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BS-EN-ISO-14644-13-2017
BS-EN-ISO-14644-13-2017
National foreword
This British Standard is the UK implementation of EN ISO 14644-13:2017 .
ICS 13.040.35
English Version
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
© 2017 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN ISO 14644-13:2017 E
worldwide for CEN national Members.
BS EN ISO 14644‑13:2017
EN ISO 14644-13:2017 (E)
European foreword
This document (EN ISO 14644-13:2017) has been prepared by Technical Committee ISO/TC 209
“Cleanrooms and associated controlled environments” in collaboration with Technical Committee
CEN/TC 243 “Cleanroom technology” the secretariat of which is held by BSI.
This European Standard shall be given the status of a national standard, either by publication of an
identical text or by endorsement, at the latest by February 2018 and conflicting national standards shall
be withdrawn at the latest by February 2018.
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. CEN shall not be held responsible for identifying any or all such patent rights.
According to the CEN-CENELEC Internal Regulations, the national standards organizations of the
following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria,
Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,
France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,
Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and the United Kingdom.
Endorsement notice
The text of ISO 14644-13:2017 has been approved by CEN as EN ISO 14644-13:2017 without any
modification.
3
BS EN ISO 14644‑13:2017
ISO 1 4644-1 3 : 2 01 7(E)
Foreword
I S O (the I nternational O rgani zation for Standardi zation) is a worldwide federation of national s tandards
bodies (ISO member bodies). The work of preparing International Standards is normally carried out
through ISO technical committees. Each member body interested in a subject for which a technical
committee has b een es tabli shed has the right to b e represented on that committee. I nternational
organi z ations , governmental and non- governmental, in l iaison with I SO, al so take p ar t in the work.
ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of
elec trotechnical s tandardiz ation .
T he pro cedures used to develop this do cument and those intended for its fur ther maintenance are
describ ed in the I SO/I EC D irec tives , Par t 1 . I n p ar ticular the different approval criteria needed for the
different types of ISO documents should be noted. This document was drafted in accordance with the
editorial rules of the I SO/I EC D irec tives , Par t 2 (see www. iso . org/direc tives) .
Attention is drawn to the possibility that some of the elements of this document may be the subject of
patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of
any patent rights identi fied during the development of the document will be in the Introduction and/or
on the I SO l is t of p atent declarations received (see www. iso . org/p atents) .
Any trade name used in this document is information given for the convenience of users and does not
cons titute an endors ement.
For an explanation on the voluntary nature of standards, the meaning of ISO speci fic terms and
expressions related to conformity assessment, as well as information about ISO’s adherence to the
World Trade O rgani zation ( WTO) principles in the Technical B arriers to Trade ( TB T ) see the fol lowing
This document was prepared by Technical Committee ISO/TC 209, Cleanrooms and associated controlled
environments.
A lis t of al l p ar ts in the I SO 146 4 4 series can b e found on the I S O webs ite.
Introduction
T he term s urface refers to the interface b etween two phases . For the purp os e of this do cument, the
s urface is a sol id. A “clean s urface” is where one or more of the contamination categories (p ar ticles ,
chemical) are under control due to cleaning/decontamination. The degree of cleanliness is speci fied
in the corresponding surface cleanliness classi fications (see ISO 14644-9 and ISO 14644-10). Different
cleaning methods are necessary depending on the degree of cleanliness (cleanliness class) required.
This document gives guidance on the selection of cleaning methods to achieve speci fied cleanliness
levels. For the selection procedure, the aspects of surface description, cleanliness speci fications, types
of contamination, cleaning techniques, material compatibility, and assessment methodology are taken
into cons ideration . Mos t of the metho ds are s uitable for removal of more than one contam ination
category at the same time; therefore, a common standard for the selection of a cleaning method for both
p ar ticles , as wel l as chemical contamination, is needed.
Part 1 3 :
Cleaning of surfaces to achieve de fined levels of cleanliness
in terms of particle and chemical classi fications
1 Scope
This document gives guidelines for cleaning to a speci fied degree on cleanroom surfaces, surfaces of
equipment in a cleanroom and s urfaces of material s in a cleanroom . Under cons ideration are al l s urfaces
(external or internal) that are of interes t. I t provides guidance on the as ses s ment of cleaning methods
for achieving the required surface cleanliness by particle concentration (SCP) and surface cleanliness
by chemical concentration (SCC) classes and which techniques should be considered to achieve these
speci fied levels.
T he appropriatenes s of cleaning techniques wi l l make reference to the clean l ines s clas ses and
2 Normative references
The following documents are referred to in the text in such a way that some or all of their content
constitutes requirements of this document. For dated references, only the edition cited applies. For
undated references, the latest edition of the referenced document (including any amendments) applies.
Cleanrooms and associated controlled environments — Part 8: Classification ofair cleanliness
I SO 146 4 4 - 8 ,
For the purposes of this document, the terms and de finitions given in ISO 14644-9, ISO 14644-10 and
the following apply.
I SO and I E C maintain terminological datab ases for us e in s tandardiz ation at the fol lowing addres ses:
— I E C E lec trop edia: avai lable at http:// www. elec trop edia . org/
— I SO O n l ine brows ing platform: avai lable at http:// www. iso . org/obp
3 .1
cleanliness
< of a solid s urface> condition of a solid s urface where the amount of contamin ation (3 .4) (p ar ticle,
conditions
Note 1 to entry: In some languages, the term cleaning efficacy is used to indicate cleaning appropriateness.
Note 2 to entry: In case of real operational conditions or monitoring, the term cleaning effectiveness is used.
3.3
cleaning efficiency
3 .4
contamination
unwanted matter in an undes irable lo cation
3.5
particle
minute piece of matter with de fined physical boundaries
[SOURC E: I SO 146 4 4 -1 : 2 01 5 , 3 . 2 .1]
3 .6
particle contamination
particles (3 . 5 ) having the p otential to affec t the proces s , the pro duc t, the p ersonnel or the facil ities
3 .7
particle size
diameter of a sphere that produces a response, by a given particle-sizing instrument, that is equivalent
to the response produced by the particle (3 . 5 ) b eing meas ured
4 General methodology
4.1 Overview
Multiple as p ec ts need to b e cons idered for cleaning. Figure 1 provides an over view of the fac tors that
contribute to the suitability of cleaning methods to achieve a de fined level of surface cleanliness. For
more detai ls , see Annex A.
