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Review Article
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Arthur originates the cohesive gold foil method allowing material, a mixture of bleached gutta‑percha and carbonate
dentists to insert gold into a cavity with minimal pressure. of lime and quartz.[22]
A powdered gold encapsulated in fibrous gold foil was
Various cements have been used under the restorative
introduced in 1962.
material:
In the succeeding years, direct gold changed very little, • 1858 ‑ zinc oxide eugenol cement
except for the introduction of mat gold and gold pellets, • 1860 ‑ zinc oxychloride cement
both of which enhanced the speed of compaction. • 1879 ‑ zinc phosphate cement
• 1920 ‑ calcium hydroxide cement (Hermann).
History of Amalgam
A medical text in China mentions the use of “silver paste,”
History of Tooth Colored Restorative Materials
a type of amalgam in 700. August taveau, of Paris, mixed In 1908, silicate cement was introduced in the United
shavings from French five‑franc pieces with Mercury States, although earlier, cruder forms were used in Europe
in 1826.[16] The Crawcour brothers introduced amalgam in the late 1800s.[23] Silicate cement had the advantage of
into the United States in 1833. Unfortunately, they used high fluoride release but was highly soluble in oral fluids.
the material unscrupulously and gave it a bad name, so
To replace silicate, methacrylate resins were introduced
major rift known as amalgam war occurred. The American
in 1947.[24] These resins have tooth color like appearance,
Society of Dental Surgeons was established and a couple of
insolubility in oral fluids, ease of manipulation and low
years later they banned the use of silver amalgam (1840).
cost. In 1955, Dr. Michael Baunocore opened the way
First amalgam war of bonding of resins by applying phosphoric acid to
enamel.[25,26] As a result, Dr. Ray L. Bowen of American
In 1843, American Society of Dental Surgeons condemned
Dental Association research unit in 1962 developed
the use of all filling materials other than gold as toxic,
a new type of composite material. He innovated
thereby igniting “First Amalgam War.”[17,18] Dr. Towsend
Bis‑GMA, a dimethacrylate resin and organic silane
of Philadelphia (1855) proposed the combination of 4
coupling agent to form a bond between filler particle
parts of Ag and 5 parts of Sn. However, it was unbalanced
and resin matrix.
having poor edge strength and was used until about 1863.
This “battle” pitted many highly‑respected dentists against In the late 1960s and early 1970s, pit and fissure sealants
each other.[19] G.V. Black introduced a balanced amalgam advocated for prevention of caries in children accompanied
formula to the profession in 1895.[20,21] This formulation by early skepticism and later with better material gain
and its derivatives remained essentially unchanged until acceptance.[27,28] Such practice has become widespread and
at least the 1960s and were responsible for the salvation has been responsible for the adoption of very conservative
of countless millions of teeth. In late 1870, an organized restorative procedure.
movement supporting the use of amalgam to become
Microfilled resin introduced in 1977 was highly polishable
known as “new departure” begins.
and stain resistant.[29] First composite was cured by
Second amalgam war chemical activation polymerizing process by mixing two
pastes. Its drawbacks were; trapping of oxygen in pores,
In mid‑1920s German dentist Professor A. Stock started the
inhibit polymerization, and weaken the structure. To
so‑called “Second Amalgam War.” Absorption of mercury
overcome these problems resins were developed which
from dental Amalgam, led to various health problems,
use photosensitive initiator system and light source for
stating that nearly all dentists had excess mercury in their
activation. In 1973, ultraviolet lights were used.[29] Soon it
urine. Mercury released from amalgam responsible for
replaced by more cooler visible light in 1978.
human diseases affecting cardiovascular and nervous system
recovery from multiple sclerosis, Alzheimer’s diseases Microfilled, hybrid, and microhybrid resins are used
when removing amalgam fillings. However, research in extensively in cosmetic procedures, ranging from small
the United States and other countries demonstrated clearly Class III restorations to diastema closures, large Class IV
that there is no cause‑effect relationship between dental restorations, and direct anterior veneers. In addition,
amalgam restoration and other health problems. composite resins have come into widespread use for the
Third amalgam war restoration of all classes of cavities in posterior teeth.
