Download as pdf or txt
Download as pdf or txt
You are on page 1of 8

International Journal of Trend in Scientific Research and Development (IJTSRD)

Volume 8 Issue 2, March-April 2024 Available Online: www.ijtsrd.com e-ISSN: 2456 – 6470

Potential of Polyaniline as a Versatile Conducting Polymer


Jasvinder Kaur Bindra
Assistant Professor, Vasant Rao Naik College, Jalna Road, Aurangabad, Maharashtra, India

ABSTRACT How to cite this paper: Jasvinder Kaur


Conducting polymers have attracted significant interest due to their Bindra "Potential of Polyaniline as a
unique combination of electrical conductivity and the properties of Versatile Conducting Polymer"
conventional polymers. Among them, polyaniline stands out as a Published in
promising material owing to its exceptional properties, facile International Journal
of Trend in
synthesis, environmental stability, and versatility. This review Scientific Research
provides a comprehensive overview of polyaniline, covering its and Development
synthesis methods, structure and properties, diverse applications, (ijtsrd), ISSN: 2456-
recent advances, and future perspectives. Chemical and 6470, Volume-8 | IJTSRD64569
electrochemical polymerization represent the primary synthesis Issue-2, April 2024,
routes, while novel approaches like template-assisted, microwave- pp.115-122, URL:
assisted, and green synthesis methods have emerged. Polyaniline www.ijtsrd.com/papers/ijtsrd64569.pdf
exhibits tunable electrical conductivity, reversible redox behavior,
and characteristic optical properties arising from its conjugated Copyright © 2024 by author (s) and
structure. Its applications span conductive coatings, anticorrosion International Journal of Trend in
Scientific Research and Development
coatings, sensors, energy storage devices, and emerging areas like Journal. This is an
flexible electronics and bioelectronics. Open Access article
Recent research efforts have focused on functionalization strategies, distributed under the
nano-structuring, and advanced characterization techniques to terms of the Creative Commons
enhance polyaniline’s performance and overcome limitations such as Attribution License (CC BY 4.0)
(http://creativecommons.org/licenses/by/4.0)
poor processability and environmental instability. Despite the
progress made, challenges persist, necessitating further investigation
KEYWORDS: Potential of
into improving conductivity, stability, and solubility. Future
Polyaniline, Electrical Conductivity,
directions include integrating polyaniline with emerging
Versatile Polymer
technologies, exploring sustainable synthesis methods, and
developing advanced energy storage and biomedical applications.
Overall, this review highlights the immense potential of polyaniline
as a versatile conducting polymer and provides insights into ongoing
research and future opportunities in this exciting field.

INTRODUCTION
Conducting polymers represent a unique class of redox behavior, good mechanical strength, and
materials that possess both the properties of chemical stability, making it an attractive candidate
conventional organic polymers and the electrical for a wide range of applications. Its unique
conductivity of metals. Initially discovered in the combination of properties has led to extensive
1970s, these materials have garnered significant research efforts aimed at exploring its potential in
attention due to their intriguing combination of fields such as corrosion protection, sensing, energy
properties and their potential applications in various storage, and electrochemical devices.
fields such as electronics, sensors, energy storage, and
The primary objective of this review paper is to
biomedical devices. The development of conducting provide a comprehensive overview of the current
polymers has opened up new avenues for research
state of research on polyaniline as conducting
and innovation in materials science and engineering. polymers. By synthesizing and analyzing the existing
Among the various conducting polymers, polyaniline literature, this paper aims to:
holds particular significance due to its exceptional  Summarize the various synthesis methods of
properties, facile synthesis methods, environmental polyaniline and their respective advantages and
stability, and versatility in applications. Polyaniline limitations.
exhibits tunable electrical conductivity, reversible

