Jee mock 3

JEE MAIN MOCK TEST # 3
M.M.: 300 Time: 3 Hours

Important Instructions:
1. The test is of 3 hours duration.
2. The Test Booklet consists of 75 questions. The maximum marks are 300.
3. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having
25 questions in two section (Section A and Section B).
4. Section A contain 20 multiple choice questions with single correct answer. Section B contains 5 integer type
questions.
5. Each question is allotted 4 (four) marks for each correct response.
6. Candidates will be awarded marks as started above in instruction No. 5 for correct response of each question.
¼ (one fourth) marks of the total marks allotted to the question (i.e. 1 mark) will be deducted for indicating
incorrect response of each question. No deduction from that total score will be made if no response is
indicated for an item in the answer sheet.
7. Do not fold or make any stray mark on the Answer Sheet.
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JEE Main Mock Test # 3
PART 1 : PHYSICS
SECTION 1
This section contains 20 multiple choice questions. Each question has four choice (A), (B), (C) and (D) out
of which ONLY ONE is correct.
1. An air bubble of radius r in water is at a depth h below the water surface at some instant. If P is
atmospheric pressure, d and T are density and surface tension of water respectively, the pressure
inside the bubble will be
4T 2T 2T 4T
(A) P  hdg  (B) P  hdg  (C) P  hdg  (D) P  hdg 
r r r r
2. A tank 5 m high is half filled with water and then filled to the top with oil of density 0.85 g/cm3.
The pressure at the bottom of the tank, due to these liquids is
(A) 1.85 g/cm2 (B) 89.25 g/cm2 (C) 462.5 g/cm2 (D) 500 g/cm2
3. Two concentric spheres are of radii r1 and r2. The outer q
sphere is given a charge q. The charge q on the inner q
r1
sphere will be (inner sphere is grounded)
r2
(A) q (B)  q
r1
(C)  q (D) zero
r2
4. Five cells, each of emf E and internal resistance r are connected in series. If due to over sight,
one cell is connected wrongly, then the equivalent emf and internal resistance of the combination
is
(A) 5E and 5r (B) 3E and 3r (C) 3E and 5r (D) 5E and 3r
5. A galvanometer has a resistance of 3663 ohm. A shunt S is connected across it such that (1/34)
of the total current passes through the galvanometer. Then the value of shunt is
(A) 3663  (B) 111  (C) 107.7  (D) 3555.3 
6. If electron velocity is 2iˆ  3 ˆj and it is subjected to magnetic field of 4k̂, then its
(A) speed will change (B) path will change (C) both (A) and (B) (D) none of these
7. The angle of dip is the angle
(A) between the vertical component of earth's magnetic field and magnetic meridian
(B) between the vertical component of earth's magnetic field and geographic meridian
(C) between earth's magnetic field direction and horizontal direction
(D) between the magnetic meridian and the geographic meridian
8. A conducting rod AB moves parallel to x- Y
axis in a uniform magnetic field, pointing in A
the positive x-direction. The end A of the rod
gets:

