SAFETY DATA SHEET

PETRON XTRA ADVANCE

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY

Product Name PETRON XTRA ADVANCE

Product Type Regular Grade Automotive Gasoline

Recommended Use Fuel for Gasoline Engine

Company Information PETRON CORPORATION

San Miguel Had Office Complex
40 San Miguel Avenue, Mandaluyong City
PHILIPPINES

General Contact Numbers (632) 802-7777

Website www.petron.com

SECTION 2: HAZARDS IDENTIFICATION

GHS CLASSIFICATION Flammable Liquids, Category 1

Acute Toxicity, Skin Category 5
Skin Corrosion / Irritation, Category 2
Carcinogenicity, Category 2
Specific Target Organ Toxicity (Single Exposure),
Category 3 (Narcotic Effect)
Aspiration Hazard, Category 2
Hazardous to the aquatic environment
Acute hazard, Category 2
Chronic hazard, Category 2
GHS LABELING

Symbol(s)

Signal Word Danger

Hazard Statements H224 Extremely flammable liquid and vapor

H305 May be harmful if swallowed and enters airways
H313 Maybe harmful in contact with skin
H315 Causes mild skin irritation
H351 Suspected of causing cancer
H336 May cause drowsiness and dizziness
H411 Toxic to aquatic life with long lasting effects

PRECAUTIONARY STATEMENTS

General Precautionary Statement

P101 If medical advice is needed, have product container or label at hand
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 P102 Keep out of reach of children
P103 Read label before use

Prevention Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P261 Avoid breathing fume/gas/mist/vapor
P271 Use only in a well-ventilated area
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye and face protection
P281 Use personal protective equipment as required

Response Precautionary Statements

P301 + P310 + P331 IF SWALLOWED: Immediately call a Poison Center or Physician. Do not
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse with water / shower.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position
comfortable for breathing.
P308 + P313 If exposed or concerned: Get medical advice/attention.
P312 Call a Poison Center or Physician if you feel unwell.
P332 + P313 If skin irritation occurs, get medical advice/attention
P370 + P378 In case of fire: use foam, carbon dioxide or dry chemical extinguishers
for extinction.
P391 Collect spillage.

Storage Precautionary Statements

P403 + P235 Store in well-ventilated place. Keep cool.
P405 Store locked up.

Disposal Precautionary Statement

P501 Dispose of contents/container in accordance to
local/regional/national/international regulations.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Composition CAS Number % Weight

Gasoline 86290-81-5 90

Ethanol 64-17-15 10

Petron XTRA Advance is a complex blend of petroleum-derived normal and branched-chain alkane,
cycloalkane, alkene, aromatic hydrocarbons and multifunctional additives. In general, the product
contains components that may be a significant health and safety hazard thus proper handling of
petroleum products and observing precautions must be observed. In addition to this, good standards of
industrial and personal hygiene must be maintained.

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SECTION 4: FIRST AID MEASURES

Eye Contact Rinse eyes immediately with plenty of water until irritation subsides.
If irritation persists, get prompt medical attention.

Skin Contact Remove contaminated shoes and clothing, and flush affected
areas(s) with large amounts of water. If skin surface is damaged,
apply a clean dressing and seek medical attention. If skin surface is
not damaged, cleanse affected area(s) thoroughly by washing with
mild soap and water or a waterless hand cleaner. If irritation or
redness develops, see medical attention. Remove contaminated
shoes and clothing and cleanse affected area(s) thoroughly by
washing with mild soap and water or a hand cleaner.

Ingestion Seek medical attention.

Inhalation If respiratory symptoms or other symptoms of exposure develop,

move victim away from source of exposure and into fresh air. If
symptoms persist, seek immediate medical attention. If victim is not
breathing, clear the airway and immediately begin artificial
respiration. If breathing difficulties develop, oxygen should be
administered by qualified personnel. Seek immediate medical
attention.

SECTION 5: FIRE-FIGHTING MEASURES

Flash Point, oC < -56

Extinguishing Media In case of fire, use foam, carbon dioxide or dry chemical
extinguishers.

Special Fire-fighting Do not spray water directly on fire; product will float and could
Procedures reignite on the surface of the water. Highly flammable vapors which
are heavier than air may accumulate in low areas and/or spread
along the ground away from handling site. Flashback along vapor
trail may occur.

Unusual Fire Hazards Extremely flammable. Contains hazardous material. Firefighters

should consider protective equipment indicated in Section 9. Vapor is
flammable and heavier than air. Vapor may travel across the ground
and reach remote ignition sources, causing a flashback fire danger.

