CAPITULO 3 - MATERIALES NO FERROSOS

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Rules for Classification and Construction

II Materials and Welding


1 Metallic Materials

3 Non-Ferrous Metals

Edition 2009
The following Rules come into force on April 1st, 2009

Alterations to the preceding Edition are marked by beams at the text margin.

Germanischer Lloyd Aktiengesellschaft

Head Office
Vorsetzen 35, 20459 Hamburg, Germany
Phone: +49 40 36149-0
Fax: +49 40 36149-200
headoffice@gl-group.com

www.gl-group.com

"General Terms and Conditions" of the respective latest edition will be applicable
(see Rules for Classification and Construction, I - Ship Technology, Part 0 - Classification and Surveys).

Reproduction by printing or photostatic means is only permissible with the consent of


Germanischer Lloyd Aktiengesellschaft.

Published by: Germanischer Lloyd Aktiengesellschaft, Hamburg


Printed by: Gebrüder Braasch GmbH, Hamburg
II - Part 1 Table of Contents Chapter 3
GL 2009 Page 3

Table of Contents

Section 1 Aluminium Alloys


A. Wrought Aluminium Alloys ....................................................................................................... 1- 1
B. Aluminium Casting Alloys ......................................................................................................... 1- 9

Section 2 Copper Alloys


A. Pipes of Copper and Wrought Copper Alloys ............................................................................ 2- 1
B. Cast Copper Alloys .................................................................................................................... 2- 7
II - Part 1 Section 1 A Aluminium Alloys Chapter 3
GL 2009 Page 1–1

Section 1

Aluminium Alloys

A. Wrought Aluminium Alloys truded followed, where necessary, by drawing. Pipes


may also be fabricated from longitudinally welded
1. Scope strips.
All products shall be delivered in the material condi-
1.1 These Rules are applicable to the wrought tions specified for the alloy concerned.
aluminium alloys which are described below and
which are intended for the fabrication of ships' hulls, 4. Suitable alloys
superstructures and other ship structures as well as for
pipelines. They are not applicable to wrought alumin- All alloys shall be suitable for use within seawater
ium alloys which are intended for the manufacture of atmosphere or under exposure to seawater. The alloys
systems designed to transport liquefied gases at low mentioned in 4.1 and 4.2 may be used, if this precon-
temperatures. dition is satisfied. Aluminium alloys according to
other standards and specifications may be used, if they
1.2 These Rules are applicable to products made are equivalent to those mentioned in 4.1 and 4.2 and if
from wrought aluminium alloys having a product their suitability is confirmed by GL.
thickness of 3 to 50 mm inclusive. Requirements ap-
plicable to products having thicknesses outside this 4.1 Alloys for use in load bearing structures
range are to be specially agreed with GL. Table 1.1 specifies aluminium alloys which are suit-
able as welded, bonded or mechanically joint struc-
1.3 Alloys and material conditions which differ tural members exposed to marine environment.
from the specified requirements given below, but
which conform to national standards or the manufac- Depending on the product type the wrought alloys
turer’s material specifications may be used provided may be supplied in the material conditions given in
that their properties and suitability for use, and also Table 1.1.
their weldability have been checked by GL and that As regards chemical composition Table 1.3 applies,
GL has approved their use. Table 1.4 as regards mechanical properties of plates
and strips and Table 1.5 as regards mechanical proper-
1.4 Alloy designations and material conditions ties of extruded sections, bars and pipes.
which are indicated in these Rules comply with the
designations of the Aluminium Association. 4.2 Wrought aluminium and wrought alloys
for use in non-load bearing structures and
1.5 With regard to the definition of the material for rivets
conditions EN 515 is applicable.
Aluminium and aluminium alloys which are suitable
as welded, bonded or mechanically joint structural
2. Requirements to be met by manufacturers members in non-load bearing structures exposed to
Manufacturers wishing to supply products in accor- marine environment are given in Table 1.2.
dance with these Rules shall be approved by GL for The chemical composition of these materials shall be
the alloys and product forms in question. This is con- taken from EN 573-3 or equivalent standards.
ditional upon their fulfilling the manufacturing and
quality control requirements stated in Chapter 1 – The recommended product types for these alloys are
Principles and Test Procedures, Section 1, C. and also given in Table 1.2. They may be used in the mate-
furnishing proof of this to GL prior to the commence- rial conditions specified in the relevant European or
ment of supplies. GL reserves the right to carry out equivalent standards.
performance tests on products selected for this pur- The alloys specified in Table 1.1 may also be used for
pose. non-load bearing structures applicable to all products
and material conditions.
3. Manufacture and material condition
Note:
The starting material for rolled and pressed products is
manufactured by continuous casting. Plates may be Products made from the 5000 and 6000 series of al-
hot or cold rolled according to the characteristics loys shall not come into direct contact with seawater.
(strength, dimensions, tolerances, etc.) required. Sec- Where necessary, they are to be protected by anodes
tions shall be extruded. Pipes and bars shall be ex- or coatings.
Chapter 3 Section 1 A Aluminium Alloys II - Part 1
Page 1–2 GL 2009

Table 1.1 Wrought aluminium alloys:


Alloys, products and material conditions, recommended for use in load bearing structures

Sheets,
Designation of alloy Extruded products Drawn products Forgings
strips and
plates
Bars Pipes Sections Bars Pipes
O/H111
GL AW-5059 H112
–– –– –– –– –– ––
(AlMg5,5Mn0,8ZnZr) H116
H321
GL AW-5083
(AlMg4,5Mn0,7) O/H111
H112 O/H111 O/H111
und H112 O/H111 O/H111 H112
H116 H112 H112
GL AW-5383
(AlMg4,5Mn0,9) H32

O/H111
GL AW-5086 H112 O/H111 O/H111
H116 H112 O/H111 O/H111 ––
(AlMg4) H112 H112
H32/H321
O/H111 O/H111
GL AW-5454 O/H111
H112 H112 H112 –– –– ––
(AlMg3Mn) H112
H32/H321
O/H111
GL AW-5754 O/H111 O/H111
H112 H112 O/H111 O/H111 H112
(AlMg3) H112 H112
H32
GL AW-6005A
(AlSiMg(A)) –– T6 1 T6 1 T6 1 –– –– ––

GL AW-6061
(AlMg1SiCu) –– T6 1 T6 1 T6 1 –– –– ––

GL AW-6082 T5
(AlSiMgMn) T6/T651 T6 1 T6 1 T6 1 T6 1 T6 1 T6

GL AW-6106
(AlMgSiMn) –– –– –– T6 1 –– –– ––
1 The properties may be achieved by quenching at the press.
II - Part 1 Section 1 A Aluminium Alloys Chapter 3
GL 2009 Page 1–3

Table 1.2 Wrought aluminium and wrought aluminium alloys:


Alloys and products recommended for use in non-load bearing structures and for rivets

Sheets,
Designation of strips Extruded products Drawn products Forgings Electrical Drawn
alloy and welded wire
plates Bars Pipes Sections Bars Pipes pipes for rivets
EN AW-1050 A
(Al99,5)
+ + + + + + × × –