(A) positively charged v
(B) negatively charged
(C) neutral
(D) first positively charged and then B
X
negatively charged
9. The rms value of emf given by e  8 2 sin t + 6 2 sin 2t volt is
(A) 8 (B) 6 (C) 10 (D) 14
Ashwani Tyagi Sir 2 Code: ATJEE/ATNEET
10. The frequency of incident light falling on a photosensitive metal plate is doubled, the KE of the
emitted photoelectrons is
(A) double the earlier value (B) unchanged
(C) more than doubled (D) less than doubled
11. Strength of magnetic field at the centre of circular coil is
I
0 I  1  0 I  1 
(A) 1   (B) 1    R
R   2R   
0 I  1  I
0 I
(C)  (D) 1  
R 2R   
12. A magnetic field of (0.004 k̂ ) tesla exerts a force of ( 4 î  3ˆj)  10 10 N on a particle having charge of
1  10-9 C and moving in x – y plane. The velocity of particle is
(A) ( 75 î  100 ĵ) ms  1 (B) ( 75 î  100 ˆj) ms  1 (C) (  75 î  100 ˆj) ms  1 (D) (  75 î  100 ˆj) ms  1
13. The radio waves which are received after reflection in ionosphere are called
(A) ground waves (B) sky waves (C) space waves (D) surface waves
14. A wheel with N spokes is rotated in a plane perpendicular to the x x x x x x x
magnetic field of earth such that an e.m.f e is induced between axle and x x x x x
rim of the wheel. In the same wheel, number of spokes is made 3N and x x x x x
the wheel is rotated in the same manner in the same field then new e.m.f x x x x x x x
x x x x x x x
is
3 e
(A) 3e (B)e (C) (D) e
2 3
o
15. A ray of light makes an angle of 10 with the horizontal
and strikes a plane mirror which is inclined at an angle  
x
to the horizontal. The angle  for which the reflected ray
becomes vertical is
(A) 400 (B) 300 (C) 600 (D) 500
16. A short linear object of length b lies along the axis of a
b
concave mirror of focal length f at a distance u from the pole.
The size of image is u
2 2 2 2
uf  uf   f   f 
(A) b   , erect (B) b   ,inverted (C) b   , erect (D) b   , inverted
 f   f  uf  uf 
17. The electron in the lowest (n = 1) orbit in hydrogen atom has energy – 13.6 eV. How much energy is
required to ionize a hydrogen atom which is already in the first excited level?
(A) 3.4 eV (B) 10.2 eV (C) 13.6 eV (D) 1.9 eV
18. The ratio of the longest wavelength to shortest wavelength in Lyman series hydrogen spectra is
25 17 4 9
(A) (B) (C) (D)
9 6 3 5
19. The following truth table belongs to which of the gates?
A B Y
0 0 0
0 1 1
1 0 1
1 1 1
(A) NAND (B) AND (C) XOR (D) OR
20. Main function of modem is to convert
(A) analog signal into analog signal (B) digital signal into analog signal
(C) analog signal into digital signal (D) digital signal into analog signal and vice versa
SECTION 2
This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging from
0 to 9.
21. A billiard ball of radius 5 cm initially at rest is given a sharp impulse by a cue at a point, at a
height h above the centre. The ball leaves cue with a speed v0 and acquires a final velocity of
9v 0
. Find the value of h (in cm).
7
22. A cylinder is filled with a liquid of refractive index  = 4/3. observer
The radius of the cylinder is decreasing at a constant rate
1mm/sec. The volume of the liquid inside the container
remains constant at V  2m 3 , r  10 cm. The observer and
L
the object O are in a state of rest and at a distance L from each
other. What is the apparent speed of the object as seen by the y
observer, at the instant shown in the figure?
O
2r
23. A satellite is orbiting around a planet in a circular path of v0
radius R. A meteorite of mass m collides with the satellite
and sticks to the satellite. After collision, the satellite is seen v
to have gone into an orbit whose minimum distance from M m
R 9m
the planet is R/2. Mass of satellite is 9m and that of planet
is M and assume that the meteorite is moving radially
towards the satellite’s orbit with speed v before collision as
86GM
shown in the figure. If v  , find the value of n.
nR
24. A solid cylinder is placed on one edge of a plank of same
mass and length 25 m placed on a smooth surface as shown
in the figure. The coefficient of friction between the
cylinder and the plank is 0.5. The plank is given a velocity
of 20 m/s towards right. Find the time (in sec) after which 25m
2
plank and cylinder will separate. (g = 10 m/s )
25. A radioactive sample can decay either simultaneously or individually by two processes X and
1 1
Y. The half life for process X is Hr and for process Y is Hr. The sample decays for first half
4 6
hour by process X, for next one hour by process Y and for next half hour by process X and Y
both. The initial number of nuclei of the sample is N0. After 2hr, the number of nuclei of the
n
N 1
sample are 0   . Find the value of n.
32  2 