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 115
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
 Examine the structural and property gold, or indium tin oxide) through the application of
characteristics of polyaniline, including its an electric potential. The electrolyte solution typically
electronic structure, conductivity mechanisms, contains aniline monomers, dopants, and supporting
and physical properties. electrolytes to facilitate polymerization and enhance
 Explore the diverse applications of polyaniline in conductivity.
fields such as coatings, sensors, energy storage Electrochemical polymerization allows for fine-
devices, and beyond. tuning of the polymerization conditions, such as the
 Discuss recent advances in polyaniline research, applied potential, electrolyte composition, and
including novel synthesis approaches, deposition time, to control the thickness, morphology,
functionalization techniques, and emerging and conductivity of the resulting polyaniline films.
applications. Moreover, this method enables the direct deposition
of polyaniline onto specific substrates, making it
 Identify the challenges and limitations associated suitable for applications such as coatings, sensors,
with polyaniline and propose potential strategies and electronic devices. However, electrochemical
for addressing them. polymerization requires specialized equipment and
 Provide insights into future research directions expertise, limiting its scalability for industrial
and potential applications of polyaniline-based production compared to chemical polymerization.
materials. In addition to chemical and electrochemical
Through this review, we aim to contribute to the polymerization, several alternative methods have
collective understanding of polyaniline as a been developed for synthesizing polyaniline with
conducting polymer and stimulate further research unique structures and properties. These include:
and development in this exciting field.  Template-assisted synthesis: Utilizing templates
Synthesis Methods of Polyaniline or sacrificial substrates to control the morphology
Chemical Polymerization and structure of polyaniline during synthesis.
Chemical polymerization represents one of the most  Microwave-assisted synthesis: Applying
widely used methods for synthesizing polyaniline due microwave irradiation to accelerate the
to its simplicity, scalability, and versatility. In this polymerization process and improve the yield and
method, aniline monomers undergo oxidative purity of polyaniline.
polymerization in the presence of a suitable oxidizing
agent. Common oxidizing agents employed in  Supercritical fluid synthesis: Employing
chemical polymerization include ammonium supercritical fluids as reaction media to enhance
persulfate (APS), potassium permanganate (KMnO₄), the solubility, reactivity, and control over the
ferric chloride (FeCl₃), and hydrogen peroxide polymerization process.
(H₂O₂). The polymerization process typically occurs  Interfacial polymerization: Conducting
in aqueous or organic solvents at room temperature or polymerization at the interface between
slightly elevated temperatures. immiscible phases to produce polyaniline
Various factors such as the choice of oxidizing agent, nanoparticles or composite materials with tailored
solvent, temperature, and pH influence the properties properties.
of the resulting polyaniline, including its molecular These alternative methods offer unique advantages
weight, chemical structure, morphology, and such as rapid synthesis, improved control over
conductivity. Moreover, the addition of dopants morphology, and the ability to produce novel
during polymerization can further modulate the polyaniline nanostructures or composites. By
properties of polyaniline, such as its conductivity, expanding the repertoire of synthesis methods,
stability, and color. Chemical polymerization offers researchers can further explore the diverse properties
excellent control over the synthesis parameters, and applications of polyaniline in various fields.
enabling the production of polyaniline with tailored
Structure and Properties of Polyaniline
properties for specific applications.
Chemical Structure
Electrochemical Polymerization Polyaniline is a conjugated polymer composed of
Electrochemical polymerization offers a precise and repeating units of aniline monomers linked together
controllable method for synthesizing polyaniline through covalent bonds. The chemical structure of
films with well-defined structures and properties. In polyaniline consists of alternating aromatic rings and
this technique, aniline monomers are polymerized on nitrogen atoms, giving rise to its π-conjugated
the surface of a conductive substrate (e.g., platinum, backbone. The polymerization of aniline can occur in