Key
4.2 Methodology
Appropriateness of a cleaning technique for an application depends on many factors. For complex
objects, it is advised to follow the sequence described in this clause and in the decision tree (see
Figure 2 ). By using this procedure, it can be assured that all important issues are covered. For simple
objects or surfaces, deviations from the sequence are allowable, as long as the critical information is
do cumented.
The approach starts with describing the object that has to be cleaned. The description should cover,
among others, composition of materials, chemical characteristics, surface finish and shape factors like
geometrical complexity and size (step 1). In the second step, the objective of the cleaning procedure
is to be speci fied in terms of the desired cleanliness of the object. To have a starting point, the initial
contamination level should b e as ses s ed (s tep 3 ) and other requirements shal l b e lis ted (s tep 4) . B ased
on type of contaminants and the required removal efficiency, a cleaning technique or a combination of
techniques can be selected (step 5). The cleaning methodology shall be checked against the materials
from the first step in order to avoid material compatibility issues (step 6). At the last step, a validation
metho d shal l b e carried out (s tep 7 ) . T he validation shal l at leas t comprise methods for determination of
the cleaning performance and material compatibility. The performance of the cleaning shall be checked
against the speci fication.
— physical dimensions;
— form/shape/complexity of the object;
— critical s urfaces .
A general description of the object shall be given. Size, shape, complexity and identi fication of the
critical surfaces set many boundary conditions for a cleaning method.
Surface(s) :
shou ld b e taken into account when cho os ing a cleaning method. S ome combinations of materials can
be very difficult to clean as one cleaning method may be suitable for one material but not the other.
T he selec tion of the cleaning metho d shal l b e the b es t compromise b etween minimal damage of the
— chemical composition;
— state of the surface (hydrophobic, hydrophilic, lypophobic, lipophilic, etc.);
— energetic s tate of the s urface (zeta p otential) .
Physical and chemical properties of a surface have a large in fluence on the choice of a cleaning method.
C hoice of a metho d shal l take into account al l involved material s/chemical comp os ition of the s urface(s)
The activity of the surface is determined by the chemical con figuration of the final atomic layer. This is
an important parameter in determining the choice of method. These layers may be hydrophilic (water
wettable-lipophobic) or hydrophobic (water repellent but oil-wettable-lipophilic). The cleaning method
used can in fluence the surface activity. The surface activity also in fluences the electrostatic properties
of a material — a hydrophilic surface will have fewer tendencies to electrically charge.
Morphology:
Cleaning is in fluenced by the morphological aspects of a surface such as shape, size, structure, surface
roughness or porosity. Morphological aspects may further complicate cleaning due to the accessibility
of the s urfaces to b e cleaned and to the retention of cleaning agents and material s used for cleaning.
of concern, as wel l as accep table level s of contamination for the appl ication .
The required cleanliness shall be speci fied in terms of particle concentration according to ISO 14644-9
and/or in terms of the concentration of a speci fic group of chemicals according to ISO 14644-10.
The speci fication of the targeted cleanliness class can be determined in various ways:
— cleanliness class required by customer;
— common cleanliness class required for similar objects;
— by performing an analysis on the impact of contamination of the surface in the (future) function of
a product or process where the cleaned surface will be used;
— by performing tests or simulations with various cleanliness classes of the considered surface and/or;
— by performing an analysis of the contamination that caused failure or quality loss.
7.1 General
To selec t the cleaning pro cedure for achieving a required s urface clean l ines s level, the initial s urface
cleanliness shall be established. The initial surface cleanliness by chemical and/or particle concentration
shall be determined for the surfaces of interest. This can be determined qualitatively or quantitatively.
Qualitative evaluation is a non-numerical as ses s ment (e. g. a vis ual ins p ec tion) .
Where the quantitative surface cleanliness is determined, it can be related to the efficiency of the
cleaning procedure in respect to the required surface cleanliness by particle concentration and/or
chemical concentration. The quanti fied contamination (particle and/or chemical) shall be related to the
area of the representative s urface. T his evaluation al lows determination of the initial clean l ines s clas s .
The initial surface cleanliness by particle concentration shall be determined for the different surfaces.
D ep ending on the required clean lines s clas s , a qualitative as ses s ment of the initial clean lines s level
may be sufficient. For quantitative assessment, the number and size of particles shall be characterized
by a measurement method as described in C lause 1 2 . The surface cleanliness classi fication as outlined
in I S O 146 4 4 -9 shal l b e applied.
The quanti fied particle concentration shall be related to the area of the representative surface. This
evaluation al lows determination of the initial clean l ines s clas s .
The initial surface cleanliness by chemical concentration shall be determined for the different surfaces.
Depending on the speci fic application, a qualitative assessment (e.g. water break test) of the initial
cleanliness level might be sufficient. For quantitative assessment of the mass and nature of the chemical
contaminants , a meas urement technique according to C lause 1 2 and I SO 146 4 4 -10 shal l b e appl icable.
The quanti fied chemical contamination shall be related to the area of the representative surface. This
evaluation al lows determination of the initial clean lines s clas s .
8 Other requirements
In addition to requirements for cleaning appropriateness and product integrity, many other elements
in fluence the applicability of the cleaning method. In step 5 of the decision tree (see Figure 2 ) , thes e
other aspects shall be listed and requirements shall be de fined. The contents of these requirements are
strongly related to the object or surface and its application.
Typical examples for other requirements are time available for cleaning, number of items that
wi l l b e cleaned, avai lable footprint, was te, inves tment and lab our cos ts , level of op erator skil l and
environmental as p ec ts .
Requirements for cleaning are de fined in C lause 5 to C lause 8 . T hes e requirements shal l b e cons idered
during the selection process for the cleaning methodology to ensure the greatest uniformity between
the requirements and the metho d.
The final decision of the choice of cleaning methodology shall be based on a combination of all aspects to
find the technically and financially optimal, most efficient solution. The customer, the clean technology
supplier and the process owner of the surface/object/component to be cleaned should be involved in
this selection process. The decision optimizes the various parameters and shall assure speci fied surface
quality. Table B .1 and Table B . 2 can aid the s elec tion pro ces s .
A cleaning methodology consists of a cleaning technique (e.g. wiping, plasma cleaning and ultrasonic
cleaning) and a cleaning proces s . T he cleaning pro ces s is lin ked to the cleaning techniques and involves
the amount of mechanical energy, chemical energy, temperature and process time. By using a balanced
combination of these four proces s p arameters , the op timum cleaning res ult can b e achieved. Final
cleanliness can be limited by substrate damage and/or selection criteria de fined in C lause 8 .