PART 2 : CHEMISTRY
SECTION 1
26. Silver is extracted from Ag2S by
(A) fusing it with KCl and electrolyzing the melt.
(B) reducing it with zinc.
(C) treating it with sodium cyanide followed by zinc.
(D) roasting it and reducing the resultant product by smelting.
27. The hybridization of central atom in species OF2, SF4, NO3 and I 3 are respectively
(A) sp3d, sp3, sp2 and sp3d2 (B) sp3, sp3d, sp2 and sp3d
(C) sp3, sp2, sp3d and sp3d2 (D) sp3, sp3d, sp3d2 and sp2
28. The final product (III) obtained in the sequence of reactions

pchlorotoulene  ( i ) KMnO , OH
 4
 ( I )  SOCl
 ( II )  CH
 CH
2
OH
 ( III )
3 2
( ii ) H 
O
(A) Cl CH2.CH3(B) Cl C  O  CH 2  CH 3
O O
(C) Cl C  CH 2  CH 2Cl (D) C  O  CH 2  CH 3
o
29. Given: E Ag |Ag  0.799 V and E oZn 2
| Zn
  0 . 673 V , which of the following is true.
(A) Ag+ can be reduced by H2(g) (B) Ag can be oxidized by H+

(C) Zn2+ can be reduced by H2 (D) Ag can reduce Zn2+
30. In an electrolytic cell which of the following is not true?
(A) Cathode is negative terminal (B) Cathode is positive terminal
(C) Reduction occurs at cathode (D) Oxidation occurs at anode
31. Which of the following compounds is expected to give red colouration while performing
Lassaigne’s test of nitrogen?
(A) Urea (B) Thiourea (C) Aniline (D) Nitrobenzene
3
32. The EAN of Cr in [Cr(SCN)6] is
(A) 35 (B) 33 (C) 34 (D) 37
33. The diamagnetic complex among the following is
(A) [CoF6]3 (B) [Fe(H2O)6]3+ (C) K3[Fe(CN)6] (D) K4[Fe(CN)6]
34. The phenomenon when the composition of the activated complex includes a substance which
does not take part stoichiometrically in the chemical process, but changes the kinetic properties
of the system is called
(A) Chemical equilibrium (B) Catalysis
(C) Osmosis (D) Demulsification
35. The structure of amino acid of pH = 6 is
(A) H2N  CH2COO (B) H2N  CH2  COOH
+
(C) H3N  CH2COOH (D) H3N+  CH2COO

36. The type of isomerism shown by [Co(en)2(NCS)2]Br and [Co(en)2(NCS)Br]NCS is
(A) co-ordinate isomerism (B) ionization isomerism
(C) linkage isomerism (D) all of these
37. Which graph represents adsorption isotherm?
x/m x/m
(A) (B)
T T
x/m
(C) (D) T
T P
38. Diagonal relationship is shown by
(A) Li and Na (B) Be and Mg (C) Si and C (D) B and Si
39. The correct order of increasing thermal stabilities of the compounds K2CO3 (I), MgCO3 (II), CaCO3
(III) and BeCO3 (IV) is :
(A) I < II < III < IV (B) IV < II < III < I (C) IV < II < I < III (D) II < IV < III < I
40. Dehydration of 1-butanol gives 2-butene as a major product. The most stable intermediate formed is

(A) CH3  CH2  CH2  CH2 (B) CH 3  CH 2  C  CH 3
CH3

(C) CH3  CH2  CH  CH3 (D) CH3  CH  CH2
CH3
41. The product X in the following reaction is
CH3  C  CH  2  X
HBr
(A) CH3  CH  CH2 (B) BrCH2HC=CHBr

Br Br
Br Br
(C) CH3  CH2  CH (D) CH3  C  CH3
Br Br
42. Nitrogen present in an organic compound is estimated as ………… in Duma’s method and as ……….
in Kjeldahl’s method respectively
(A) NH3, N2 (B) N2, NH3 (C) (NH4)2SO4, NH4Cl (D) N2, NCl3
43. The reaction of 1-Bromo-4-chlorocyclohexane with metallic sodium in dioxane under reflux conditions
gives
(A) Cl Cl (B) Br Cl
(C) Br Br (D)

