Sec: SR.

IIT_*COSC(MODEL-A&B) WAT-54 Date: 14-07-24

Time: 3 Hrs 2018_P1 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 ABCD 2 ABC 3 ABC 4 ABC 5 ACD
6 AB 7 7 8 4 9 8 10 7
11 3 12 5 13 3 14 6 15 A
16 A 17 A 18 A

PHYSICS
19 BD 20 AD 21 AC 22 ABC 23 ACD
124.00 17.00
24 C 25 to 26 20 27 2500 28 to
126.00 18.00
4135
29 to 30 0.3 31 3.5 32 0.5 33 A
4145
34 B 35 C 36 D

CHEMISTRY
37 ABCD 38 ACD 39 ABC 40 ABD 41 ABC
42 AB 43 4 44 280.80 45 23 46 4
47 12 48 5 49 3 50 1.80 51 D

52 C 53 C 54 D
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SOLUTIONS
MATHEMATICS
1.

2.

5.

6.

7.

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8.

9.

11.

12.

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13.

14.

CHEMISTRY
37. All these salts react with dil.H 2 SO4

Hence,(A), (B), (C)and(D)are the correct answers.

38. White salts orions giving colourless beads donot give borax bead test.

Hence,(A),(C)and(D)are the correct answers.

39. AgCliscompletelysolublewhileAgBrispartiallysolubleinNH4OH. Hence, (A)

and (B)and (C) are the correct answers.
40. Chromyl chloride test
41. Ag 2 SO3  H  
 2 Ag   SO2  H 2O
42. A,B do not have plane of symmetry

(C)  PtCl  dien   Cl complex is square planar whereas  NiCI 2  PPh3  2  is tetrahedral.

(D Co  NO3 3  NH 3 3  has plane of symmetry but cis   Pt  en  2 Cl2  Cl2 shows optical isomerism

43. Hybridisation of Cr in (A) and (B) is d 2 sp 3 having 3 unpaired electrons  3d 3 

For d 3 configuration, the magnetic moment is always 3.87 with weak field or strong field liagnd.
Magnetic moment = 3.87 B.M.

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2
44. Net stabilization energy of Fe with CN –
ligands t 2 g 2,2,2 eg 0,0  – 2.40  2 P  m  –2.4  25000  2  15000  cm –1
 –30000 cm –1
Net stabilisation energy of Fe 2  ions with H2O ligands t 2 g 2,1,1 eg 1,1  – 0.40
 4000 cm –1
So required difference  26000 cm –1  26  105 m –1

 6  10 –34  3  108 26  105  6  10 23  10 –3 kJ / mole

 2808  10 –1 kJ / mole  280.8 kJ / mol
45. The brown ring is due to the formation of complex,  Fe  H 2O 5 NO  SO4 .
46. transition metal ions give
47. all will give either NO2 or O2
48. except sulphate all evolve gases
The complex Co  en  NH 3 3  H 2O  
3
49. has two following isomers:

Option (B): When bidentate ‘en’ is replaced by two cyanide ligands complex
Co  CN  2  NH 3 3  H 2O   will have three following isomers:


Option (D): In complex Co  en  NH 3 4 

3
there is larger gap between t2 g and eg than in complex

Co  en  NH 3 3  H 2O   . Hence Co  en  NH 3 3  H 2O  

3 3
will absorb light at longer

wavelength as compared to Co  en  NH 3 4 

3

9
50.  1.80
5
51. NH 4 NaHPO4  4 H 2O  NH 3  NaPO3  5H 2O
P Q

NaPO3  CoO  NaCoPO4

 bluebead 
52. CONCEPTUAL

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