EN AW-1200
(Al99,0)
+ + + + + + × × –

EN AW-3103
(AlMn1)
+ + + + + + × + –

EN AW-5005
+ + + + + + + + –
(AlMg1(B))
EN AW-5050
(AlMg1,5(C))
+ × × × × × × + –

EN AW-5251
(AlMg2)
+ + + + + + × + –

EN AW-5052
(AlMg2,5)
+ + + + + + × × –

EN AW-6060
(AlMgSi) × + + + + + × × –

EN AW-6063
(AlMg0,7Si) × + + + + + × × –

EN AW-5154
– – – – – – – – *
(AlMg3,5)
EN AW-5754
– – – – – – – – *
(AlMg3)
+ The recommended alloy is included in the relevant product standard.
× The recommended alloy is not included in the relevant product standard.
* The recommended alloy, particularly in the material condition 0 and H32, is included in the relevant
standard.
– The alloy is not recommended.
Other
Chemical composition [%]
Alloy additions Additional
Page 1–4

number [%] 2 requirements Table 1.3


Chapter 3

Al Si Fe Cu Mn Mg Cr Zn Ti
single total

GL AW-5059 remainder ≤ 0,45 ≤ 0,50 ≤ 0,25 0,60 - 1,2 5,0 − 6,0 ≤ 0,25 0,40 - 0,90 0,20 ≤ 0,05 ≤ 0,10 0,05 - 0,25 Zr
Section 1

GL AW-5083 remainder ≤ 0,40 ≤ 0,40 ≤ 0,10 0,40 - 1,0 4,0 - 4,9 0,05 - 0,25 ≤ 0,25 ≤ 0,15 ≤ 0,05 ≤ 0,15
A

GL AW-5086 remainder ≤ 0,40 ≤ 0,50 ≤ 0,10 0,20 - 0,70 3,5 - 4,5 0,05 - 0,25 ≤ 0,25 ≤ 0,15 ≤ 0,05 ≤ 0,15

GL AW-5383 remainder ≤ 0,25 ≤ 0,25 ≤ 0,20 0,70 - 1,0 4,0 - 5,2 ≤ 0,25 ≤ 0,40 ≤ 0,15 ≤ 0,05 ≤ 0,15 ≤ 0,20 Zr

GL AW-5454 remainder ≤ 0,25 ≤ 0,40 ≤ 0,10 0,50 - 1,0 2,4 - 3,0 0,05 - 0,20 ≤ 0,25 ≤ 0,20 ≤ 0,05 ≤ 0,15
Aluminium Alloys

GL AW-5754 remainder ≤ 0,40 ≤ 0,40 ≤ 0,10 ≤ 0,50 2,6 - 3,6 ≤ 0,30 ≤ 0,20 ≤ 0,15 ≤ 0,05 ≤ 0,15 0,10 ≤ Mn + Cr ≤ 0,6

GL AW-6005-A remainder 0,50 - 0,90 ≤ 0,35 ≤ 0,30 ≤ 0,50 0,4 - 0,70 ≤ 0,30 ≤ 0,20 ≤ 0,10 ≤ 0,05 ≤ 0,15 0,12 ≤ Mn + Cr ≤ 0,5

GL AW-6061 remainder 0,40 - 0,80 ≤ 0,70 0,15 - 0,40 ≤ 0,15 0,80 - 1,2 0,04 - 0,35 ≤ 0,25 ≤ 0,16 ≤ 0,05 ≤ 0,15

GL AW-6082 remainder 0,70 - 1,3 ≤ 0,50 ≤ 0,10 0,40 - 1,0 0,60 - 1,2 ≤ 0,25 ≤ 0,20 ≤ 0,10 ≤ 0,05 ≤ 0,15
Chemical composition of selected wrought aluminium alloys 1

GL AW-6106 remainder 0,30 - 0,60 ≤ 0,35 ≤ 0,25 0,05 - 0,20 0,4 - 0,80 ≤ 0,20 ≤ 0,10 ⎯ ≤ 0,05 ≤ 0,10

1 Minor deviations of the prescribed composition may be accepted, cf. A.7.2


2 Other elements are seen as permissible additions. They need not to be specified, if their limit values are not exceeded.
GL 2009
II - Part 1
II - Part 1 Section 1 A Aluminium Alloys Chapter 3
GL 2009 Page 1–5

Table 1.4 Material condition and mechanical properties of rolled products from wrought aluminium
alloys 1
(Product thickness t = 3,0 up to 50 mm)

Alloy Material Yield Tensile Thickness Elongation


number condition strength strength [%]
Rp0,2 Rm t min.
[N/mm2] [N/mm2] [mm]
min. A50mm A
t ≤ 12,5 16 ––
0/H111/H112 125 275 – 350
t > 12,5 –– 15
t ≤ 12,5 12 ––
GL AW-5083 H116 215 ≥ 305
t > 12,5 –– 10
t ≤ 12,5 10 ––
H32/H321 215 305 – 380
t > 12,5 –– 9
t ≤ 12,5 17 ––
0/H111/H112 100 240 – 310
t > 12,5 –– 16
t ≤ 12,5 10 ––
GL AW-5086 H116 195 ≥ 275
t > 12,5 –– 9
t ≤ 12,5 10 ––
H32/H321 185 275 – 335
t > 12,5 –– 9
t ≤ 12,5 18 ––
0/H111/H112 80 190 – 240
GL AW-5754 t > 12,5 –– 17
H32 165 ≥ 240 3 ≤ t ≤ 40 –– 10
0/H111 85 ≥ 215
GL AW-5454 3 ≤ t ≤ 40 –– 10
H32 180 ≥ 250
0/H111 145 ≥ 290 3 ≤ t ≤ 40 –– 17
GL AW-5383
H116/H321 220 ≥ 305 3 ≤ t ≤ 40 –– 10
0/H111 160 ≥ 330 3 ≤ t ≤ 50 24
––
GL AW-5059 270 ≥ 370 3 ≤ t ≤ 20 10
H116/H321
260 ≥ 360 20 ≤ t ≤ 40 –– 10
1 The mechanical properties are applicable to both longitudinal and transverse specimens.
Chapter 3 Section 1 A Aluminium Alloys II - Part 1
Page 1–6 GL 2009

5. General characteristics of products 7.4 The material to be used for welded structural
members should be made from ingots or billets with a
5.1 The products shall have a smooth surface hydrogen content of maximum 0,2 ml per 100 g alu-
compatible with the method of manufacture and shall minium, when measurement is carried out on the liq-
be free of defects liable to impair further manufactur- uid metal during casting.
ing processes or the proposed application of the prod-
ucts, e.g. cracks, laps, appreciable inclusions of extra- 8. Mechanical properties
neous substances and major mechanical damage.
The required values of tensile strength, 0,2 % proof
5.2 Surface defects may be repaired only by stress and elongation specified in Table 1.4 and 1.5
grinding provided that this is accomplished with a shall be fulfilled under tensile test.
gentle transition to the adjacent surface of the product
and that the dimensions remain within the tolerance
limits. Repair by welding is not permitted. For repair 9. Tests
purposes only tools are to be used which are exclu-
sively applied for aluminium processing. 9.1 Definition of test batch

