Sec: INSR.IIT_*CO SC(MODEL-A) WAT-59 Date: 21.08.

22
Time: 3 HRS 2014_P2 Max. Marks: 180
KEY SHEET
PHYSICS
1 C 2 B 3 D 4 D 5 D
6 B 7 A 8 D 9 A 10 C
11 C 12 C 13 B 14 D 15 B
16 A 17 B 18 B 19 C 20 D

CHEMISTRY
21 C 22 C 23 A 24 A 25 D

26 A 27 C 28 B 29 B 30 B

31 A 32 C 33 D 34 D 35 A

36 C 37 A 38 D 39 B 40 C

MATHEMATICS
41 B 42 C 43 C 44 D 45 A

46 C 47 B 48 A 49 B 50 D

51 B 52 A 53 A 54 B 55 D

56 B 57 A 58 B 59 C 60 D
Narayana IIT Academy 21-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-59_Key&Sol’s
SOLUTIONS
PHYSICS
9
2D 2  600  10 2
3. 
a 10 3
= 2.4 × 10–3 m = 2.4mm

I0 I0 /2
4.
 I0  I0
 
 2 cos 60º =2 8 .
1
15. 
mq
12.27
16.  e = Å
V

CHEMISTRY
21. Conceptual
22. Conceptual
23. Conceptual
24. Conceptual
25. Conceptual
26. Conceptual

27. MgCl 2 .6H 2 O   MgO  2HCl  5H 2O
 3
2K 2 Cr2 O 7   2K 2 CrO 4  Cr2 O3  O 2 
2

K 2 CO3   does not decompose but melts
 1
Cu(NO3 ) 2   CuO  2NO 2   O 2 
2

28. MgCl 2 .6H 2 O   MgO  2HCl  5H 2O

29. 2FeSO 4 .7H 2 O 
300ºC
14H 2 O
2FeSO 4   Fe 2 O3 (s)  SO 2  SO3 

30. 2NH 4 ClO 4   N 2   Cl 2  2O 2  4H 2 O

CaCOl   CaO CO2 
Basic Acidic

NH 4 NO 2 
 N 2  2H 2 O
1
NaNO3  below
500ºC
 NaNO 2  O 2 
2
31. (1) For salt ‘R’

(A) NH 4 NO3   N 2O  H 2O
( Neutral) ( Neutral)

(B) (NH 4 ) 2 CO3 
 NH 3   CO 2   H 2 O
(Basic) (Acidic)

(C) (NH 4 ) 2 S 
 NH 3   H 2S 
(Basic) (Acidic)

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Narayana IIT Academy 21-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-59_Key&Sol’s

(D) NH 4 Cl 
 NH 3   HCl 
(Basic) (Acidic)


32. (C) (NH 4 ) 2 CrO 7   N 2  Cr2 O3  H 2 O
(Orange) ( Neutral (Coloured ( Neutral
gas) solid) vapours)

33.  2FeSO 4   Fe 2 O3  SO 2  SO3 

 SnSO 4   SnO 2  SO 2 

 H 2 C 2 O 4   CO   CO 2   H 2 O

 2Na 2 HPO 4   Na 4 P2 O 7  H 2 O
 1
34.  Pb(NO3 ) 2   PbO  2NO 2   O3
Red in hot
(Lith arg e)  2
Two different paramagnetic gases

 Hg(NO 3 ) 2   Hg  2NO 2   O 2 

 FeC 2 O 4   FeO  CO   CO 2 
800ºC 1
 ZnSO 4   ZnO  SO 2   O 2 
2
35. Conceptual
36. Conceptual
37. Oxalate – on heating with conc. H 2SO 4 gives a mixture of CO and CO 2 gases
Acetate – on heating with conc. H 2SO 4 , a vinegar smell of acetic acid is produced and with FeCl3
(neutral), gives a red ppt.
Sulphide – with dil. H 2SO 4 producing SO 2 gas which turns lead acetate paper black and sodium
nitroprusside produces violet of Na 4 [Fe(CN 5 )(NOS)] .
Thiosulphate – with dil. H 2SO 4 producing SO 2 gas and colloidal sulphur
38. Conceptual
39. Conceptual
40. Conceptual

MATHS
41.

