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12 Book Back One Mark EM
12 Book Back One Mark EM
QUESTIONS
1.METALLURGY
1. Bauxite has the composition
a) Al2O3 b) Al2O3.nH2O c) Fe2O3.2H2O d) none of these
2. Roasting of sulphide ore gives the gas (A).(A) is a colourless gas. Aqueous solution of (A) is
acidic. The gas (A) is
a)CO2 b) SO3 c) SO2 d) H2S
3. Which one of the following reaction represents calcinations?
a) 2Zn + O2 →2ZnO b) 2ZnS + 3O2 → 2ZnO + 2SO2
c) MgCO3 → MgO + CO2 a) (a) and (c)
4. The metal oxide which cannot be reduced to metal by carbon is
a) PbO b) Al2O3 c) ZnO d) FeO
5. Which of the metal is extracted by Hall-Heroult process?
a) Al b) Ni c) Cu d) Zn
6. Which of the following statements, about the advantage of roasting of sulphide ore before
reduction is not true?
a).,∆Gf0 of sulphide is greater than those for CS2 and H2S
b).∆Gr0 is negative for roasting of sulphide ore to oxide
c).,Roasting of the sulphide to its oxide is thermodynamically feasible.
d).,Carbon and hydrogen are suitable reducing agents for metal sulphides
7. Match items in column -I with the items of column II and assign the correct code.
Column-I Column-II A B C D
A Cyanide process (i) Ultrapure Ge (i) (ii) (iii) (iv)
(a)
Froth floatation
B (ii) Dressing of ZnS (b) (iii) (iv) (v) (i)
process
Electrolytic (c) (iv) (ii) (iii) (i)
C (iii) Extraction of Al
reduction
(d) (ii) (iii) (i) (v)
D Zone refining (iv) Extraction of Au
(v) Purification of Ni
523 K 1800 K
Zr( impure) + 2I2 ZrI4 : ZrI4 Zr (pure) + 2I2
a) Liquation b) van Arkel process c) Zone refining d) Mond’s process
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
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Karur-Dt.
15. Match items in column - I with the items of column – II and assign the correct code.
15.
Column-I Column-II A B C D
A Borazole 1 B(OH)3 (a) 2 1 4 3
B Boric acid 2 B3N3H6 (b) 1 2 4 3
C Quartz 3 Na2[B4O5(OH)4]8H2O (c) 1 2 4 3
D Borax 4 SiO2 (d) none of these
16. Duralumin is an alloy of
16.
a) Cu,Mn b) Cu,Al,Mg c) Al,Mn d) Al,Cu,Mn,Mg
17. The compound that is used in nuclear reactors as protective shields and control rods is
17.
a) Metal borides b) metal oxides c) Metal carbonates d) metal carbide
18. The stability of +1 oxidation state increases in the sequence
18.
a) Al <Ga<In<Tl b) Tl<In<Ga<Al c) In<Tl<Ga<Al d) Ga<In<Al<Tl
3.p
3.p – BLOCK ELEMENTS-
ELEMENTS-II
1. In which of the following, NH3 is not used?
a) Nessler’s reagent
b) Reagent for the analysis of IV group basic radical
c) Reagent for the analysis of III group basic radical d) Tollen’s reagent
2. Which is true regarding nitrogen?
a) least electronegative element b) has low ionisation enthalpy than oxygen
b) c) d- orbitals available d) ability to form Pπ- Pπ bonds with itself
3. An element belongs to group 15 and 3 rd period of the periodic table, its electronic
configuration would be
a) 1s22s22p4 b) 1s22s22p3 . c) 1s22s22p63s23p2 d) 1s22s22p63s23p3
4. Solid (A) reacts with strong aqueous NaOH liberating a foul smelling gas(B) which
spontaneously burn in air giving smoky rings. A and B are respectively a) P4 (red) and PH3 b)
P4 (white) and PH3 c) S8 and H2 S d) P4 (white) and H2 S
a) P4(red) and.PH3 b) P4(white) and.PH3
c) S8. and.H2S d) P4(white) and.H2S
5. On hydrolysis, PCl3gives
a) H3PO3 b) PH3 c) H3PO4 d) POCl3
6. P4O6 reacts with cold water to give
a) H3PO3 b) H4P2O7 c) HPO3 d) H3PO4
7. The basicity of pyrophosphorous acid ( H4P2O5 )is
a) 4 b) 2 c) 3 d) 5
8. The molarity of given orthophosphoric acid solution is 2M. its normality is
a) 6N b) 4N c) 2N d) none of these
P.Suresh, PG Assistants
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Govt.Hr.Sec.School, Kaniyalampatti, Karur-
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Karur-Dt.
9. Assertion : bond dissociation energy of fluorine is greater than chlorine gas
Reason : chlorine has more electronic repulsion than fluorine
a) Both assertion and reason are true and reason is the correct explanation of assertion.
b) Both assertion and reason are true but reason is not the correct explanation of assertion.
c) Assertion is true but reason is false.
d) Both assertion and reason are false.
10. Among the following, which is the strongest oxidizing agent?
10.
a) Cl2 b) F2 c) Br2 d) I2
11. The correct order of the thermal stability of hydrogen halide is
11.
a) HI > HBr > HCl > HF b) HF > HCl > HBr > HI
c) HCl> HF > HBr > HI d) HI > HCl > HF > HBr
12. Which one of the following compounds is not formed?
12.
a) XeOF4 b) XeO3 c) XeF2 d) NeF2
13. Most easily liquefiable gas is
13.
a) Ar b) Ne c) He d) Kr
14. XeF6 on complete hydrolysis produces
14.
a) XeOF4 b) XeO2F2 c) XeO3 d) XeO2
15. Which of the following is strongest acid among all?
15.
a) HI b) HF c) HBr d) HCl
16. Which one of the following orders is correct for the bond dissociation enthalpy of halogen
16.
molecules? (NEET)
a) Br2>I2>F2>Cl2 b) F2>Cl2>Br2 >I2 c) I2>Br2>Cl2>F2 d) Cl2>Br2>F2>I2
17. Among the following the correct order of acidity is (NEET)
17.
a) HClO2<HClO<HClO3<HClO4 b) HClO4<HClO2<HClO<HClO3
c) HClO3<HClO4<HClO2<HClO d) HClO<HClO2 <HClO3<HClO4
18. When copper is heated with conc HNO3 it produces
18.
a) Cu(NO3)2, NO and NO2 b) Cu(NO3)2 and N2O
c) Cu(NO3)2 and NO2 d) Cu(NO3)2 and NO
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Karur-Dt
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Karur-Dt.
