Aits 2223 Ft Viii Jeea Paper 2 Sol

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ALL INDIA TEST SERIES

JEE (Advanced)-2023
FULL TEST – VIII
PAPER –2
TEST DATE: 07-05-2023
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. B
Sol. Flux enclosed is
1 
   8R  3R  R
qin  2 
 
0 0
12R3

0
2. C
Sol. Force weight of liquid above the sphere
2
F  P0 r 2  (r 2  3r  r 3  r 3 )g
3
10 3 r 2
 P0 r 2  r g = (3P0  10gr)
3 3
3. B
Sol. Since current is
 
I  J  S  JS  ES  KE2  4r 2
1 I
 E
r 4K
a
  I b

Also, V   E  dr  n  
4K  a 
b
4KV 2
I= 2
  b 
 n   
  a 
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2
AITS-FT-VIII (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023
4. C
2M
Sol. Let density be , where  
4 
 (2R)3  (R)3 
3  
2M

4
(7R3 )
3
Moment of inertia of remaining part (about point of contact)
I = IT  Icavity
7 7
I  MT (2R)2  MCR2
5 5
16M 2M
MT  and MC 
7 7
62 2
I MR
5
2
1 2 1  62  2 V 
K.E. = I    MR  
2 2 5   2R 
31
K.E. = Mv 2
20
5. B, D
Sol. usin 30 = v sin60 P 
u
 v …(i)
3
3R 3R 3 30
mu   mv   mR2 
2 2 2
C
2u
  …(ii) 60
3R m u
v
Coefficient of restitution,
v 3
 R
2 2 v  3 R
e 
3 3u
u
2
Or e = 1
6. A, C
Sol. zero error =  1.25 mm
Reading = 18 + 0.34 + 1.25 = 19.59 mm
7. C, D
Sol. At P, path difference
4  3 
x    1 9    1 2  2
3  2 
IP = 4I0

3
8. B, C, D
 
Sol. n  n   3nn
 1 
r 
n  n   2nn
 r1 
A 
 h  n   4nn
 A1 
 n2 
rh  r0  
 z
 
9. A, D
qE 1
Sol.  mv 2
2 2
qE
 v
m
v 2 qE
a 
 m
m  qE 
T  qE  
  m 
 T = 2qE
10. B, C
Sol. For A, m
J J1 = mu …(i) C
For C, J2
J2 = mv …(ii) v1
Component of velocity of B in direction BA must be u. 30 J
2
Let its vertical component perpendicular to BA be v1 m u
u
Velocity component of B along CB is A J1 J1 B 2m
u sin 30  v1 cos 30 = v …(ii)
For B
J1  J2 cos 60 = 2mu
2J1  J2 = 4mu …(iv)
and J2 cos 30 = 2mv1
3
J2  2mv1 …(v)
2
Solving (ii), (iii) and (iv) and (v)
4u 3u
v , v1  and vB  u2  v12
11 11
4 31 u
vB 
11

4
Section – B
11. 5
2m 2 2 m 3
Sol. FA    , FC  2 
3 3 2 4
FA 32
 n=5
FC 27
12. 2
Sol. Elastic potential energy,
1  YA 
U  (  )2
2   
Here y, ,  are same for both the wire
UB S
  B 2
UA S A
13. 2
k0A dT
Sol. I0 
   dx
cos  x
 6L 
6I0L   
 T  T0 sin  x
k 0 A  6L 
 T = 2T0 at x = L
14. 5
Sol. Potential due to rod at C r0
A B C
r0 L
GM dx
V
L  x r
r0 dr
GM  L
v n  1   , where r0 changes from L to
L  r0 
L
then kinetic energy gained by m is
2
1 mGM  3 
mu2  n  
2 L 2
2GM  3 
v n  
L 2
x+y=2+3=5

5
15. 4
Sol. 2Tsin  = BidR Bide
2T = Bi(R  2)
T = BiR
T BiR
v 
S S
T
V 2S 10  10  2  103  0.2  104 T
B 
iR 1 1  
B = 4T
16. 2
mg
Sol. Amplitude of block =  1 mm
k
1 1 1
   v =  60 cm
v (30) 20
v
Magnification, m =  2
u
Thus, amplitude of image = 2 mm
17. 3
3a 3a/2
Sol. tan  
2h
2  4aT  cos  = 4ag
g  h
 cos  
2T
3ga
 h
2 4T 2   2 g2
18. 4
v vC
Sol. (1000)  1500
 v  vC cos   
  = 30
  sin   cos 
Also,   
v v bullet vC
1 1  3v  5
   1 
2v bullet v  2v C  4v