T he required cleanl ines s level and the initial clean lines s level in p ar ticle and/or chemical concentration
lead to a selec tion of cleaning metho ds . I n cas e the initial clean lines s clas s is high and the required
The cleaning techniques can be divided depending on the major cleaning mechanism into physical and
chemical cleaning which additionally could be divided into wet and dry cleaning techniques. Whether
a process is categorized as physical/chemical or as wet/dry depends on the dominant mechanism used
for the cleaning. A non-exhaustive list of physical cleaning techniques can be found in B . 2 (mechanical
cleaning) , B . 3 (f luidic cleaning), and B .4 ( blas ting cleaning techniques) . A l is t of chemical cleaning
techniques can b e found in B . 5 (chem ical cleaning) . References to the categories of cleaning techniques
T he numb ers refer to s ub clauses within Annex B that provide a brief description of the major cleaning
techniques .
Table B .1 and Table B . 2 support the choice of an appropriate cleaning technique (physical/chemical)
that ful fils the cleanliness speci fications. With the help of feasibility tests on material compatibility (see
C lause 10) and empirical values/evaluation, the b es t s uitable technique shal l b e chos en for validation
In Table B .1 and Table B.2 , an over view is given on the working ranges for di fferent cleaning
techniques . I n these ranges , op timum pro ces s conditions are as s umed. Since material prop er ties and
other requirements might force use of less than optimal conditions, the actual cleaning efficiency
and appropriateness might be lower. The process settings shall be de fined either by an experimental
inves tigation or from exp erience.
The compatibility of materials with cleaning agents shall be considered. These cleaning agents (e.g.
chemicals, solvents, high pressure gas or liquid) shall be selected with respect to their compatibility with
the materials or items to be cleaned and their efficiency in removing different kinds of contaminants:
p ar ticle or chemical contaminants .
Detrimental effects on surfaces can be caused by the cleaning agents and/or the cleaning technique.
The chemical nature of the materials of the surface — individually or in combination depending on the
composition of the surface — should be evaluated technically.
T he fol lowing describ es s uch direc t, indirec t and long duration effec ts .
— Direct effects are changes of intrinsic material properties (physical and/or chemical) as a
consequence of the interac tion with a pro ces s p arameter from the cleaning technique: chemical
EXAMPLE 1 The change of the chemical surface structure may strongly change the physical
behaviour. Change of the hydrophilic character of the last atomic layer to hydrophobic through the cleaning
process may change the physical behaviour of the cleaned surface, i.e. wettability and electrostatic charge.
Hydrophobic surface is not wettable and is easily charged which may attract particles.
— Long duration effec ts res u lt from a slow proces s (e. g. induced corro s ion from chemical convers ion
Annex C gives an overview of compatibility with chemical solvents; it is a non-exhaustive list. In the
case of a lack of information for a speci fic cleaning solvent, the chemical resistance of the material shall
b e as ses s ed through an appropriate tes t.
1 1 Cleaning validation
1 1 .1 General
To assess the suitability of a selected cleaning procedure, the cleaning efficiency and the cleaning
appropriatenes s shou ld b e cons idered.
For the validation of a cleaning pro ces s to reach the required s urface clean lines s with res p ec t to
p ar ticle concentration and/or chemical concentration, the achieved s urface clean l ines s SC P and/or S CC
p erformance. Although these requirements are taken into account during the selec tion of the cleaning
method, the validation process shall verify that these requirements are ful filled.
Figure 3 and Figure 4 are depictions of the terms cleaning efficiency and cleaning appropriateness.
Cleaning efficiency = 1 − final cleanliness level/initial cleanliness level (expressed as a percentage)
Cleaning appropriateness = required cleanliness level/final cleanliness level
Figure 3 — E xample for a method with low cleaning efficiency leading to unsuitable cleaning
appropriateness
Figure 4 — E xample for a method with high cleaning efficiency leading to suitable cleaning
appropriateness
1 1 .2 .1 Evaluation
For evaluation of the cleaning efficiency, the initial surface cleanliness level and final cleanliness level
shal l b e determined.
ini
CSCP;
is the initial s urface concentration, in p articles p er square metre of s urface, of p articles that
D are equal to or larger than the cons idered p ar ticle s ize D in µm;
fin is the final surface concentration, in particles per square metre of surface, of particles that
CSCP; D are equal to or larger than the cons idered p ar ticle s ize D in µm .
In accordance with ISO 14644-9, the relation with the surface cleanliness class is given by Formu la (2 ) :
SCP; N
10
CSCP; D = k (2 )
D
where
CSCP; D i s the ma xi mu m p erm itte d to tal s u rface concentration, i n p ar ticles p er s quare metre of
surface, of particles that are equal to or larger than the considered particle size;
C ombining Formu la (1) and Formu la (2 ) gives the cleaning efficiency in terms of SCP, in Formu la (3 ) :
SCP; N fin
10
k
C eff = 1 − D = 1−
10
SCP; N fin
= 1 − 10
( SCP; N fin
− SCP; N ini ) (3 )
SCP; N ini SCP; N ini
10 10
k
D
where
SCP; Nfin is the SCP classi fication number of the final surface cleanliness of particles;
SCP; Ni n i is the SCP classi fication number of the initial surface cleanliness of particles.
NOTE The cleaning efficiency can also be expressed as a percentage (%).
E X AM PLE I n th i s example, the s ma l les t p ar ticle s i z e that cou ld b e me as ured with the appl ied me as urement
The initial surface cleanliness class number SCP; Ni n i = 6,5 for particles equal to or larger than 5 µm.
fin
After cleaning, the final concentration of particles ≥5 µm per m 2 C SCP; 5
is 1 000. T herefore, the
The final surface cleanliness class number SCP; Nfin = 3,7 for particles equal to or larger than 5 µm.
The cleaning efficiency in terms of particle concentration = 1 − (1 000)/(600 000) = 1 − 1/600 = 0,998 or 99,8 %
for particles ≥5 µm.
Similarly, the cleaning efficiency in respect to the SCP class numbers = 1 − 10 (3,7 − 6,5) = 1 – 10 -2 , 8 = 0,998 4 or
99,8 % for particles ≥5 µm.
