Physical Chemistry Lab

Experiment: 13
Kinetics of the Iodide-Catalyzed Decomposition of Hydrogen
Peroxide
Student name :
Shifa ghannam
Partner : sondos
Objectives
To determine the reaction order and activation energy of the Iodide-
Catalyzed Decomposition of Hydrogen Peroxide.
Data and calculation:
Part 1 for different concentration of peroxide :
Run 1
t(min) t(s) vi
0.5 30 1.5
1 60 2.1
1.5 90 1.5
2 120 2.2
2.5 150 2.5
V t vs. t 3 180 2
3.5 210 1.9
12 4 240 2
y = 0.0092x 10 4.5 270 1.6
R² = 0.9273 5 300 1.9
8
6 Vt 6 360 1.6
4 7 420 3.8
2 8 480 5
0 9 540 5.8
1500 1000 500 0 10 600 5.9
) t(s 11 660 6.8
12 720 7.3
13 780 8
slope= 0.0092 initial rate 14 840 8.6
15 900 8.6
16 960 9
17 1020 9.6
18 1080 9.5
19 1140 9.3
20 1200 9.8
Run 2
V t vs. t t(s) v(ml)
30 1.4
30
60 1.5
y = 0.0191x + 3.6464
R² = 0.6841 25 90 1.7
120 1.5
20
150 1.6
15 180 1.3
210 1.1
10
240 0.8
5 270 16.9
0
300 17.5
1500 1000 500 0 330 17.7
390 17
slope= 0.0191 initial rate 450 18
510 18.6
570 19
630 19.5
690 20.1
810 20.3
870 20.6
930 20.8
990 21.4
1050 21.6
1110 22.1
1170 21.7
1200 22
t(s) v(ml)
30 3.4
60 3.9 Run 3
90 4
120 4.4 12
f(x) = 0.0100858737655646 x
R² = 0.90620864653498
150 4.5 10

180 4.5 8

210 4.4 6

240 4.6 4

2
270 5
0
300 5.1 1400 1200 1000 800 600 400 200 0

360 5.1
420 5.6
480 8.2
540 5.7
600 6.1
660 7.4
720 7.7
780 7.8
840 9.6
900 9.6
960 9.3
1020 9.1
1080 9.3
1140 9.4
1200 9.2
 calculation to find order
run pecent of H2O2 con.of H2O2 initial rate log initial rate log [H2O2]
1 2% 0.587958608 0.0092 -2.036212173 -0.23065325
2 1.40% 0.411571025 0.0191 -1.718966633 -0.38555521
3 1% 0.293979304 0.0101 -1.995678626 -0.53168324
initial rate increase as percent of H2O2 decrease

2 g H2 O 2 1 g sol. 1000 mL sol. 1molH2 O 2

2% = × × × = 0.0588 mol/L
100 g sol. 1mL sol. 1L sol. 34.016 g H2 O 2

0
0 -0.5 -0.1 -0.2 -0.3 -0.4 -0.5 -0.6

log initial rate

-1 y = 4.5269x
R² = -18.36
-1.5
-2
-2.5
-3
] log[H2O2]

the slope of the line = m (order with respect to[H2O2]) 5

slope 4.529
 Part2 change temperature
vol.(40
vol.(32 Run1
ln(V
ln(Vꚙ -V
ꚙ-Vtt )
ꚙ t )
C°) vol.(25C°) Time(s)
Time(sec)
2.45958884
2.944439
2.322388 2.25 1 30 30
2.41591378 3.4
2.674149
2.197225 9.5 1.5 60 60
2.37954613 11.6
2.517696
2.116256 4.1 1.9 90 90
2.3321439 12.7
2.424803
2.066863 4.5 2.4 120 120
2.30258509
2.322388
1.987874 13.8
5.1 2.7 150 150
2.27212589 14.5
2.251292
1.931521 5.5 3 180 180
2.2300144 14.9
2.208274
1.856298 6 3.4 210 210
2.14006616 15.1
2.186051
1.791759 6.4 4.2 240 240
2.10413415
2.163323
1.740466 15.3
6.7 4.5 270 270 Run 2
2.07944154 15.7
2.116256
1.648659 7.2 4.7 300 300
2.10413415 7.5
1.94591
1.589235 17 4.5 360 360
1.98787435 17.6
1.856298
1.547563 7.7 5.4 420 420
1.94591015
1.568616
1.435085 19.2
8.2 5.7 480 480
1.79175947 19.5
1.504077
1.435085 8.2 6.7 540 540
1.68639895 8.4
1.386294 20 7.3 600 600
1.58923521 20.2
1.335001
1.223775 9 7.8 660 660
1.5260563
1.131402
0.832909 20.9
10.1 8.1 720 720
1.38629436 10.4
1.029619
0.693147 21.2 8.7 780 780
0.74193734 10.7
0.788457
0.530628 21.8 10.6 840 840 Run3
0.64185389 10.9
0.587787
0.405465 22.2 10.8 900 900
0.26236426
0.587787
0.336472 11 11.4 960 960
22.2
-0.3566749 11.6
0.530628
-0.22314 22.3 121020 1020
-0.9162907
-0.91629 0 23 12.31080 1080
12
-1.6094379 12.2
-0.69315
-1.60944 23.5 12.51140 1140
#NUM! 12.4 24 12.71200 1200
 ln V  V t  vs . t
3.5

2.5

˺ ΔϠ
γϠγ 1.5

˺ ΔϠ
γϠγ ϲ ρΧ 1

0.5
y = -0.0025x + 2.8372 0
R² = 0.962 1200 1000 800 600 400 200 0
-0.5

-1

the slope of the line equals -kʹ -0.0025

k'= 0.0025
 Calculation to find activation energy and A and S

lnK K 1/T T (k) T (C°)

-
5.84304 0.0029 0.003354 298.15 25
-5.9145 0.0027 0.003277 305.15 32
-
5.99146 0.0025 0.003193 313.15 40

Plot ln kʹ vs. 1/T

-5.75
0.0034 0.00335 0.0033 0.00325 0.0032 0.00315
-5.8
=INTERCEPT(E2:E4;C2:C4)
-5.85

˺ ΔϠ
γϠγ -5.9

˺ ΔϠ
γϠγ ϲ ρΧ -5.95

-6

y = -1805.5x -6.05
R² = -7.733
-6.1

the slope of the line = -Ea /R -1805.5

Ea/R 1805.5
R= 8.314
Ea= 15010.93 j
 E act 1
lnk =  + ln A
R T
The intercept = ln A -8.94147
A 1.36*10^-4dm3/mol s

kT S *
ln A  ln 1
h R
k 1.38E-23 J/K
h 6.626*10^-34 Js
R 8.314
T 298 k

ΔS* -327.155