44. Match the lists I and II and pick the correct matching from codes given below:
List I (haloalkane/arene) List II
a. Iodoform 1. CF4
b. BHC 2. antiseptic
c. Freon-14 3.moth repellent
d. Halothane 4. inhalative anesthetic
e. p-dichlorobenzene 5. termite pesticide
(A) a – 2 ; b – 4 ; c – 5 ; d- 3 ; e –1 (B) a – 2 ; b – 5 ; c – 1 ; d- 4 ; e –3
(C) a – 3 ; b – 4 ; c – 2 ; d- 1 ; e –5 (D) a – 1 ; b – 3 ; c – 5 ; d- 2 ; e – 4
45. CH bond energy is about 101 kcal/mol for methane, ethane and other alkanes but it is only 77 kcal/mol
for CH bond of CH3 in toluene. This is because
(A) of inductive effect due to CH3 in toluene.
(B) of the presence of benzene ring in toluene.
(C) of hyperconjugation effect of CH3 in toluene.
(D) aromaticity of toluene.
SECTION 2
0 to 9.
46. One mole of the following compound (A) is completely oxidised by x moles of periodic acid to
form y moles of formic acid and z moles of formaldehyde. What is the value of x + y + z?
OH OH OH
R–CH–CH–CH–CH2–OH + xHIO4  yHCOOH + zHCHO
(A)
47. In the complex with formula MCl3.4H2O, the hybridization of metal is sp3d2 and there is no
molecule of hydration in it. Volume of 0.1M AgNO3 solution needed to precipitate the free
chloride ions with 25mL of 0.02M solution of complex?
48. The emission spectrum of a sample of single hydrogen atom contains 3 lines. The value of ‘n’
to which the hydrogen atom gets excited is ________ .
49. (R)–CH3CH(I)C2H5 + 137I–  CH3CH(I)C2H5 containing some I137
obs = –15.9° obs = –15.26°
How much of the compound has undergone racemization?
50. The number of salts formed by telluric acid (H6TeO6) when treated with strong base (NaOH),
is/are ________ .
SPACE FOR ROUGH WORK

PART 3 : MATHEMATICS
SECTION 1
f x 
b
51.  f x   f a  b  x dx is equal to
a
ab ab ba

(A) (B) (C) (D) none of these
2 2 2
   
52. Let a , b , c be three vectors such that a . ( b + c ) + b . ( c + a ) + c . ( a + b ) = 0 and |

  
 
a | = 1, | b | = 4, | c | = 8, then | a + b + c | equals
(A) 13 (B) 81 (C) 9 (D) 5
53. For the triangle whose sides are along the lines y = 15, 3x – 4y = 0 , 5x + 12y = 0, the incentre is
(A) (1, 8) (B) (–1, 8) (C) (8, 1) (D) none of these
If n  N, then integral part of 5  2 6  is
n
54.
(A) an even integer (B) an odd integer (C) a prime integer (D) none of these
55. The order of the differential equation, of which xy = cex + be–x + x2 is a solution is
(A) 1 (B) 2 (C) 3 (D) none of these
2ay
56. The equation of the curve through the point (1, 1) and whose slope is is
xy  a 
(A) y a . x 2 a  e y 1 (B) y a . x 2 a  e y (C) y 2 a . x a  e y 1 (D) none of these
57. Three forces P, Q, R acting at a point in a plane are in equilibrium. If the angle between P and Q
is 150o and that between Q and R is 120o, then P : Q : R is same as
(A) 1 : 2 : 3 (B) 1 : 2 : 3 (C) 3 : 2 : 1 (D) 1 : 3 : 2
58. A particle is thrown vertically upwards with a velocity of 490 cm/sec. It will return to this
position after
(A) 1 second (B) 0.5 second (C) 2 seconds (D) none of these
59. The trigonometric equation sin–1x = 2sin–1a, has a solution for
(A) 1  | a | 1 (B) all real values of a
2 2
1
(C) | a | (D) | a |  1
2 2
60. The value of tan 1
1  tan 1
2  tan 1
3 is