According to ISO 14644-10, the relation with the surface cleanliness class by chemical concentration
(SCC) is given by Formu la (5 ) :
C SCC = 10 SCC; N (5 )
where
C ombining Formu la (4) and Formu la (5 ) gives the cleaning efficiency in terms of SCC, in Formula (6) :
SCC; N fin
10 ( SCC; N fin − SCC; N ini )
C eff = 1 − = 1 − 10 (6)
SCC; N ini
10
T herefore, the
(
SCC; N ini = lg 50 × 10
−3
)=− 1 ,3
for hydrocarbons.
T herefore, the
(
SCC; N fin = lg 10 × 10 �
−6
) =−
� 5 ,0 .
Similarly, the cleaning efficiency in respect to the SCC classes = 1 − 10 (−5,0 + 1,3) = 1 − 10 −3,7 = 0,999 8 or 99,98 %
for hydrocarbons.
1 1 .3 Cleaning appropriateness
1 1 .3 .1 Assessment
For evaluation of the cleaning appropriateness, the final cleanliness level obtained shall be determined
and comp ared to the required s urface clean l ines s .
According to ISO 14644-9, the relation with the surface cleanliness class is given by Formu la (8) :
10 SCP; N
CSCP; D = k (8)
D
where
C ombining Formu la (7 ) and Formu la (8) gives the cleaning appropriatenes s in terms of S C P clas s
C app =
10
SCP; N requ
= 10
(SCP; N requ
− SCP; N fin ) (9)
SCP; N fin
10
I f the cleaning appropriatenes s is les s than 1 , the chosen cleaning pro cedure was not s uitable.
I f the cleaning appropriatenes s is equal or greater than 1 , the chosen cleaning pro cedure was s uitable
E X AM PLE I n th i s example, the s ma l les t p ar ticle s i z e that cou ld b e me as ured with the appl ied me as urement
The required SCP; Nre qu = 4,0 for particles equal to or larger than 10 µm.
requ
T h i s me ans that C SCP; 10
(10 µm) = 10 000/10 µm = 1 000 particles/m².
fin
The final concentration of particles obtained ≥ 10 µm C SCP; 10
is 1 250 particles/m².
requ fin
Cleaning appropriateness = C SCP; 10
/C
SCP; 10
= 1 000/1 250 = 0,8 → 80 % for particles ≥10 µm.
I n term s of S C P:
(
SCP; N fin = lg 1 250 × 10 = 4 , 1 . )
The cleaning appropriateness = 10 (4,0 − 4,1) = 10 −0,1 = 0,8 or 80 %.
The cleaning appropriateness is the ratio of the required surface cleanliness by chemical concentration
under controlled conditions to the (final) chemical concentration after cleaning, given by Formu la (10) :
requ
CSCC
C app = (10)
fin
�
C SCC
where
requ is the required ma ximum concentration of the cons idered chemical (g/m 2 );
CSCC
fin is the final concentration of the considered chemical (g/m 2 ) .
CSCC
According to ISO 14644-10, the relation with the surface cleanliness class by chemical concentration
(SCC) is given by Formu la (11) :
where
C SCC is the maximum allowable concentration of the speci fied chemical substance or group of
s ub s tances , expres sed in g/m 2 ;
C ombining b oth Formu la (10) and Formu la (11) gives the cleaning appropriatenes s in term s of SCC , in
Formu la (1 2 ) :
C SCC
where
requ is the required ma ximum concentration of the cons idered chemical (g/m 2 );
CSCC
fin is the final concentration of the considered chemical (g/m 2 ) .
CSCC
I f the cleaning appropriatenes s is s mal ler than 1 , the chosen cleaning pro cedure was not appropriate.
I f the cleaning appropriatenes s is equal to or greater than 1 , the chos en cleaning procedure was
appropriate and res ults in a s urface at the required clean lines s clas s .
EXAMPLE The required SCC; Nre qu = −4,0 for hydrocarbons. SCC; Nre qu = 10 −4 g/m 2 = 100 µg/m 2 .
SCC; N requ = lg 70 × 10
�
( −6
)=− 4 , 15 .
1 2 Measurement methods
1 2 .1 General
T he p ar ticle concentration and/or concentration of chemical s on a cleaned s urface can b e meas ured in a
direct or indirect way. Direct surface cleanliness measurement may be appropriate in situations where
the surface is accessible. The surface under study shall be brought to the measurement instrumentation
or the ins trumentation shal l b e brought to the s urface.
T he area of the s urface selec ted for meas urement shal l b e b oth representative of the entire area b eing
as ses sed and the level p ar ticle and/or chemical contamination present.
T he selec ted s urface clean lines s meas urement metho d can b e appl ied to determine the initial and/or
1 2 .2 .1 General
A direc t meas urement method determines the s urface clean lines s with res p ec t to p ar ticle concentration
or chemical concentration on the surface of interest of the object that has been cleaned. The resulting
concentration of p ar ticles or the chemical of interes t shal l b e expres sed as either concentrations or
C ount the numb er of p ar ticles > D p er s urface area. For D, a set of different s ize bins (D i and D i+1 ) cou ld
b e selec ted. T he s mal les t s i ze D 1 shal l b e equal to or s mal ler than the p ar ticle s i ze of interes t.
By using a particular magni fication by a magnifying glass or (stereo) microscope, smaller particle sizes
can be counted, but the field of view will be also smaller. When the field of view is too small, the surface
may need to be scanned to measure a representative surface area. A representative area is determined
by the area that may contain at least 20 particles of the size of interest within the intended SCP class
[see Formula (1 3 ) ] .
D
A ≥ 20 × (1 3 )
10 SCP
Use a spectroscopic or advanced surface analysis technique to measure the chemical contamination of
interes t on the s urface.
In an enclosed heating or vacuum system, the SCC can be determined by measuring the outgassing of
the surface using mass spectroscopy and associated residual gas analysis techniques.
In some cases, a part of the surface could be removed from the object to fit into an advanced
measurement system.
1 2 .3 .1 General
An indirect method should be used when the surface to be measured cannot be reached by, is too small,
or too large for the available measurement system.
For this metho d, p ar ticles shou ld b e removed from the s urface into either another medium (air, l iquid)
The transfer efficiency shall be taken into account and will depend on the transfer method, particle size
and s urface prop er ties .
For particles suspended in a liquid or a gas, either a filtration method with subsequent microscopic
analysis or discrete particle counting method can be used. For transfer surfaces, a direct measurement
metho d can b e used.