6. Dimensional and geometrical tolerances For test purposes, products are to be grouped together
in test batches. A test batch is made up of products:
6.1 Unless otherwise agreed with GL, the follow- – made from the same alloy and from the same
ing specified requirements are applicable in respect of charge
permitted thickness tolerances.
– for plates and strips: Table 1.6 – of the same product shape and with the same
dimensions (for plates and strips of the same
– for open sections: Table 1.7 thickness)
– for closed sections: Table 1.8 – with the same forming process
Other product shapes and other dimensional and geo-
metrical tolerances are subject to the applicable stan- – with the same material condition
dards.
– with the same heat treatment
6.2 Compliance with tolerances and the require-
ments applicable to the general characteristics is the 9.2 Tensile test
responsibility of the manufacturer. Examination of the
products by the Surveyor does not release the manu- 9.2.1 Number of tensile test specimens
facturer from this responsibility.
For rolled products, one tensile test specimen shall be
Where the performance of non-destructive tests is taken from each test batch. Where the weight of a test
necessary, method and evaluation criteria shall be batch exceeds 2000 kg, an additional tensile test
agreed with GL. specimen shall be taken from each additional 2000 kg
or parts thereof.
7. Chemical composition
9.2.2 For extruded products with a weight per
meter of less than 1 kg/m, one tensile test specimen
7.1 The chemical composition of the alloys shall be taken from each 1000 kg of a test batch or
specified in these Rules shall correspond to the data parts thereof.
given in Table 1.3. For wrought aluminium and
wrought alloys which are not specified therein the For weights per meter of 1 to 5 kg/m, one tensile test
requirements of the standards or approved specifica- specimen shall be taken from each 2000 kg of a test
tions shall be satisfied. batch or parts thereof. Where the weight per meter
exceeds 5 kg/m one tensile test specimen shall be
7.2 The manufacturer shall determine the chemi- taken from each 3000 kg of a test batch or parts
cal composition on test specimens taken from each thereof.
charge. Slight variations from the specified composi-
tion may be permitted by agreement of GL provided 9.2.3 Location of specimens
that the suitability of the product concerned for its
intended purpose is not impaired thereby. For plates and strips, transverse specimens are gener-
ally taken. Where the width of a product is less than
7.3 The analysis certificate produced by the 300 mm, longitudinal specimens are also permitted.
manufacturer is normally accepted, with the Surveyor
reserving the right to have occasional check analyses In the case of extruded products, longitudinal speci-
carried out. mens are normally taken.
II - Part 1 Section 1 A Aluminium Alloys Chapter 3
GL 2009 Page 1–7

Table 1.5 Material condition and mechanical properties of plates and strips made of wrought aluminium
alloys ¹
(product thickness t = 3,0 to 50 mm)

Yield Tensile Thickness Elongation


strength strength [%]
Alloy Material
Rp0,2 Rm t min.
number condition
[N/mm2] [N/mm2] [mm]
min. A50mm A
GL AW-5059 H112 200 ≥ 330 3 ≤ t ≤ 50 –– 10
0/H111 110 270 – 350 t ≤ 12,5 10 ––
GL AW-5083
H112 125 > 270 t > 12,5 –– 12
0/H111 t ≤ 12,5 15 ––
GL AW-5086 95 240 – 320
H112 t > 12,5 –– 18
0/H111 145 ≥ 290 17
GL AW-5383 3 ≤ t ≤ 50 ––
H112 190 ≥ 310 13
t ≤ 12,5 8 ––
GL AW-6005A T5/T6 215 ≥ 260
t > 12,5 –– 6
t ≤ 12,5 10 ––
GL AW-6061 T5/T6 240 ≥ 260
t > 12,5 –– 8
t ≤ 12,5 10 ––
GL AW-6082 T5/T6 260 ≥ 310
t > 12,5 –– 8
1 The mechanical properties are applicable to both longitudinal and transverse test specimens.

Table 1.6 Permitted lower thickness tolerances for plates and strips

Thickness tolerances for product widths [mm]


Nominal thickness
[mm] over 1 500 mm over 2 000 mm
up to 1 500 mm
up to 2 000 mm up to 3 500 mm
up to 4 0,10 0,15 0,15
over 4 up to 8 0,20 0,20 0,25
over 8 up to 12 0,25 0,25 0,25
over 12 up to 20 0,35 0,40 0,50
over 20 up to 50 0,45 0,50 0,65

Table 1.7 Permitted lower thickness tolerances for open sections

Thickness tolerances for sections which section shape


Nominal thickness t is enclosed by a circle of [mm] diameter
[mm] over 250 mm
up to 250 mm over 400 mm
up to 400 mm
from 3 up to 6 0,25 0,35 0,40
over 6 0,30 0,40 0,45
Chapter 3 Section 1 A Aluminium Alloys II - Part 1
Page 1–8 GL 2009

Table 1.8 Permitted lower thickness tolerances for closed sections

Thickness tolerance for sections which section shape


Nominal thickness t is enclosed by a circle of [mm] diameter
[mm] over 250 mm
up to 250 mm
up to 400 mm
from 3 up to 6 0,15 0,25
over 6 0,20 0,30

