SAFETY DATA SHEET

PETRON TURBO DIESEL

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY

Product Name PETRON TURBO DIESEL

Product Type Hydrocarbons and Additive

Recommended Use Fuel for Diesel Engine

Company Information PETRON CORPORATION

San Miguel Had Office Complex
40 San Miguel Avenue, Mandaluyong City
PHILIPPINES

General Contact Numbers (632) 802-7777

Website www.petron.com

SECTION 2: HAZARDS IDENTIFICATION

GHS CLASSIFICATION Flammable Liquids, Category 3

Acute Toxicity, Inhalation Category 5
Acute Toxicity, Ingestion Category 5
Skin Corrosion / Irritation, Category 2
Carcinogenicity, Category 2
Specific Target Organ Toxicity
(Single Exposure – Lungs, Kidney), Category 2
(Repeated Exposure – Lungs, Blood, Kidney), Category 2
Aspiration Hazard, Category 2
Hazardous to the aquatic environment
Acute hazard, Category 2
Chronic hazard, Category 2
GHS LABELING

Symbol(s)

Signal Word Warning

Hazard Statements H226 Flammable liquid and vapor

H303 May be harmful if swallowed
H333 May be harmful if inhaled
H315 Causes mild skin irritation
H351 Suspected of causing cancer
H373 May cause damage to lungs, blood, kidney through prolonged or
repeated exposure
H305 May be harmful if swallowed and enters airways
H411 Toxic to aquatic life with long lasting effects

PRECAUTIONARY STATEMENTS

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General Precautionary Statement
P101 If medical advice is needed, have product container or label at hand
P102 Keep out of reach of children
P103 Read label before use

Prevention Precautionary Statements

P201 Obtain special instructions before use
P202 Do not handle until all safety precautions have been read and understood
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking
P233 Keep container tightly closed
P242 Use only non-sparking tools
P243 Take precautionary measures against static discharge
P260 Do not breathe fume/gas/mist/vapor
P271 Use only in a well-ventilated area
P273 Avoid release to the environment
P280 Wear protective gloves/protective clothing/eye and face protection
P281 Use personal protective equipment as required

Response Precautionary Statements

P301 + P310 + P331 IF SWALLOWED: Immediately call a Poison Center or Physician. Do not induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse with
water / shower.
P302 + P352 If on skin: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
P308 + P313 If exposed or concerned: Get medical advice/attention.
P309 + P311 If exposed or if you feel unwell: Call a Poison Center or doctor physician
P314 Get medical advice/attention if you feel unwell.
P332 + P313 If skin irritation occurs, get medical advice/attention
P362 Take off contaminated clothing and wash before reuse
P370 + P378 In case of fire: use foam, carbon dioxide or dry chemical extinguishers for extinction.
P391 Collect spillage.

Storage Precautionary Statements

P403 + P235 Store in well-ventilated place. Keep cool.
P405 Store locked up.

Disposal Precautionary Statement

P501 Dispose of contents/container in accordance to local/regional/national/international
regulations.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

Composition CAS Number % Weight

Diesel 68476-34-6 98-100

Coconut Methyl Ester 61788-59-8 0-2

Petron Turbo Diesel is a complex mixture of hydrocarbons produced by crude oil distillation predominantly C-9 to C-20
desulfurized product. It also contains distillate and multi-functional additives. In general, the product contains

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components that may be a significant health and safety hazard thus proper handling petroleum products and observing
precautions must be observed and good standards of industrial and personal hygiene must be maintained.

SECTION 4: FIRST AID MEASURES

Eye Contact Rinse eyes immediately with plenty of water until irritation subsides. If irritation
persists, get prompt medical attention.

Skin Contact Remove contaminated shoes and clothing, and flush affected areas(s) with
large amounts of water. If skin surface is damaged, apply a clean dressing
and seek medical attention. If skin surface is not damaged, cleanse affected
area(s) thoroughly by washing with mild soap and water or a waterless hand
cleaner. If irritation or redness develops, see medical attention. Remove
contaminated shoes and clothing and cleanse affected area(s) thoroughly by
washing with mild soap and water or a hand cleaner.

Ingestion Seek medical attention.

Inhalation If respiratory symptoms or other symptoms of exposure develop, move victim

away from source of exposure and into fresh air. If symptoms persist, seek
immediate medical attention.