Decomposition Products Oxides of carbon, nitrogen and other gases are products of
combustion.
under Fire Conditions

SECTION 6: ACCIDENTAL RELEASE MEASURES

Land Spill Taking normal safety precaution, eliminate sources of ignition.

Prevent additional discharge of material, if possible to do so without
hazard. For small spills, implement cleanup procedures. For large
spills, implement clean-up procedures and, if in public area, keep
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 public away and advise authorities. Prevent liquid from entering
sewers, water courses, or low areas. Contain spilled liquid with sand
or earth. Recover by pumping or with a suitable absorbent. If liquid is
too viscous for pumping, scrape up. Consult an expert on disposal
of recovered material and ensure conformity to local disposal
regulations.

Water Spill Use booms to confine spills immediately. Remove from water
surface by skimming or with suitable adsorbents. If allowed by local
authorities and environmental agencies, sinking and/or suitable
dispersants may be used in non-confined waters. Consult an expert
on disposal of recovered material and ensure conformity to local
disposal regulations.

SECTION 7: HANDLING AND STORAGE

Handling Procedures
Keep away from potential sources of ignition. Open container in a
well- ventilated area. Avoid breathing vapors. Keep containers
closed when not in use. Wash thoroughly after handling. “Empty”
containers with retained product residue (liquid or vapor) can be
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat, flame, sparks, static electricity or other
sources of ignition; they may explode and cause death or injury.
Empty drums should be completely drained, properly bunged and
promptly returned to a drum re-conditioner, or properly disposed off.

Storage Procedures Do not store near potential sources of ignition. Store in well-
ventilated area.

SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Controls

Components CAS-No. Source Value

ACGIH TWA 300ppm

ACGIH TWA 890 mg/m3
Gasoline 86290-81-5
ACGIH STEL 500ppm
ACGIH STEL 1480 mg/m3
ACGIH TWA 1000ppm
NIOSH TWA 1900 mg/m3
Ethanol 64-17-5
OSHA PELS 1000ppm
TWA 1900 mg/m3

Personal Protection

Ventilation Procedures The use of local exhaust ventilation is recommended to control mists
or vapors. Additional ventilation or exhaust may be required to
maintain air concentrations below exposure limits.

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 Respiratory Protection Vapor respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is
inadequate.

Hand Protection Butyl rubber gloves, nature rubber gloves, neoprene rubber gloves,
nitrile rubber gloves.

Eye Protection Chemical splash goggles.

Clothing Recommendation Use protective clothing which is chemical resistant to this material.
Safety shoes and boots should also be chemical resistant.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear liquid, red

Odor Characteristic of petroleum
Density at 15°C products
743.9
Flash Point, °C < - 56
pH No data
Boiling Point, °C 33 – 210 (typical)
Melting Point, °C No data
Vapor Pressure, kPa 57
Vapor Density No data
Solubility in Water Insoluble
Evaporation Rate No data
Flammability Flammable
Partition Coefficient No data
Auto-ignition Temperature, °C >280
Decomposition Temperature, No data
°C
Explosion limits LEL 1:4; UEL 7.6

SECTION 10: STABILITY AND REACTIVITY

Stability Material is normally stable at ambient temperature. May decompose

on exposure to heat; extremely flammable. Vapor can cause flash
fire

Incompatibility May react with strong oxidizing agents, halogens, strong acids

Polymerization Not Applicable

Hazardous Decomposition Material will not decompose at ambient temperature. Thermal

Products decomposition is highly dependent on conditions. Carbon monoxide,
carbon dioxide and other organic compounds will be evolved when
this material undergoes combustion or thermal or oxidative
degradation. May form explosive peroxides

