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The Nalco
Water
Handbook
Fourth Edition
ISBN: 978-1-25-986098-0
MHID: 1-25-986098-1
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Contents
Foreword. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxiii
Preface. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxv
Acknowledgments. . . . . . . . . . . . . . . . . . . . . . . . . . . xxvii
Section 1 Introduction
1 The Business Case for Managing Water. . . . . . . . 1.3
Global Trends Affecting Water Supply. . . . . . . . . . 1.4
The Impact of Climate Change on
Glacial Water . . . . . . . . . . . . . . . . . . . . . . . 1.4
Impact of Population Trends on Surface
and Groundwater. . . . . . . . . . . . . . . . . . . 1.5
Sustainability as a Business Driver. . . . . . . . . . . . . 1.6
Sustainability Reporting and Regulations. . . 1.7
Making the Business Case for Managing Water. . . 1.9
Calculate the Full Value of Water . . . . . . . . 1.10
Perform a Total Plant Assessment of
Water Use. . . . . . . . . . . . . . . . . . . . . . . . . . 1.12
Value and Prioritize. . . . . . . . . . . . . . . . . . . . 1.12
Water Risk Monetizer Case Studies. . . . . . . . . . . . . 1.13
Business Expansion Projects. . . . . . . . . . . . . 1.14
Existing Facility Water Improvement
Projects . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1.14
2 Water Sources and Stressors. . . . . . . . . . . . . . . . . . 2.1
Water Sources. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2.1
Surface Water—Rivers. . . . . . . . . . . . . . . . . . 2.3
Surface Water—Lakes. . . . . . . . . . . . . . . . . . 2.8
Groundwater . . . . . . . . . . . . . . . . . . . . . . . . . 2.16
Connate Water . . . . . . . . . . . . . . . . . . . . . . . . 2.17
Desalination . . . . . . . . . . . . . . . . . . . . . . . . . . 2.17
Recycled Wastewater. . . . . . . . . . . . . . . . . . . 2.19
Stress on Water Sources. . . . . . . . . . . . . . . . . . . . . . . 2.21
Groundwater Stress . . . . . . . . . . . . . . . . . . . 2.21
Surface Water Stress. . . . . . . . . . . . . . . . . . . . 2.24
3 Water Quality. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3.1
Natural Factors Affecting Water Quality. . . . . . . . 3.1
Seasonal Changes That Affect Water Quality . . . 3.4
Impact of Dams on River Water Quality . . . 3.4
Macrofouling . . . . . . . . . . . . . . . . . . . . . . . . . 5.27
Dissolved Gases. . . . . . . . . . . . . . . . . . . . . . . 5.30
Water Reuse and Recycle . . . . . . . . . . . . . . . . . . . . . 5.31
Erythorbate. . . . . . . . . . . . . . . . . . . . . . . . . . . 10.33
Diethylhydroxylamine . . . . . . . . . . . . . . . . . 10.34
Methylethylketoxime. . . . . . . . . . . . . . . . . . . 10.35
Hydroquinone . . . . . . . . . . . . . . . . . . . . . . . . 10.37
Monitoring and Control . . . . . . . . . . . . . . . . . . . . . . 10.37
Background. . . . . . . . . . . . . . . . . . . . . . . . . . . 10.39
Monitoring and Control Tools. . . . . . . . . . . 10.40
At-Temperature ORP Monitoring. . . . . . . . 10.42
11 Boiler Feedwater Treatment . . . . . . . . . . . . . . . . . . 11.1
Hardness Scale. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.3
Silica Scale. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.4
Iron Deposits. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11.6
The Problem with Iron . . . . . . . . . . . . . . . . . 11.7
Iron Deposition Mechanism. . . . . . . . . . . . . 11.7
Sources of Iron . . . . . . . . . . . . . . . . . . . . . . . . 11.9
Polymers and Iron Control. . . . . . . . . . . . . . 11.12
Iron Control. . . . . . . . . . . . . . . . . . . . . . . . . . . 11.13
Effects of Boiler Scale. . . . . . . . . . . . . . . . . . . . . . . . . 11.16
Internal Chemical Treatment Programs. . . . . . . . . 11.20
Phosphate Residual Programs—Low
Pressure Industrial Systems. . . . . . . . . . . 11.21
Phosphate-Polymer Programs. . . . . . . . . . . 11.25
Phosphate Programs—High Pressure
Industrial Systems . . . . . . . . . . . . . . . . . . 11.28
Chelates and Chelate-Polymer
Programs. . . . . . . . . . . . . . . . . . . . . . . . . . . 11.33
All-Polymer Programs. . . . . . . . . . . . . . . . . . 11.37
12 Turbines . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12.1
Turbine Mechanics. . . . . . . . . . . . . . . . . . . . . . . . . . . 12.1
Turbine Problem Areas. . . . . . . . . . . . . . . . . . . . . . . 12.6