4. Which one of the following ions has the same number of unpaired electrons as present in V3+?
a) Ti 3+ b) Fe3+ c) Ni2+ d) Cr3+
5. The magnetic moment of Mn2+ ion is
a) 5.92 BM b) 2.80 BM ., c) 8.95 BM d) 3.90 BM
6. The catalytic behaviour of transition metals and their compounds is ascribed mainly due to
a) their magnetic behaviour b) their unfilled d orbitals
c) their ability to adopt variable oxidation states
d) their chemical reactivity
7. The correct order of increasing oxidizing power in the series
a) VO2+< Cr2O72--< MnO4- b) Cr2O72--< VO2+< MnO4-
c) Cr2O72--< MnO4-< VO2+ d) MnO4- < Cr2O72--< VO2+
8. In acid medium, potassium permanganate oxidizes oxalic acid to
a) oxalate b) Carbon dioxide c) acetate d) acetic acid
a) Both assertion and reason are true and reason is the correct explanation of assertion.
b) Both assertion and reason are true but reason is not the correct explanation of assertion.
c) Assertion is true but reason is false. d) Both assertion and reason are false.
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
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Karur-Dt.
17. The most common oxidation state of actinoids is
17.
a) +2 b) +3 c) +4 d) +6
18. The actinoid elements which show the highest oxidation state of +7 are
18.
a) Np,Pu,Am b) U,Fm,Th c) U,Th,Md d) Es,No,Lr
19. Which one of the following is not correct?
19.
a) La(OH)3 is less basic than Lu(OH)3
b) In lanthanoid series ionic radius of Ln3+ ions decreases
c) La is actually an element of transition metal series rather than lanthanide series
d) Atomic radii of Zr and Hf are same because of lanthanide contraction
5.COORDINATION CHEMISTRY
1. The sum of primary valence and secondary valence of the metal M in the complex
[M(en)2(Ox]Cl is
a) 3 b) 6 c) -3 d) 9
2. An excess of silver nitrate is added to 100ml of a 0.01 M solution of
pentaaquachloridochromium(III) chloride. The number of moles of AgCl precipitated would be
a) 0.02 b) 0.002 c) 0.01 d) 0.2
3. A complex has a molecular formula MSO4Cl.6H2O.The aqueous solution of it gives white
precipitate with Barium chloride solution and no precipitate is obtained when it is treated with
silver nitrate solution. If the secondary valence of the metal is six, which one of the following
correctly represents the complex?
a) [M(H2O)4Cl]SO4.2H2O b) [M(H2O)6]SO4
c) [M(H2O)5Cl]SO4.H2O d) [M(H2O)3Cl]SO4.3H2O
4. Oxidation state of Iron and the charge on the ligand NO in [Fe(H2O)5NO]SO4 are
a) +2 and 0 respectively b) +3 and 0 respectively
c) +3 and -1 respectively d) +1 and -1 respectively
5. As per IUPAC guidelines, the name of the complex [Co(en)2(ONO)Cl]Cl is
a) chlorobisethylenediaminenitritocobalt(III) chloride
b) chloridobis(ethane-1,2-diamine)nitro -ƙ–O cobaltate (III) chloride
c) chloridobis(ethane-1,2-diammine)nitrito -ƙ–O cobalt(II)) chloride
d) chloridobis(ethane-1,2-diammine)nitrito-ƙ–O cobalt(III) chloride
6. IUPAC name of the complex K3[Al(C2O4)3] is
a) potassiumtrioxalatoaluminium(III) b) potassiumtrioxalatoaluminate(II)
c) potassiumtrisoxalatoaluminate(III) d) potassiumtrioxalatoaluminate(III)
7. A magnetic moment of 1.73 BM will be shown by one among the following (NEET)
a) TiCl4 b) [CoCl6]4- c) [Cu(NH3)4]2+ d) [Ni(CN)4]2-
8. Crystal field stabilization energy for high spin d5 octahedral complex is
a) – 0.6 ∆0 b) 0 c) 2(P- ∆0 ) d) 2(P+∆0 )
9. In which of the following coordination entities the magnitude of ∆0 will be maximum?
a) [Co(CN)6]3- b) [Co(C2O4)3]3- c) [Co(H2O)6]3+ d) [Co(NH3)6]3+
10. Which one of the following will give a pair of enantiomorphs?
10.
a) [Cr(NH3)6][Co(CN)6] b) [Co(en)2Cl2 ]Cl
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
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c) [Pt(NH3)4][PtCl4] d) [Co(NH3)4Cl2 ]NO2
11. Which type of isomerism is exhibited by [Pt(NH3)2Cl2 ]?
11.
a) Coordination isomerism b) Linkage isomerism
c) Optical isomerism d) Geometrical isomerism
12. How many geometrical isomers are possible for [Pt(Py)(NH3)(Br)(Cl)]?
12.
a) 3 b) 4 c) 0 d) 15
13. Which one of the following pairs represents linkage isomers?
13.
a) [Cu(NH3)4][PtCl4] and [Pt(NH3)4][CuCl4]
b) [Co(NH3)5(NO3)]SO4 and [Co(NH3)5(ONO)]
c) [Co(NH3)4 (NCS)2]Cl and [Co(NH3)4 (SCN)2]Cl
d) both (b) and (c)
14. Which kind of isomerism is possible for a complex [Co(NH3)4Br2]Cl ?
14.
a) geometrical and ionization b) geometrical and optical
c) optical and ionization d) geometrical only
15. Which one of the following complexes is not expected to exhibit isomerism?
15.
a) [Ni(NH3)4(H2O)2]2+ b) [Pt(NH3)2Cl2]
c) [Co(NH3)5SO4]Cl d) [FeCl6]3-
16. A complex in which the oxidation number of the metal is zero is
16.
a) K4[Fe(CN)6] b) [Fe(CN)3(NH3)3]
c) [Fe(CO)5] d) both (b) and (c)
17. Formula of tris(ethane-1,2-diamine)iron II phosphate
17.
a) [Fe(CH3-CH(NH2)2)3](PO4)3 b) [Fe(H2N-CH2-CH2-NH2)3](PO4)
c) [Fe(H2N-CH2-CH2-NH2)3](PO4)2 d) [Fe(H2N-CH2-CH2-NH2)3]3(PO4)2
18. Which of the following is paramagnetic in nature?
18.
a) [Zn(NH3)4]2+ b) [Co(NH3)6]3+ c) [Ni(H2O)6]2+ d)[Ni(CN)4]2-
19. Fac-mer isomerism is shown by
19.
