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13-07-2024_Sr.Super60_NUCLEUS&STERLING-BT_Jee-Main_RPTM-01_Q.PAPER
13-07-2024_Sr.Super60_NUCLEUS&STERLING-BT_Jee-Main_RPTM-01_Q.PAPER
13-07-2024_Sr.Super60_NUCLEUS&STERLING-BT_Jee-Main_RPTM-01_Q.PAPER
.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________
Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
SRI CHAITANYA IIT ACADEMY, INDIA 13-07-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-01_Q.P
13-07-2024_Sr.Super60_ NUCLEUS & STERLING_BT _ Jee-Main_RPTM-01_Test Syllabus
PHYSICS : Thermal physics: Thermal expansion of solids, liquids and gases;
Calorimetry, latent heat; Ideal gas laws; Specific heats (Cv and Cp for
monoatomic and diatomic gases); Isothermal and adiabatic processes, bulk
modulus of gases; Equivalence of heat and work; First law of
thermodynamics and its applications (only for ideal gases); Mean free path,
Experiments: Plotting a cooling curve for the relationship between the
temperature of a hot body and time, Specific heat capacity of a given (i) solid
and (ii) liquid by method of mixtures, Specific heat of a liquid using
calorimeter.
CHEMISTRY : Nomenclature, Isomerism: Structural, Stereo, Hybridisation of carbon ;
bonds, shapes of simple organic molecules, structural and geometrical
isomerism; Optical isomerism of compounds containing upto two
asymmetric centres, (R,S and E,Z nomenclature excluded) IUPAC
nomenclature of simple organic compounds(only hydrocarbons, mono-
functional and bi-functional compounds) Conformations of ethane and
butane (Newman projections)
6. The temperature of equal masses of three different liquids A, B and C are 120 C, 190 C
and 280 C respectively. The temperature when A and B are mixed is 160 C and when B
and C are mixed is 230 C. The temperature when A and C are mixed is
1)18.20 C 2) 220 C 3) 20.20 C 4) 25.20 C
7. In an industrial process 10kg of water per hour is to be heated from 200 C to 800 C. To do
this steam at 1500 C is passed from a boiler into a copper coil immersed in water. The steam
condenses in the coil and is returned to the boiler as water at 900 C. The mass of steam
required per hour is
(Specific heat of steam = 1 calorie per gm°C, Latent heat of vaporisation 540 cal / gm)
1) 1gm 2)1kg 3) 10gm 4)10kg
8. A faulty thermometer has its lower fixed point marked as 10 and upper fixed point marked
as 1100 . If the temperature of the body shown in this scale is 620 , the temperature shown on
the Celsius scale is.
1) 720 C 2) 820 C 3) 600 C 4) 420 C
9. Match C P / CV ratio for ideal gases with different type of molecules:
Molecular type C P / CV
(A) Monoatomic (I) 7/5
(B) Diatomic rigid (II) 9/7
(C) Diatomic non-rigid (III) 4/3
(D) Triatomic rigid (IV) 5/3
1) A - IV, B – I, C – II, D – III 2) A - IV, B – II, C – I, D – III
3) A - III, B – IV, C – II, D – I 4) A - II, B – III, C – I, D – IV
10. A gas undergoes a process in which the pressure and volume V are related as VP n
constant. The bulk modulus for the gas in the process is.
1
P
1) n P 2) P n 3) 4) P n
n
11. The minimum attainable pressure of ideal gas in the process T T0 V 2 , where T0 and
are positive constants and V is volume of one mole of the gas is.
1) 2R T0 2) R T0 3) 3R T0 4) 6R T0
P
P
v v
1) 2)
P
P
v v
3) 4)
1) 2 31 2) 2 41 3) 1 3 2 4) 1 4 2
15. In an exhaust pump using a barrel of certain volume, the pressure falls to half of its initial
value in just two strokes. The percent fraction of volume of gas removed with each
stroke is approximately
1) 20 2) 30 3) 40 4) 50
16. A typical dark nebula is about 20 light years in diameter (shaped spherically ) and
contains about 50 hydrogen atoms per cubic centimetre (monatomic hydrogen and not
H 2 ) at a temperature of about 20K (A light year = 9.46 1015 m Boltzman’s constant
1.38 1023 JK 1) . The pressure inside a dark nebula is:
1) 1.4 1014 Pa 2) 2.8 1014 Pa 3) 1.4 1016 Pa 4) 2.8 1016 Pa
17. Assertion (A):- When a trough of water is placed in a very large evacuated room, part of it
evaporates and the remaining freezes to ice.