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 116
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
different oxidation states, resulting in various forms applications such as electrochromic devices and
of polyaniline, including emeraldine base, emeraldine sensors.
salt, and pernigraniline.
In terms of mechanical properties, polyaniline
In its most common form, known as emeraldine base, exhibits good flexibility, processability, and
polyaniline exhibits a semi-ordered structure with mechanical strength, allowing it to be fabricated into
alternating single and double bonds along the various forms such as films, fibers, coatings, and
polymer chain. The nitrogen atoms in the polymer composites. The mechanical properties of polyaniline
backbone can be protonated or deprotonated, leading can be further enhanced through structural
to changes in the polymer’s electrical conductivity, modifications or by blending with other polymers or
optical properties, and chemical reactivity. The reinforcing materials.
chemical structure of polyaniline can be further
Overall, the unique combination of electrical, optical,
modified through doping or functionalization to tailor
and mechanical properties makes polyaniline a
its properties for specific applications.
promising candidate for a wide range of applications,
Conducting Mechanisms including sensors, actuators, electronic devices,
The electrical conductivity of polyaniline arises from energy storage devices, and functional coatings.
the delocalization of π-electrons along its conjugated
Applications of Polyaniline
backbone, enabling the transport of charge carriers
Conductive Coatings
through the polymer matrix. The conducting
Polyaniline’s high electrical conductivity, coupled
mechanisms in polyaniline depend on its oxidation
with its corrosion resistance and adhesion properties,
state and chemical environment. In its fully reduced
makes it an excellent candidate for conductive
form (leucoemeraldine base), polyaniline is an
coatings. These coatings find applications in various
insulator due to the absence of π-conjugation.
industries, including electronics, aerospace,
Upon oxidation, polyaniline undergoes a transition to automotive, and telecommunications. Polyaniline
a conducting state (emeraldine salt), where charge coatings can be applied through techniques such as
carriers (polarons and bipolarons) are generated spray coating, dip coating, or electrodeposition. They
through the doping of nitrogen atoms with protonic are used to impart conductivity to non-conductive
acids. These charge carriers facilitate the conduction substrates, protect against electrostatic discharge, and
of electricity through the polymer chain via hopping provide electromagnetic interference (EMI) shielding.
or tunneling mechanisms. The conductivity of Additionally, polyaniline coatings are employed in
polyaniline can be further enhanced by increasing the flexible electronics, smart textiles, and anti-static
degree of doping or by introducing dopants that packaging materials.
facilitate charge transport.
Anticorrosion Coatings
The conducting mechanisms in polyaniline are highly Polyaniline-based anticorrosion coatings offer a
sensitive to factors such as oxidation state, doping promising solution for protecting metallic surfaces
level, chemical structure, and morphology, making it from corrosion in harsh environments. By forming a
possible to modulate its electrical conductivity over a dense and adherent polymer film on the substrate
wide range. surface, polyaniline coatings act as a barrier against
Electrical, Optical, and Mechanical Properties corrosive agents such as moisture, salts, acids, and
Polyaniline exhibits a unique combination of alkalis. Furthermore, the intrinsic redox properties of
electrical, optical, and mechanical properties that polyaniline enable self-healing mechanisms, where
make it attractive for various applications. In terms of the polymer can undergo reversible oxidation and
electrical properties, polyaniline can exhibit both reduction processes to repair damaged areas and
metallic and semiconducting behavior depending on prolong the coating’s lifespan. Polyaniline
its oxidation state and doping level. The electrical anticorrosion coatings find applications in marine, oil
conductivity of polyaniline can range from insulating and gas, automotive, and infrastructure sectors,
(10^-10 S/cm) in its reduced state to highly offering superior corrosion protection compared to
conductive (10^2 S/cm) in its oxidized and doped traditional coatings.
states. Sensors and Biosensors
Optically, polyaniline displays a characteristic color Polyaniline’s sensitivity to various analytes and its
change upon oxidation and doping, transitioning from facile modification make it an attractive material for
a colorless or pale yellow in its reduced state to green, sensor and biosensor applications. Polyaniline-based
blue, or violet in its oxidized and doped states. This sensors can detect a wide range of analytes, including
tunable optical behavior has been exploited in gases, vapors, chemicals, ions, and biomolecules. The

