NISHCHAY Batch Aldehyde and Ketones LECTURE-5

-
in -Ecc
* C-c=0 thec

5)
⑪

in/b
1)
[ =

*
For Ketones :
unsymmetric
&
O
&
- O

CH5-CH-l-Chy # Ch--UChy
CHsCH-a
- =
A

CH3-CH2-C=0
&
,
+HCH--H
I
- Us

I
C
CHz-CH-C=
as
⑪ I care
of unsymmetrical
To this
ketones
multiple bonds are

formed avoid situation , we use LDA

1
Bulkybar) which causes directed alda
·

LDA e Lithium
disopropyl
.
amide
Ei
① Aldol in acidic medium :-
O
O
⑰ II
Chy-"c-h -
CHz
-

CH = CH -
c -
H

M:
-
-
un--H
-
↓
-H
Uz-CH-ch2- -H
CH3-CH-c
E

on
Ti
·

O
II i
-H
CHz-CH
-
CH -
c -
Hd CH3-CH=LC-
i
①d
&