28 11th Chemistry Vol.2 One Mark Study Material Tamil Medium

s cs.cc.c s cs.cc.c s cs.cc.c s cs.cc.cTrbTnpsc.
com
n p p n p p nTnp p nTn p p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTrb Tb b
.T.rTr
T
b .T.rTrb Tb
wwww wwww w ww
w w www w ww
w
ww ww ww ww ww
SRI RAMAKRISHNA MET HR SEC SCHOOL –SIVANARAGARAM-612201
s c .cc.ocmom
s c .cc.ocm om
s c .cc.ocm
om c .cc.ocm om
b TbnTpnp
HIGHER s SECONDARY
b T
b nTpnFIRST
p s YEAR – CHEMISTRY
b TbnTpnp s - ONE MARK
b T
b
s
nTpnp - 2018-2019 bTbnTpns
s
ww.T.rTr ww .T.rTr ww .T.rTr ww.T.rTr ww.T.rTr
w
ww w www w www w ww w w www w
VOLUME-2
s c .cc.ocmom
s c .cc.ocm om
s c .cc.ocm
om
s c .cc.ocm om
b TbnTpnp s
b T
b
s
pnp 8 - Physical and chemical
nTUnit- b Tb
s
nTpnp equilibrium b T
b nTpnp s
b TbnTpns
ww.T.rTr ww .T.rTr ww .T.rTr ww T.rTr
.−𝟒 ww.T.rTr
w
ww w 1. If 𝑲𝒃 and 𝑲 w w
w𝒇wfor a reversible reactions w w −𝟓 w w
wware 𝟎. 𝟖 × 𝟏𝟎 and 𝟏. 𝟔w×w𝟏𝟎 respectively, thewvalue w w
w of
the equilibrium constant is,
c . c ocm
. o m
c . c.ocm o−𝟏m c . c.ocm
om c . c.ocm om
s c s c s c c
b Tb
s
nTpna)p 20 b
b)n𝟎.
T
b T
s
pn𝟐p × 𝟏𝟎
b Tb
s
nTpnp c) 0.05 b T
b
s
nTpnpd) none of these bTbnTpns
s
ww.T.rTr 2. At a given temperature ww .T.rTr and pressure, thewequilibrium w.T.rTr constant values ww .rTrthe equilibrium www
.Tfor .T.rTr
w
ww w www w w
ww 𝟑 w 𝟏 ww w w ww w
𝟑𝑨𝟐 + 𝑩𝟐 + 𝟐𝑪 ⇌ 𝟐𝑨𝟑 𝑩𝑪 and 𝑨𝟑 𝑩𝑪 ⇌ 𝟐 [𝑨𝟐 ] + 𝟐 𝑩𝟐 + 𝑪 The relation between 𝑲𝟏 and 𝑲𝟐 is
s c .cc.ocmom 𝟏
s c .cc.oc−𝟏𝟐m
om
s c com
𝟐.c.c
om 𝑲𝟏 sc.c c.ocm om
b TbnTpna) s
p 𝑲𝟏 = √𝑲𝟐
b
b)n𝑲p
Tb T n s
𝟐p= 𝑲𝟏
b TbnTc)pnp s
𝑲𝟏 = 𝟐𝑲𝟐 d) 𝟐np
b T
b T =p𝑲𝟐
n s
b TbnTpns
ww.T.rTr 3. The equilibriumww T.rTr
.constant watw .rTr temperature isww
.Troom .rTr that at 700 K iswK2.