2v 2
 vbullet   (360)  4(36) m/s
5 5

6
Chemistry PART – II
Section – A
19. D
n
nPCl3  nCl2  P 
Sol. KP   
nPCl5  n
1
1 1  1 
  
4 7
1

28
20. C
Sol. 9
Me
8
Me
7 6
O


O 1 CO 2H O
O
2 5
4
3
4, 7, 8-trioxo nonanoic acid
21. B
Sol. In polar protic solvent down the group nucleophilicity increases and when the attacking atom is
same generally stronger the base stronger the nucleophile provided there is no unfavourable
steric hindrance.
22. B
Sol. Alanine is a neutral amino acid. The isoelectric points of neutral amino acids are in the pH range
5.5 to 6.3
23. B, D
Sol. If the diol/polyol involves the OH group oriented in such a way that they accurately match the
structural parameters required by a tetrahedrally coordinated boron, a strong complex is formed.
24. A, C
Sol. 
H Ph NHNH2
 
O OH OH H OH H
O N
NH
Ph

7
H
OMe 
H
 OMe Me
MeOH
S  
OMe S S
Me OMe
Me O Me
PhNH  NH2
H H2N NH Ph
N NH Ph IMPT
Me
S Me S
+ O Me
O
H Me
MeOH
N NH Ph
S C
Me
25. C, D
Sol.
O
O O
 
MeO
Br MeO
Br
MeO
26. B, D
Sol. bN2  bO2
Since volume of N2 molecule is greater than O 2 molecule. Both are non-polar molecule, in that
case a is proportional to molecular mass.
27. A, D
Sol.
P O Q

8
28. A, C, D
Sol. (A) Tf  K f  m
0.04
 1.86   1000
200
= 0.372
(B) G  RT lnK eq
G  H  TS
H So
lnK eq  
RT R
(C) A  g  2B  g   C  g
t0 a
t  t eq ax 2x x
Po  a
Pt  a  2x
P  Po
x t
2
 {P  Po 
a  x  Po   t 
 2 
3Po  Pt

2
1 a
k  n
t ax
1 Po
k  n
t 3Po  Pt
2
1 2Po
k  n
t 3Po  Pt
(D) 2r  n
o
2  0.5n2  n  12.56 A
3.14  n  12.56
n4
Section – B
29. 1
Sol. Cl Cl H Cl Br H Br
Br
H H H H
H Br H H
H H I H H Cl I
I
H H H H H I H H
P has four diastereomers and each of the diastereomers exhibits enantiomerism.
30. 5
Sol. CO2 , CH3 CN, NO 2 , N2 O & C3 O2

9
31. 7
Sol. NaBH4 can reduce only following group.
CH O CH2OH
C O CH OH
C Cl CH2OH
O
R-X R-H
(2o/3o halide)
32. 6
Sol. Dichloridobis (glycinato) cobaltate (III) ion CoCl  gly  
 2 2
Cl
Dichloridobis (glycinato) cobaltate (III) ion

10
Total number of optical active isomers = 6(six)
33. 5
Sol. 7A  B
t0 a0
tt a0  7x x
Now, a0  8x
t t t
8x  1/2
 4x 
1/ 2
 2x 
1/ 2
x
Given 3t1/2  900 hr
t1/2  300 hr
300
 days
24
300 4
 0.4t1/2   days
24 10
= 5 days
34. 4
Sol. In the given molecule there are 4 acidic hydrogen atoms are present.
35. 9
Sol. FeSO4 .  NH4 2 SO4 .6H2 O  Fe 2  2NH4  2SO24
x=5
2CuSO4  4KCN  2CuCN  K 2 SO4   CN 2 
3KCN  CuCN  K 3 Cu  CN 4 
3
K 3 Cu  CN 4   3K   Cu  CN4 
y=4
36. 4
Sol. Lattice energy  charge of cation × charge of anion.