Dechlorination . . . . . . . . . . . . . . . . . . . . . . . . 24.3
Disinfection By-products . . . . . . . . . . . . . . . 24.4
Solids Removal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24.4
Ammonia Reduction. . . . . . . . . . . . . . . . . . . . . . . . . 24.4
Ammonia Stripping. . . . . . . . . . . . . . . . . . . . 24.5
Selective Ion Exchange . . . . . . . . . . . . . . . . . 24.5
Breakpoint Chlorination. . . . . . . . . . . . . . . . 24.6
Phosphate Removal. . . . . . . . . . . . . . . . . . . . . . . . . . 24.6
Aluminum Treatment . . . . . . . . . . . . . . . . . . 24.6
Iron Treatment . . . . . . . . . . . . . . . . . . . . . . . . 24.7
Calcium Treatment. . . . . . . . . . . . . . . . . . . . . 24.8
Organics Removal . . . . . . . . . . . . . . . . . . . . . . . . . . . 24.8
25 Heavy Metal Removal. . . . . . . . . . . . . . . . . . . . . . . 25.1
Regulatory Issues. . . . . . . . . . . . . . . . . . . . . . . . . . . . 25.1
Sources of Metals. . . . . . . . . . . . . . . . . . . . . . . . . . . . 25.2
Chemistry of Metals. . . . . . . . . . . . . . . . . . . . . . . . . . 25.3
Ionic Strength. . . . . . . . . . . . . . . . . . . . . . . . . 25.5
Chelation Effects. . . . . . . . . . . . . . . . . . . . . . . 25.6
Metal Removal. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25.9
Operational Factors. . . . . . . . . . . . . . . . . . . . 25.9
Equipment Methods . . . . . . . . . . . . . . . . . . . 25.10
Chemical Methods. . . . . . . . . . . . . . . . . . . . . 25.15
Associated Pretreatment. . . . . . . . . . . . . . . . 25.22
26 Sludge Manipulation. . . . . . . . . . . . . . . . . . . . . . . . 26.1
Sludge Thickening. . . . . . . . . . . . . . . . . . . . . . . . . . . 26.3
Gravity Thickening . . . . . . . . . . . . . . . . . . . . 26.3
Flotation Thickening. . . . . . . . . . . . . . . . . . . 26.5
Rotary Drum Thickener . . . . . . . . . . . . . . . . 26.6
Gravity Table Thickeners . . . . . . . . . . . . . . . 26.7
Centrifugal Thickening. . . . . . . . . . . . . . . . . 26.8
Sludge Dewatering . . . . . . . . . . . . . . . . . . . . . . . . . . 26.10
Nature of Sludge . . . . . . . . . . . . . . . . . . . . . . 26.10
Belt Filter Press. . . . . . . . . . . . . . . . . . . . . . . . 26.11
Centrifugation . . . . . . . . . . . . . . . . . . . . . . . . 26.11
Vacuum Filters. . . . . . . . . . . . . . . . . . . . . . . . 26.12
Screw Presses . . . . . . . . . . . . . . . . . . . . . . . . . 26.13
Plate-and-Frame Filter Presses. . . . . . . . . . . 26.15
Drying Beds . . . . . . . . . . . . . . . . . . . . . . . . . . 26.18
27 Emulsion Treatment. . . . . . . . . . . . . . . . . . . . . . . . . 27.1
Theory of Emulsions. . . . . . . . . . . . . . . . . . . . . . . . . 27.2
Oily Waste. . . . . . . . . . . . . . . . . . . . . . . . . . . . 27.4
Waste Oil. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27.5
Emulsion Treatment. . . . . . . . . . . . . . . . . . . . 27.5
Section 5 Industries
32 The Paper Industry. . . . . . . . . . . . . . . . . . . . . . . . . . 32.3
Industry Profile. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.6
Virgin Fiber Production. . . . . . . . . . . . . . . . . . . . . . . 32.8
Wood Yard Operations . . . . . . . . . . . . . . . . . 32.8
Groundwood Pulping. . . . . . . . . . . . . . . . . . 32.11
Thermomechanical Pulping. . . . . . . . . . . . . 32.12
Chemical Pulping—Kraft Process. . . . . . . . 32.13
Chemical Pulping—Non Kraft. . . . . . . . . . . 32.25
Recycled Pulp Production. . . . . . . . . . . . . . . . . . . . . 32.26
Deinking and Secondary Fiber Use. . . . . . . 32.26
Pulp Bleaching. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.29
Stock Preparation. . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.33
Paper Machine Operations. . . . . . . . . . . . . . . . . . . . 32.35
Paper Machine Headbox. . . . . . . . . . . . . . . . 32.35
Paper Machine Wet End. . . . . . . . . . . . . . . . 32.36
Paper Machine Press Section. . . . . . . . . . . . 32.38
Paper Machine Dryer Section. . . . . . . . . . . . 32.39
33 The Power Industry . . . . . . . . . . . . . . . . . . . . . . . . . 33.1
Energy Conversion . . . . . . . . . . . . . . . . . . . . . . . . . . 33.2
The Power Cycle . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33.3
Water: The Working Fluid. . . . . . . . . . . . . . . . . . . . . 33.7
[4] Enough.