.Tand
w ww.TIf.rTr
w
ww w www w for a reactionwww w ww wK1 ww w
K1>K2 then
m
om reaction is exothermic
.cc.ocforward .cc.ocm om ocm
om reaction is endothermic
.cc.forward .cc.ocm om
a)
s cthe s c b)sThec s c
b Tb
s
nTpnc)pThe reaction doesbnot Tb
pnp
nTattain s
equilibrium. b Tb
pnp
nTd) s
The reverse reaction b T
b
is
pnp s
nTexothermic b T
b nTpns
ww.T.rTr .T.rTr
wofw .T.rTr
wand
w .T.rTr
wreaction
w ww.T.rTr
w
ww w 4. The formation
www w ammonia from 𝑵 www
𝟐(𝒈) w 𝑯 𝟐(𝒈) is a reversible
ww w w 𝑵 𝟐(𝒈) + 𝟑𝑯 w w
ww𝟐(𝒈) ⇌
𝟐𝑵𝑯𝟑(𝒈) +Heat What is the effect mof increase of temperature m on this equilibrium reaction
c . c ocm
. o m
c . c.ocm o c . c.ocm
o c . c.ocm om
s c s c s c s c
b Tb
a)
nTpnp s
equilibrium is unaltered
b Tb nTpnp s
b TbnTpnp s b) formation of
b
ammonia
T
b nTpnp s is favored
b T
b nTpns
ww.T.rTr c) equilibrium iswshifted .T.rTr to the left
w ww .T.rTr d) reaction ww T.rTrdoes not change ww
.rate .T.rTr
w
5. Solubility of carbon dioxide gas in cold water can be increased by
s c .cc.ocm
a) increase om in pressure b) decrease
s c .cc.ocm om in pressure
.cc.ocm
c) increase
s c om in volume d) none ofcthese
s c .c.ocm om
b T6.np
b T n p s
Which one of the following
b Tb
s
nTpnpis incorrect statement? b TbnTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) for a systemwatw .rTr
.Tequilibrium, Q is always .T.rTthan
wless
w
r the equilibrium constant
ww.T.rTr ww.T.rTr
w
b) equilibrium can be attained from either side of the reaction
s c .cc.ocm
c) presence om of catalyst affects
s c c.ocm
.cboth om the forward reaction.cand
s c c .ocm m
oreverse reaction to the
s c
mom extent
.cc.ocsame
b Tb
s
nTpnd)p equilibrium constant b Tb
s
pnp with temperatureTnTpnp
nTvaried b b
s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr 7. 𝑲 and 𝑲 are w thew
rTr
.T.equilibrium constants w w
for .rTr reactions respectively.
.Tthe ww.T.rT𝑵r + 𝑶 ⇌ 𝟐𝑵𝑶(𝒈) ww.T.rTr
w
ww w 𝟏 𝟐 www w www w ww w w 𝟐(𝒈) 𝟐(𝒈) www w
𝟐𝑵𝑶(𝒈) + 𝑶𝟐(𝒈) ⇌ 𝟐𝑵𝑶𝟐(𝒈) What is the equilibrium constant for the reaction
c ocm
.cc𝟐(𝒈)
. om 𝟏 c . c.ocm o𝟏 m c . .ocm
c𝟏/𝟐om 𝟏
c . c.ocm𝟏om 𝟑/𝟐
s s c s c s c
b TbnTpnp𝑵𝑶 s ⇌ 𝑵
𝟐 𝟐(𝒈)
+
b
𝑶
Tb
𝟐(𝒈) sa)
nTpnp √𝑲𝟏𝑲𝟐 b)( 𝑲
b T
=
𝟏np p 𝟐
b T n
𝑲 s ) c) 𝟐𝑲𝟏 𝑲𝟐 Tnp
b b T n p 𝟐𝑲𝟏𝑲𝟐)
d)s (
b T
b nTpns
ww.T.rTr 8. In the equilibrium ww
rTr
.T.2A(g)⇌ 𝟐𝑩(𝒈) + 𝑪𝟐w (𝒈)ww T.rTequilibrium
.the r
ww.T.rTr of A, B and 𝑪𝟐 at 400
concentrations ww.TK.rTr
w
ww w www w ww w ww w w www w
are 1× 𝟏𝟎−𝟒 M, 2.0× 𝟏𝟎−𝟑 M, 1.5× 𝟏𝟎−𝟒 M respectively. The value of 𝑲𝒄 for equilibrium at 400 K
is ca) ocmom
.cc.0.06 b) 0.09c.cc.ocm om c) 0.62
c .cc.ocm
om d) 3× 𝟏𝟎c−𝟐 .cc.ocm om
s
nTpnAn s
p equilibrium constant s s
pnp3.2× 𝟏𝟎−𝟔 for a reaction
nTof s s
nTpnmeans,
p s
nTispnp s nTpns
b T9.