Reason(R):- A liquid boils at its boiling point temperature but can evaporate at any
temperature.
1) Both (A) and (R) are true and (R) is the correct explanation of (A).
2) Both (A) and (R) are true and (R) is NOT the correct explanation of (A).
3) (A) is true and (R) is false.
4) (A) is false and (R) is true.
18. Which one of the following gases possesses the largest internal energy
1)2 moles of helium occupying 1m3 at 300K
2) 56kg of nitrogen at 107Nm2 and 300K
3)8 grams of oxygen at 8 atm and 300K
4) 6 1026 molecules of argon occupying 40m3 at 900K
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SRI CHAITANYA IIT ACADEMY, INDIA 13-07-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-01_Q.P
19. Assertion(A): If positive work is done by a system in a thermodynamic process, its
volume must increase.
Reason(R) : When heat is added to a system its temperature must increase.
1) Both (A) and (R) are true and (R) is the correct explanation of (A).
2) Both (A) and (R) are true and (R) is NOT the correct explanation of (A).
3) (A) is true and (R) is false.
4) (A) is false and (R) is true.
20. A cylindrical tube of uniform cross-sectional area A is fitted with two air tight frictionless
pistons. The pistons are connected to each other by a metallic wire. Initially the pressure
of the gas is P0 and temperature is T0 , atmospheric pressure is also P0 . Now the
temperature of the gas is increased to 2T0 , the tension in the wire will be.
P0 A
1) 2P0 A 2) P0 A 3) 4) 4P0 A
2
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A cube of side (a) and of coefficient of linear expansion S is floating in a liquid of
coefficent of real expansion (γ L ) at 00 C. Even if the temperature of the system (cube and
liquid) is raised depth of the cube submerged in the liquid remains same. L / S is equal to
_____
22. A thin rod of negligible mass and area of cross-section 4 107 m2 suspended vertically
from one end, has a length of L m at 1000 C . The rod is cooled to 00 C , but prevented from
contracting by attaching a mass at the lower end. Find the mass attached in kg. (Given :
g 10 ms2 )
Sec: Sr.Super60_ NUCLEUS & STERLING_BT Page 7
SRI CHAITANYA IIT ACADEMY, INDIA 13-07-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-01_Q.P
23. In the P-V diagram shown, the gas does 5 J of work in isothermal process ab and 4 J in
adiabatic process bc. What will be the change in internal energy(in Joules) of the gas in
straight path c to a ?
24. P.V diagram of an ideal gas is as shown in figure. Work done by the gas in the process
ABCD is xP0V0 . x
P
2P0 C D
P0 A
B
V0 2V0 3V0 V
25. In a thermodynamic process helium gas obeys the law TP 2/5 constant. The heat given to
the gas when the temperature of 2 moles of the gas is raised from T to 4T is xRT .
(R is the universal gas constant). Find the value of x.
26. A gas consisting of monatomic molecules (degrees of freedom = 3) was expanded in a
polytropic process so that the rate of collisions of the molecules against the vessel’s wall
did not change. The molar heat capacity of the gas in the process is kR. The value of ' k ' is.
28. The net work done(in J) in a thermodynamic cycle that expands isobarically at pressure of
29. What amount of heat( in J ) is to be transferred to nitrogen in the isobaric heating process for
that gas to perform work of 2J?
30. 1gm of ice at 00 C is mixed with 1gm of water at 1000 C the resulting temperature( in 0C )
will be.
H OH
H Br
CH2-CH3
S O =A
O
O O
ph O S S O
1) O 2) O
O O
ph S O ph HO S
3) O 4) O
3) A iii ; B iv ; C ii ; D i 4) A ii ; B iv ; C iii ; D i
35. For which of the following pairs of compounds are the CORRECT combination given
ph
ph ph
N=N N=N
syn azobenzene
ph
1) anti azobenzene
C H3 C H2 C H3 C H2
OH
C=N C=N
H OH H
Z-ISOMER E-isomer
4)
H Cl and H Cl Br H Br H
and
Cl H H Cl H Br Br H
CH3 H H CH3
3) CH3 4) H
37. Assertion (A) : Acetone and Acetaldechyde are functional group isomers
Reason (R) : Alkanones and alkanals are functional group isomers having only same
molecular formula.