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Narayana IIT Academy 21-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-59_Key&Sol’s
42.

Number of cubes obtained from one face which are painted on only one side   n  2 
2
43.
No.of cubes which are unpainted   n  2 
3

 n  2  6   n  2
2 3

n=8
44.

45. 8
C2  1 6C2  22  28  15  14  1680

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Narayana IIT Academy 21-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-59_Key&Sol’s
46.

47.

120
48. Let  x4  x1 x2 x3  120  23  3  5
a
49.

51. 8
C3  36  3C1 26  3C216 
52. 2985984  17282  1443  126
 required value equal to 2985984 – 1728 – 144 + 12
53.

54.

55. For every choice of r  1, 2,....  n  1 , when the n th object an goes to the rth place, there are Dn1  Dn2
ways of the other  n  1 objects a1 , a2 ,.......an1 to be deranged.
Hence Dn   n  1 Dn 1  Dn  2 

 1
r
n
Dn  n !
56. r!
r 0

1 1 1 1
 D5   5!       44
 2! 3! 4! 5! 
1  2n  !
57. (A) Required number of selection  2 n C0  2 n C1  ...  2n
Cn  22 n 1 
2  n !2
(B) n C4 (each quadrilateral gives one point of intersection)
(C) x4  x3  x2  x1  x0
10
C5 (5 distinct digits selection)
(D) Terms is involving 30 , 31/3 , 32/3  3
58.
xy = 15! = 211 36 53 72 111 131
(A) No. of the integral solutions = no. of ways of fixing x
= the no. of factors of 15!

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Narayana IIT Academy 21-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-59_Key&Sol’s
= (1 + 11) (1 + 6) (1 + 3) (1 + 2) (1 + 1) (1 + 1) = 4032.
 Total no. of integral solutions = 2 × 4032 = 8064
(B) HCF (, ) = 1. So identical primes should not be separated
So, no. of solutions = 26 = 64
(C) The largest number whose perfect square can be made with 15! is 25 33 5–1 71
So the no. of ways of selecting x will be
(1 + 5) (1 + 3) (1 + 1) (1 + 1) = 96
(D) Let  = 351 and  = 35 where HCF (1, 1) = 1
Now,  = 15!  11 = 211 36 51 111 131
So, no. of solutions = 25 = 32.
 133   16 
59.  A  3    3   560
   
 13 43   12 
 B  3    3   220
   
 1310  3
 6
C   3    3   20
   
 D  
4
Coefficient of x13 in x  x 2  x 3  x 4

 
4
= coefficient of x 9 in 1  x  x 2  x 3

= coefficient of x 9 in 1  x  1  x 2  
4 4

= 4 + 16 = 20
60. Let n be the number of sides.
 number of diagonals = n C 2  n = 54 (given)
n  n  1
   54
2
 n 2  n  2n  108
 n 2  3n  108
 n 2  3n  108  0
  n  12  n  9   0  n  12
 n cannot be -ve 
(B) The number of divisors of the form 4n  2  n  0  of the integer 240 is 0, 6, 10, 30. These are 4 in
numbers .
 B  p, B  r
(C) 63  2n 1 C1  2n 1 C 2  ....  2n 1C n
 64  2n 1 C 0  2n 1 C1  ......  2n 1 C n
1
2
 1

 2n 1 C0  2n 1 C1  ......  2n 1 C 2n 1  .2n 1  128  22n 1
2
2n 1
 2 2
7

 7  2n  1  n  3
 n 1  3 1  4
 c  p,c  r
(d)As 0  x  x1, we have p  q.
The number of rational numbers
 5  4  3  2  1  15.
When p, q have a common factor, we get some rational numbers, which are not different from those already
counted. There are 4 such numbers

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Narayana IIT Academy 21-08-22_INSR.IIT_*COSC(MODEL-A) _WAT-59_Key&Sol’s
2 2 3 4
, , , .
4 6 6 6
 the required number of rational numbers
 15  4  11
 K  11  K  1  12
 D-q, D-s

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