SECTION 5: FIRE-FIGHTING MEASURES

Flash Point, oC 60

Flammability Limits LEL:05 UEL:5.0

(Approximate Volume % in air)

Auto-ignition temperature >250°C

Extinguishing Media In case of fire, use foam, carbon dioxide or dry chemical extinguishers.

Special Fire-fighting Do not spray water directly on fire; product will float and could
Procedures reignite on the surface of the water. Highly flammable vapors which are
heavier than air may accumulate in low areas and/or spread along the ground
away from handling site. Flashback along vapor trail may occur.

Unusual Fire Hazards Extremely flammable. Contains hazardous material. Firefighters should
consider protective equipment indicated in Section 9. Vapor is flammable and
heavier than air. Vapor may travel across the ground and reach remote
ignition sources, causing a flashback fire danger.

Decomposition Products Smoke, fume, aldehydes, Sulphur oxides and other gases are products of
under Fire Conditions combustion.

SECTION 6: ACCIDENTAL RELEASE MEASURES

NOTIFICATION PROCEDURES In the event of a spill or accidental release, notify relevant authorities in
accordance with all applicable regulations.

PROTECTIVE MEASURES Avoid contact with spilled material. Warn or evacuate occupants in
surrounding and downwind areas if required, due to toxicity or flammability of

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 the material. See Section 5 for firefighting information. See the Hazard
Identification Section for Significant Hazards. See Section 4 for First Aid
Advice. See Section 8 for advice on the minimum requirements for personal
protective equipment. Additional protective measures may be necessary,
depending on the specific circumstances and/or the expert judgment of the
emergency responders. For emergency responders: Respiratory protection:
half-face or full-face respirator with filter(s) for organic vapor and, when
applicable, H2S, or Self Contained Breathing Apparatus (SCBA) can be used
depending on the size of spill and potential level of exposure. If the exposure
cannot be completely characterized or an oxygen deficient atmosphere is
possible or anticipated, SCBA is recommended. Work gloves that are resistant
to aromatic hydrocarbons are recommended. Note: gloves made of polyvinyl
acetate (PVA) are not water-resistant and are not suitable for emergency use.
Chemical goggles are recommended if splashes or contact with eyes is
possible. Small spills: normal antistatic work clothes are usually adequate.
Large spills: full body suit of chemical resistant, antistatic material is
recommended.

SPILL MANAGEMENT

Land Spill Taking normal safety precaution, eliminate sources of ignition. Prevent
additional discharge of material, if possible to do so without hazard. For small
spills, implement cleanup procedures. For large spills, implement clean-up
procedures and, if in public area, keep public away and advise authorities.
Prevent liquid from entering sewers, water courses, or low areas. Contain
spilled liquid with sand or earth. Recover by pumping or with a suitable
absorbent. If liquid is too viscous for pumping, scrape up. Consult an expert
on disposal of recovered material and ensure conformity to local disposal
regulations.

Water Spill Use booms to confine spills immediately. Remove from water surface by
skimming or with suitable adsorbents. If allowed by local authorities and
environmental agencies, sinking and/or suitable dispersants may be used in
non-confined waters. Consult an expert on disposal of recovered material and
ensure conformity to local disposal regulations.

SECTION 7: HANDLING AND STORAGE

Handling Procedures Avoid all personal contact. Do not use as a cleaning solvent or other non-
motor fuel uses. For use as a motor fuel only. It is dangerous and/or unlawful
to put fuel into unapproved containers. Do not fill container while it is in or on
a vehicle. Static electricity may ignite vapor and cause fire. Place container on
ground when filling and keep nozzle in contact with container. Do not use
electronic devices (including but not limited to cellular phones, computers,
calculators, pagers or other electronic devices etc) in or around any fueling
operation or storage area unless the devices are certified intrinsically safe by
an approved national testing agency and to the safety standards required by
national and/or local laws and regulations. Prevent small spills and leakage to
avoid slip hazard. Do not siphon by mouth. Material can accumulate static
charges which may cause an electrical spark (ignition source). When the
material is handled in bulk, an electrical spark could ignite any flammable
vapors from liquids or residues that may be present (e.g., during switch-
loading operations). Use proper bonding and/or earthing procedures.
However, bonding and earthing may not eliminate the hazard from static
accumulation. Consult local applicable standards for guidance. Additional