1) Both (A) and (R) are true and (R) is the correct explanation of (A).
2) Both (A) and (R) are true and (R) is NOT the correct explanation of (A).
3) (A) is true and (R) is false.
4) (A) is false and (R) is true.
38. The compound
Br
Br
CH3
1) 2) H
H H
H 3C
3) CH 2 C CH 2 4) CH3
CH 3 NH2
H Cl H HO c CH3
T
1) F 2) D 3) COOH 4) H
O O
O
44. IUPAC name of
1) 2-ethyl -1- methyl acetate 2) Ethyl - 2-methyl - 3- oxo - butanoate
3) Ethyl-3-methyl butanoate 4) Ethyl – 3 – oxo – 2 – methyl Butanoate
45. Which of the following compound will exhibit geometrical isomersm?
1) 3 – methyl butene – 1 2) 2 – methyl butene – 1
3) 1, 1 – diphenyl propene – 1 4) 1, 2 - diphenyl propene – 1
46. Which one of the following compounds will show enantiomerism?
1) Cis – 1, 4 – dimethyl cyclohexane
2) Trans -1, 3 – dimethyl cyclobutane
3) Cis – 1, 2 - dimethyl cyclopentane
4) Trans – 1, 2 - dimethyl cyclopropane
47. The compound 2, 4 – dimethyl hex – 3 – enoic acid exhibits is ____
1) Geometrical Isomerism only
2) Optical Isomerism only
3) Both Geometrical and optical isomerism
4) Tautomerism
H H
Me Me
Me OH
48. IUPAC name of
1) 3,3,4 – trimethyl 2 – hexanol 2) 4, 4 ,5 – trimethyl 2 – hexanol
3) 3, 3, 2 – trimethyl 5 – hexanol 4) 4, 4, 5 – trimethyl 5 –hexanol
CX Y Z
49. Among the following, the Newmann projections of meso form of CX Y Z is /are (X=Me,
Y=OH,Z=Deuterium)
X X X X
Z Y Z Y Y X X Z
Y Z Z Y Y Z Z Y
A) X B) X C) Z D) Y
1) A, B 2) A,C 3) C, D 4) B, D
50. Statement -1. Compounds containing chiral carbon atoms are always optically active.
Statement -2. The neassary condition carbon compounds become optically active is chiral
carbon atoms and compound does not have any symmetry.
Statement-3. Optical activity of compound can be determined by using plane polarized light.
Statement-4. Racemic mixture is optically inactive due to internal compensation.
1) (i),(ii) and (iii) are correct 2) Only (iii) is correct
3) (i), (ii) and (iv) are correct 4) (i), (iii) and (iv) are incorrect
C H 3 -C ( C H 3) -C H -C ( C H 3) -C H - C H 3
CH3 CH3
CH3
52. Total number of possible isomers of C2 FClBrI is/are (including stereo)
53. Total number of stereo isomers possible for the given structure.
OH Br
Cl F
55. Specific rotation of optically pure compound is 200 observed rotation of the mixture is
2n; n 2, 4,6,8,.....
61. Let a function f : N N be defined by f ( n) n 1; n 3,7,11,15,.... Then f is.
n 1
; n 1,5,9,13,....
2
1) one-one and on to 2)one-one but not on to
3) on to but not one-one 4) neither one-one nor on to
32 x 1 2 2024
62. If f ( x) , x R then f f ..... f is equal to.
32 x 3 2025 2025 2025
1) 1010 2)1011 3) 1012 4) 1013
63. Let (a , b) (0,2 ) be the largest interval for which sin 1(sin ) cos 1(sin ) 0 ,
(0, 2 ) holds. If x 2 x sin 1( x2 8 x 17) cos1( x2 8 x 17) 0 and
b a then is equal to.
3 3
1) 2) 3) 4)
12 40 20 40
n
1
6r
64. Sn Tan and p lim sn then cot p
22r 1 32r 1 n
r 1
3 2
1) 2) 3) 0 4)
2 3 2
65. Statement 1: Let f :[0,3] [1,13] is defined by f ( x) x 2 x 1 , then inverse is,
1 4 x 3
f 1 ( x )
2
Statement 2: many one function is not invertible.
1) Statement 1 incorrect and statement 2 is correct
2) Both statement 1 and statement 2 are correct
3) Statement 1 is correct and statement 2 is incorrect.
4) Statement 1 is incorrect and statement 2 is incorrect.
