Paper Id : 4869 (Set-1)

Class: Junior Inter ASSIGNMENT - HYDROCARBONS Date: 29-03-2024

Time: 60 Minutes SUB-BATCH: Max marks: 120

CHEMISTRY
1. KMnO 4 /H
+

−−−−−−−→

2.

3. ⟶

4.

5. Groups to be eliminated should be trans diaxial in chair conformation.

6. Greater than stability of carbocation faster is the rate of dehydration.

7. During hydroboration-oxidation, addition of H O across the double bond
2

occurs anti to Markownikoff's rule and since the stereochemistry of addition

is cis, therefore trans-2-methylcyclopentanol is formed

8. Heat of hydrogenation a No. ofπ-bonds;

In case of same no. of π -bonds, Heat of hydrogenation α 1/ Stability of alkene

9.
Conceptual

10. NO
+
generated as follows:
2

− +
H2 S O4 + HN O3 → HS O + H2 N O
4 3

+
O 2 N − OH 2 → N O + H2 O
2

Here, HNO 3 accept H

⊕
, hence, act as base

11. H2 Pd mainly gives syn hydrogenation product

12. Conceptual

13. Conceptual

14.

15. The difference between any two successive members of the homologous series
−CH i.e., the molecular weight of every two adjacent members differ by 14
2

(C H2 = 12 + 2 = 14)
16. Limiled water

CaO −−−−−−−−→ Ca(OH)2( s)

the process is k/a slaking of lime and the product
(Lim())

is slaked lime. It is an exothermic process.

Ca(OH) aq. solution is k/a Lime water and used for test of
2 CO2 .

17.

18. Conceptual

19. More electron releasing group increase the electrophilic substitution reaction.

20. Ph − CH = CH − CH3 ⟶ Ph − CH = CH − CH3

Trans cis

21. Conceptual

22. Al4 C3 given CH4

23. Ag O
2

CH3 − C ≡ C − H −−−→ CH3 − C ≡ C − Ag ↓

White Ppt.

24. propyne

25.

26. H2 O/H
+

←
27. Reductive Ozonolysis

28.

29.

30. Value of N is 6, that includes two enantiomeric paris. On fractional distillation four
fraction will be obtained. So answer is 4.

Paper Setter Created Date & Time

HYD-RO-ACAD-NSPIRA 5009 12-03-2024 12:45:36 PM