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Static Accumulator
Storage Procedures
SECTION 8:
Exposure Controls
Components
Diesel Fuel
Personal Protection
Ventilation Procedures
Respiratory Protection
Hand Protection
Eye Protection
Clothing Recommendation
references include American Petroleum Institute 2003 (Protection Against
Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire
Protection Agency 77 (Recommended Practice on Static Electricity) or
CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance
of hazards due to static electricity).
This material is a static accumulator. A liquid is typically considered a
nonconductive, static accumulator if its conductivity is below 100pS/m
(100x10E-12 Siemens per meter) and is considered a semi conductive, static
accumulator if its conductivity is below 10,000pS/m. Whether a liquid is
nonconductive or semi-conductive, the precautions are the same. A number
of factors, for example liquid temperature, presence of contaminants, anti-
static additives and filtration can greatly influence the conductivity of a liquid.
Do not store near potential sources of ignition. Store in well-ventilated area.
The container choice, for example storage vessel, may affect static
accumulation and dissipation. Keep container closed. Handle containers with
care. Open slowly to control possible pressure release. Store in a cool well-
ventilated area. Storage containers should be earthed and bonded. Fixed
storage containers, transfer containers and associated equipment should be
earthed and bonded to prevent accumulation of static charge.
EXPOSURE CONTROLS AND PERSONAL PROTECTION
CAS-No. Source Value
68476-34-6 ACGIH TWA 100 mg/m3
The use of local exhaust ventilation is recommended to control mists or
vapors. Additional ventilation or exhaust may be required to maintain air
concentrations below exposure limits.
Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Wear appropriate respirator when ventilation is inadequate. Use
NIOSH/OSHA approved full-face respirator with a combination organic vapor
and high efficiency filter cartridge if the recommended exposure limit is
exceeded. Use self-contained breathing apparatus for entry into confined
space, for other poorly ventilated areas and for large spill clean-up sites.
Butyl rubber gloves, nature rubber gloves, neoprene rubber gloves, nitrile
rubber gloves.
Chemical splash goggles.
Use protective clothing which is chemical resistant to this material. Safety
shoes and boots should also be chemical resistant.
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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance Clear liquid

Odor Characteristic of petroleum products
Kinematic Viscosity at 40oC, cSt 3.201
Kinematic Viscosity at 100oC, cSt No data
Specific Gravity at 60°F 0.8405
Flash Point, °C 79
pH No data
Boiling Range, at 760mm Hg, °C 150-360
Melting Point, °C No data
Vapor Pressure, at 20°C, mmHg 0.5
Vapor Density No data
Solubility in Water Insoluble
Evaporation Rate No data
Flammability Flammable
Partition Coefficient >3.3
Auto-ignition Temperature, °C >220
Decomposition Temperature, °C No data
Explosion limits UEL-5%, LEL -0.7%

SECTION 10: STABILITY AND REACTIVITY

Stability Material is normally stable at ambient temperature. Avoid temperatures above

flash point.

Incompatibility May react with strong oxidizing agents

Polymerization Not Applicable

Hazardous Decomposition Thermal decomposition is highly dependent on conditions. Carbon

Products monoxide, carbon dioxide and other organic compounds will be evolved when
this material undergoes combustion or thermal or oxidative degradation. May
form explosive peroxides

SECTION 11: TOXICOLOGICAL INFORMATION

Basis for Assessment Information given is based on data on the components and the
toxicology of similar products.

Acute Toxicity

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 Route of Exposure Conclusion/Remarks
Inhalation
Toxicity (Rat): LC50 >4000mg/m3 Moderately toxic. Based on test data for
structurally similar materials.

Irritation: Data available Elevated temperatures or mechanical

action may form vapors, mist, or fumes
which may be irritating to the eyes, nose,
throat, or lungs. Based on test data for
structurally similar materials.

Ingestion
Toxicity (Rat): LD50> 5000mg/kg Minimally Toxic. May cause mild to severe
lung damage. Based on test data for
structurally similar materials.

Skin
Toxicity (Rat): LD50> 5000mg/kg Minimally Toxic. Based on test data for
structurally similar materials.

Irritation (Rabbit): Data available. Irritating to the skin. Based on test data for
structurally similar materials.

Eye
Irritation (Rabbit): Data available May cause mild, short-lasting discomfort to
eyes. Based on test data for structurally
similar materials.