C ount the numb er of p ar ticles > D p er s urface area. For D, a set of different s ize bins (D i and D i+1 ) cou ld
b e selec ted. T he s mal les t s i ze D 1 shal l b e equal to or s mal ler than the p ar ticle s i ze of interes t.
To determine the original s urface contam ination, the meas ured numb er of p ar ticles shou ld b e divided
To measure the concentration of chemicals of interest on the surface of an object, the chemicals can
be extracted by the chemical contamination being dissolved into a solvent. The solvent containing the
extracted chemicals can then be analysed by an appropriate chemical analysis technique. In a heating
or vacuum system, the chemical contaminants can be concentrated in a sorbent and measured by an
appropriate chemical analysis technique.
The transfer efficiency should be taken into account and depends on the transfer method, the chemicals
of interes t and the s urface prop er ties .
The mass of the chemicals of interest shall be divided by the surface area from which the chemicals are
removed to determine the original concentration .
1 3 Documentation
T he res u lts from each s tep in the decis ion tree (see Figure 2 ) shal l b e recorded and s ubmitted as a
comprehensive report, along with a statement of compliance or non-compliance with the speci fied
go al s , as describ ed in C lause 5 to C lause 1 2 . For simple cases, steps may be combined and reported in
one do cument.
ISO 14644-8 for classi fication air cleanliness by chemical concentration and ISO 14644-10 surface
cleanliness by chemical concentration;
g) the measuring instruments applied and proof of calibration;
h) the res u lts , either from as ses s ments/selec tion pro cedures or exp erimental res u lts . For the res ults
on cleaning val idation, the do cumentation requirements of I SO 146 4 4 -9 and I SO 146 4 4 - 8 and/or
NO TE I n the deci s ion tree (s ee Figu re 2 ) a s s es s ments , s ele c tion pro cedu res and exp eri mental s tud ies are
involved. Therefore, the text refers to executive organization and staff identi fication instead of the often used
terms testing organization and operator identi fication.
Annex A
(informative)
Aspects of cleaning
Annex B
(informative)
Cleaning methods
B.1 General
It is important to note that some cleaning methods are only for application outside the cleanroom for
pre- cleaning.
T he numb er of available techniques is extens ive. T his over view gives an indication of the avai lable
— mechanical cleaning;
— f luidic cleaning;
— chemical cleaning;
— blas ting cleaning techniques .
For all dry cleaning techniques, tribo-electrical effects may cause charging of the surface. Electrostatic
attraction plays an important role in the adhesion of dust particles to a product surface. In order to
el iminate this adhes ive force, an equal numb er of p os itive and negative ions can b e generated in ionized
air and transported to the surface of the product where they neutralize the electrostatically charged
dust particles and the surface itself. By neutralizing the surface particle re-deposition is avoided.
B.2 .1 Wiping
Principle: Soft, non-abrasive, non-cross contaminating materials can be utilized to remove lightly-
adhering contaminants (dust, dirty water, etc.). If a wiping process is performed using a cleaning fluid,
the chemical action of the cleaning agent is essentially responsible for the cleaning effect. In order to
detach and remove contam inants with a wip e or a s upp or ted wip e, the adhes ive forces b etween the
B.2 .2 Brushing/sweeping
Principle: The cleaning technique of brushing/sweeping is the purely mechanical wiping off or abrading
of generally solid contaminants from an object surface through the action of bristles. Brushes with soft
bristles made of plastic or natural fibres are used to remove easily-detachable contamination, such as
dust. For strongly-adhering contaminants such as oxides, scale or paint, stiffened, non-shedding bristles
may be utilized. All materials which are not damaged by the chosen brush or where a minimum degree
of surface abrasion is tolerated can be cleaned in this way.
Areas of application: Brushing/sweeping is frequently used to clean flat surfaces.
B.2 .3 Scraping/abrading
P rinciple: S craping or abrading is a mechanical sep aration technique in which adhering solids are lifted
up by a tool placed beneath them (e.g. blade or scraper) and then removed.
Areas of application: Scraping/abrading is implemented to remove strongly-adhering material residues
from essentially smooth surfaces.
B.2 .4 Grinding
Principle: Grinding is the removal of super ficial contamination by abrasion, where usually rotating
grinding discs or high-speed circular grinding belts are used. Grinding is capable of removing strongly-
adhering contaminants such as scales, oxides, rust, coatings or paints quickly and effectively. The fact
that a cer tain amount of b ase material wi l l b e abraded as wel l shou ld b e taken into account.
Areas of appl ication: As the grinding discs used are made of grains of hard material (e. g. s i licon carbide,
diamonds) emb edded in a b onding material, the selec tion of the grain/ b onding material is decis ive for
B.3 .1 Washing/rinsing/drying
P rinciple: C leaning with the aid of liquid agents often involves washing in order to remove the
detached/emulsi fied contamination, as well as the active ingredients of the solvent cleaning agent
itself, e.g. surfactants and emulsi fiers, from the object surface. This prevents contaminants from being
transferred to the next cleaning step or causing re-contamination in a subsequent rinsing or drying
pro ces s .
Rins ing is appl ied to remove unwanted res idues of the washing pro ces s .
Drying is generally the final step. It removes the remains of the cleaning medium of the previous
pro ces s . I t do es not remove contamination from the previous proces s .
Areas of application: Rinsing processes are principally used to achieve improved cleanliness levels after
cleaning with aqueous fluids.
Principle: With this cleaning technique, surfaces are cleaned by the action of a jet of gas which is
directed at an object at high speed via a nozzle. The gas jet exerts an aerodynamic force on the particle.
If the aerodynamic resistance of a particle exceeds the adhesive force between the particle and the
surface, the particle is detached from the surface and carried away with the flow of gas. In particular,
the technique allows dry, loosely-adhering contaminants, such as dust, to be removed effectively.
Particles in the micrometre size range can no longer solely be removed by use a high-speed jet of gas.
Par ticles are s us p ended in the gas and can b e re- dep os ited at other location s . Ioni zed gas can s uppres s
Areas of application: If only dry contamination is present, good cleaning results can be achieved for
particles larger than 5 µm. Liquid or paste-like contamination can also be removed partially as long as
higher pressures, e.g. by using supersonic (Venturi) nozzles, are applied.