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 117
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
conductivity of polyaniline changes in response to the material for addressing diverse societal and
presence of analytes, enabling the development of technological challenges. Continued research and
electrochemical, optical, and impedance-based development efforts are expected to further expand
sensing platforms. Polyaniline sensors are used in the scope of polyaniline applications in the future.
environmental monitoring, food safety, medical
Recent Advances in Polyaniline Research
diagnostics, industrial process control, and homeland
Novel Synthesis Approaches
security applications. Moreover, the biocompatibility
Recent research in polyaniline synthesis has focused
and stability of polyaniline make it suitable for
on developing novel approaches to enhance control
fabricating implantable biosensors for healthcare and
over the polymerization process and tailor the
biomedical research.
properties of the resulting materials. Some notable
Energy Storage Devices advances include:
Polyaniline exhibits pseudocapacitive behavior and 1. Green synthesis methods: Utilizing
high specific capacitance, making it a promising environmentally friendly reagents and sustainable
candidate for energy storage devices such as approaches to synthesize polyaniline, such as
supercapacitors and batteries. Polyaniline-based using natural dopants or renewable resources as
electrodes can store and release charge rapidly starting materials.
through reversible redox reactions at the electrode- 2. Template-directed synthesis: Employing
electrolyte interface. Supercapacitors incorporating templates or nanostructures as guides to control
polyaniline offer high power density, fast the morphology and structure of polyaniline,
charging/discharging rates, and long cycle life, leading to the fabrication of well-defined
making them suitable for applications requiring rapid nanostructures with enhanced properties.
energy storage and release, such as electric vehicles,
renewable energy systems, and portable electronics. 3. Microwave-assisted and sono-chemical
Additionally, polyaniline can be integrated into synthesis: Harnessing microwave irradiation or
hybrid electrode materials for lithium-ion batteries, ultrasound waves to accelerate the polymerization
enhancing their cycling stability and rate process, reduce reaction times, and improve the
performance. yield and purity of polyaniline.
4. In situ polymerization techniques: Integrating
Other Emerging Applications
polymerization with other processes or substrates
In addition to the aforementioned applications,
to directly deposit polyaniline onto specific
polyaniline is being explored for various emerging
surfaces or interfaces, enabling the fabrication of
applications, including:
functionalized materials and devices.
Flexible and stretchable electronics: Polyaniline’s
Functionalization Techniques
mechanical flexibility and conductivity make it
Functionalization of polyaniline involves modifying
suitable for flexible and stretchable electronic devices
its chemical structure or surface properties to impart
such as wearable sensors, e-skins, and conformal
specific functionalities or enhance its performance in
electronics.
various applications. Recent advances in
Tissue engineering and regenerative medicine: functionalization techniques include:
Polyaniline-based scaffolds and substrates are being 1. Surface modification: Coating polyaniline with
investigated for their potential in promoting cell thin films or functional layers to improve its
adhesion, proliferation, and differentiation in tissue stability, adhesion, and compatibility with
engineering and regenerative medicine applications. different substrates or environments.
Water purification: Polyaniline-based adsorbents 2. Chemical doping and cross-linking: Introducing
and membranes show promise for removing dopants or cross-linking agents to modify the
pollutants and contaminants from water through electronic structure, conductivity, and mechanical
processes such as adsorption, filtration, and properties of polyaniline, thereby tailoring its
photocatalysis. suitability for specific applications.
Gas separation and purification: Polyaniline 3. Molecular engineering: Designing and
membranes and films exhibit selective permeability to synthesizing novel polyaniline derivatives with
specific gases, enabling their use in gas separation tailored chemical structures and functionalities to
and purification processes for industrial and achieve desired properties such as solubility,
environmental applications. processability, and biocompatibility.
These emerging applications highlight the versatility 4. Biomimetic approaches: Drawing inspiration
and multifunctionality of polyaniline as a promising from biological systems to engineer polyaniline-