CHRONIC / OTHER EFFECTS

For the product itself
Vapor concentrations above recommended exposure levels are irritating to
the eyes and the respiratory tract, may cause headaches and dizziness, are
anesthetic and may have other central nervous system effects. Small amounts
of liquid aspirated into the lungs during ingestion or from vomiting may cause
chemical pneumonitis or pulmonary edema.

Diesel fuel: Carcinogenic in animal tests. Caused mutations in-vitro. Repeated

dermal exposures to high concentrations in test animals resulted in reduced
litter size and litter weight and increased fetal resorptions at maternally toxic
doses. Dermal exposure to high concentrations resulted in severe skin
irritation with weight loss and some mortality. Inhalation exposure to high
concentrations resulted in respiratory tract irritation, lung
changes/infiltration/accumulation, and reduction in lung function. Diesel
exhaust fumes: Carcinogenic in animal tests. Inhalation exposures to exhaust
for 2 years in test animals resulted in lung tumors and lymphoma. Extract of
particulate produced skin tumors in test animals. Caused mutations in-vitro.

Reproductive Toxicity Not a developmental toxicant

Carcinogenicity Overall Carcinogenic Evaluation: Group 2B (source: IARC, Toxicology Data

Network)
TWA (100mg/m3 vapor and aerosol as total hydrocarbons)

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 Skin: Confirmed animal carcinogen with unknown relevance to humans

Specific Target Organ Toxicity No available information

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicological data have not been determined specifically for this product. Information given is based
on a knowledge of the components and the ecotoxicology of similar products.

ECOTOXICITY Material – Expected to be toxic to aquatic organisms. May cause long-term

adverse effects in the aquatic environment.

Environmental Mobility Oil component of this product floats and can migrate from water to land.

Environmental Degradability Data have not been determined specifically for this product, but it is expected
to be inherently biodegradable.

Ecotoxicity & Bioaccumulation Data have not been determined specifically for this product, but it is expected
to be harmful to aquatic organisms.

Atmospheric Oxidation More volatile component -- Expected to degrade rapidly in air

SECTION 13: DISPOSAL CONSIDERATIONS

Waste Disposal Material, if discarded, is expected to be hazardous waste due to toxicity.

Waste management should be in compliance with local and national
regulations.

SECTION 14: TRANSPORT INFORMATION

UN
UN Number 1202
Packing Group III
Hazard Class 3

IMDG
UN Number 1202
Hazard Class 3.3
Packaging Group III
IMDG-MFAG 311
Em8 3-07

IATA Cargo Transport

UN Number 1202
Hazard Class 3
Packaging Group III

IATA Cargo Transport

ICAO UN Number 1202
ICAO Packing Group II
ICAO Hazard Class 3

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Label Flammable liquid

SECTION 15: REGULATORY INFORMATION

Material is hazardous under Occupational Safety and Health (Classification, Labeling, and Safety Data Sheet of
Hazardous Chemical) Regulations 2013.

The chemical substances present in this product are listed under Philippine Inventory of Chemicals and Chemical
Substances (PICCS).

SECTION 16: OTHER INFORMATION

Approvals Research and Development Department

Petron Corporation

This safety data sheet contains the following revisions 3

This is a computer-generated form and does not require a signature.

The information and recommendations contained herein are based on the data sheet and sources believed to be accurate and correct and Petron makes no expressed or
implied warranty with respect to the accuracy of the information or the suitability of the recommendations contained in the SDS. It is your responsibility to contact Petron to
ensure that this document is the most current available from Petron. The information and recommendations are offered for the user's consideration and examination. It is the
user's full responsibility to satisfy itself that the product is suitable for the intended use and to ensure the safe handling and use of the product. If the user repackages this
product, it is the user's responsibility to ensure proper health, safety and other necessary information is included with and/or on the container. Appropriate warnings and safe-
handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Petron accepts no responsibility and hereby disclaim all liability
for any harmful effects which may be caused by purchase, resale, use, exposure or disposal of the product. Users must comply with all local laws and regulations. Except to
the extent required by law, re-publication or retransmission of this document, in whole or in part, is not permitted. The term, "Petron" is used for convenience, and may include
any one or more of Petron Corporation, Petron Oil & Gas International Sdn Bhd or any affiliates in which they directly or indirectly hold any interest. In no event, shall Petron or
its suppliers be liable for any direct or indirect loss of profits or for any other special, indirect or consequential damages, nor shall the liability of Petron on any claim for damages
arising out of or connected with the sale, delivery or use of the product purchased exceed the purchase price of the product.

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