Principle: A suction nozzle is placed above the object’s surface to be cleaned and being connected to
a pump creates a negative pressure which causes an air flow away from the object’s surface. This
air flow exerts an aerodynamic force on the particle contamination. If the aerodynamic resistance of the
p ar ticle exceeds the adhes ive force b etween the p ar ticle and the s urface, the p ar ticle is detached from
the surface and carried away with the air flow. Vacuum cleaning is especially suitable for removing dry
contamination such as dust particles. Usually, this technique is unsuitable for removing particles in the
micrometre range.
Areas of appl ication: Vacuum cleaning is used in control led environments and for hard to reach areas .
Principle: With ultrasonic cleaning, the objects to be cleaned are suspended in a bath filled with a
s uitable cleaning agent. U ltrasound waves are created in the cleaning b ath via osci l lating wal ls that
spread longitudinally through the cleaning agent. Imploding cavitation bubbles create very high
pressures of approximately 1 000 bar which will blast off contamination from surfaces which are then
dissolved or dispersed into the cleaning fluid. After cleaning, the surfaces need to be rinsed and dried.
U ltrasonic ac tion is al so ac tive at internal s urfaces that are other wise hard to clean .
Areas of application: Ultrasonic cleaning achieves extremely high quality results within a very short
time, even for complex-shaped objects, crevices and drill holes. In general, ultrasonic cleaning is a gentle
cleaning technique which can b e used to clean del icate s urfaces without damaging them .
P rinciple: Megasonic cleaning relates to the group of sonic cleaning. As megasonic cleaning uses higher
creates les s cavitation and therefore causes les s damage to the s urfaces to b e cleaned. Acous tic waves
in the cleaning fluid generate pressure variations which remove contamination from surfaces. Only the
surface of the object facing the transducer(s) is cleaned.
Areas of application: Medical implant, flat panel and wafer manufacturing or industrial parts cleaning.
P rinciple: C leaning l iquid enters under increased pres s ure in the cleaning environment (chamb er) .
A wide range of cleaning agents can b e used in combination with water. T he cleaning ac tion is
characterized by a high impact of cleaning spray and a continuous refreshment of the cleaning agent. In
a spray cleaner, either the object to be cleaned or the nozzle can be moved in order to cover the entire
object surface.
Areas of application: Spray cleaning is used for a wide range of objects.
B.4.1 General
a nd l iqu id .
P rinciple: Surfaces are cleaned through the ac tion of various blas ting agents which are carried in the
compressed gas blast and applied at fixed or fluctuating speeds to the object to be cleaned. The method
is highly versatile as it removes contamination, debris, corrosion, scale and paint. The high kinetic
energy transferred by the blasting agent impacting onto the surface may cause damage.
Areas of application: Suitable for cleaning components and structures of every size and description,
only areas in direct contact with the impacting media will be cleaned properly.
Principle: The method is similar to that of compressed gas blasting. However, here a blasting jet
comp osed of air is used to accelerate water and a blas ting agent.
Areas of application: The method is appropriate for cleaning surfaces and structures of every size and
shape. After application, the surface to be cleaned will be covered with a slurry which needs to be
removed with an air or water jet after the cleaning is completed.
Principle: Dry ice pellets at approximately −80 °C (diameter/length in millimetre range) are accelerated
to al mos t s upersonic s p eed (3 0 0 m/s) . T he rapid cooling of the s urface leads to embrittlement of the
surface layers. During sublimation of CO 2 , adhered contamination can be easily removed from the
surface. It is less abrasive than pressurized fluid blasting.
Areas of application: The method can be utilized on nearly all materials. As the method has abrasive
character, some “soft” surfaces might be visibly roughened.
P rinciple: Accelerated CO 2 snow cleaning is a dry and solvent-free process. As carbon dioxide expands
rapidly; it changes from liquid CO 2 to a mi xture of solid CO 2 (dry ice) and gaseous CO 2 . The dry ice is
then blasted onto the surface to be cleaned accelerated by pure nitrogen. CO 2 s now cleaning is a fur ther
development of the CO 2 p el let cleaning. CO 2 s now cleaning is les s abras ive than CO 2 p el let cleaning.
Areas of application: CO 2 s now cleaning has a bro ad scop e of us age, ranging from precis ion cleaning
right up to the cleaning of large surface areas. It can be utilized to clean highly sensitive surfaces.
Particle contamination can be removed, as well as oil films, grease, fingerprints and flux residues.
Principle: A jet of liquid under high pressure is directed via a nozzle at the surface to be cleaned. A solid
blasting material can be added to the liquid to increase the abrasive action. Ideally, even single layers of
a coating system can be cleaned off. After application, the surface to be cleaned will be covered with a
slurry which needs to be removed with an air or water jet after the cleaning is completed.
Areas of application: Suitable for all sizes and shapes of cleaning surfaces and structures; only the areas
in direct contact with the impacting media will be cleaned properly.
Principle: Method similar to that of compressed air blasting. However, very little water is added to the
blas ting agent/air mi xture in front of the no z zle. I n contras t with compres sed air blas ting, a s urface
Principle: A fine-grained material dispersed in water or other liquid is blasted at high speed onto the
s urface to b e cleaned. I n contras t to wet compres sed air, the liquid accelerates the blas ting agent.
Elutriation blasting is used to clean and micro- finish surfaces at the same time. After elutriation
cleaning, rinsing is necessary to get rid of any adhering blasting agent residues. Elutriation blasting is
suitable for producing a fine and even surface pro file.
Areas of application: P recis ion cas ting, m icro -/precis ion deburring, p ol ishing s urfaces , cleaning
Principle: Heated, pressurized water expands in a nozzle, resulting in a hot vapour spray being
applied to surfaces. This highly efficient method for cleaning oily surfaces can be enhanced by adding
detergents .
Areas of appl ication: Steam blas ting is applied where s trong mechanical washing and rins ing ac tions
are required.
B.5 .1 General
With chemical cleaning techniques , a cleaning agent reac ts with the contam ination pres ent to remove
it. The cleaning agent then either evaporates or can be easily removed.
B.5 .2 Etching
Principle: Etching is the removal of the surface layer with contamination by chemical reaction.
Areas of application: Removal of coatings and final cleaning of components.
Principle: Speci fically selected chemicals are used in a targeted way to convert contamination through
a chemical reaction into other compounds which are either volatile or easy to remove.
Areas of application: With this principle, surfaces can be descaled, for example, by using acidic aqueous
solutions .
Principle: Vapour cleaning is often used in combination with ultrasonic cleaning in a fast drying
environment-friendly solvent. The effect can be enhanced by using a mixture of chemicals. After
immersion, a film of solvent covers the surface of the object. In this film, the remaining contamination is
dissolved or dispersed. By moving the object through a cold zone, the film is stripped from the surface.