The current controversy, sometimes termed as “Third Historical Development of Glass Ionomer
Amalgam War” began in 1980 primarily through the Cement
seminars and writings of Dr. Huggins, a practicing dentist
GIC was invented in 1968 and first described by Wilson
in Colorado.
and Kent in 1971 which has high fluoride and low
Gutta‑percha was discovered in India in 1842. In 1847, solubility.[30,31] Glass ionomers used the aluminosilicate
Hill Developed “Hill’s‑stopping” a restorative temporary powder from silicates and the polyacrylic acid liquid of
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polycarboxylates. Its earliest commercial product was also French dentist Agiulhon da Saran (1844) reported to form
known as aluminosilicate polyacrylic acid. investment mold from the impression of the cavity and
pour gold to make inlay.
In 1980s, to increase physical properties of GIC, it was
modified by adding metal filler particles and termed as Ceramic
metal modified GIC which are of two types: miracle mix
In 16 century, Jacques Guillemeau (1550–1613 AD)
(Simmons 1983) and cermet (Lean and Gasser 1985)
prepared a paste by fusing waxes gums, ground mastic,
particle reinforced.
and powdered pearl and white corelle. It was used as filling
In early 1990s, GIC was further modified by replacing filler material. It is a forerunner of esthetic fused porcelain.
particle and making the setting reaction more composite Gueseppangelo Fonzi (1806) prepared 1st baked porcelain
like and termed as resin‑modified glass ionomer. single tooth with attached platinum hooks. He also made
Polyacid‑modified resin composite or compomers is 26 shades of porcelain by using metal oxides. Porcelain
most recent evolution of GIC. It has 2 components: inlays were described at least as early as 1857. In the
polymer‑based composite and glass ionomer except water. period from 1900 to 1910, there was a particularly large
It is excluded to prevent premature setting of material number of articles published on porcelain inlays, whereas
and to ensure that setting occurs through polymerization after 1915 the number was vastly reduced.
reaction. 1902
Indirect Restorative Materials Dr. C. H. Land develop fused porcelain jacket crown design
to replace all or major part of the enamel of the tooth.
Indirect restorations have generally been fabricated from
impressions taken of prepared teeth. 1908‑Basic principle of porcelain inlay given by John Q
Byram.
The earliest impression was probably beeswax. A reference
to the use of wax for dental impressions was made in In recent years, inlays and onlays nade of high strength
1684 by a German surgeon.[32] Wax was a poor impression plastic materials and porcelain have been introduced.
material by todays’ standards, but it functioned adequately In 1985, the first ceramic inlay made by a chairside
in its day by being capable of removal over undercuts. computer‑aided design/computer‑aided manufacturing
Still, for the present time Von Horn (1910) recommended device was cemented into a patient’s tooth.[37] In 2000, the
wax pattern investment at a temperature equal to mouth CEREC 3® was introduced. This latest system provides a
temperature using high silica content investment. means by which a sophisticated ceramic inlay or onlay can
be fabricated, with a hand‑held scanner reading the details
Gutta‑percha, obtained from certain trees in Malaysia, may
of the preparation and software subsequently being used to
have been introduced as impression material in 1848, but it
drive the mechanism to precision mill (grind) a restoration
was not very satisfactory for the purpose.
without the use of an impression and without the need for a
Reversible hydrocolloid was introduced to the second dental appointment.
dental profession in 1925, 85 by Alphonse Poller, an
Financial support and sponsorship
Austrian.[33] The product was patented as “Nogacoll.”
In 1931, the material was also sold under the name of Nil.
“denticole.” The fundamental ingredient of hydrocolloid is
Conflicts of interest
agar‑agar, a colloid obtained from seaweed.
There are no conflicts of interest.
During the World War II era, or just before, irreversible
hydrocollois was developed and they were introduced to References
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