9.2.4 Marking of specimens 9.5 Corrosion test


Specimens shall be marked so that they can be traced 9.5.1 On rolled products from alloys of the series
back to the product from which they were taken and 5XXX supplied in the condition H116, H32 or H321,
also so that their location in the product itself can be a test of resistance against exfoliation corrosion and
verified at all times. intercrystalline corrosion is to be carried out according
to ASTM-G66 (ASSET) and ASTM-G67 (NAMLT).
9.2.5 Shape and arrangement of specimens
The indices for exfoliation corrosion shall be within
For product thicknesses up to and including 12,5 mm, the level EA and those for crevice corrosion rate shall
flat specimens with a gauge length of 50 mm shall be be within PB according to ASTM-G66.
prepared, the rolling skin being maintained on both
sides. In case of testing in accordance with ASTM-G67 the
mass loss shall not exceed 15 mg/cm2.
For product thicknesses above 12.5 mm, round test
Testing shall be carried out by batch. The scope of
specimens of 10 mm ∅ and with an initial gauge
testing may be reduced due to special approval by GL.
length of 50 mm shall be prepared. In the case of
product thicknesses up to and including 40 mm, the
9.6 Retests
axis of the round test specimen shall be positioned in
the centre of the product thickness and for thicknesses 9.6.1 If, during tensile testing, a test specimen fails
in excess of 40 mm it is to be positioned at a distance to meet the standards, two additional specimens shall
of one quarter of the thickness of the product, meas- be taken from the same test piece. If both retest
ured from the surface. specimens satisfy the test conditions, the test piece
from which the retest specimens were taken and the
9.2.6 Tensile test procedure other test pieces included in the test batch may be
accepted.
Tensile testing shall be performed in accordance with
Chapter 1 – Principles and Test Procedures, Section 2, 9.6.2 Where one or both of the retest specimens
D. described in 9.6.1 fail to meet the standards, the test
piece from which the specimens were taken shall be
9.3 Test of surface finish rejected. The remaining test pieces in the batch may
be accepted provided that the result of tests performed
Products shall be presented to the Surveyor for testing
on specimens from two other test pieces is satisfac-
of their surface finish.
tory. Where these specimens also fail to meet the
standards, the entire test batch shall be rejected.
9.4 Test of press welding of closed sections
9.6.3 In the case of products which fail to satisfy
The manufacturer shall demonstrate, by means of
the test requirements but which already bear the GL
macrosections of each test batch, that the press welds
stamp, the stamp marks shall be removed to avoid
have no lack of fusion. In case of round pipes or pipes
confusion.
with quadratic cross section (with rounded edges) which
outer diameter does not exceed 100 mm, this may be
carried out alternatively by means of a drift expanding 10. Marking
test.
10.1 The manufacturer shall mark each product in
9.4.1 Drift expanding test at least one place with the following details:
Of every fifth section, but at minimum of one section, – manufacturer's mark
samples are to be taken. Sections with length of more – short designation of alloy
than 6 m shall be individually tested unless otherwise
agreed with GL. – short designation of the condition of the material
II - Part 1 Section 1 B Aluminium Alloys Chapter 3
GL 2009 Page 1–9

– rolled products which were corrosion tested in to call for performance tests to be carried out on cast-
accordance with 9.5 are to be marked with the ings selected for the purpose.
letter "M" additionally (e.g. GL AW-5083-H321
M). 2.2 If castings are required to be weldable, this is
to be stated in the order and proof of suitability fur-
– number of the manufacturing batch enabling the nished to GL.
manufacturing process to be traced back
Products shall also be marked with the GL “batch 3. Permitted grades of casting
stamp”.
3.1 Suitable grades of castings to international or
10.2 Where sections, bars or pipes are bundled national standards, e.g. to EN 1706 shall generally be
together or packed in crates, the markings specified in used. Where castings conforming to manufacturer’s
10.1 may be affixed to the products by a securely specifications are to be used, these are to be submitted
fastened tag or label. to GL for examination and approval.

3.2 Castings such as fittings, housings and fan


11. Certificates issued by the supplier
rotors which are exposed without protection to the
action of seawater or salty atmosphere should be made
11.1 For each delivery accepted, the manufacturer
of alloys suitable for this kind of use. AlSi-, AlSiMg-
shall supply the Surveyor with an acceptance certifi-
and AlMg-alloys with a maximum copper content of
cate or delivery specification containing the following
0,1 % should normally be used. AlSi- and AlSiMg-
details:
alloys shall not come into direct contact with seawater.
– customer and order number Where necessary, they are to be protected by anodes
– project number or newbuilding number, where or coatings.
known
– number, dimensions and weight of the products 3.3 For the applications mentioned in 1.1, use
– designation of the alloy and material condition may be made of the casting alloys conforming to
– method of manufacture EN 1706 listed in Table 1.9.
– chemical composition Use may be made of other alloys provided these are
– manufacturing batch number or identifying suitable for the intended application and their use has
mark been approved by GL.
– results of the mechanical tests, where testing is
carried out by the manufacturer 4. Requirements
– details of heat treatment, where applicable
4.1 The chemical composition of the castings
11.2 Where the alloys are not cast in the same shall correspond to the standards or to recognized
works in which they are made into semi-finished manufacturer’s specifications and shall be demon-
products, the Surveyor shall be given a certificate strated by the manufacturer of the castings for each
issued by the smelting plant which indicates charge charge.
numbers and chemical composition. The manufacturer
of the ingots or extrusion billets shall be approved by 4.2 With regard to mechanical properties, the
GL. requirements stated in the standards or the manufac-
turer’s specifications are applicable. Specimens taken
from integrally cast test pieces shall meet the require-
B. Aluminium Casting Alloys ments for separately cast sample bars.

1. Scope 4.3 All castings shall be free from internal and


external defects which could have more than just a
1.1 These Rules are applicable to aluminium slight adverse effect on the application and any appro-
casting alloys which are intended for the fabrication of priate further manufacturing processes carried out on
ships’ hulls and also machine construction parts and the castings. Where defects are to be repaired by weld-
other shipbuilding components. ing, a welding specification shall be produced by the
manufacturer for this purpose and the approval of the
1.2 Also applicable to the manufacture and test- Surveyor sought.
ing of casting are Chapter 1 – Principles and Test
Procedures, Section 1 and Section 2. 5. Tests

2. Requirements to be met by aluminium 5.1 Castings which shall form part of the ship’s
foundries hull or are designed as structural components of the
propulsion system are to be presented to the Surveyor
2.1 Foundries wishing to supply castings con- for testing. A tensile test shall be performed on the
forming to these Rules shall be approved by GL for castings in his presence to establish their mechanical
the grades of castings concerned. GL reserves the right properties.
Chapter 3 Section 1 B Aluminium Alloys II - Part 1
Page 1–10 GL 2009

Table 1.9 Aluminium-casting alloys

Designation of alloy Cast procedure Material condition Sea water suitability


EN AC-41000
S, K F, T6 good
(AlSi2MgTi)
EN AC-42100
S, K, L T6, T64 good
(AlSi7Mg0,3)
EN AC-42200
S, K, L T6, T64 good
(AlSi7Mg0,6)
EN AC-43100
S, K, L F, T6, T64 good / moderate
(AlSi10Mg(b))
EN AC-44100
S, K, L, D F good / moderate
(AlSi12(b))
EN AC-51000
S, K, L F very good
(AlMg3(b))
EN AC-51300
S, K, L F very good
(AlMg5)
EN AC-51400
S, K, L F very good
(AlMg5(Si))
S = sand casting
K = permanent mould casting
L = investment casting
D = pressure die casting
F = cast condition
T6 = solution annealed and completely artificially aged
T64 = solution annealed and not completely artificially aged - under aged (only for permanent mould casting)

5.2 For the tensile test, one test specimen is to be – manufacturer’s mark
provided from each charge or each heat treatment
batch. For unfinished castings weighing 300 kg and – short designation of the casting alloys
over, a tensile test specimen is required for each cast-
ing. – short designation of the condition of the material