The object leaves this zone with a dry surface.
Areas of application: Metallic objects, electronic parts, degreasing.
P rinciple: I n plas ma cleaning, a m i xture of reac tive s p ecies is created that s putter the s urface of the
object. This cleaning action releases contamination from the surface and additionally creates a reaction
that transfers contamination into a gas phase which can be removed by a vacuum system.
A plasma cleaning process is executed in a vacuum system. However, there are also atmospheric
solutions available. The agitation energy is either in the RF range (13,6 MHz) or in the microwave
range (2 ,4 GH z) . As a cleaning gas , several pure gases or combinations can b e selec ted: argon, nitrogen,
P rinciple: I n o zone, reac tive O 3 s p ecies are used to oxidi ze organic contamination. T he o zone is
cleaning techniques. The grey area within the tables is the area where these techniques can be applied.
Annex C
(informative)
Chemical compatibility of materials with cleaning liquids has been tested extensively. Table C .1 gives
examples of compatibility for a variety of materials with the most common organic cleaning liquids.
This table gives insights into liquids that can be used for cleaning with minimal damage to the object.
This table only applies for room temperature. Chemical blends, elevated temperatures and high
mechanical action may still result in damage. Note that tables like Table C .1 can be used only as an
indication. It is strongly recommended to conduct experimental compatibility tests. Same materials
(notably polymeric materials) from different suppliers are likely to behave differently. Even batch-to-
b atch variation can b e exp ec ted.
Table C .1 — E xamples of compatibility of various solvents with listed materials (indicative only)
I so -
pro - Methyl D ichlo -
Abbrevi- Meth- Etha- Ace- C hloro -
Type of material pylic Ethyl Ke- rometh-
ation anol nol tone form
alco - tone ane
hol
polymer
Acetal (polyoxymethylene) AC L A A A A C A
Epoxy B A A B C C
Ethylene-chlorotri fluoroethylene
E - C T FE A A A B A C A
copolymer
Ethylene-tetra f luoroethylene E T FE A A A B A B A
Fluoroethylene propylene FE P A A A A A A A
Polyamide D D D A A B C
Polycarbonates PC B A A D D D D
Polyimide B B B B B B B
Polymethyl methacrylate PM M A D D D D D D D
Polyketone PK
A A A A C
(PE E K)
Polystyrene PS B A A D D D D
Polysulfone PSF A A B D D D D
Polyethylene terephthalate PE T A A A C A D D
Polypropylene PP A A A B B C D
Polyurethane PU R C C C D D D D
Si l icone A C A D D D D
Table C .1 (continued)
Iso -
pro - Methyl D ichlo -
Abbrevi- Meth- Etha- Ace- C hloro -
Type of material pylic Ethyl Ke- rometh-
ation anol nol tone form
alco - tone ane
hol
metal
Alum i nium A B B A B B
C opp er B A B A A A
3 16 Stai n les s s te el A A B A A A
Titanium B A B A A A
miscellaneous
Al 2 O 3 A A A A A A
SiC A A A A A A
Annex D
(informative)
Cleanliness measurement
D.1 General
Vis ual ins p ec tion can b e us ed to determine initial s urface clean l ines s . I f contam ination is detec ted
at this s tage, more extens ive and exp ens ive detec tion pro ces ses can b e deferred unti l the s urface
formation and high-contact angles may indicate the presence of organic contaminants. While a large
contact angle is usually an indication of residual contamination, the converse is not necessarily true.
S alts or res idues from cleaning agents can res u lt in a low contac t angle, giving a fals e indication of
clean l ines s .
Direct surface observation may be appropriate in situations where the surface is accessible. The surface
under study will either be brought to the measurement instrumentation or the instrumentation will be
p or table and brought to the s urface.
Potential meas urement metho ds are describ ed in D. 5 and in I SO 146 4 4 -10 in more detai l .
D.4.1 General
Where the performance of the cleaning process cannot readily be performed on the surface of the object
to be evaluated, extractive methods are appropriate. Examples of instances where direct analysis is not
appropriate include evaluation of objects with complex structures such as blind holes, situations where
the analyte(s) of concern occur in a mixture and should be separated from each other and objects that
have physical dimensions that cannot readily be analysed with the pertinent equipment.
The extraction process may include chemicals, heat and force. Extraction may be performed directly
from the substrate or it may involve separation of the contaminant or analyse from a swab or wipe. The
rationale of choices for s ampl ing and extrac tion shou ld b e do cumented.
Sampling technique should be de fined. The areas of the surface selected for extraction should include
areas difficult to clean (e.g. blind holes or around seals). The amount of contaminant collected from the
object needs to be sufficient to allow detection. The area sampled should be representative for the total
surface area of the object including the range of material components.
If there is a single contaminant of concern, using a single extraction agent may be adequate. Usually, it
is necessary to use at least two extraction agents to account for different polarities of the contaminant.
Even with extraction of particles, because particles are held in place using both physical and chemical
forces, it may be necessary to use several different extraction agents.
I n s elec ting extrac tion solvents , a numb er of fac tors shou ld b e cons idered and those fac tors should b e
documented. Examples of such factors include purity of the extraction solvent, solubility parameters,
wettability (surface tension, viscosity) and compatibility with the substrate or with the wipe or swab
us ed for s ampl ing.
Sampling and extraction can show variability. Wipes and swabs contain potentially interfering
materials. Therefore, controls (blanks, where swabs or wipes are subjected to a given extraction
technique) shou ld b e documented.
D.5 .1 General
T his s ub clause gives an over view of the mos t imp or tant methods for determination of p ar ticle or
chemical contaminant concentrations . I n I SO 146 4 4 -9 and I SO 146 4 4 -10 , a more complete lis t i s given .
For objects that require a low cleanliness level, a visual inspection can be used. The inspection can be
enhanced by using a flash light under a glancing angle or a UV lamp. Under ideal conditions, particles
larger than 25 μm can be observed. The minimum size of detectable particles increases enormously
when some s urface roughnes s is present. Since detec tion dep ends on the ob ser vation ski l l s of the
Light microscopes are used for measuring particles larger than 1 μm. Direct measurement of surface
particle cleanliness often requires microscopes having automatic stages and autofocus systems
and/or using backlit systems. These systems can make series of images of subsequent fields. This
al lows meas urement of a much larger s urface area and evaluation of s urfaces with low s urface p ar ticle
concentrations .