b b Tb b T
b the equilibriumb T
b b T
b
ww.T.rTr ww .T.rTr ww .T.rTr .T.rTr
wtowards
w ww.T.rTr
w
ww w a) largely w w
towards
ww forward direction www w b) w
largely
ww w reverse w
direction
ww w
c) never established d) none of these
𝑲 .c.o
m
om ocm om com om .cc.ocm om
c cthe
10.p𝑲sp𝒄csfor +sp𝟑𝑯cs.cc.𝟐(𝒈) ⇌ 𝟐𝑵𝑯𝟑(𝒈) is pspcs.c.c s c
b TbnTn 𝒑 reaction 𝑵𝟐(𝒈) p
b Tb nTn b T
b nTn b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) 1/RT ww .T.rTrb) √𝑹𝑻 ww .T.rTr c) RT ww.T.rTd)r (𝑹𝑻)𝟐 ww.T.rTr
w
s c .cc.ocmom
s c .cc.ocm om
s c .cc.ocm
om
s c .cc.ocm om
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
M.Sc(Chemistry).,M.Ed.,M.A(YOGA).,DTP.,DSP.,
b b b T
b nTpnp s
b T
b nTpnp s
Page 1 b T
b nTpns
ww.T.rTr ww .T.rTr ww .T.rTr ww.T.rTr ww.T.rTr
w
mm mm mm mm
c.cc.oco c.cc.oco c.cc.oco
http://www.trbtnpsc.com/2018/06/latest-plus-one-11th-study-materials-tamil-medium-english-medium-new-syllabus-based.html c.cc.oco
s cs.cc.c s cs.cc.c s cs.cc.c s cs.cc.cTrbTnpsc.com
n p p n p p p
nTn p p
nTn p nTpns
.T.rTr
T
b .T.rTrb T
b
wwww wwww w www w www w ww
w
ww ww
11. For the reaction 𝑨𝑩(𝒈) ⇌ 𝑨(𝒈) + 𝑩(𝒈),
ww at equilibrium, AB is 20% ww dissociated at a total w w
pressure
of P,
c ocm
.ccThe
. om equilibrium constant.c𝑲
c .oc𝑷moismrelated to the totalc.cpressure c.ocmom by the expression c .cc.ocmom
s s c s s
b Tb
s
nTpna)p P=24 𝑲𝑷 b b)
T
b nTP=8 s
pnp 𝑲𝑷
b Tb nTc)pnp s
24 P=𝑲𝑷 d)
b T
b
s
nTpnpof these
none b T
b nTpns
ww.T.rTr 12. In which of thewfollowing.T.rTr equilibrium, 𝑲𝑷wand
w w.T.rT𝑲r𝒄 are not equal? ww .T.rTr ww .T.rTr
w
ww w ww w w ww w w www w www w
a) 2NO(g) ⇌ 𝑵𝟐(𝒈) + 𝑶𝟐(𝒈) b) 𝑺𝑶𝟐(𝒈) + 𝑵𝑶𝟐 ⇌ 𝑺𝑶𝟑(𝒈)+NO(g)
c) c𝑯.cc.ocmo+m 𝑰𝟐(𝒈) ⇌ 𝟐𝑯𝑰(𝒈) c.cc.ocm om c cm
.cc.od) m
o𝑷𝑪𝒍 𝟓(𝒈) ⇌ 𝑷𝑪𝒍𝟑(𝒈)s+ c .c𝑪𝒍 m
om
c.oc𝟐(𝒈)
s s 𝟐(𝒈)
nTpnIfpx is the fraction ofbTb𝑷𝑪𝒍 s s
nTpnpdissociated at equilibrium s s
nTpnp in the reaction 𝑷𝑪𝒍 nTp⇌
n p s nTpns
b Tb
13. b Tb b T
b 𝑷𝑪𝒍 + 𝑪𝒍 then b T
b
ww.T.rTr w .T.rTr 𝟓
w ww .T.rTr ww.T.rTr 𝟓 𝟑 𝟐
ww .T.rTr
w
ww w starting ww
with w w
0.5 mole of 𝑷𝑪𝒍 𝟓 , ww
𝒕𝒉𝒆 w w
total number of moleswww w
of reactants and w
products w
ww at
equilibrium
. c.ocmo m is a) 0.5-x b) x+0.5
. c .ocm o m . c.