(A)  (B) 2 tan–12 (C) (D) none of these
2
xdx
61.  1 x 
1 x   x 
(A) log C
 (B) log C
 x  1  x 
(C) 2 x  2 tan 1 x C (D) 2 x  tan 1 x C
62. e
x
sec x1  tan xdx =
(A) excosx (B) exsecx (C) exsinx (D) extanx

f a  f a 
ex I2
63. If f  x  , I1   xgx1  xdx and I 2   gx1  xdx , then the value of is
1 ex f a   
f a I1
(A) 2 (B) –3 (C) –1 (D) 1
   
64. For any vector a , the value of ( a  î )2 + ( a  ĵ )2 + ( a  kˆ )2 is equal to
   
(A) a 2 (B) 3 a 2 (C) 4 a 2 (D) 2 a 2
65. The plane intersection of x2 + y2 + z2 + 2x + 2y + 2z + 2 = 0 and 4x2 + 4y2 + 4z2 + 4x + 4y  1 = 0 is
(A) 4x + 4y + 4z + 9 = 0 (B) x + y + z + 9 = 0 (C) 4x + 4y + 4z + 1 = 0 (D) they do not intersect
Direction: Questions number 66 - 70 contain Statement-1 and Statement -2. Of the four choices given after the
statements, choose the one that best describes the two statements.
66. Statement-1: Two circles cut a third circle orthogonally, then the radial axis of the two circles passes
through the centre of the third circle.
Statement-2: The radical axis of three circles taken in pairs are concurrent or parallel.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True
67. Statement-1: The minimum value of the expression sin  + sin  + sin  where , ,  are real numbers
such that  +  + = , is negative.
Statement-2: , ,  are angles of a triangle.
68. Statement-1: The equation sin-1x =cos-1x has one and only one solution.
Statement-2: The equation tan-1x = 1 has only one solution.
x2
69. Statement-1: If b > 0, the area bounded by the parabolas y = x – bx2 and y = is maximum if
b
b = 1.
x2
Statement-2: The area bounded by the parabolas y = x – bx2 and y = is 2 – (b – 1)2 is.
b
 2 1
70. Statement-1: The lines (a + b)x + (a – 2b)y = a are concurrent at the point  , 
 3 3
 2 1
Statement-2: The lines x + y –1 = 0 and x – 2y = 0 intersect at the point  ,  .
 3 3

SECTION 2
0 to 9.
71. There are 100 employee in sale office of a multinational company. Let PEi  be the probability
that exactly i out of 100 employee are infected with swine flu virus. If PEi  is directly
proportional to ii  2; 1  i  100 . If the probability that a person selected at random is found
108 p
to be positive for this virus is given by , then p is equal to
575
72. If x1 , x 2 , ........x n are independent variables such that sum of coefficient of
 Cx
n 2
1 1  n C2  x1  x2   n C3  x1  x2  x3   ........ n Cn  x1  x2  ......xn 
2 2

2 n
is
2
n n  1n 2 n  kn
, find the value of k.
1
3 x
(1  a )  8e 2 2
73. If a and b are positive numbers and lim 1
 2 , then find the value of a  b .
x0
1  ( 2  b  b 2 )e x
74. Consider the collection of all curves of the form y  a  bx 2 that passes through the point
(2, 1) where a and b are positive real numbers. if the minimum area of the region bounded by
A
y  a  bx 2 and the x-axis is A , then find the value of .
8
75. With usual notations the triangle ABC is inscribed in a circle of unit radius then find least value
s
of .