6 2
1 x x 4
66. 2
If x * y x y 3
and x *1 *1 x * 1*1 then the value of 3sin is
6 2
x x 2
3 2
1) 2) 3) 4)
2 2 6 3
5
67. If f ( x) sin 2 x sin 2 x cos x cos x and g 2 then the graph of
3 3 4
y g ( f ( x)) is.
1) A circle 2) A straight line 3) A parabola 4) Ellipse
68. The exhaustive solution set satisfying the equation 3cos 1 x sin 1 ( 1 x 2 )(4 x 2 1) is
[a,b]then [2a+b] equal to (where [.] denotes G.I.F).
1) 1 2)3 3)2 4) 4
69. If f ( x) x3 x 2 x a sin x b cos x is invertible then maximum value of a 2 b 2 is.
1 2 4
1) 2) 3) 1 4)
3 3 9
1 1 3
70. Let f : R R such that f f ( x) 1 x then f 2 f f
4 2 4
1 1 3
1) 2) 3)2 4)
4 2 4
71. If f ( x ) x 2 2 for x 4,4 then the number of real solutions of f f ( x) 1 is.
1) 3 2) 4 3)8 4)16
e x e x e1002 1
72. Let f ( x) and If
f g ( x ) then g 501 k then least positive prime
x
2 2e
which divides K is.
1) 2 2) 3 3) 5 4) 7
73. Which of the following relations is NOT TRUE.
1) Tan Tan 1x x 2) cot cot 1 x x
Column-I Column-II
(A) x (0,cos1) (p) t1 t2 t4 t3
1 (q) t4 t3 t1 t2
(B) x cos1,
2
1 (r) t2 t1 t4 t3
(C) x ,sin1
2
(D) x (sin1,1) (s) t3 t4 t1 t2
1) A S ; B Q; C P; D R 2) A Q; B S ; C R; D P
3) A R; B Q; C S ; D P 4) A R; B Q; C P; D S
2
1 n 10n 21.6
75. If cot n N then the number of integral values of n are.
6
1) 3 2) 4 3) 5 4) 7
76. f : 1, 2,3, 4,5 1,2,3,4 such that f (i ) even if ‘i’ is even and f (i ) f ( j ), for i j , than
the number of functions are.
1) 10 2) 12 3) 16 4)45
50
y x
77. If 2 f ( xy ) f ( x ) f ( y ) x, y R and f (1) 3 then the value of f ( y)
y 1
79. If is the only real root of the equation x3 bx 2 cx 1 0 , (b c) then the value of
1
Tan1( ) Tan 1 is ______
1) 2) 3) 0 4)
2 2
5 1 4 5
80. If Tan sin(2cos 1 ) and cos sin 1 sec1 then the inverse
16 5 5 3
trigonometric functions take principal values then the equation whose roots are and is.
1) 25 x 2 18 x 7 0 2) 25 x 2 18 x 7 0
3) 25 x 2 18 x 7 0 4) 25 x 2 18 x 7 0
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
3 x 22 3x2 8x 5
81. If the domain of the function sin 1 log 2 is ( , ] then 5 is.
2 x 19
x 3x 10
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SRI CHAITANYA IIT ACADEMY, INDIA 13-07-24_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee-Main_RPTM-01_Q.P
82. If s a R : 2a 1 3[a ] 2{a} , where [.] denotes the G.I.F and {t} represents the
84.
Let f ( x) [ k ] 5[k ] 4 x5 6{k }2 5{k } 1 x Tanx (sgn( x )) , be an even function for
2
all x R , where [.]denotes G.I.F and {.} denotes fractional part function. The sum of all
possible values K is then 3 =
1
85.
1
80Tan 3Tan 1 2cos1
2
5
+ 4 2Tan
1
2
Tan 1
2 2
3 3 b
86. Let f ( x ) arcTanx arcCotx If the range of f ( x ) is [a,b). Then the value of is__
a
87. Number of solutions of the equation
d x10 x8 7
1 2 9 9x
cos ec sin sin x x x will be
dx 10 8 7
x 9
2 3 12
88. The value of sin 1 cot sin 1 cos 1 sec1 2 is then =_____
4 4
2
89. If Tan1 sin 2 2sin 3 cot 1 5sec y 1 then the value of
2
sin 2 cos sin is.
x 1 x
1 1
90. If S x R : sin sin , then
x 1 4
2 2
x 2x 2