a (atm dm6 mol-2) b (dm3 mol-1) R (dm3 atm k-1 mol-1)

3.61 0.0429 0.0820574

pressure(atm)
Vm T1(K) T2(K) T3(K) T4(K) T5(K) T6(K)
(L/mol) 273.15 283.15 293.15 303.15 313.15 323.15
0.072 73.87 102.06 130.26 158.46 186.66 214.86
0.076 52.16 76.95 101.74 126.53 151.32 176.11
0.080 40.09 62.21 84.32 106.44 128.56 150.68
0.084 33.73 53.70 73.66 93.63 113.59 133.56
0.088 30.82 49.01 67.21 85.40 103.59 121.79
0.092 29.98 46.70 63.41 80.12 96.83 113.55
0.10 31.54 45.91 60.28 74.65 89.02 103.39
0.11 35.69 47.92 60.15 72.38 84.61 96.84 van der waa
0.12 40.02 50.66 61.30 71.95 82.59 93.23 350.00

0.13 43.73 53.15 62.57 71.99 81.41 90.83 300.00

0.14 46.65 55.10 63.55 72.00 80.45 88.90
250.00
0.16 50.39 57.40 64.41 71.42 78.42 85.43

pressure(atm)
200.00
0.18 52.07 58.05 64.04 70.02 76.01 81.99
0.20 52.42 57.65 62.87 68.09 73.32 78.54 150.00

0.22 51.97 56.61 61.24 65.87 70.51 75.14 100.00

0.24 51.05 55.21 59.37 63.53 67.70 71.86 50.00
0.26 49.84 53.62 57.40 61.18 64.96 68.74
0.00
0.28 48.49 51.95 55.41 58.87 62.33 65.79 0.000 0.100 0.200

0.30 47.07 50.26 53.45 56.64 59.84 63.03

0.32 45.63 48.60 51.56 54.52 57.48 60.44
0.34 44.21 46.98 49.74 52.50 55.26 58.02
0.36 42.83 45.42 48.00 50.59 53.18 55.77
0.38 41.49 43.92 46.36 48.79 51.23 53.66
0.40 40.20 42.50 44.80 47.10 49.40 51.69
0.42 38.97 41.15 43.32 45.50 47.68 49.85
0.44 37.80 39.86 41.93 44.00 46.06 48.13
0.46 36.68 38.64 40.61 42.58 44.55 46.51
0.48 35.61 37.49 39.37 41.24 43.12 45.00
0.50 34.60 36.39 38.19 39.98 41.78 43.57
0.52 33.63 35.35 37.07 38.79 40.51 42.23
0.54 32.71 34.36 36.01 37.66 39.31 40.96
0.56 31.83 33.42 35.01 36.59 38.18 39.77
0.58 31.00 32.53 34.06 35.58 37.11 38.64
0.60 30.21 31.68 33.15 34.62 36.10 37.57
 CO2

van der waals Isotherms of CO2

350.00

300.00

250.00 273.15K
283.15K
pressure(atm)

200.00 293.15K
303.15K
150.00
313.15K
100.00 323.15K

50.00

0.00
0.000 0.100 0.200 0.300 0.400 0.500 0.600 0.700

Vm (L/mol)
2022
 [KMnO4]0(M) = 0.04 [H2C2O4]0(M)= 0.95

Run V KMnO4 V H2C2O4 V DW Vtotal min sec.

1 0.5 2.5 3.0 6.0 7 47
2 0.5 5.0 0.5 6.0 3 53
3 1.0 2.5 2.5 6.0 7 21
t(s) [KMnO4]i (M) [H2C2O4]i(M) Rate(M/s)
467 0.0033 0.3958 3.568879E-06
233 0.0033 0.7917 7.153076E-06
441 0.0067 0.3958 7.558579E-06
 T (C) min sec. t(s) T(K) 1/T(K)
17 7 48 468 =(B2*60)+C2 290.2 0.0034
35 2 17 137 308.2 0.0032
42 0 57 57 315.2 0.0032

[KMnO4]i (M) [H2C2O4]i(M)

0.0033 0.3958

Rate= k [H2C2O4]ix [KMnO4]iy

useful information
Slope = -7355.57103861
ln(k) = Y -Intrecept = 19.84762309667
R= 8.314 (J/K.mol)
Ea = -(Slope×R) = 61154.21761498 (J/mol)
Ea = -(Slope×R) = 61.15421761498 kj/mol
A = Frequency factor= 416594171.7569 (s-1)

Arrhenius eqauation :
lnk= -45.1985486132 =-(((C23/C22)*(H2))+LN(C25))
Rate(M/s) k (M-1s-1) lnk
3.526E-06 0.004 -5.451 k=I2/'Kinetics (Conc. Effect) '!$W$18 =I2/'Kinetics (Conc. Effect) '!$W$18
1.204E-05 0.015 -4.222
2.895E-05 0.035 -3.345

temp.effect
0
0.0035 0.0034 0.0033 0.0032 0.0031
-1

-2 temp.effect
Linear (temp.effect)
ln(K)

-3 Linear (temp.effect)
Linear (temp.effect)
f(x) = − 7355.57103860665 x-4
+ 19.8476230966714
R² = 0.971269243763722
-5

-6
1/T
tics (Conc. Effect) '!$W$18
2023