a) [Co(en)3]3+ b) [Co(NH3)4(Cl)2]+ c) [Co(NH3)3(Cl)3] d) [Co(NH3)5Cl]SO4
20. Choose the correct statement.
20.
a) Square planar complexes are more stable than octahedral complexes
b).,The spin only magnetic moment of [Cu(Cl)4]2-- is 1.732 BM and it has square planar
.,.,.,structure.
c) Crystal field splitting energy (∆0) of [FeF6]4-- is higher than the (∆0) of [Fe(CN)6]4--
d) crystal field stabilization energy of [V(H2O)6]2++is higher than the crystal field stabilization of
.,..,[Ti(H2O)6]2++
6. SOLID STATE
1. Graphite and diamond are
a) Covalent and molecular crystals b) ionic and covalent crystals
c) both covalent crystals d) both molecular crystals
2. An ionic compound AxBy crystallizes in fcc type crystal structure with B ions at the centre of
each face and A ion occupying corners of the cube. the correct formula of AxBy is
a) AB b)AB3 c) A3B d) A8B6
3. The ratio of close packed atoms to tetrahedral hole in cubic packing is
a) 1:1 b) 1:2 c) 2:1 d) 1:4
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
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Karur-Dt.
4. Solid CO2 is an example of
a) Covalent solid b) metallic solid c) molecular solid d) ionic solid
16. If ‘a’ stands for the edge length of the cubic system; sc , bcc, and fcc. Then the ratio of radii
16.
of spheres in these systems will be respectively
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
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Karur-Dt.
1 3 2
a) a : a: a
2
b) ( 1a : 3a : 2a )
2 2
1 3 1 1 1
c) a : a: a d) 2 a : 3a : a
2 4 2 2 2
17. If ‘a’ is the length of the side of the cube, the distance between the body centered atom and
17.
one corner atom in the cube will be
2 4 3 3
a) a b) a c) a d) a
3 3 4 2
18. Potassium has a bcc structure with nearest neighbor distance 4.52 A0 . its atomic weight is 39.
18.
its density will be
a) 915 kg m-3 b) 2142 kg m-3 c) 452 kg m-3 d) 390 kg m-3
19. Schottky defect in a crystal is observed when
19.
a) unequal number of anions and cations are missing from the lattice
b) equal number of cations and anions are missing from the lattice
20. The cation leaves its normal position in the crystal and moves to some interstitial position, the
20.
defect in the crystal is known as
a) Schottky defect b) F center c) Frenkel defect d) non-stoichiometric
21. Assertion: due to Frenkel defect, density of the crystalline solid decreases.
21.
Reason: in Frenkel defect cation and anion leaves the crystal.
a) Both assertion and reason are true and reason is the correct explanation of assertion.
b) Both assertion and reason are true but reason is not the correct explanation of assertion.
c) Assertion is true but reason is false. d) Both assertion and reason are false
22. The crystal with a metal deficiency defect is
22.
a) NaCl b) FeO c) ZnO d) KCl
23. A two dimensional solid pattern formed by two different atoms X and Y is shown below. The
23.
black and white squares represent atoms X and Y respectively. the simplest formula for the
compound based on the unit cell from the pattern is
a) XY8 b) X4Y9
c) XY2 d) XY4
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
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Karur-Dt.
7.CHEMICAL KINETICS
1. For a first order reaction A → B the rate constant is x min−1 . If the initial concentration of
A is 0.01M , the concentration of A after one hour is given by the expression.
a) 0.01e-x b) 1X 10-2 (1- e -60x ) c) (1X 10-2 )e -60x d) none of these
2. A zero order reaction X →Product, with an initial concentration 0.02M has a half life of 10
min. if one starts with concentration 0.04M, then the half life is
a) 10 s b) 5 min
c) 20 min d) cannot be predicted using the given information
3. Among the following graphs showing variation of rate constant with temperature (T) for a
reaction, the one that exhibits Arrhenius behavior over the entire temperature range is
a) b) c) d) both (b) and (c)
.,.,......................................................... .................................................................................
-dt [ NH 3 ] d [N2 ]
5. For the reaction, 2NH3 → N2 + 3H2 , if = k1 [ NH 3 ] , = k2 [ NH 3 ] ,
dt dt
d [H 2 ]
= k3 [ NH 3 ] then the relation between K1 , K2 and K3
dt
a) k1=k2=k3 b) k1=3k2=2k3 c) 1.5k1=3k2=k3 d) 2k1=k2=3k3
6. The decomposition of phosphine (PH3) on tungsten at low pressure is a first order reaction. It
is because the (NEET)
a) rate is proportional to the surface coverage
b) rate is inversely proportional to the surface coverage
c) rate is independent of the surface coverage
d) rate of decomposition is slow
7. For a reaction Rate = K [acetone]3/2 then unit of rate constant and rate of reaction
respectively is
a) (mol L-1 s-1), (mol-1/2 L1/2 s-1) b) (mol-1/2 L1/2 s-1), (mol L-1 s-1)
1/2 1/2 -1 -1 -1
c) (mol L s ), (mol L s ) d) (mol L s-1), (mol 1/2 L1/2 s)
8. The addition of a catalyst during a chemical reaction alters which of the following quantities?
(NEET)
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a) Enthalpy b) Activation energy c) Entropy d) Internal energy
9. Consider the following statements :
(i) increase in concentration of the reactant increases the rate of a zero order reaction.
(ii) rate constant k is equal to collision frequency A if Ea = 0
(iii) rate constant k is equal to collision frequency A if Ea =
(iv) a plot of ln ln (k) vs T is a straight line.
(v) a plot of ln ln (k) vs (1/T ) is a straight line with a positive slope.
Correct statements are
a) (ii) only b) (ii) and (iv) c) (ii) and (v) d) (i), (ii) and (v)
10. In a reversible reaction, the enthalpy change and the activation energy in the forward
10.
direction are respectively –x kJ mol-1 and y kJ mol-1 . Therefore,the enery of activation in the
backward direction is
a) (y-x)kJmol-1 b) (x+y)Jmol-1 c) (x-y)kJmol-1 d) (x+y) X103 Jmol-1
11. What is the activation energy for a reaction if its rate doubles when the temperature is raised
11.
from 200K to 400K? (R=8.314 JK-1 mol-1 )
a) 234.65 kJ mol-1 b) 434.65 kJ mol-1 c) 2.305 kJ mol-1 d) 334.65J mol-1
12.
12. ; This reaction follows first order kinetics. The rate constant at
particular temperature is 2.303X10-2 hour-1 . The initial concentration of cyclopropane is 0.25 M.