5.3 Specimens for tensile testing shall normally – charge number or some other mark to permit
be taken from integrally cast sample bars which may identification of the casting
only be separated from the casting when the final heat
treatment has been performed. 7. Certificates
The use of separately cast sample pieces shall be sub-
ject to special agreement with GL with regard to their For each delivery, the manufacturer shall present the
casting and the requirements applicable to the me- Surveyor with a certificate or delivery specification
chanical properties of the tensile test specimens taken giving the following minimum details:
from them.
– purchaser and order number
5.4 Where stipulated following examination of
the drawings or in the order, and also where there is – type of casting and grade of casting
some doubt as to whether the castings are free from
– item numbers and quantities
defects, the manufacturer of the castings shall perform
non-destructive tests at the places specified for the – method of manufacture
purpose, and the results are to be certified by him.
Critical areas of casting and repaired defects are also – heat numbers and chemical composition
to be incorporated in the test.
– details of heat treatment
6. Marking
– test pressures, where applicable
As a minimum requirement, the manufacturer shall
apply the following marks on the castings: – weight of the delivery
II - Part 1 Section 2 A Copper Alloys Chapter 3
GL 2009 Page 2–1

Section 2

Copper Alloys

A. Pipes of Copper and Wrought Copper 4.2 Copper and wrought copper alloy pipes for
Alloys condensers and heat exchangers according to
EN 12451, preferably in the grades of pipe shown in
Table 2.1.
1. Scope

1.1 These Rules are applicable to pipes and fit- 4.3 Pipes conforming to other standards or speci-
tings made of copper and wrought copper alloys and fications, provided that they are comparable to the
intended for use in pressurized lines and for condens- grades specified in 4.1 and 4.2 and their suitability has
ers and heat exchangers. In the case of finned pipes, been confirmed by GL.
specifications shall be submitted to GL for approval.
5. Surface finish
2. Requirements to be met by pipe manufac-
turers
5.1 Pipes shall have a smooth surface compatible
Manufacturers wishing to supply products in accor- with the method of manufacture. The surface shall be
dance with these Rules shall be approved by GL. This free from impurities, e.g. pickling residue or burnt
is conditional upon their fulfilling the requirements drawing lubricants, and may not be cracked or have
indicated in Chapter 1 – Principles and Test Proce- suffered mechanical damage. Die marks and lamina-
dures, Section 1, C. and furnishing proof of this to GL tions which may impair further manufacturing opera-
prior to the commencement of supplies. tions or the use of the material are not allowed.

3. Method of manufacture 5.2 Surface defects may be repaired by grinding


provided that a gradual transition is made to the sur-
3.1 The pipes shall generally be manufactured by face of the pipe and that the dimensional tolerances
seamless methods, e.g. by hot pressing followed by are not exceeded. Repairs by welding or soldering are
rolling and cold drawing. not permitted.

3.2 Where welded pipes or fittings are to be used, 6. Dimensions; dimensional and geometrical
the characteristics of these and the method of manu- tolerances
facture employed shall be made known to GL. GL
reserve the right to demand a procedure approval test The tolerances on wall thickness and diameter shall be
in these cases. those prescribed in EN 12449, see on this also Tables
2.4 to 2.9. Pipe ends shall be cut off at right angles to
3.3 Cold-formed pipes and fittings shall be sub- the pipe axis and shall be free from burrs.
jected to recrystallization annealing. Notwithstanding
this, copper pipes which are to be supplied in the "half 7. Resistance to leakage
hard" to "hard" condition (e.g. conditions R250 and
R290, EN 12449) may be cold formed after annealing. Pipes shall not leak when submitted to the hydraulic
CuNi2Si-pipes are cold formed in the solution an- pressure test at the prescribed test pressures.
nealed condition or hot formed with simultaneous
solution annealing and subsequent quenching. After
cold forming hardening occurs. 8. Requirements applicable to the material

4. Suitable grades of pipe 8.1 Chemical composition

All pipes shall be suitable for the intended application The chemical composition shall conform to Table 2.1.
and satisfy the requirements specified in 8. Subject to
these conditions, the following grades of pipe may be
8.2 Mechanical properties
used:
The mechanical properties shall conform to the rele-
4.1 Copper and wrought copper alloy pipes ac- vant standards. Table 2.2 gives an extract from
cording to EN 12449 in the grades shown in Table 2.1. EN 12449 for the grades of pipe specified in 4.1.
Page 2–2

Table 2.1
Chapter 3

Material designation Composition: Weight fraction [%]


Section 2

Others
Material code Number Element Cu Al As C Co Fe Mn Ni P Pb S Si Sn Zn
total
A

min. 99,90 1 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ 0,015 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯


Cu-DHP CW024A
max. ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ 0,040 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯
Suitable grades of pipe

min. ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ 1,6 ⎯ ⎯ ⎯ 0,4 ⎯ ⎯ ⎯


CuNi2Si CW111C remainder
max. ⎯ ⎯ ⎯ ⎯ 0,2 0,1 2,5 ⎯ 0,02 ⎯ 0,8 ⎯ ⎯ 0,3

min. ⎯ ⎯ ⎯ ⎯ 1,0 3 0,5 9,0 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯


CuNi10Fe1Mn CW352H remainder
max. ⎯ ⎯ 0,05 0,1 2 2,0 3 1,0 11,0 0,02 0,02 0,05 ⎯ 0,03 0,5 0,2
Copper Alloys

min. ⎯ ⎯ ⎯ ⎯ 0,4 0,5 30,0 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯


CuNi30Mn1Fe CW354H remainder
max. ⎯ ⎯ 0,05 0,1 2 1,0 1,5 32,0 0,02 0,02 0,05 ⎯ 0,03 0,5 0,2

min. 76,0 1,8 0,02 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ residue ⎯


CiUm20Al2As CW702R
max. 79,0 2,3 0,06 ⎯ ⎯ 0,07 0,1 0,1 0,01 0,05 ⎯ ⎯ ⎯ ⎯ 0,3
1
including Ag up to max. 0,015 %
2
Co max. 0,1 is counted as Ni.
3
for applications exposed to seawater: 1,5 ≤ Fe ≤ 1,8
GL 2009
II - Part 1
II - Part 1 Section 2 A Copper Alloys Chapter 3
GL 2009 Page 2–3

Table 2.2 Condition and mechanical properties of pipes made of copper and wrought copper alloys to
EN 12449

Wall Yield Tensile Elongation


Material thickness strength strength
Material condition t Rp0,2 Rm A
designation
[mm] [N/mm2] [N/mm2] [%]
min.
soft R200 ≤ 20 ≤ 110 ≥ 200 40
Cu-DHP half-hard R250 ≤ 10 ≥ 150 ≥ 250 20
hard 1 R290 ≤ 5 ≥ 250 ≥ 290 5
CuZn20Al2 annealed R340 ≤ 10 ≥ 120 ≥ 340 45
CuNi10Fe1Mn annealed R290 ≤ 20 ≥ 90 ≥ 290 30
CuNi30Mn1Fe annealed R370 ≤ 10 ≥ 120 ≥ 370 35
solution annealed R260 ≥ 60 ≥ 260 30
solution annealed 1 and
≥ 300 ≥ 460 12
precipitation hardened R460
CuNi2Si solution annealed and ≤ 10 ≥ 260 ≥ 380 6
cold formed R380
solution annealed,
cold formed and ≥ 480 ≥ 600 8
precipitation hardened R600
1 Without former annealing, cold forming is not possible.