SPACE FOR ROUGH WORK

JEE MAIN MOCK TEST # 3
ANSWERS & SOLUTIONS
PHYSICS
1. Let pressure inside the bubble = Po
and total pressure on air bubble at a depth h be P
Here, P '  P  hdg
2T
Po  P ' 
r
2T
Po = P  hdg 
r
 (B)
2. (C)
3. (C)
4. (C)
5.
I Rg = 3663 
Ig
(I  I g)
1
Given I g  I 
34
I 331
I  Ig  I  or I  Ig 
34 34
I  I g 
S  I g Rg
331 I
S 3663 
34 34
3663
S  111 
33
 (b) 
6. (B)
7. (C)
8. Force on negative charge is along +y - axis.
 (B) 
A12 A22
9. Rms value of emf = E = 
2 2
where, A1 = 8 2 , A 2  6 2
64  2 36  2
E   10
2 2
 (C)
10. KEmax = h - 
KE1 = h -  (1)
KE2 = 2h -  (2)
2KE1 = 2h - 2 (3)
Comparing equation (2) and (3),
KE2 > 2KE1
 (C)
11. B
say B1 = field of long wire
& B2 = field of closed loop
  I   I
 B 1  o k̂ & B 2  o (  k̂ )
2 R 2R
   o Ik̂  0 i  I  1
Bnet = B 1  B 2 =  k̂ = o 1  (k̂)
2R 2R 2R   
12. C

B  0 .004 k̂

 
F  4 î  3 ĵ  10 10 N
-9
q = 1 10 C

say , V = V x î  V y ˆj  V z k̂
  

  
F  q V  B = 10  9 V x î  V y ˆj  V z k̂  0 . 004 k̂ 
4 i  3 j   10  10 
 4  10  12  V x ˆj  V y iˆ 
 Vx = -75
Vy = 100
13. B
14. D
15. D

100
90 
 i +  r = 100
290  10    100
 = 500
16. B
1 1 1
  ------------- (i)
v u f

1 1
 2
.dv  2 .du = 0
v u
1 1
 2 .dv  2 .du
v u
dv v2
 2
du u
u u
from equation (i) 1 
v f
u u u u f 
 1 ,   
v f v  f 
v  f 
 
u u f 
we know du = b
dv v2 f2
m=    2 
du u (u  f ) 2
dv f2

b (u  f ) 2
 f2 
Image size = dv = b  2 
 (u  f ) 
17. A
18. C
19. D
20. D
21. I  mv 0 I
h
2 
Ih   MR 2 0
5 
1 5v0

h 20 R 2
5v 0 h
 0 
2R 2
9v 0
 v 0  gt
7
9v 0 mgR
 0  t
7R 2 2
mR
5
9 v 0 5v 0 h 5 g   2 v 0 
   
7 R 2R 2 2 R  7g 
9 5h 5
 
7 2R 7
4R 4  5
h  = 4 cm
5 5

Ans.: 4
22. Apparent depth of object is y' .
y
y'  L  y 

dy ' dy  1 
   1  r 2 y  constant
dt dt   
dr dy
2  0
r y
2y
dy   dr
r
dy 2 y dr

dt r dt
dy ' 2 y dr  1    V
   V  r 2 y , y 
dt r dt    r 2
dy' 2 V dr  1    2V  1    dr
     3    1 ms–1
dt 2
r r dt    r    dt
Ans.: 1
23. Applying conservation of linear Gm
momentum v0  v
R 
v
mv  10 mv ' sin   v ' sin  
10 v m 
M R/2
9v R
9 mv 0  10 mv ' cos   v ' cos   0
10
u
v 2  81v 02
 v'2 
100
R
Applying conservation of angular momentum 10 mv ' cos R   10 mu
2
9v 0
 u  2 v ' cos  
5
Applying conservation of energy
GM 10 m  1  GM 10 m 1
  10 mv ' 2   10 mu 2
R 2 R/2 2
GM 1  v 2  81v 02  2GM 81v 02
   
 
R 2  100  R 50
43GM 86GM  GM 
v   v 0  
R 2R  R 

n=2
Ans.: 2
24. Drawing free body diagram of the cylinder with
respect to plank. a mg (pseudo force)
2mg  ma  a  2g 
mg