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 118
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
based materials with hierarchical structures, self- behavior for advanced applications in sensing,
healing capabilities, or stimuli-responsive actuation, and drug delivery.
Characterization Methods
Advances in characterization methods have enabled researchers to probe the structural, morphological, and
electronic properties of polyaniline with unprecedented precision and resolution. Key techniques include:
1. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM): Providing high-
resolution imaging of polyaniline morphology, nanostructure, and particle size distribution.
Chemically Synthesized Electrochemically Template-Synthesized
Property
Nanofibers Synthesized Films Nanotubes
350 ± 150 nm Outer: 230 ± 30 nm
Diameter 65 ± 25 nm (average)
(globular, average) Inner: 70 ± 10 nm
20% < 1 μm - Up to 50 μm
Length 60% between 1-5 μm
20% > 5 μm
Core: 40 ± 15 nm
Core/Wall - Wall thickness: 20-50 nm
Skin layer: 10 ± 5 nm
Crystallinity - 25-40% (from XRD) -
Roughness - 10-30 nm (RMS) -
2. X-ray diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR): Offering insights into the
crystalline structure, molecular conformation, and chemical bonding of polyaniline.
Technique Property Value/Range
Crystallinity index 20-50% for chemically synthesized PANI
2θ = 15.2° (011), 20.6° (020), 25.4° (200) for
Major diffraction peaks
X-ray Diffraction emeraldine salt
(XRD) Crystallite size (from FWHM of
5-15 nm for PANI nanofibers
(020) peak)
Interplanar spacing (d-spacing) ~0.43 nm for emeraldine salt (from (020) peak)
Quinoid/Benzenoid ring stretching 1566 cm^-1 / 1482 cm^-1 for emeraldine salt
Fourier-Transform Oxidation state estimation
0.5 (leucoemeraldine) to 1.2 (emeraldine salt)
Infrared (I1566/I1482 ratio)
Spectroscopy 1300 cm^-1 (C-N), 1240 cm^-1 (C=N), 800 cm^-1
Other characteristic peaks
(FTIR) (aromatic C-H)
N-H stretching band ~3400 cm^-1 (protonation and hydrogen bonding)
3. X-ray photoelectron spectroscopy (XPS) and nuclear magnetic resonance (NMR) spectroscopy:
Characterizing the elemental composition, oxidation states, and chemical environments of polyaniline,
elucidating its electronic structure and doping mechanisms.
Technique Property Value/Range
399.0-399.5 eV (benzenoid N), 400.5-401.5 eV
Nitrogen 1s binding energies
X-ray (quinoid N=), 403-405 eV (positively charged N+)
Photoelectron 0.16-0.18 for emeraldine base, 0.22-0.25 for
Atomic composition (N/C ratio)
Spectroscopy emeraldine salt
(XPS) 0.25-0.5 (leucoemeraldine), 0.5 (emeraldine base),
Oxidation state estimation
0.75 (emeraldine salt)
6.5-7.5 ppm (aromatic protons), 3-4 ppm (N-H
1H NMR chemical shifts
protons)
120-145 ppm (aromatic carbons), 150-165 ppm
Nuclear Magnetic 13C NMR chemical shifts
(quinoid carbons)
Resonance (NMR)
3JH-H = 7-9 Hz (aromatic protons), 3JC-N = 5-7
Spectroscopy Spin-spin coupling constants
Hz (C-N bonds)
Increased broadening with higher oxidation state
Linewidth/Peak broadening
(emeraldine salt)

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 119
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
4. Electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV): Investigating the
electrochemical behavior, redox properties, and charge transport mechanisms of polyaniline-based electrodes
and devices.
Technique Property Value/Range
10-1000 Ω cm^2 (depending on doping level
Charge transfer resistance (Rct)
and electrode composition)
Electrochemical Double-layer capacitance (Cdl) 10-100 μF cm^-2
Impedance Spectroscopy 0.1-0.5 Ω cm^2 s^-1/2 (indicating diffusion-
Warburg coefficient (σ)
(EIS) controlled processes)
10^-5 - 10^2 S cm^-1 (depending on oxidation
Electrical conductivity
state and doping level)
+0.2 V (leucoemeraldine/emeraldine) and +0.7
Redox peak potentials
V (emeraldine/pernigraniline) vs. Ag/AgCl
0.2-0.4 V (indicating quasi-reversible redox
Cyclic Voltammetry Peak separation (ΔEp)
behavior)
(CV)
200-800 F g^-1 (depending on electrode
Specific capacitance
composition and electrolyte)
Cyclic stability >80% capacitance retention after 1000 cycles