What will be the concentration of cyclopropane after 1806 minutes? (log2=0.3010)
a) 0.125 M b) 0.215 M c) 0.25X2.303M d) 0.05 M
-1
13. For a first order reaction, the rate constant is 0.6909 min .the time taken for 75% conversion
13.
in minutes is
3 2 3 3 2 4
a) log2 b) log2 c) log d) log
2 3 2 4 3 3
14. In a first order reaction x → y; if k is the rate constant and the initial concentration of the
14.
reactant x is 0.1M, then, the half life is
log2 0.693 ln2
a) b) c) d) none of these
k (0.1)k k
15.. Predict the rate law of the following reaction based on the data given below 2A + B → C+3D
15
a) rate = k[A]2[B] b) rate = k [A] [B]2 c) rate = k [A][B] d) rate = k [A]1/2[B] 3/2
16. Assertion: rate of reaction doubles when the concentration of the reactant is doubles if it is a
16.
first order reaction. Reason: rate constant also doubles
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
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Karur-Dt.
a) Both assertion and reason are true and reason is the correct explanation of assertion.
b) Both assertion and reason are true but reason is not the correct explanation of assertion.
c) Assertion is true but reason is false. d) Both assertion and reason are false.
-2 -1
17. The rate constant of a reaction is 5.8 X 10 s . The order of the reaction is
17.
a) First order b) zero order c) Second order d) Third order
18. For the reaction N2O5 (g) →2NO2(g) + ½ O2 (g), the value of rate of disappearance of N2O5is
18.
given as 6.5X 10-2 molL-1 s-1. The rate of formation of NO2 and O2 is givenrespectively as
a) (3.25 X 10-2 mol L-1 s-1) and (1.3 X 10-2 mol L-1 s-1)
b) (1.3 X 10-2 mol L-1 s-1) and (3.25 X 10-2 mol L-1 s-1)
c) (1.3 X 10-11 mol L-1 s-1) and (3.25 X 10-2 mol L-1 s-1) d) None of these
19. During the decomposition of H2O2 to give dioxygen, 48 g O2 is formed per minute at certain
19.
point of time. The rate of formation of water at this point is
a)0.75 mol min-1 b) 1.5 mol min-1 c) 2.25 mol min-1 d) 3.0 mol min-1
20. If the initial concentration of the reactant is doubled, the time for half reaction is also
20.
doubled. Then the order of the reaction is
a) Zero b) one c) Fraction d) none
21. In a homogeneous reaction A → B+C+D, the initial pressure was P0 and after time t it was
21.
P.expression for rate constant in terms of P0, Pand t will
2.303 2Po 2.303 2Po
a) k= log b) k= log
t 3Po - P t Po - P
8.IONIC EQUILIBRIUM
1. Concentration of the Ag+ ions in a saturated solution of Ag2C2O4 is 2.24 X 10-4 molL-1
solubility product of Ag2C2O4 is (NEET – 2017)
a) 2.42 X 10-8mol3 L-3 b) 2.66 X 10-12mol3 L-3
c) 4.5 X 10-11mol3 L-3 d) 5.619X 10-12mol3 L-3
2. Following solutions were prepared by mixing different volumes of NaOH of HCl different
concentrations. (NEET – 2018)
M M M M
i.…60 ml HCl + 40 ml NaOH ii. 55 ml HCl + 45 ml NaOH
10 10 10 10
M M M M
iii. 75 ml HCl + 25 ml NaOH iv. 100 ml HCl + 100 ml NaOH
5 5 10 10
pH of which one of them will be equal to 1?
a) iv b) i c) ii d) iii
3. The solubility of BaSO4 in water is 2.42 X 10-3 gL-1 at 298K. The value of its solubility
product (Ksp) will be (NEET -2018). ((BaSO4 Given molar mass of =233g mol-1 )
a) 1.08 X 10-14mol2 L-2 b) 1.08 X 10-12mol2 L-2
c) 1.08 X 10-10mol2 L-2 d) 1.08 X 10-8mol2 L-2
4. pH of a saturated solution of Ca(OH)2 is 9. The Solubility product (Ksp) of Ca(OH)2
a) 0.5 X 10-15 b) 0.25 X 10-10 c) 0.125 X 10-15 d) 0.5 X 10-10
5. Conjugate base for Bronsted acids H2O and HF are
a) OH- and H2FH+ respectively b) H3O+ and F- respectively
c) OH- and F- respectively d) H3O+ and H2F+ respectively
6. Which will make basic buffer?
a) 50 mL of 0.1M NaOH + 25mL of 0.1M CH3COOH
b) 100 mL of 0.1M CH3COOH + 100mL of 0.1M NH4OH
c) 100 mL of 0.1M HCl + 200mL of 0.1M NH4OH
U) 100 mL of 0.1M HCl + 100mL of 0.1M NaOH
7. Which of the following fluro compounds is most likely to behave as a Lewis base?
a) BF3 b) PF3 c) CF4 d) SiF4
8. Which of these is not likely to act as Lewis base?
a) BF3 b) PF3 c) CO d) F-
9. The aqueous solutions of sodium formate, anilinium chloride and potassium cyanide are
Respectively
a) acidic, acidic, basic b) basic, acidic, basic
c) basic, neutral, basic d) none of these
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10.. The percentage of pyridine (C5H5N) that forms pyridinium ion (C5H5NH) in a 0.10M aqueous
10
pyridine solution (Kb for C5H5N = 1.7 X 10-9 ) is
a) 0.006% b) 0.013% c) 0.77% d) 1.6%
11. Equal volumes of three acid solutions of pH 1,2 and 3 are mixed in a vessel. What will be the
11.