2g
mgR   1 mR 2  ; 
2 r
Acceleration of point of contact with respect to plank is 4g
Velocity of point of contact after time t with respect to plank  v  4gt
When pure rolling starts,
 v  4gt  0
20
t  1s
4  0.5  10
Distance traveled by cylinder with respect to plank in 1s is
1
s '  vt  2g t 2  15m
2
At t = 1s, the velocity of cylinder with respect to plank is
vrel = -v + 2gt = -20 + 2  0.5  10 = –10 m/s
10
Remaining 10m will be travelled in time t '   1s
10
 total time = 2s
Ans.: 2
25. T1 / 2 x  1 Hr ; T1/ 2  y  1 Hr
4 6
1 1 1
 
T1/ 2  xy T1/ 2  x T1/ 2  y
T1/ 2 xy   1  Hr
 10 
2
1 1
After Hr; N  N 0  
2 2
2 6
1 1
After 1Hr; N '  N 0    
2  2
8 5 8
1 1 1 N 1
After Hr; N ' '  N 0      0    n = 8
2 2  2 32  2 
Ans.: 8
CHEMISTRY
26. (c)
Total number of valence electrons Remainder
27. x= ,y=
8 2
Hybridized orbitals = x + y
OF2:
6  2  7 20 4
x=   2; y =  2
8 8 2
x+y=4
 sp3

SF4:
6  4  7 34 2
x=   4; y = 1
8 8 2
x+y=5
 sp3d
NO3 :
5  3  6  1 24 4
x=   3; y =  2
8 8 2
 sp2
I 3 :
3  7  1 22 6
x=   2; y =  3
8 8 2
x+y=5
 sp3d
 (b)
28.
CH3 COOH COCl COOCH2CH3

(
i ) KMnO 4 / OH
    SOCl
2  CH
3CH OH
2 
( ii ) H
Cl Cl Cl Cl
 (b)
29. (A)
30. (B)
31. (B)
32. EAN = (24  3) + (2  6) = 33
 (B)
33. (D)
34. (B)
35. In acidic medium amino acid exist as cations.
 (C)
36. B
These complexes produce different ions on ionization.
37. C
38. D
39. B
Down the group thermal stability of carbonate of alkali metals and alkaline earth metals
increases.
40. C
  
H
CH3CH2CH2CH2OH  CH3CH2CH2 CH 2  rearrange
   CH3CH2 CHCH3
 H 2O
41. D
Br Br
CH3CCH HBr
 CH3C=CH2 HBr
  CH3CCH3

Br
42. B

43. A
Na
2Cl Br  Cl Cl
dioxane
44. B
45. C
R
H OH
46. H OH Total moles of HIO4 consumed = x = 3.
H OH Moles of HCOOH formed = y = 2
CH2OH Moles of HCHO formed = z = 1
x+y+z =6
Ans. 6
47. From hybridization, we get that coordination number of complexes is = 6
As there is no water of hydration.
 formula of complex = [M(H2O)4Cl2]Cl, hence one free Cl– ion is given by one molecule of
complex.
(AgNO3) (Complex)
M1V1 = M2V2
0.1 × V1 = 0.02 × 25
V1 = 5mL
Ans. 5
48. For a sample of single hydrogen atom, the maximum number of lines observed in the spectrum
is (n – 1) where ‘n’ is the excited energy level. Thus, ‘n’ will be 4.
Ans. 4
15 .26
49. Optical purity of recovered iodide =  100 = 96%.
15 .9
Thus, 4% of the iodide is racemized.
Ans. 4
50. H6TeO6 has an octahedral shape and is a weak dibasic acid.
 H 2O NaOH
H6TeO6 + NaOH    NaTeO(OH)5  Na2TeO2(OH)4
H O 2
Thus, it forms only 2 types of salt on reaction with NaOH.