Cutting-Edge Applications Challenges and Future Perspectives


Recent advancements in polyaniline research have Limitations of Polyaniline
paved the way for the development of innovative Despite its promising properties and widespread
applications across diverse fields. Some cutting-edge applications, polyaniline still faces several limitations
applications include: that hinder its full potential utilization. Some of the
1. Flexible and stretchable electronics: Integrating key challenges include:
polyaniline-based conductive polymers into 1. Poor processability: Polyaniline exhibits limited
flexible and stretchable substrates for wearable solubility in common solvents, making it
electronics, electronic skin, and soft robotics. challenging to process into desired forms such as
thin films, fibers, or composites.
2. Smart textiles and wearable sensors:
Incorporating polyaniline coatings or fibers into 2. Environmental instability: Polyaniline can
textiles to impart conductivity, sensing undergo degradation upon prolonged exposure to
capabilities, and functional properties such as oxygen, moisture, and UV radiation, leading to
moisture sensing, temperature regulation, and loss of conductivity and mechanical properties.
antibacterial activity. 3. Limited conductivity: Intrinsic conductivity of
3. Bioelectronics and implantable devices: polyaniline is lower compared to metals and other
Engineering biocompatible polyaniline-based conducting polymers, restricting its performance
materials for bioelectronic devices, neural in high-conductivity applications.
interfaces, and drug delivery systems with 4. Doping-induced variability: The conductivity and
enhanced biocompatibility, stability, and properties of polyaniline strongly depend on the
responsiveness to physiological signals. type and level of dopants used, leading to
4. Environmental remediation and energy variability in performance and reproducibility.
harvesting: Utilizing polyaniline-based materials Strategies for Improving Performance
for pollutant removal, water purification, and Addressing the limitations of polyaniline requires the
energy conversion/storage applications, including development of innovative strategies to enhance its
solar cells, supercapacitors, and batteries, to performance and overcome existing challenges. Some
address pressing environmental and energy potential approaches include:
challenges. 1. Solubility enhancement: Designing novel
These cutting-edge applications demonstrate the polyaniline derivatives with improved solubility
versatility, adaptability, and potential impact of and processability through chemical modification
polyaniline-based materials in addressing societal or molecular engineering.
needs and driving technological innovation in the 21st 2. Stability improvement: Incorporating stabilizing
century. agents, protective coatings, or nanostructures to

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 120
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
enhance the environmental stability and durability material for various applications ranging from
of polyaniline-based materials. conductive coatings to energy storage devices.
3. Conductivity enhancement: Exploring new  Chemical and electrochemical polymerization are
doping strategies, nano structuring techniques, or the primary methods for synthesizing polyaniline,
composite formulations to increase the with recent advances in green synthesis, template-
conductivity and charge transport properties of directed synthesis, and in situ polymerization
polyaniline. techniques.
4. Process optimization: Optimizing synthesis,  Recent research efforts have focused on
processing, and fabrication parameters to achieve enhancing the performance of polyaniline through
better control over the morphology, structure, and functionalization, nano structuring, and process
properties of polyaniline-based materials. optimization to overcome limitations such as poor
Potential Future Directions in Research and solubility, environmental instability, and limited
Applications conductivity.
Looking ahead, several exciting research directions  Polyaniline finds applications in diverse fields
and potential applications of polyaniline are including electronics, sensors, biomedical
emerging, including: devices, energy storage, and environmental
1. Advanced energy storage and conversion remediation, with emerging opportunities in
devices: Exploiting the high surface area, redox flexible electronics, smart textiles, and sustainable
activity, and pseudocapacitive behavior of technologies.
polyaniline for next-generation batteries,
supercapacitors, and electrochemical capacitors. Implications for the Field
The findings presented in this review have significant
2. Biomedical and healthcare applications:
implications for the field of conducting polymers and
Harnessing the biocompatibility, conductivity,
materials science:
and stimuli-responsive behavior of polyaniline for
 Understanding the synthesis methods, structure-
biomedical sensors, drug delivery systems, tissue
property relationships, and applications of
engineering scaffolds, and implantable devices.
polyaniline can guide researchers and engineers in
3. Sustainable and green technologies: Developing designing and developing tailored materials for
eco-friendly synthesis methods, recyclable specific applications.
materials, and energy-efficient processes for the
production and utilization of polyaniline-based  Advances in polyaniline synthesis,
materials in environmental remediation, catalysis, functionalization, and characterization techniques
and green energy technologies. open up new avenues for research and innovation
in areas such as nanotechnology, biotechnology,
4. Integration with emerging technologies: and sustainable materials.
Exploring synergies between polyaniline and
emerging technologies such as 3D printing,  The diverse applications of polyaniline highlight
nanotechnology, artificial intelligence, and its potential to address pressing societal
internet-of-things (IoT) for innovative challenges in areas such as energy storage,
applications in smart materials, wearable healthcare, environmental protection, and
electronics, and internet-connected devices. sustainable development.
By addressing the current challenges and pursuing Call to Action for Further Research
these future research directions, polyaniline has the Despite the progress made in polyaniline research,
potential to revolutionize various industries, several challenges and opportunities remain,
contribute to sustainable development, and address necessitating further investigation:
pressing societal needs in the coming years.  Continued research is needed to overcome the
limitations of polyaniline such as poor solubility,
Conclusion environmental instability, and limited
Summary of Key Findings conductivity through the development of novel
In this review, we have provided a comprehensive synthesis methods, functionalization strategies,
overview of polyaniline as a conducting polymer, and characterization techniques.
covering its synthesis methods, structure and
properties, applications, recent advances, challenges,  Exploring new applications and integrating
and future perspectives. Key findings include: polyaniline with emerging technologies such as
 Polyaniline exhibits unique electrical, optical, and additive manufacturing, artificial intelligence, and
mechanical properties, making it a versatile internet-of-things (IoT) can unlock novel