H+ ion concentration in the mixture?
a) 3.7 X 10-2 b) 10-6 c) 0.111 d) none of these
12. The solubility of AgCl(s) with solubility product 1.6 X 10-10 in 0.1M NaCl solution would be
12.
a) 1.26 X 10-5 M b) 1.6 X 10-9 M c) 1.6 X 10-11 M d) Zero
13. If the solubility product of lead iodide is 3.2 X 10-8, its solubility will be
13.
a) 2 X 10-3M b) 4 X 10-4 M c) 1.6 X 10-5M d) 1.8 X 10-5M
14. MY and NY3 , are insoluble salts and have the same Ksp values of 6.2 X 10-13 at room
14.
temperature. Which statement would be true with regard to MY and NY ?
a) The salts MY and NY3 are more soluble in 0.5M KY than in pure water
b) The addition of the salt of KY to the suspension of MY and NY3 will have no effect on
..,.,.,.,.,.,.,.,.,their solubility’s
c) The molar solubilities of MY and NY3 in water are identical
d) The molar solubility of MY in water is less than that of NY3
15. What is the pH of the resulting solution when equal volumes of 0.1M NaOH and 0.01MHCl
15.
are mixed?
a) 2.0 b) 3 c) 7.0 d) 12.65
16. The dissociation constant of a weak acid is 1 X 10-3 . In order to prepare a buffer solution
16.
with a pH=4, the [Acid]/[Salt]
a) 4:3 b) 3:4 c) 10:1 d) 1:10
17. The pH of 10-5M KOH solution will be
17.
a) 9 b) 5 c) 19 d) none of these
-
18. H2PO4 the conjugate base of
18.
a) PO43-- b) P2O5 c) H3PO4 d) HPO42--
19. Which of the following can act as Lowry – Bronsted acid as well as base?
19.
a) HCl b) SO42-- c) HPO42-- d) Br-
20. The pH of an aqueous solution is Zero. The solution is
20.
a) slightly acidic b) strongly acidic c) neutral d) basic
21.. The hydrogen ion concentration of a buffer solution consisting of a weak acid and its salts is
21
given by
Ka [acid]
a) H + = b) H + = Ka [salt]
[salt ]
Ka [salt]
c) H + = Ka [acid] d) H + =
[acid]
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22. Which of the following relation is correct for degree of hydrolysis of ammonium acetate?
22.
Kh Ka Kw K a .K b
a) h = b) h = c) h = d) h =
C Kb K a .K b Kw
23. Dissociation constant of NH4OH is 1.8X10-5 the hydrolysis constant of NH4Cl would be
23.
a) 1.8 X 10-19 b) 5.55X 10-10 c) 5.55 X 10-5 d) 1.80 X 10-5
9. ELECTRO CHEMISTRY
1. The number of electrons that have a total charge of 9650 coulombs is
a) 6.22 X 1023 b) 6.022 X 1024 c) 6.022 X 1022 d) 6.022 X 10-34
2. Consider the following half cell reactions:
+ - + + -
Mn2 + 2e Mn, E0=-1.18V Mn2 Mn3 +e E0=-1.51V
The E0 for the reaction 3Mn2++ Mn + 2Mn3++, and the possibility of the forward reaction are
.,.,..,..,.,respectively.
a) 2.69V and spontaneous b) -2.69 and non spontaneous
c) 0.33V and Spontaneous d) 4.18V and non spontaneous
3. The button cell used in watches function as follows
Zn(s) + Ag2O(s) + H2O (l) 2Ag (s) + Zn2++ (aq) +2OH- (aq) E0 =0.76V half cell
-
.,.,.,.,.,.,potentials .are Ag2O(s)+H2O (l) 2e 2Ag (s)+ 2OH- (aq) E0 =0.34V The cell potential
.,..,.,..,,will Be
a) 0.84V b) 1.34V c) 1.10V d) 0.42V
4. The molar conductivity of a 0.5 mol dm-3 solution of AgNO3 with electrolytic conductivity of
5.76 X10-3 S cm-1 at 298 K is
a) 2.88 Scm2mol-1 b) 11.52 Scm2mol-1 c) 0.086 Scm2mol-1 d) 28.8 Scm2mol-1
5.
Calculate Ʌ0HOAC using appropriate molar conductances of the electrolytes listed above at infinite
dilution in water at 250C .
a) 517.2 b) 552.7 c) 390.7 d) 217.5
6. Faradays constant is defined as
a) charge carried by 1 electron b) charge carried by one mole of electrons
c) charge required to deposit one mole of substance
d) charge carried by 6.22 X 1010 electrons.
7. How many faradays of electricity are required for the following reaction to occur ?
- +
MnO4 Mn2
a) 5F b) 3F c) 1F d) 7F
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8. A current strength of 3.86 A was passed through molten Calcium oxide for 41minutes and 40
seconds. The mass of Calcium in grams deposited at the cathode is (atomic mass of Ca is 40
g/mol and 1F = 96500C).
a) 4 b) 2 c) 8 d) 6
9. During electrolysis of molten sodium chloride, the time required to produce 0.1mole of chlorine
gas using a current of 3A is
a) 55 minutes b) 107.2 minutes c) 220 minutes d) 330 minutes
10. The number of electrons delivered at the cathode during electrolysis by a current of 1A in
60 seconds is (charge of electron =1.6 X 10-19 C)
a) 6.22 X 1023 b) 6.022 X 1020 c) 3.75 X 1020 d) 7.48X 1023
11. Which of the following electrolytic solution has the least specific conductance
a) 2N b) 0.002N c) 0.02N d) 0.2N
12. While charging lead storage battery
a) PbSO4 on cathode is reduced to Pb b) PbSO4 on anode is oxidised to PbO2
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18. A conductivity cell has been calibrated with a 0.01M, 1:1 electrolytic solution (specific
conductance (ĸ=1.25X10-3 Scm-1) in the cell and the measured resistance was 800 Ω at 250 C.
The cell constant is,
a) 10-1 cm-1 b) 101 cm-1 c) 1 cm-1 d) 5.7 X 10-12
19. Conductivity of a saturated solution of a sparingly soluble salt AB (1:1 electrolyte) at 298K is
1.85 X 10-5 S m-1. Solubility product of the salt AB at 298K (Ʌm0 )AB =14 X 10-3 S m2 mol-1.
a) 5.7 X 10-12 b) 1.32 X 10-12 c) 7.5 X 10-12 d) 1.74 X 10-12
20. In the electrochemical cell: Zn|ZnSO4(0.01M)||CuSO4(1.0M)|Cu, the emf of this Daniel cell is
E1. When the concentration of ZnSO4 is changed to 1.0 M and that CuSO4 changed to 0.01M,
the emf changes to E2. From the above, which one is the relationship between E1 and E2?
a) E1 < E2 b) E1 > E2 c) E1 ≥ E2 d) E1 = E2
21. Consider the change in oxidation state of Bromine corresponding to different emf values
as shown in the diagram below
6. Statement : To stop bleeding from an injury, ferric chloride can be applied. Which comment
about the statement is justified?
a) It is not true, ferric chloride is a poison.
b) It is true, Fe3++ ions coagulate blood which is a negatively charged sol
c) It is not true; ferric chloride is ionic and gets into the blood stream.
d) It is true, coagulation takes place because of formation of negatively charged sol with Cl-
7. Hair cream is
a) gel b) emulsion c) solid sol d) sol.