c) 2x+0.5
ocmo m d) x+1m
c.ocoifmdegree of
.9:1
s c c s c c s c c s c c
b T
14.pThe
bnTnp s values of 𝑲 𝑷𝟏 and
b T
b
𝑲
nTpnp
𝑷𝟐 sfor the reaction X⇌
b Tb
𝒀
nTpnp + 𝒁
s A⇌ 𝟐𝑩 are in the
b T
b
ratio
nTpnp s
b T
b nTpns
ww.T.rTr dissociation and ww T.rTr concentration of w
.initial T.rTrA be equal than total
X .and
w ww .rTr
.Tpressure at equilibrium .𝑷T𝟏.rTr
ww
w
ww w w w
and 𝑷𝟐 arewinwthe ratio a) 36:1 ww b) 1:1 w w c) 3:1ww w w d) 1:9 wwww
𝟑+
15. In theom oreaction
m Fe(𝑶𝑯)𝟑 (𝑺) ⇌o𝑭𝒆 mo m (𝒂𝒒) + 𝟑𝑶𝑯− (𝒂𝒒) oifm o the concentration of o𝑶𝑯
m m
o m −
ions is
s c c
.c.c s c c
.c.c s c c
.c.c 𝟑+ s c c
.c.c
b Tb
s
nTpndecreased
p by ¼ times,Tthen
b b
s
nTpnpthe equilibrium concentration b Tb
s
nTpnp of 𝑭𝒆 will bTbnTpnp s
b T
b nTpns
ww.T.rTr a) not changedww .T.rTrb) also decreased w byw.T¼.rTtimes
r c) increased by ww.T rtimes
4.T r d) increased by .64
wwT.T
rr
w
times
.cc.ocm
16. Consider
s c om the reaction where 𝑲
s c .cc𝑷.oc=mom 𝟎. 𝟓 at a particular temperature
s c .cc.ocmom 𝑷𝑪𝒍𝟓(𝒈) ⇌ 𝑷𝑪𝒍
s c ocm
.cc𝟑(𝒈)
. om+ 𝑪𝒍𝟐(𝒈) If
b Tb
p p s
nTnthe three gases are mixed b T
b
p p s
nTnin a container so that b T
b thep p s
nTnpartial pressure of each b T
b
p
nTgas
n p sis initially 1 atm, bT b nTpns
ww.T.rTr then which onewof w
rTr
.T.the following is true ww .T.rTr ww.T.rTr ww .T.rTr
w
a) more 𝑷𝑪𝒍𝟑 will be produced b) more 𝑪𝒍𝟐 will be produced
c)
s c .cc.ocm
more m will be produced.c.ocm
o𝑷𝑪𝒍
s c c om c cm
.cc.od) m of these
onone c .cc.ocmom
s s
nTpnp to equilibrium binTbanTpn1pliter flask. What bTbnTpns
𝟓
s
nTpnEquimolar
p s
nTpnpof 𝑯 and 𝑰 arebTb s s
b T17.
b b
concentrationsT
b heated
ww.T.rTr w .T.rTr
w
𝟐 𝟐 Tr r
ww . .T ww.T.rTr w w.T.rTr
w
ww w percentage ww w
of w
initial concentration of w
ww 𝟐𝑯w has reacted at w w
equilibrium
ww if rate constant w
for
ww w
both
forward and reverse reactions are equal
a)
s c .cc.ocm
33%
om b) 66%s c .cc.ocm om c) c
(𝟑𝟑)
s
m
om
.cc.o𝟐c% d) 16.5% s c .cc.ocmom
b TbnTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpns
.T.rTr 18. In a chemical wequilibrium,
.T.rTr .T.rTr for the forward reaction .T.rTr is 2.5× 𝟏𝟎 andwthe .T.rTr
𝟐
the rate constant
w ww
w w w w w www w www w w w
ww equilibriumwconstant
w is 50. The rate constant ww for the reverse reaction ww is ww
𝟐 −𝟑
a) 11.5 c) 2× 𝟏𝟎 d) 2× 𝟏𝟎 om
.cc.ocm
b) 5
s c om
s c .cc.ocm om
s c .cc.ocmom
s c .cc.com
b T19.
