Paper Id : 4869 (Set-1)

Class: Junior Inter ASSIGNMENT - HYDROCARBONS Date: 29-03-2024

Time: 60 Minutes Max marks: 120

Exam Instructions :
Answer all the questions
Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If ONLY the correct option is chosen;
Zero Marks : 0 If the question is unanswered;
Negative Marks : -1 In all other cases

CHEMISTRY
1. An organic compound 'A' C4 H 8 on treatment with KMnO4 /H
+
yields compound 'B'
C H O.
3 6

Compound 'A' also yields compound 'B' an ozonolysis. Compound 'A' is:
1) 2-Methylpropene 2) 1-Methylcyclopropane

3) But-2-ene 4) Cyclobutane

2. Which of the following statements is incorrect for ethylene dichloride and ethylidene
chloride?
1) These are structural isomers

2) Both of these yields same product on reaction with alcoholic KOH solution

3) Both of these yields same product on treatment with aqueous KOH solution

4) Both of these yields same product on reduction

3. Compound 'X' reacts with diborane followed by alkaline hydrogen peroxide to form
compound Y. 'Y' on reaction with a mixture of sodium bromide in sulphuric acid
followed by bromobenzene and sodium in ether gives n-pentylbenzene. Compound 'X'
1) 2)

3) 4)
4. In the reactions,
+ +
H D

CH 3 − CH = CH 2 −−→ (A) CH 3 − CH = CH 2 −−→ (B)

D2 O H2 O

the compounds (A) and (B) are

1) CH 3 − CH(OH)CH 2 D and CH 3 CH(OD)CH 3

2) CH 3 CH(OD)CH 3 and CH 3 CH(OD)CH 2 D

3) CH 3 CH 2 CH 2 OD and CH 3 CHD CH 2 OH

4) CH 3 CH(OD)CH 3 and CH 3 CH(OH)CH 2 D

5. The major product obtained when following substrate is subjected to E2 reaction will
be:

1) 2) 3) 4) None of these

6. Arrange following alcohols in decreasing order of their reactivity for dehydration

reaction in acidic medium

(1) (2)

(3) (4)

1) IV > II > III > I 2) IV > I > II > III 3) I > III > II > IV 4) II > III > IV > I

7. The major product formed during the hydroboration- oxidation of 1-

methylcyclopentene is
1) 2)

3) 4)

8. Which of the following has the smallest heat of hydrogenation per mole?
1) 1-butene 2) Trans-2-butene
3) cis-2-butene 4) 1, 3-butadiene
9. The increasing order of heat of combustion of the following compound is:

1) III < I < II 2) II < III < I

3) II < I < III 4) III < II < I

10. Benzene react with nitrating mixture (conc.HNO3 and conc.H2SO4) to produce
nitrobenzene. In the nitrating mixture, HNO3 acts as a
1) Base 2) Acid
3) Reducing agent 4) Catalyst

11. Product of the below reaction will be.

1) Racemic mixture 2) Diastereomers

3) Meso compound 4) Constitutional isomers

12. CH 2 = CH − C ≡ CH on reaction with 1 mole DBr gives

1) CH 2 = CH − CBr = CHD 2) CH 2 Br − CHD − C ≡ CH

3) DCH2 − CHBr − C ≡ CH 4) CH 2 = CH − CD = CHBr

13. HBr reacts fastest with

1) 1-butene 2) 1-pentane
3) 2-pentane 4) 2-methyl propene

14. Which of the following compound evolve 2 mole of CO2 on gentle heating :
1) 2)

3) 4)
15. Which one of the following statements incorrect, in case of homologous series of
alkanes
1) the members of the series are isomers of each other

2) The members of the series have

3) The members of the series have the general formula Cn H2n+2 , Where n is an
integer

4) The difference between any two successive members of the series corresponds to
14 unit of relative atomic mass

16. Lime reacts exothermally with water to give 'A' which has low solubility in water.
Aqueous solution of ' A ' is often used for the test of CO , a test in which insoluble
2

B is formed. If B is further reacted with CO2 then soluble compound is formed. ' A '
is
1) Quick lime 2) Slaked lime
3) White lime 4) Lime water

17.

1) 2) 3) 4)

18. A hydrocarbon `X' with formula uses two moles of H2 on catalytic hydrogenation
of its one mole. On ozonolysis, `X' yields two moles of methane dicarbaldehyde. The
hydrocarbon `X' is:
1) hexa-1, 3, 5-triene 2) 1-methylcyclopenta-1, 4-diene
3) cyclohexa-1, 3-diene 4) cyclohexa-1, 4-diene

19. The correct arrangement for decreasing order of reactivity towards electrophilic
substitution reaction is

1) III > I > II > IV 2) IV > I > II > III 3) III > IV > II > I 4) II > IV > III > I

20. Choose the correct set of reagents for the following conversion.
trans (Ph − CH = CH − CH 3 ) →cis(Ph − CH = CH − CH 3 )

1) Br2 , alc −KOH, NaNH2 , H 2 Lindlar Catalyst

2) Br2 , aq −KOH, NaNH2 , Na (LiqNH3 )

3) Br2 , alc −KOH2 NaNH2 , Na (LiqNH3 )

 4) Br2 , aq −KOH, NaNH2 , H 2 Lindlar Catalyst

21. The molecules that will have dipole moment is/are

1) 2.2-dimethyl propane 2) trans-2-pentene
3) Trans-2-butene 4) 2,2,3,3-Tetra methyl butane

22. Ethane cannot be obtained by the following.

1) Heating methyl iodide with sodium metal in ether

2) Hydrogenation of Ethene

3) Sodium acetate on Kolbe's electrolysis

4) Hydrolysis of Al4 C3

23. Consider the following reactions:

' A ' is:

1) CH 2 = CH 2 2) CH 3 − C ≡ CH

3) CH ≡ CH 4) CH 3 − C ≡ C − CH 3

24. Consider the following reactions, What is A

1) Acetylene 2) propyne 3) ethylene 4) 2-butyne

25.

The degree of unsaturation of product Y is?

1) 4 2) 5 3) 3 4) 6

26.

If R is aromatic and S is aliphatic, then:

A) Rate of EAS of (R) is more than that in benzene.
B) enol content of " S " is more than the enol content of acetaldehyde
C) R is more acidic than C H OH 2 5

1) A and C are correct 2) B and C are correct

3) Only C is correct 4) All A, B and C are correct

27. Which compound will yield 2-methyl 6-oxo heptanal on treated with o3 followed by
Zn/H O ? 2

1) 2) 3) 4)

28. The major product [R] in the following sequence of reactions is :

1) 2)

3) 4)

29. An alkane with molecular mass 86 on bromination gives only two monobromo
derivatives (excluding stereoisomers). The alkane is
1) (CH 3 ) CHCH2 CH 2 CH 3
2
2) (CH 3 ) C − CH 2 CH 3
2

3) (CH 3 ) CH − CH(CH 3 )
2 2
4) (CH 3 ) C
4

30.

Find the value of M.

1) 4 2) 3
3) 2 4) 1

Paper Setter Created Date & Time

HYD-RO-ACAD-NSPIRA 5009 12-03-2024 12:45:36 PM