8. Which one of the following is correctly matched?
a) Emulsion - Smoke
b) Gel - butter
c) foam - Mist
d) whipped cream - sol
11. The phenomenon observed when a beam of light is passed through a colloidal solution is
11.
a) Cataphoresis b) Electrophoresis c) Coagulation d) Tyndall effect
12. In an electrical field, the particles of a colloidal system move towards cathode. The coagulation
12.
of the same sol is studied using (i) K2SO4 (ii) Na3PO4 (iii)K4[Fe(CN)6] and (iv) NaCl Their
coagulating power should be
a) II > I > IV > III b) III > II > I > IV
c) I > II > III > IV d) none of these
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13. Collodion is a 4% solution of which one of the following compounds in alcohol – ether
13.
mixture?
a) Nitroglycerine b) Cellulose acetate c) Glycoldinitrate d) Nitrocellulose
16. The coagulation values in millimoles per litre of the electrolytes used for the coagulation of
16.
As2S3 are given below
I) NaCl=52 II) BaCl2 = 0.69 III) MgSO4 = 0.22 The correct order of their coagulating
.,.,.,.,.,.,power is
a) III > II > I b) I > II > III c) I > III > II d) II > III > I
17. Adsorption of a gas on solid metal surface is spontaneous and exothermic, then
17.
a) ∆H increases b) ∆S increases c) ∆G increases d) ∆S decreases
18. If x is the amount of adsorbate and m is the amount of adsorbent, which of the following
18.
relations is not related to adsorption process?
a) x /m = f(P) at constant T b) x /m = f(T) at constant P
c) P = f(T) at constant x /m d) x/ m = PT
19. On which of the following properties does the coagulating power of an ion depend ?
19.
(NEET – 2018)
a) Both magnitude and sign of the charge on the ion.
b) Size of the ion alone
c) The magnitude of the charge on the ion alone
d) The sign of charge on the ion alone.
20. Match the following
20.
A) Pure nitrogen - i) Chlorine A B C D
B) Haber process - ii) Sulphuric acid (a) (i) (ii) (iii) (iv)
C) Contact process - iii) Ammonia ( b) (ii) (iv) (i) (iii)
iv) sodium azide (c) (iii) (iv) (ii) (i)
(or) (d) (iv) (iii) (ii) (i)
D) Deacons Process -
Barium azide
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11.HYDROXY COMPOUNDS AND ETHERS
1. An alcohol (x) gives blue colour in Victormeyer’s test and 3.7g of X when treated with metallic
sodium liberates 560 mL of hydrogen at 273 K and 1 atm pressure what will be the possible
structure of X?
a) CH3–CH(OH)CH2–CH3 b) CH3–CH(OH)–CH3
c) CH3–C(OH)(CH3)2 d) CH3–CH2–CH(OH)–CH2–CH3
2. Which of the following compounds on reaction with methyl magnesium bromide will give
tertiary alcohol.
a) benzaldehyde b) propanoic acid c) methyl propanoate d) acetaldehyde
i) BF3 / THF
3. X . The ʻXʼ is
-
ii) H2O2 / OH
OH
CH2 CH2 CH CH2 CH2
a) H3C CH2 CH2 b) H3C CH2 CH2 CH3
OH
CH2 CH2
c) H2C CH2 CH2 d) None of these
OH OH
HOCl
4.. In the reaction sequence, Ethene A X ethan -1,2-diol . A and X respectively are
a) Chloroethane and NaOH b) ethanol and H2SO4
c) 2 – chloroethan -1-ol and NaHCO3 d) ethanol and H2O
5. Which one of the following is the strongest acid
a) 2 - nitrophenol b) 4 – chlorophenol
c) 4 – nitrophenol d) 3 – nitrophenol
7. Carbolic acid is
a) Phenol b) Picric acid c) benzoic acid d) phenylacetic acid
8. Which one of the following will react with phenol to give salicyladehyde after hydrolysis.
a) Dichloro methane b) trichloroethane c) trichloro methane d) CO2
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c) CH2=C(CH3)–CH2–CH3 d) CH2=C(CH3)–CH2–CH2–CH3
CH3
10. The correct IUPAC name of the compound, H3C–CH–CH–CH–CH2–OH
10.
Cl CH3
a) 4–chloro–2,3–dimethyl pentan–1-ol b) 2,3–dimethyl–4-chloropentan -1-ol
c) 2,3,4–trimethyl–4- chlorobutan -1-ol d) 4–chloro–2,3,4–trimethyl pentan–1-ol
Can be classified as
a) dehydration b) Williamson alcoholsynthesis
c) Williamson ether synthesis d) dehydrogenation of alcohol
17. Which of the following compound can be used as artifreeze in automobile radiators?
a) methanol b) ethanol c) Neopentyl alcohol d) ethan -1, 2-diol
18. OH O
i) NaOH
CH2
OH ii) CH2I2 O
The reactions is an example of
a) Wurtz reaction b) cyclic reaction c) Williamson reaction d) Kolbe reactions
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19. One mole of an organic compound (A) with the formula C3H8O reacts completely with two
moles of HI to form X and Y. When Y is boiled with aqueous alkali it forms Z. Z answers the
iodoform test. The compound (A) is
a) propan – 2-ol b) propan -1-ol c) ethoxy ethane d) methoxy ehane
20. Among the following ethers which one will produce methyl alcohol on treatment with hot HI?
a) (H3C)3C–O–CH3 b) (CH3)2–CH–CH2–O–CH3
c) CH3–(CH2)3–O–CH3 d) CH3–CH2–CH–O–CH3
CH3
21. Williamson synthesis of preparing dimethyl ether is
a) SN1 reactions b) SN2 reaction
c) electrophilic addition d) electrophilic substitution
OH O OH OH
a) b) c) d)
a) Tollen’s test b) Victor meyer test c) Iodoform test d) Fehling solution test
i)O3 NH3
5. CH2=CH2 X Y . ‘Y’ is
ii)Zn/H2O
a) Formaldelyde b) di acetone ammonia
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c) hexamethylene tetraamine d) oxime
6. Predict the product Z in the following series of reactions
Ethanoic acid PCl5 X C6H6 Y i)CH3MgBr Z
Anhydrous AlCl3 +
ii)H3O
a) (CH3)2C(OH)C6H5 b) CH3CH(OH)C6H5
c) CH3CH(OH)CH2-CH3 d) CH2-OH
7. Assertion : 2,2 – dimethyl propanoic acid does not give HVZ reaction.
Reason : 2,2, dimethyl propanoic acid does not have α- hydrogen atom
a) if both assertion and reason are true and reason is the correct explanation of assertion.
b) if both assertion and reason are true but reason is not the correct explanation of assertion.
c) assertion is true but reason is false d) both assertion and reason are false.