As with light microscopy, the image of a surface is depicted on a digital camera using the required
magni fication. By using oblique illumination with parallel light on the surface, existing surface
structures are only minimally illuminated and light scattered by particles enters the camera. This
technique is also known as dark field microscopy. This method enables detection of sub-resolution
particles on a relatively large area. Size information is not reliable because the amount of scattered
light dep ends on b oth the p ar ticle s i ze and refrac tive index. T he s i ze of the s mal les t detec table p ar ticle
SEM is capable of imaging very small particles (as small as 10 nm). The sample is exposed to an electron
beam in vacuum. The secondary electrons are detected. The smallest particles can only be imaged at a
large magni fication. At those conditions, the depth of focus enables imaging of low roughness samples
in a small field of view. Therefore, measurement of the surface cleanliness by particles with a SEM is
limited to high SCP classes only.
When an indirec t method is used, p articles are trans ferred to air, gases or liquids and the particle
concentration is measured by optical particle counting. Particles that are present in the medium generate
scattered light that is registered by photo-detectors and analysed, on passing through the laser.
An equivalent particle size is calculated from the intensity of the scattered light. In air and gasses,
p ar ticles larger than 10 0 nm can b e meas ured us ing an airb orne p ar ticle counter. For a high p ar ticle
concentration, a Scanning Mobility Particle Sizer (SMPS) can be used. When only particle concentrations
are required, a C ondens ation Par ticle C ounter (C PC ) can b e used. T he s ample air is lead through
s aturated (water, alcohol) gas . T he comp onent condenses on the p ar ticle which can b e detec ted more
In both methods of detecting particles (extinction and scattering of light), a change in light intensity
measured by the detector is converted to an electrical signal. Light extinction is useful for particles
1 μm and greater in size. In this method, the detector looks directly into the light source and measures
the s ize of the “shadow” of the p ar ticle as it p as ses through the b eam .
Scattered-light scanners are implemented especially to examine surfaces with a very low roughness
(e.g. silicon wafers, glass). A focused laser scans the component surface using a de fined beam angle.
The light re flected directly from the surface is guided into a light trap and thus eliminated. Particles
present on the surface cause the laser light to be diffusely scattered. The scattered light is registered by
a photomultiplier and ampli fied. Based on the intensity of scattered light, detected conclusions can be
drawn ab out the s i ze and lo cation of the p ar ticles . T he s i ze is often expres sed as the equivalent s phere
diameter. The detection limit of scattered-light scanners lies at a particle size of >0,05 μm. Since a large
s urface area can b e scanned, this metho d is s uitable for low S C P clas s es .
The atomic force microscope is a very-high-resolution type of scanning probe microscope, with
demons trated resolution of frac tion s of a nanometre, more than 1 0 0 0 times b etter than the op tical
diffrac tion limit. T he AFM cons is ts of a micronscale canti lever with a sharp tip (prob e) at its end that is
This method can only be applied on a small detection area (100 µm 2 × 100 µm 2 ) and p ar ticles larger
than 1 µm cannot be measured correctly. Because of the small measurement area, it is difficult to select
a repres entative meas urement lo cation .
D.5 .2 .9 Gravimetry
Gravimetry is a method that is used for indirect measurement of particles. The particle load on a surface
or test object transferred to a gas or a liquid which is filtered. The increase in mass of an analysis filter
(differential weight) is a s tandard for the s urface p ar ticle clean lines s . T he measurement l im it lies at
approximately 0,1 mg per analysis filter. Therefore, this method can be used for high SCP classes only.
D.5 .3 .1 General
T his s ub clause describ es meas urement metho ds for chemical contamination . More information can b e
Most methods for measurement of chemical contamination can be applied on hydrocarbons. In this
s ub clause, a selec tion of methods is describ ed that can either b e appl ied on the relevant s urface itsel f
(direc t meas urement) or can b e us ed after extrac ting the contamination (indirec t metho ds) . Mos t
Mass spectrometry is used to measure the mass-to-charge quotient and abundance of secondary ions
emitted from a s ample after ion b omb ardment. I t is a quantitative metho d us ing s tandard material s
that characterizes trace contamination of surfaces, thin films, multilayer structures and interfaces.
SIMS is often combined with a time-of- flight method (TOF-SIMS) for analysing the mass.
TXRF is an X-ray spectrometer measuring energy distribution of fluorescent X-rays emitted from
surface irradiated by primary X-rays under condition of total re flection. TXRF gives a qualitative
elemental screening of unknown s amples , metal lic s urface contam ination on semiconduc tor wafers
F TI R is a meas urement for infrared ab sorp tion s p ec tra in which a s p ec trometer is used to meas ure
the infrared energy. It is used for identi fication of chemical structure of organic compounds, films,
particles, powders and liquids. Quanti fication is possible by using a standard.
D.5 .3 .3 Microgravimetry
Devices, in which piezoelectric quartz crystals respond to the condensation of gasses by reducing
operating frequency in a linear mass-to-frequency relationship, can be used for direct deposition flux
measurement of any chemical thin films in the range of nm to µm. Depending on their sensitivity, either
a quartz crystal microbalance (QCM) or a surface acoustic wave sensor (SAW), which is 100 times more
sens itive than a QC M , can b e selec ted.
T he contaminants on the s ub s trate s urface are dis solved with appropriate s olvent. A p or tion of s olvent
is analysed with gas chromatography/mass spectrometry (GC/MS). This method gives compositions
and quantity of organic contaminants on a surface.
In this method, contaminants on substrate surface are thermally desorbed and concentrated into an
ab sor p tion colu m n . C oncentrates are then i ntro duce d to a gas chromatograph with mas s s p ec trome ter.
The method can be used for trace analysis of organic species, evaluation of contaminants, e.g. on
s i l icon wafers .
T he contam inants are dis solved with appropriate solvent and are introduced to high-p erformance
Bibliography
[1] I S O 146 4 4 -1 , Cleanrooms and associated controlled environments — Part 1: Classification o f air
[8] K ohli R. , & M ittal K. eds . D evelopments in Surface C ontamination and C leaning. Vol 5 , 1st
E dition. Contaminant Removal and Monitoring. E l sevier, I SBN 9 78143 7778 816 , 2 01 2 .
[9] K ohli R. , & M ittal K. eds . D evelopments in Surface C ontamination and C leaning, Vol 8 , 1st
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