8.3 Formability Table 2.3 Test batches


With the exception of pipes made of copper Cu-DHP
in condition R290 and CuNi2Si in condition R460, all Test batch No. of specimens for
pipes shall be capable of being cold formed with the [kg] testing according to
degrees of deformation customary in workshop prac- 9.3 to 9.8
over up to
tice, e.g by bending and expansion.
500 1 each
8.4 Absence of stresses
500 1000 2 each
Pipes made of copper zinc alloys shall be free from
stresses liable to cause stress cracks. 1000 2000 3 each

8.5 Resistance to hydrogen embrittlement 2000 3000 4 each


Copper pipes may not become brittle due to the effect each subsequent 1000 1 more each
of hydrogenous gases and elevated temperatures such
as occur, for example, in gas welding, soldering and
hot forming. same material, and are in the same condition and of
the same thickness. It is not necessary for a test batch
8.6 Grain size to originate from a single heat or heat treatment.
The average grain diameter of the materials specified
Where 2 or more test specimens are required, they
in Table 2.2 in the conditions mentioned in the Table
shall be taken from different pipes in the test batch.
shall be between 0,01 and 0,05 mm. An exception is
material Cu-DHP in condition R290. If pipes are supplied in rings, a test specimen shall be
taken from every fifth ring; if there are less than five
9. Testing rings, however, at least one specimen shall be taken.
9.1 For the purpose of testing, the pipes shall be
grouped into test batches in accordance with Table 9.2 Test of chemical composition
2.3.
The manufacturer shall determine the chemical com-
A test batch shall comprise pipes which have been position of each manufacturing batch and pass this
manufactured by the same method, are made of the information on to the Surveyor.
Chapter 3 Section 2 A Copper Alloys II - Part 1
Page 2–4 GL 2009

Table 2.4 Limiting sizes for the diameter

Diameter (nominal) Limiting size for the diameter


[mm] [mm]
applicable to every diameter
applicable to the
over up to including ovality in case
average diameter
of linear lengths 1, 2
33 10 ± 0,06 ± 0,12
10 20 ± 0,08 ± 0,16
20 30 ± 0,12 ± 0,24
30 50 ± 0,15 ± 0,30
50 100 ± 0,20 ± 0,50
100 200 ± 0,50 ± 1,0
200 300 ± 0,75 ± 1,5
300 450 ± 1,0 ± 2,0
1 The limiting sizes in this column are not applicable for:
– coiled pipes (limiting sizes for coiled pipes, see Table 2.8)
– pipes with OD/t > 50 (OD = outside diameter, t = wall thickness)
– pipes in annealed condition
2 If not otherwise agreed, the outside diameter sizes in way of the pipe ends, i.e. within a distance of 100 mm or one time the nominal
outside diameter whichever is the lesser, may be increased by a factor of 3.
3 Including 3.

Table 2.5 Limiting sizes for the wall thickness

Outside diameter (nominal) Limiting sizes for the wall thickness t (nominal)
[mm] [%]
from 0,3 mm over 1 mm over 3 mm over 6 mm
over up to over 10 mm
up to 1 mm up to 3 mm up to 6 mm up to 10 mm
31 40 ± 15 ± 13 ± 11 ± 10 ––
40 120 ± 15 ± 13 ± 12 ± 11 ± 10
120 250 –– ± 13 ± 13 ± 12 ± 11
250 450 –– –– ± 15 ± 15 ± 15
1 Including 3.

Table 2.6 Limiting sizes for fixed lengths of linear pipes

Outside diameter (nominal) Limiting sizes for fixed lengths


[mm] [mm]
over 250 over 1000
over up to up to 250 up to 1000 up to 4000 over 4000

+1 +3 + 5
31 25
0 0 0
+2 +5 + 7 upon
25 100
0 0 0 agreement
+3 +5 + 10
100 450
0 0 0
1 Including 3.
II - Part 1 Section 2 A Copper Alloys Chapter 3
GL 2009 Page 2–5

Table 2.7 Limiting sizes for fixed lengths of coiled pipes (non-helical coiled)

Nominal length [m] Deviation limit [%]

+2
up to 50
0
over 50 +3
up to 100 0
+2
over 100
0

Table 2.8 Limiting sizes for the diameter including ovality of coiled pipes

Outside diameter (nominal) Limiting sizes for the Applicable for the
[mm] nominal diameter inner ring diameter of
including ovality
over up to [mm] [mm]
31 6 ± 0,30 400
6 10 ± 0,50 600
10 20 ± 0,70 800
20 30 ± 0,90 1000
1 Including 3.

Table 2.9 Straightness tolerance

Ratio of outside diameter/ wall thickness Depth 1 [mm]


h1 h2
over up to per 1000 mm length A1 per 400 mm length A2
max. max.
–– 5 2 0,8
5 10 3 1,2
10 20 4 1,6
20 40 5 2,0
40 –– 6 2,5
1 See Fig. 2.1

2=
400 ter on at least one specimen from each test batch ac-
cording to ISO 2624.
h2
9.4 Tensile test
h1
Pipes shall be subjected to tensile test to determine the
1 = 1000 tensile strength, the 0,2 % proof stress and the elonga-
tion.
Fig. 2.1 Measuring of straightness
9.5 Ring flattening test
9.3 Determination of grain size Pipes shall be submitted to the ring flattening test.
In the case of condenser and heat exchanger tubes, the The test specimens shall be flattened until the inner
manufacturer shall determine the average grain diame- surfaces touch. This shall not cause cracks visible to
Chapter 3 Section 2 A Copper Alloys II - Part 1
Page 2–6 GL 2009

the eye. Cu-DHP copper pipes in condition R290 are 2 ⋅ S ⋅ t


to be annealed before testing. CuNi2Si-pipes are to be P =
D
solution annealed beforehand.
P = inner water pressure
9.6 Expanding test
t = wall thickness (nominal) of the pipe
Pipes with an outside diameter of up to 76 mm shall
be subjected to the expanding test using a drift with a D = outer diameter (nominal) of the pipe
45° taper. The expansion shall equal at least 30 % of
the original inside diameter and no cracks may appear. S = half of the minimum value for the 0,2 %
Cu-DHP copper pipes in condition R290 are annealed proof stress
before testing. CuNi2Si-pipes have to be in the solu- The pipes need not to be tested with a water pressure
tion annealed condition. above 6,9 MPa, if not otherweise agreed.