8. Which of the following represents the correct order of acidity in the given compounds
a) F-CH2COOH > CH3COOH > Br-CH2COOH > Cl-CH2COOH
b) F-CH2COOH > Cl-CH2COOH > Br-CH2COOH > CH3COOH
c) CH3COOH > Cl-CH2COOH > F-CH2COOH > Br-CH2COOH
d) Cl-CH2COOH > CH3COOH > Br-CH2COOH > l-CH2COOH
i)NH3 NaOBr NaNO2/HCl
9. Benzoic acid A A B C “ C ” is
ii) ∆
a) anilinium chloride b) O – nitro aniline
c) benzene diazonium chloride d) m – nitro benzoic acid
10. Ethanoic acid
10. P/Br 2 2–bromoethanoic acid. This reaction is called
a) Finkelstein reaction b) Haloform reaction
c) Hell–Volhard–Zelinsky reaction d) none of these
+
KCN H3O PCl5
11. CH3Br
11. (A) (B) (C) Product (C) is
a) acetylchloride b) chloro acetic acid
c) α-chlorocyano ethanoic acid d) none of these
i)Mg,ether H3O+
13.
13. Br A B ‘B’ is
ii) CO2
COOH COOH
a) b)
O
c) d) C
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.O
14.
14. The IUPAC Name of
OH
a) but – 3- enoicacid b) but – 1- ene-4-oicacid
c) but – 2- ene-1-oic acid d) but -3-ene-1-oicacid
O
N2H4
C Identify the product formed in the reaction
C2H5ONa
15.
15.
CH3
O
C
a) b) N c) O-C2H5 d)
16. , In which case chiral carbon is not generated by reaction with HCN
16.
.O OH .O .O
a) b) c) d)
Ph Ph
O OH
17. Assertion : p – N, N – dimethyl aminobenzaldehyde undergoes benzoin condensation
17.
Reason : The aldehydic (-CHO) group is meta directing
a) if both assertion and reason are true and reason is the correct explanation of assertion.
b) if both assertion and reason are true but reason is not the correct explanation of assertion.
c) assertion is true but reason is false d) both assertion and reason are false.
18. Which one of the following reaction is an example of disproportionation reaction
18.
a) Aldol condensation b) cannizaro reaction
c) Benzoin condensation d) none of these
19. Which one of the following undergoes reaction with 50% sodium hydroxide solution to
19.
give the corresponding alcohol and acid
a) Phenylmethanal b) ethanal c) ethanol d) methanol
20. The reagent used to distinguish between acetaldehyde and benzaldehyde is
20.
a) Tollens reagent b) Fehling’s solution
c) 2,4 – dinitrophenyl hydrazine d) semicarbazide
21. Phenyl methanal is reacted with concentrated NaOH to give two products X and Y. X reacts
21.
with metallic sodium to liberate hydrogen X and Y are
a) sodiumbenzoate and phenol b) Sodium benzoate and phenyl methanol
c) phenyl methanol and sodium benzoate d) none of these
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22. In which of the following reactions new carbon – carbon bond is not formed?
22.
a) Aldol condensation b) Friedel craft reaction
c) Kolbe’s reaction d) Wolf kishner reduction
23. An alkene “A” on reaction with O3 and Zn –H2O gives propanone and ethanol in equimolar
23.
ratio. Addition of HCl to alkene “A” gives “B” as the major product. The structure of product
.,.,..,.,.,.,“B” is
CH3 CH2Cl
a) Cl-CH2-CH2-CH-CH3 b) H3C-CH2-CH-CH3
CH3 CH3
c) H3C-CH2-C-CH3 d) H3C-CH2-CH-Cl
Cl
24. Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of
24.
comparable molecular mass. It is due to their (NEET)
a) more extensive association of carboxylic acid via van der Waals force of attraction
b) formation of carboxylate ion
c) formation of intramolecular H-bonding d) formation of intermolecular H – bonding
6. Which one of the following nitro compounds does not react with nitrous acid
a) CH3-CH2-CH2-NO2 b) (CH3)2-CH-CH2NO2
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c) (CH3)3C-NO2 d) CH3-C-CH-NO2
.,O CH3
7. Aniline + benzoylchloride NaOH C6H5-NH-CO-C6H5 this reaction is known as
a) Friedel – crafts reaction b) HVZ reaction
c) Schotten – Baumann reaction d) none of these
8. The product formed by the reaction an aldehyde with a primary amine (NEET)
a) carboxylic acid b) aromatic acid c) schiff ’s base d) ketone
9. Which of the following reaction is not correct.
HNO2
a) CH3CH2NH2 CH3CH2OH + N2
b) (CH3)2 N NaNO2 / HCl (CH3)2N N=NCl
Br2/NaOH
c) CH3CONH2 CH3NH2 d) none of these
10. When aniline reacts with acetic anhydride the product formed is
10.
a) o – aminoacetophenone b) m-aminoacetophenone
c) p – aminoacetophenone d) acetanilide
11.. The order of basic strength for methyl substituted amines in aqueous solution is
11
a) N(CH3)3 >N(CH3)2H >N(CH3)H2 >NH3 b) N(CH3)H2 >N(CH3)2H >N(CH3)3 >NH3
c) NH3 >N(CH3)H2 >N(CH3)2H >N(CH3)3 d) N(CH3)2H >N(CH3)H2 >N(CH3)3 >NH3
NO2 .NO2
12.
12. A ʻAʼ is
Br Br
N=N-Cl
a) H3PO2 Z[\] H2O b) H+/ H2O c) HgSO4/ H2SO4 d) Cu2Cl2
Fe/HCl H2O
13. C6H5NO2
13. A NaNO2/HCl B C ʻCʼ is
273K 283K
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c) 2,4 – dinitroaniline d) 2,4 – dibromoaniline
N
19.
19. O O When is reduced with Sn/HCl the pair of compound formed are
a) Ethanol, hydroxylamine hydrochloride b) Ethanol, ammonium hydroxide
c) Ethanol, NH2OH d) C3H5NH2 , H2O
CH3
OCH3
a) CH2-OH b) CO-CH3 c) CHO d) COOH
22. Ammonium salt of benzoic acid is heated strongly with P2O5and the product so formed
22.
is reduced and then treated with NaNO2/HCl at low temperature. The final compound
,..,.,.,.,.,.formed is
a) Benzene diazonium chloride b) Benzyl alcohol
c) Phenol d) Nitrosobenzene
Cl
a) H2N Cl b) C≡N Cl
c) N≡C Cl d) CH3-NH Cl
24. Among the following, the reaction that proceeds through an electrophilic substitution, is :
24.
