For ‘C’ a + d = 0 (-2, 2), (-1, 1), ( 0, 0)
I sphere  mL2  (0.2 kg)(0.5 m) 2  0.2·0.25  0.05 kg·m 2
(2, -2), (1, -1)
3. Total Moment of Inertia of the System:  n  C   5  5  5  125
I  I disk  I sphere  2 kg·m 2  0.05 kg·m 2  2.05 kg·m 2
4. Angular Acceleration : For  A  B 
 8.2 Nm
   4 rad/s 2 a b 
I 2.05 kg·m 2 M 
5. Final Angular Velocity c d 
   ·t  4 rad/s 2·2 s  8 rad/s
M 2  I  a 2  b 2  1, b 2  d 2  1, b  a  d   0
6. 50 times the Final Angular Velocity
50  50·8  400 rad/s b=0 b0
29. Consider the setup in the figure where we have two infinite strips of charge with surface charge  a 2  1, d 2  1 a+d=0
densities  and-. The width of each strip is b. 2 2  4  a  d  0 & b2  1
Electric Field due to One Strip
Let's slice one of the strips into narrow rods and then integrate over the rods. Consider a rod with  n  A  B  6 n  A  B  C
width dr at a distance r from a given point P, which itself is a distance x away from the edge of the a+d=0
strip. a = 1, d = - 1, b = 0
a = 1, d = 1, b = 0
a = 0, d =- 1, b =  1
n  A  B  C  4
 n   A  B  C  n  A  B  n  C  n  A  B  C
 6  125  4 = 1 27
The electric field at P due to the rod:    dr . 9. a, b, c are collinear
The distance r runs from x to x + b. b c
10.   Z  b 2  ac
So the total field at P due to the strip is: E ( x)  
xb  dr

  xb
ln   a b
x 2 0 r 2 0  x 
b2 b2 b 6
Force between Two Strips a   2b  c  1  2  2 
Consider a rod with finite height h and width dx within one of the strips. The force on this rod due to a a a a
2
the other strip is ( h dx ) E ( x ) . Since the strips are right next to each other, the distance x runs from 0 to  b  6  b 
b. So the total force on a height h of one of the strips, due to the other strip, is:   1   a  6,   1   1
b a  a a 
Fh   ( h dx) E ( x )
0
b
SubstituteE(x):  1  1  b  0  Re ject 
b   xb  2h b  xb a
Fh   ( h dx ) ln   Fh   ln   dx
2 0  x  2 0  x  3 3
cot 1 cot 12  sin 1 sin 6  12  3   6  2 
0 0

Fh    ln( x  b) dx   lnx dx

 2h
2 0
b

0
b

0
2 2
 12  3  9  3  3
ln y dy   lnx dx  (substitute y  x  b)
2   
 h 2

n  R 1   n  R 2   n  R 1  R 2   5  32
2b b
F 
h b 0 11.
0

Fh 
 2h
 y ln y  y  2b
  x ln x  x 0
b
 Fh 
 2h
 2b ln(2b)  2b  b ln b  b  b ln b  b  0  3  32  3  32  32  2  32  63
2 0 2 0
 cos   sin   cos   sin    sin   cos   cos   sin  
b

 h 2

 2b ln 2 
12. (E, F) is  ,  &  M, N  is  , 
Fh 
2 0  2 2   2 2 
31. y 
D sin   d  sin   cos   2
(n0  kt )
For every  n,  n  1   we get a point as f  x   e  sin x  cos x 
x
dy D sin   k
13.
32. 
dt (n0  kt )2

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Narayana IIT Academy 30-06-24_SR.IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL Narayana IIT Academy 30-06-24_SR.IIT_*CO-SC_JEE-ADV_REVIEW TEST-1_KEY&SOL
14,15: Put t – 3 = p PHYSICS
x 3 G 4 3 
2
Gm1m2 2
f x   16 / 3 dp 18. dP  4r 2    r   4r dr
 
  sin p  p r2 r2 3 
4
2 G2 R 2
f 7  0  P( r )  G2 [R 2  r 2 ]  P R 
3 r 2
2
2 16
f '  x   sin  x  3   x  3  19. In equilibrium position, tension T   mg 2   ma 2  2  mg  ma  cos 60
3
f  x   f 7  0 T 5
Also, geff  g
m 2
   x 
   2.  l 4 2l
1 4x  1
 2  T  2  2
16,17: f  x   sin   sin 2 g 7 g 7
  x2    x 
R 2
 4 1  4   1    1 2 1  r2 
    2  20. k   dk   2 (dm )  v    2rdr  v 02 1  2   l
2 0  R 
 1  x 
 2 tan  2  ; 2  x  2  v 02 R 3
   21. FA = 11.2N; FB = 28N; Fc = 49N; FD = 10.5N;

 x 23. Only in B, its path is circular.
    2 tan 1   ; x2 
 2 Only in E , its path is parabola.
 1  x  If E is switched off for the time less than time period, path is not a straight line.
  2 tan   ; x  2
 2 If E is switched off for the time equal to multiples of time period, its path is a straight line.
25. The effective length from end A after including the end correction:
 7 2 1  2  l1  l1  C  43cm  2cm  45cm
  2 tan 1      2 tan  0
 7 2 The effective length from end B (remaining length of the meter bridge wire):
 2  l2  100 cm  43cm  57 cm
1 For a balanced Wheatstone bridge:
m  h '    h ' 0 
2 R1 l1

R l2
K
1
 15  45cm
1 1 
     4  R 57 cm
K 1 4  1 1 3 R  19 
4 26. Since the combination produces no dispersion, the net deviation produced by the two prisms can be
3 1 x added algebraically.
3
g  x   2x  21 x   2 3  2 27. To find the least count of the travelling microscope, we need to determine the value of one Vernier
1 scale division (VSD) and one main scale division (MSD).
1
g max at x = 0 or x = 1 i.e. 2 3  1  M  log 2  M  1  1. Calculate the main scale division (MSD):
3 Given that 40 main scale divisions are equal to 1 cm:
 x 1 1 x 1  1cm 1cm
MSD    0.025cm  0.25mm  0.25  103 m  0.25  10 3 m
g '  x    2 3.  2 3 .  ln 2 40 40
 3 3 2. Calculate the Vernier scale division (VSD):
x 1 x
 Given that 50 Vernier scale divisions are equal to 49 main scale divisions:
g '  x   0  2 3  2 3.2 3 49 MSD
50 VSD  49 MSD VSD 
1 50
22x  21  x  3. Substitute MSD to find VSD:
2 49  0.25mm 49  0.25  103 m
1 1 1 7 VSD    0.245  10 3 m
1 50 50
g    2 6  2 6  2.2 6  2 6  m 4. Calculate the least count:
2 The least count (LC) of the travelling microscope is the difference between one main scale division
7 (MSD) and one Vernier scale division (VSD):
log 2m 
6 LC  MSD  VSD LC  0.25  103 m  0.245  103 m  0.005  103 m  5  10 6 m
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