9.7 Testing for absence of internal stresses 9.11 Retests in the event of failure
(CuZn pipes)
If the required values are not met in the mechanical
The manufacturer shall prove that CuZn alloy pipes and technological tests, then, before the manufacturing
are free from internal stresses by carrying out the batch is rejected, the procedures for retests prescribed
ammonia test according to DIN 50916 or ISO 6957 in Chapter 1 – Principles and Test Procedures, Sec-
and shall then present the specimens to the Surveyor. tion 2, H. may be applied.
At the express request of the purchaser, this test may
be replaced by the mercurous nitrate test according to
ISO 196. 10. Marking
Should a specimen reveal cracks when tested, the 10.1 The following marks shall be applied by the
manufacturing batch shall be rejected. The manufac- manufacturer to each pipe with an outside diameter
turer shall be free to submit the batch to renewed heat
≥ 25 mm using an indelible and weatherproof dye:
treatment before presenting it for retesting.
– manufacturer's mark
9.8 Test of resistance to hydrogen embrittle-
ment (Cu pipes) – designation of material or material number

For this purpose, pipe specimens 10 to 20 mm in – test batch number or another mark enabling the
length shall be annealed for 30 minutes at 800 to pipe to be clearly identified
850 °C in a reducing atmosphere (hydrogen or fuel
In the case of pipes with an outside diameter < 25 mm,
gas), cooled and flattened between two parallel plates
the marking shall be in a form which enables the pipe
until the inner surfaces touch. In the case of thick-
to be matched up with the test certificate.
walled and large-diameter pipes, flattening test speci-
mens may comprise approx. 10 mm wide strips taken
from the sample pipe. The points of folding shall nei- 10.2 Where pipes are supplied in bundles or
ther reveal cracks nor fracture. packed in crates, the marks specified in 10.1 may be
affixed by means of securely fastened tags or labels;
9.9 Test of surface finish and dimensions however, pipes with an outside diameter ≥ 25 mm
shall be marked individually.
The manufacturer shall inspect the finish of the inner
and outer surfaces of every pipe and shall also check
11. Certificates issued by the manufacturers
the diameters and wall thicknesses. The pipes shall
then be submitted to the Surveyor for final inspection. For each consignment the manufacturer shall supply to
the Surveyor a certificate giving the following details:
9.10 Tightness test
– purchaser and order number
The manufacturer shall subject all pipes to a tightness
test. – number, size and weight of pipes

Preferably, this shall be done by applying an eddy- – material designation


current test carried out in accordance with a recog- – test batch number or identification mark
nized standard (e.g. EN 1971) or test specification.
Instead of the eddy-current test, another equivalent – results of the analysis, of the mechanical and
non-destructive test method may be agreed, or a hy- technological tests, the tightness test and, if
draulic pressure test shall be performed. Each pipe is specified for the type of pipe concerned or spe-
to be subjected for at least 5 s to an inner water pres- cially stipulated, of the tests to determine ab-
sure, which shall be calculated according to the fol- sence of internal stresses, resistance to hydrogen
lowing formula: embrittlement and average grain size
II - Part 1 Section 2 B Copper Alloys Chapter 3
GL 2009 Page 2–7

12. Copper and wrought copper alloy fittings B. Cast Copper Alloys

12.1 Scope 1. Scope

These Rules are applicable to saddles, T-shaped fit- These Rules are applicable to cast copper alloys for
tings, tapered transition pieces and pipe elbows. Fit- the manufacture of valve and pump housings, shaft
tings conforming to recognized standards shall be liners, bushes and similar parts.
used.
2. Requirements to be met by foundries
12.2 Approval Foundries wishing to supply products in accordance
with these Rules shall be approved by GL, see Chapter
Fitting manufacturers shall prove the suitability of 1 – Principles and Test Procedures, Section 1, C.
their products as an initial measure by means of an
approval test. The scope of testing is determined by
the relevant standards, e.g. DIN 86086 to DIN 86090 3. Manufacture
for fittings manufactured from pipes by cold or hot The method of manufacture shall be chosen to suit the
forming. For welded fittings the testing scope will be shape of the casting. Sand casting, chill casting, cen-
stipulated by GL. trifugal casting and continuous casting may be used.
Castings may be supplied in the as cast or heat-treated
12.3 Properties condition at the manufacturer's option unless this is
specified in the order.
The chemical composition and mechanical properties
of the fittings shall correspond to those of the grades 4. Suitable grades of cast alloy
of pipe used for their manufacture.
The grades of cast alloy shall be suitable for the in-
tended application. Subject to these conditions, the
12.4 Testing following grades may be used.
If testing is required under the GL Rules for Construc-
4.1 Grades stated in Table 2.10 for applications
tion, the procedure shall be as follows:
exposed to sea water.

12.4.1 The manufacturer shall furnish proof of the 4.2 Grades conforming to other standards or
chemical composition of the starting materials by specifications, provided that their suitability has been
means of certificates issued by the manufacturer of the confirmed by GL.
starting material.
5. Characteristics of castings
12.4.2 For testing, the fittings shall be grouped into
test batches. A test batch shall comprise units of the
5.1 All castings shall be supplied in a clean fet-
same shape and size, made of the same grade of mate-
tled condition. They shall be free from shrinkage cavi-
rial in the same condition and produced in a single
ties, pores, blow holes, cracks, inclusions and other
manufacturing cycle. Two specimens shall be taken
defects which impair their use and the further course
from each test batch for the following tests:
of manufacture.
– tensile test, where the nominal bore is 100 mm Small surface defects may be removed by grinding
or over provided that the dimensional tolerances are not ex-
ceeded.
– ring flattening test
5.2 Where defects are to be repaired by welding,
– test for absence of internal stresses where fit-
the details of the process shall be submitted to the
tings are made of CuZn alloys
Surveyor for approval before the repair work begins
and he shall be notified of the location, nature and
Where the number of units is 10 or less, one test
extent of the defects. Bearing bushes and liners of cast
specimen is sufficient.
CuPbSn alloys may not be welded. Welds aimed
The manufacturer shall inspect the fittings for their solely at improving the appearance of the casting are
dimensional accuracy and surface finish. unacceptable.

6. Dimensional and geometrical tolerances


12.5 Marking and certification
The dimensional and geometrical tolerances shall be
The marking and the certification of the characteristics those specified in the relevant standards. The stan-
of the material are subject, in analogous manner, to the dards shall be stated in the order and made known to
provisions of 10. and 11. the Surveyor.
Chapter 3 Section 2 B Copper Alloys II - Part 1
Page 2–8 GL 2009

7. Resistance to leakage 9.3 Test of surface finish and dimensions


Castings subjected to internal pressure by the operating The manufacturer shall inspect each casting with re-
medium shall be tight at the prescribed test pressure. gard to its surface finish and compliance with the
dimensional and geometrical tolerances, after which
8. Requirements applicable to the material the casting shall be presented to the Surveyor for final
inspection.
The chemical composition and mechanical properties
shall conform to Table 2.10 and 2.11, the relevant 9.4 Tightness test
standards or the approved specifications.
Where this is called for in the Rules for Construction,
the castings shall be subjected to a hydraulic pressure
9. Testing and scope of tests test in the presence of the Surveyor. Shaft liners shall
The following tests are to be performed: be tested at a pressure of at least 2 bar. For all other
components the test pressure is normally 1.5 times the
9.1 Test of chemical composition operating pressure.
The manufacturer shall determine the chemical com-
position of each heat and issue a relevant certificate. 10. Identification and marking