Cl Cl
- Cu2Cl2
a) N2+Cl Cl +N2 b) +Cl2 UV light Cl Cl
Cl Cl
c ) +Cl AlCl3 Cl+HCl
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COOH
25. The major product of the following reaction
25. + NH3 Strong heating
.,O COOH
COOH COOH NH2
a) b) NH c) d)
CONH2 NH2 NH2
O
14.BIO MOLECULES
1. Which one of the following rotates the plane polarized light towards left?
(NEET Phase – II)
a) D(+) Glucose (b) L(+) Glucose (c) D(-) Fructose d) D(+) Galactose
2. The correct corresponding order of names of four aldoses with configuration given below
Respectively is, (NEET Phase – I)
CHO CHO CHO CHO
H C OH HO C H HO C H H C OH
H C OH H C OH HO C H HO C H
(Hydrolysis)
4. Glucose (HCN)
Product Product ( HI+Heat)
A , the compound A is
a) Heptanoic acid b) 2-Iodohexane c) Heptane d) Heptanol
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
30 Govt .Hr .Sec .School , Kaniyalampatti, Karur-
Karur-Dt.
6. The central dogma of molecular genetics states that the genetic information flows from (NEET
Phase – II)
a) Amino acids Protein DNA
b) DNA Carbohydrates Proteins
c) DNA RNA Proteins
d) DNA RNA Carbohydrates
7. In a protein, various amino acids linked together by (NEET Phase – I)
a) Peptide bond b) Dative bond c) α - Glycosidic bond d) β - Glycosidic bond
8. Among the following the achiral amino acid is (AIIMS)
a) 2-ethylalanine b) 2-methylglycine c) 2-hydroxymethylserine d) Tryptophan
9. The correct statement regarding RNA and DNA respectively is (NEET Phase – I)
a) The sugar component in RNA is an arabinos and the sugar component in DNA is ribose
b)..The sugar component in RNA is 2’-deoxyribose and the sugar component in DNA is
.,.,.,arabinose
c) The sugar component in RNA is an arabinose and the sugar component in DNA is
.,.,.,2’-deoxyribose
d) The sugar component in RNA is ribose and the sugar component in DNA is 2’-deoxyribose
10. In aqueous solution of amino acids mostly exists in,
10.
-
a) NH2-CH(R)-COOH b) NH2-CH(R)-COO
+ + -
c) H3N -CH(R)-COOH d) H3N -CH(R)-COO
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
31 Govt .Hr .Sec .School , Kaniyalampatti, Karur-
Karur-Dt.
16. The secondary structure of a protein refers to
16.
a) fixed configuration of the polypeptide backbone b) hydrophobic interaction
c) sequence of α-amino acids d) α-helical backbone.
17. Which of the following vitamins is water soluble?
17.
a) Vitamin E b) Vitamin K c) Vitamin A d) Vitamin B
18. Complete hydrolysis of cellulose gives
18.
a) L-Glucose b) D-Fructose c) D-Ribose d) D-Glucose
19. Which of the following statement is not correct?
19.
a) Ovalbumin is a simple food reserve in egg-white
b) Blood proteins thrombin and fibrinogen are involved in blood clotting
c) Denaturation makes protein more active
d) Insulin maintains the sugar level of in the human body.
20. Glucose is an aldose. Which one of the following reactions is not expected with glucose?
20.
a) It does not form oxime b) It does not react with Grignard reagent
c) It does not form osazones d) It does not reduce tollens reagent
21. If one strand of the DNA has the sequence ‘ATGCTTGA’, then the sequence of
21.
complementary strand would be
a) TACGAACT b) TCCGAACT c) TACGTACT d) TACGRAGT
22. Insulin, a hormone chemically is
22.
a) Fat b) Steroid c) Protein d) Carbohydrates
23. α -D (+) Glucose and β-D (+) glucose are
23.
a) Epimers b) Anomers
c) Enantiomers d) Conformational isomers
24. Which of the following are epimers
24.
a) D(+)-Glucose and D(+)-Galactose (b) D(+)-Glucose and D(+)-Mannose
c) Neither (a) nor (b) (d) Both (a) and (b)
25. Which of the following amino acids are achiral?
25.
a) Alanine b) Leucine c) Proline d) Glycine
2. Antiseptics and disinfectants either kill or prevent growth of microorganisms. Identify which of
the following statement is not true.
a) dilute solutions of boric acid and hydrogen peroxide are strong antiseptics.
b) Disinfectants harm the living tissues.
c) A 0.2% solution of phenol is an antiseptic while 1% solution acts as a disinfectant.
d) Chlorine and iodine are used as strong disinfectants.
3. Drugs that bind to the receptor site and inhibit its natural function are called
a) antagonists b) agonists c) enzymes d) molecular targets
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
32 Govt .Hr .Sec .School , Kaniyalampatti, Karur-
Karur-Dt.
4. Aspirin is a/an
a) acetylsalicylic acid b) benzoyl salicylic acid
c) chlorobenzoic acid d) anthranilic acid
5. Which one of the following structures represents nylon 6,6 polymer?
a) b)
O H
c) d) C N
2 C N (CH2)6
H2N CI H3C HOOC 6 O H n
7. Nylon is an example of
a) polyamide b) polythene c) polyester d) poly saccharide
8. Terylene is an example of
a) Polyamide b) polythene c) polyester d) polysaccharide
11. Non stick cook wares generally have a coating of a polymer, whose monomer is
11.
a) ethane b) prop-2-enenitrile
c) chloroethene d) 1,1,2,2-tetrafluoroethane
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt
33 Govt .Hr .Sec .School , Kaniyalampatti, Karur-
Karur-Dt.
13. Which of the following is a co-polymer?
13.
a) Orlon b) PVC c) Teflon d) PHBV
15. Regarding cross-linked or network polymers, which of the following statement is incorrect?
15.
(NEET)
a) Examples are Bakelite and melamine
b) They are formed from bi and tri-functional monomers
c) They contain covalent bonds between various linear polymer chains
d) They contain strong covalent bonds in their polymer chain
P.Suresh, PG Assistants
Assistants in Chemistry, Govt.Hr.Sec.School,
Govt.Hr.Sec.School, Kaniyalampatti, Karur-
Karur-Dt