Ans. 2
MATHEMATICS
51. C
52. C
53. B
54. B
55. B
56. A
57. C
58. A
59. D
1 1
sin x  2 sin a
 
   sin 1 x 
2 2

 
   2 sin 1 a 
2 2
 
   sin 1 a 
4 4
  1 a 1
2 2
 | a | 1
2
No option is correct.
60. A
61. C
Put x = tan2
 dx = 2tansec2d
 I  2  tan 2  d   2  sec 2   1 d  = 2(tan  ) + C = 2[ x  tan1 x ] + C.
62. B
  e  f x   f  x   e x f  x 
x
63. A
Here f a  f  a   1
f a  f a 
I1   xgx1  xdx =  1  xgx1  xdx = I 2  I1

f a   f a
I2
 2
I1
64. D
Let a  a1 iˆ  a 2 ˆj  a 3 kˆ
so a  iˆ    a 2 kˆ  a 3 ˆj  a  iˆ 2  a 22  a 32
a  ˆj   a1 kˆ  a 3iˆ  a  ˆj 2  a 12  a 32
a  kˆ    a ˆj  a iˆ  a  kˆ 
1 2
2
 a 12  a 22
By adding all these;
 2   
   2
 
2

a  iˆ  a  ˆj  a  kˆ  2 a12  a22  a32  2.a 2 .  
65. A
Equation of second sphere can be written as
1
x2 + y2 + z=2 + x + y + z  = 0
4
 Equation f required plane is
2 x  x   2 y  y   2 z  z   2  1 = 0.
4
66. B
67. C
68. B
69. C
70. A
71. P E i   ki i  2   PE1   PE2   ........ PE100   1
100
 k ii  2  1
i 1

6
 k
100 .101 .207
100
E  100 i 432
Now P E    P E i . P    kii  2  
i 1  Ei  i 1 100 575
Ans. 4
72. Sum of coefficient C n
1  2 2 nC2  ......n 2 n Cn   nn  12 
n n 2 n
2
 n n  1 2 n
n 2n
 k=2
Ans. 2
1
73. RHL  lim

1  a   8e 3 x
2
1
x0 
1  2  b  b e 2 x
2 2
 2b b 4  b b20  b  1
1
LHL  lim
1  a   8e 3 x
2
1
x0 
1  2  b  b e 2 x
3
 1 a  2  a  1
Ans. 2
74. y  a  bx 2
when x = 2, y = 1
1  a  4b  a  1  4b
a/b a/b
2  bx 3  a a b a a 
A=2  ( a  bx ) dx  2 ax    2  . 
0  3 0  b 3 b b
2  3a a a a  2  2a a  4 (1  4b) 1  4b
=      
3 b b  3 b  3 b
 12 3 32 1 1 
b 1  4b . 4  1  4 b 
dA 4  2 2 b
  0
db 3  b 
 
1 3
 12 b  1  4 b  8b = 1  b , a
8 2
 Amin = 4 .  3 . 3 .2 2  4 3 2
3  2 2 2
A
 Minimum area = 48  A = 48  6
8
Ans. 6

R 1
75. r 
2 2
  1 s
r    2
s s 2 
Ans. 2

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JEE MAIN MOCK TEST # 3

M.M.: 300 Time: 3 Hours

Ashwani Tyagi Sir 4 Code: ATJEE/ATNEET

(A) Ag+ can be reduced by H2(g) (B) Ag can be oxidized by H+

Ashwani Tyagi Sir 5 Code: ATJEE/ATNEET

(A) CH3  CH  CH2 (B) BrCH2HC=CHBr

Ashwani Tyagi Sir 6 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 7 Code: ATJEE/ATNEET

ab ab ba

Ashwani Tyagi Sir 8 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 9 Code: ATJEE/ATNEET

SPACE FOR ROUGH WORK

Ashwani Tyagi Sir 10 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 2 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 3 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 4 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 5 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 6 Code: ATJEE/ATNEET

Thus, it forms only 2 types of salt on reaction with NaOH.

Ashwani Tyagi Sir 7 Code: ATJEE/ATNEET

I1   xgx1  xdx =  1  xgx1  xdx = I 2  I1

Ashwani Tyagi Sir 8 Code: ATJEE/ATNEET

73. RHL  lim

Ashwani Tyagi Sir 9 Code: ATJEE/ATNEET

Ashwani Tyagi Sir 10 Code: ATJEE/ATNEET

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