Where castings are made of remelting ingots of starting 10.1 The manufacturer shall employ a monitoring
material of the same grade without further additions to system which enables all castings to be traced back to
the heat, the certificate of the manufacturer of the start- their heat. On request, the Surveyor shall be given
ing material can be accepted as proof of the chemical proof of this.
composition. Minor additions to compensate for melting
losses may be disregarded. In case of doubt the compo- 10.2 Prior to final inspection by the Surveyor,
sition shall be determined by analyzing the casting. each casting shall be marked by the manufacturer as
follows:
9.2 Tensile test
– manufacturer's mark
For this purpose a specimen shall be taken from each
heat and subjected to test. If the weight of the heat – short designation of the alloy
exceeds 1000 kg, a second test specimen is required.
– charge number or a code marking enabling the
The specimens shall be taken as follows:
manufacturing process to be traced back
9.2.1 In the case of sand and chill casting, the – specimen number
specimens shall be taken from integrally cast sample
bars or from separately cast sample pieces. Separately – date of test
cast sample pieces shall have the dimensions shown in – test pressure, where applicable
Fig. 2.2, shall originate from the same heat and shall
be cast using the same mould material. At the request of the Surveyor, the test certificate
number shall also be stamped on. In the case of small
9.2.2 In the case of centrifugal and continuous castings produced in series, e.g. valve housings, the
casting, the specimen shall be taken from the cast part. marking shall be in a form which enables the casing to
be matched up with the test certificate.
9.2.3 Where castings are supplied in the heat-
treated condition, the test specimen shall be subjected
to the same heat treatment. 11. Test certificates
For each consignment the manufacturer shall supply to
» 50 ³ 150 the Surveyor a test certificate or delivery specification
containing the following details:
– purchaser and order number
– number and weight of the castings
» 100

– designation of the material and condition in


which supplied
– composition of the heat (or of the starting mate-
rial, where applicable)

» 15 – method of manufacture
25 – results of mechanical tests if performed by the
manufacturer
Fig. 2.2 Sample piece – test pressure, where applicable
GL 2009
II - Part 1

Table 2.10

Material designation Composition [%]


Section 2

GL-Material Material no. / code


Element Al B Bi C Cd Cr Cu Fe Mg Mn Nb Ni P Pb S Sb Se Si Sn Te Zn
code acc. to EN 1982
B

CC333G/ min. 8,5 ⎯ ⎯ 76,0 4,0 ⎯ ⎯ 4,0 ⎯ ⎯ ⎯ ⎯


G-CuAl10Ni
CuAl10Fe5Ni5-C max. 10,5 0,01 0,05 83,0 5,5 0,05 3,0 6,0 0,03 0,10 0,1 0,5

CC334G/ min. 10,0 72,0 4,0 ⎯ ⎯ 4,0 ⎯ ⎯ ⎯ ⎯


G-CuAl11Ni
CuAl11Fe6Ni6-C max. 12,0 78,0 7,0 0,05 2,5 7,5 0,05 0,10 0,2 0,5
Suitable cast copper alloys

CC380H/ min. ⎯ ⎯ 84,5 1,0 1,0 ⎯ 9,0 ⎯ ⎯ ⎯


G-CuNi10
CuNi10Fe1Mn1-C max. 0,01 0,10 ⎯ 1,8 1,5 1,0 11,0 0,03 0,10 0,5
Copper Alloys

CC383H/ min. ⎯ ⎯ ⎯ ⎯ ⎯ 0,5 ⎯ 0,6 0,5 29,0 ⎯ ⎯ ⎯ ⎯ 0,30 ⎯ ⎯


G-CuNi30
CuNi30Fe1Mn1NbSi-C max. 0,01 0,01 0,01 0,03 0,02 1,5 0,01 1,2 1,0 31,0 0,01 0,01 0,01 0,01 0,70 0,01 0,5

CC480K/ min. ⎯ 88,0 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ 9,0 ⎯


G-CuSn10
CuSn10-C max. 0,01 90,0 0,2 0,1 0,2 0,20 1,0 0,05 0,2 0,02 11,0 0,5

CC483K/ min. ⎯ 85,0 ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ ⎯ 11,0 ⎯


G-CuSn12
CuSn12-C max. 0,01 88,5 0,2 0,2 0,2 0,60 0,7 0,05 0,15 0,01 13,0 0,5

CC484K/ min. ⎯ 84,5 ⎯ ⎯ 1,5 0,05 ⎯ ⎯ ⎯ ⎯ 11,0 ⎯


G-CuSn12Ni
CuSn12Ni2-C max. 0,01 87,5 0,2 0,2 2,5 0,40 0,3 0,05 0,1 0,01 13,0 0,4

CC491K/ min. ⎯ 83,0 ⎯ ⎯ ⎯ 4,0 ⎯ ⎯ ⎯ 4,0 4,0


G-CuSn5ZnPb
CuSn5Zn5Pb5-C max. 0,01 87,0 0,3 0,2 0,10 6,0 0,10 0,25 0,01 6,0 6,0

CC491K/ min. ⎯ 81,0 ⎯ ⎯ ⎯ 5,0 ⎯ ⎯ ⎯ 6,0 2,0


G-CuSn7ZnPb
CuSn7Zn4Pb7-C max. 0,01 85,0 0,2 2,0 0,10 8,0 0,10 0,3 0,01 8,0 5,0
Page 2–9
Chapter 3
Chapter 3 Section 2 B Copper Alloys II - Part 1
Page 2–10 GL 2009

Table 2.11 Mechanical properties of cast copper alloys

Proof stress Tensile strength Elongation Hardness


GL- Condition of Rp0,2 Rm A HB 10
Material code supply [N/mm2] [N/mm2] [%]
min. min. min. min.
sand cast 130 270 18 70
permanent mould cast 160 270 10 80
G-CuSn10
centrifugally cast 160 270 10 80
continuously cast 170 280 10 80
sand cast 120 240 15 65
permanent mould cast 120 230 12 60
G-CuSn7ZnPb
centrifugally cast 130 270 13 75
continuously cast 130 270 16 70
sand cast 90 240 18 60
permanent mould cast 110 220 8 65
G-CuSn5ZnPb
centrifugally cast 110 250 13 65
continuously cast 110 250 13 65
sand cast 140 260 12 60
permanent mould cast 150 270 5 65
G-CuSn12
centrifugally cast 150 280 8 65
continuously cast 150 300 6 65
sand cast 160 280 14 90
G-CuSn12Ni centrifugally cast 180 300 8 100
continuously cast 180 300 10 95
sand cast 270 600 13 140
permanent mould cast 300 650 10 150
G-CuAl10Ni
centrifugally cast 300 700 13 160
continuously cast 300 700 13 160
sand cast 320 680 5 170
G-CuAl11Ni permanent mould cast 400 750 5 200
centrifugally cast 400 750 5 185
sand cast 150 310 20 100
G-CuNi10 centrifugally cast 100 280 25 70
continuously cast 100 280 25 70
G-CuNi30 sand cast 230 440 18 115

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