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 121
International Journal of Trend in Scientific Research and Development @ www.ijtsrd.com eISSN: 2456-6470
functionalities and enable transformative [3] Fratodornio, S. S., Radomskkaya, E. I.,
advancements in materials science and Baĭdakov, V. G., & Apekian, B. V. (1988).
engineering. Polyaniline: Synthesis and properties. Russian
 Collaborative efforts between academia, industry, Chemical Reviews, 57(7), 660–677.
and government agencies are essential to [4] Ćirić-Marjanović, G. (2013). Recent advances
accelerate the translation of research findings into in polyaniline research: Polymerization
practical applications, address societal needs, and processes, structural aspects, properties and
foster innovation in the field of conducting applications. Synthetic Metals, 177, 1–47.
polymers. https://doi.org/10.1016/j.synthmet.2013.06.004
In conclusion, polyaniline holds great promise as a [5] Huang, J., & Kaner, R. B. (2004). A general
versatile and multifunctional material with chemical route to polyaniline nanofibers.
applications across diverse fields. By addressing the Journal of the American Chemical Society,
current challenges and embracing future 126(3), 851–855.
opportunities, researchers can unlock the full https://doi.org/10.1021/ja0371754
potential of polyaniline and drive forward the [6] Letheby, H. (1862). XXIV.—On the production
frontiers of materials science and technology. of a blue substance by the electrolysis of
References: sulphate of aniline. Journal of the Chemical
[1] MacDiarmid, A. G. (2001). “Polyaniline and Society, 15, 161–163.
polypyrrole: Where are we headed?”. Synthetic https://doi.org/10.1039/JS8621500161
Metals, 125(1), 11–22. [7] Argun, A. A., Cirpan, A., & Reynolds, J. R.
https://doi.org/10.1016/S0379-6779(01)00508- (2003). The first truly all-polymer
2 electrochromic devices. Advanced Materials,
[2] Bhadra, S., Khastgir, D., Singha, N. K., & Lee, 15(16), 1338–1341.
J. H. (2009). Progress in preparation, [8] Zhang, X., Goux, W. J., & Manohar, S. K.
processing and applications of polyaniline. (2004). Synthesis of polyaniline nanofibers by
Progress in Polymer Science, 34(8), 783–810. “nanofiber seeding”. Journal of the American
https://doi.org/10.1016/j.progpolymsci.2009.04. Chemical Society, 126(14), 4502–4503.
003

@ IJTSRD | Unique Paper ID – IJTSRD64569 | Volume – 8 | Issue – 2 | Mar-Apr 2024 Page 122

You might also like