11
Mathematics PART – III
Section – A
37. C
1 1
Sol. Tn  2  
n n2
38. D
2
Sol. Use the function f(x) = (cot–1 (x))2 +
2
x 1
39. A
3
 4  52
Sol. Sum of elements =   3
 2r  
 3
r 0
40. C
y2
Sol. Put e x  t  y(y – x) = x loge(cey – 1)
41. A, D
Sol. A4 – 7A3 + 15A2 – 9A = 0 (Null matrix)
 B + C = 4A
42. A, B, C, D
Sol. P1 : 8x – 9y + 4z = –40 P1
P2 : 3x + 4y + 3z = –10
Line L must lie in P2 and perpendicular to P1
 10 
 A  x1, y1,  must lie in both the plane P2
 3 
20 10
 x1   , y1  0, z1 
3 3 L
43. A, B, C
Sol. Shown in the figure
4
4(x – 2)2
3
2
2(x – 1)
1
4(x–1)(2–x) 2(x – 2)
1 0 3 5
–1  1 2 3
2 –1 2 2
44. B, C

Sol. f  
1  2

12
45. A, B, C, D
  a  1 2  
a  1  ah  a   h  .....  5 1  h   4 
1  h   5 1  h   4   2  
Sol. lim = lim  
h 0
 a
h 1  h   4 1  h   3 h 0    
h  1  ah   a 
a  1  2  
 h  .....  4 1  h   3 
  2   
a  1 2  a  1
 a  5  h  a 
 h  ..... a 
 2   2   10
= lim  (a = 5) and b 
h 0   a  1 2  a4
h  a  4  h  a   h  .....
  2  
46. A, D
14 2 ic
Sol. Let z1  2eia , z 2  e , z 3  2eib
5
14 2
sin  a     2sina
5 4 7 2
 arg  z2  z1      ; cos  
14 2 3 10
cos  a     2cos a
5
3 4 
 tana   tan  a  2    arg  z1   arg  z 3  
4 3 2
Section – B
47. 4
Sol. Number of favourable cases = 7788
48. 5
1
1 5
x15  x11  x7 1 dt 5 4
Sol. I dx  I  
3
48 0 3 12
0
 3x16  4x12  6x 8  4 t4
49. 2
Sol. Let cot 1  2x  1   ; 0 <  < 
1  cot  2t t 1
 sin2     t3 – 3t2 + t + 1 = 0
2 1 t2 2t
 t = 1, 1  2 ; t  1  2 does not satisfy
1
 x  1,
2
50. 6
1 2025  1 1 
Sol. 2024
   
Cr 2026  2025 Cr 2025
Cr 1 
r 1
2023
 1 r 2025  1 1   1 1   1 1   1 1  
  2024
Cr
     2
2026  C1 C2  C

C
  3
C

C
  ..... 2023 
C

C

r 1  2 3   3 4   2023 2024  
2025  1 1 1 1 1 2024  2024 1012
=      ....    = 
2026  C1 C1 C3 C4 C2024 C2024  2026 1013

13
51. 2
3 P(t1)
Sol. PQ =

4a t12  1  2
t12
2 11 
PQ is max at t1 = 3 and t 2  3  
3 3
1 3

tan   3 11  20  11  2
1 3 33 10 3
1  Q(t2)
3 11
52. 6
    
Sol. r  xa  yb  z a  b  
..... (1)
            
   
r  a  b  r  b a   r  ab  r  b  3 , r  a  2
 
From equation (1), we get 2 = x|a|2 + y a  b  2x + y = 1
  2
3  xa  b  y b  2x + 4y = 3
1 2  4 1
 x ; y  . Also, r   z
6 3 3 2
   2
  r a b   z a  b
53. 7
a b 
Sol. Let A    ; ad – bc  0  a + b + c + d = 6
c d 
4! 4!
(A) Exactly one zero. Number of matrices =  4!
2! 3!
6 1
(B) Exactly two zeros. Number of matrices 2  C21  10
(C) No zeroes number of matrices = 6
54. 6
Sol. Let z be x + iy then 0 < x < k, 0 < y < k k
And x2 + y2 > kx, x2 + y2 > ky
 k 2 2
   k  1 k 2  
Area = k 2    2       k
 4  4  2  2 4  
 2
2 2
3  k k  
= k2   =  3    250  6   
4 2 4 4  2
2 O k
 k = 2000  k  20 5 k
2

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ANSWERS, HINTS & SOLUTIONS

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Dichloridobis (glycinato) cobaltate (III) ion

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Total number of optical active isomers = 6(six)

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Mathematics PART – III

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