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SECTION 11:
Basis for Assessment
Acute Toxicity
Gasoline
Ethanol
Skin Corrosion/Irritation
Serious Eye Damage/Irritation
Respiratory/Skin Sensitization
Germ Cell Mutagenicity
Aspiration Hazard
Carcinogenicity
Reproductive Toxicity
Specific Target Organ Toxicity
TOXICOLOGICAL INFORMATION
Information given is based on data on the components and the
toxicology of similar products.
Oral, LD50 14000 mg/kg
Dermal, LD50 >3750 mg/kg
Inhalation, LC50 >5.2 mg/L (exposure time: 4hrs)
Oral, LD50 8350 mg/kg
Dermal, LD50 >20000 mg/kg
Inhalation, LC50 50-55 mg/kg (exposure time: 6hrs)
Low order of toxicity under normal use. However, avoid prolonged or
repeated contact with the product to prevent defatting and dermatitis.
Furthermore, lead in the product can be absorbed through the skin
and accumulate in the body, affecting the blood, nerves, kidney and
the reproductive system.
May cause mild eye irritation with stinging and redness of eyes.
There was no evidence of skin sensitization when the product was
applied to human skin. Based on human experience, breathing of
vapors or mists may cause a temporary burning sensation to nose,
throat, and lungs.
May cause heritable genetic damage.
Ingestion is an unlikely event. However, accidental ingestion can
lead to vomiting and aspiration into the lungs.
Carcinogenic in animal tests. Chronic inhalation studies resulted in
liver tumours in female mice and kidney tumours in male rats.
Neither result considered significant for human health risk
assessment by the United States EPA and others. in-vitro or Did not
cause mutations in-vivo. Negative in inhalation developmental
studies and reproductive tox studies. Inhalation of high
concentrations in animals resulted in reversible central nervous
system depression, but no persistent toxic effect on the nervous
system. Non-sensitizing in test animals. Caused nerve damage in
humans from abusive use (sniffing).
No evidence of developmental toxicity was found in pregnant
laboratory animals (rats and mice) exposed to up to 9,000 ppm vapor
of unleaded gasoline via inhalation.
Gasoline vapor acts as a central nervous system depressant.
Exposure to low concentrations may produce flushing of the face,
staggering gait, slurred speech and mental confusion. In high
concentrations, gasoline vapor may cause unconsciousness, coma
and possibly death resulting from respiratory failure and harmful
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 effects to the kidneys, pancreas and liver. Gasoline contains
aromatic hydrocarbons which may result in leukemia and other
hematopoietic changes.

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is based
on a knowledge of the components and the ecotoxicology of similar products.

Environmental Mobility
More volatile component, highly volatile, will partition rapidly to air.
Not expected to partition to sediment and wastewater. Less volatile
component, low solubility and floats is expected to migrate from
water to land. Expected to partition to sediment and wastewater
solids.

Environmental Degradability Data have not been determined specifically for this product, but it is
expected that it will be inherently biodegradable. The more volatile
component is expected to degrade rapidly in air.

Ecotoxicity & Bioaccumulation
Data have not been determined specifically for this product, but it is
expected to be harmful to aquatic organisms. May cause long-term
adverse effects in the aquatic environment. Majority of the
components has the potential to bioaccumulate. However,
metabolism or physical properties may reduce the bioconcentration
or limit bioavailabilty.

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Material, if discarded, is expected to be hazardous waste due to

toxicity. Waste management should be in compliance with local and
national regulations.

SECTION 14: TRANSPORT INFORMATION

UN
UN Number 1203
Packing Group II
Hazard Class 3

IMDG
UN Number 1203
Hazard Class 3.1
Packaging Group II
IMDG-Labels 3
Em8 3-07

IATA Cargo Transport

ICAO UN Number 1203
ICAO Packing Group II

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 ICAO Hazard Class 3

Marking Gasoline, UN 1203, Marine Pollutant

Label Flammable liquid

SECTION 15: REGULATORY INFORMATION

Material is hazardous under Occupational Safety and Health (Classification, Labeling, and Safety Data
Sheet of Hazardous Chemical) Regulations 2013.

The chemical substances present in this product are listed under Philippine Inventory of Chemicals and
Chemical Substances (PICCS).

SECTION 16: OTHER INFORMATION

Approvals Research and Development Department

Petron Corporation

This safety data sheet contains the following revisions 4

This is a computer-generated form and does not require a signature.

The information and recommendations contained herein are based on the data sheet and sources believed to be accurate and correct and Petron makes no expressed or
implied warranty with respect to the accuracy of the information or the suitability of the recommendations contained in the SDS. It is your responsibility to contact Petron to
ensure that this document is the most current available from Petron. The information and recommendations are offered for the user's consideration and examination. It is the
user's full responsibility to satisfy itself that the product is suitable for the intended use and to ensure the safe handling and use of the product. If the user repackages this
product, it is the user's responsibility to ensure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-
handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Petron accepts no responsibility and hereby disclaim all
liability for any harmful effects which may be caused by purchase, resale, use, exposure or disposal of the product. Users must comply with all local laws and
regulations. Except to the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "Petron" is used for
convenience, and may include any one or more of Petron Corporation, Petron Oil & Gas International Sdn Bhd or any affiliates in which they directly or indirectly hold any
interest. In no event, shall Petron or its suppliers be liable for any direct or indirect loss of profits or for any other special, indirect or consequential damages, nor shall the
liability of Petron on any claim for damages arising out of or connected with the sale, delivery or use of the product purchased exceed the purchase price of the product.

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