b
p s
nTpnWhich of the following is
b T
b nTpnnots
p a general characteristic
b T
b
s
nTpnpof equilibrium involving b T
b
s
nTpnphysical
p process
b T
b nTpns
ww.T.rTr a) Equilibrium isww .T.rTr only in a closedw
possible .T.rTr at a given temperature
system
w ww.T.rTr ww .T.rTr
w
ww w w w
ww processes occur at the w w
wwsame rate and there is awdynamic w
w w www w
b) The opposing but stable condition
c) All
c ocm
.cc.theom physical processes stop
c .cc.ocm om
at equilibrium
c .cc.ocmom c .cc.ocmom
s s
nTpnd)p All measurable properties s s
nTpnp of the system remains s s
nTpnconstant
p nTpnps s nTpns
b Tb b T
b b T
b b T
b b T
b
ww.T.rTr 20. For the formation ww
rTr
.T.of two moles of 𝑺𝑶𝟑(𝒈) ww T.rTr 𝑺𝑶 and 𝑶 , the equilibrium
.from ww.T.rTr constant is 𝑲𝟏 .wThe w.T.rTr
w
ww w ww w w ww w w 𝟐 𝟐
www w www w
equilibrium constant for the dissociation of one mole of 𝑺𝑶𝟑 into 𝑺𝑶𝟐 and 𝑶𝟐 is
a)
s c .cc.oc𝟏m
1/𝑲 om 𝒃) 𝑲s𝟐𝟏cs.cc.co
omm 𝟏 om
c) s(𝑲cs.c)c𝟏/𝟐
. com d) 𝟐𝟏 scs.cc.co
𝑲 omm
b TbnTpnp s
b T
b nTpnp b T
b nTpnp 𝟏 b T
b nTpnp b T
b nTpns
ww.T.rTr 21. Match the equilibria ww.T.rTr with the corresponding ww .T.rTrconditions, i) Liquid⇌Vapour ww.T.rTr ii) Solid⇌Liquidww T.rTr
.iii)
w
ww w w w
ww iv) Solute(s) ⇌Solute(Solution) ww w w w w
ww2) Saturated solution 3)ww w w
Solid⇌Vapour 1) Melting point Boiling
point
s c cm
.cc.o4) m
oSublimation .cc.ocm
point 5) Unsaturated
s c om solution
s c .cc.ocmom
s c .cc.ocmom
b TbnTpnp s (i)Tn
b b T pnp s (ii)
b T
b nTpnp s (iii)
b T
b
s
nTpnp(iv) b T
b nTpns
ww.T.rTr (a) ww.T.rT1r 2ww .T.rTr 3 ww.T.rTr 4 ww .T.rTr
w
ww w ww w w ww1w w w w w w
(b) 3 4 ww 2 ww
(c) om
.cc.ocm .cc.ocm
2 om 1 o3m 4 om
s c .cc.com s c sc s c .cc.com
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 2 bTbnTpns
ww.T.rTr ww.T.rTr ww .T.rTr ww.T.rTr ww .T.rTr
w
mm mm mm mm
n p p n p p nTnp p p
nTn p nTpns
. T.rTbrTbTn . T.rTbrTbTn b
.T.rTr
Tb .T.rTr b T
b .T.rTrb Tb
wwww wwww w ww
w w www w ww
w
ww (d)
ww 3
ww2 4
ww 1
ww
s c .cc.ocm om
s c .cc.ocm om
s c .cc.ocmom
s c .cc.ocm
om
b TbnTpnp s
b T
b nTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr 22. Consider the following ww .T.rTr reversible reaction ww .rTrequilibrium, A+B⇌C,
.Tat ww.TIf.rTthe
r concentration of the
ww.T.rTr
w
ww w reactants Awand w w
w B are doubled, then the w w
wwequilibrium constant will www w www w
a) be o doubled
m m b) becomeoone m mfourth c) be halvedocm m d) remain the ocm same
m
c .cc . c o c .
−c
c. c o 𝟐− ( s) sc c . c. o c .cc. o
s s
nTpn[Co(𝑯
23. 𝟐+
p 𝟐 𝑶)𝟔 ] (aq)(pink)+𝟒𝑪𝒍 s s
nTpnp (𝒂𝒒) ⇌ [Co𝑪𝒍𝟒 ]bTbnT𝒂𝒒 pnp(𝒃𝒍𝒖𝒆)+6𝐇𝟐 𝑶(𝒍) InTthe s
nTpnpabove reaction at bTbnTpns
s
b Tb b T
b b b
ww.T.rTr equilibrium, theww T.rTr mixture is blue winw
.reaction .rTr at room temperature.
.Tcolour ww.T.rTrOn cooling this mixture, ww.T.rTr
w
ww w w w w w w w w w
it becomesw w in colour. On the basis
pink wwof this information, which wwone of the following is true? ww
.cc.ocm
a) ∆𝑯>0
s c
m the forward reaction
ofor
s c .cc.ocm omb) ∆𝑯 = 𝟎 for thecreverse
s .cc.ocmomreaction c) ∆𝑯 < c0.cfor
s c.ocm m forward
othe
b Tb
p s
nTpnreaction b d)
T
b nTsign s
pnp of the ∆𝑯 cannot beTnT
b b
pnp s
predicted
b T
b nTpnp
based on this information. s
b TbnTpns
ww.T.rTr 24. The equilibriumww T.rTr
.constants of the following ww .rTr
.Treactions are : 𝑵𝟐 +w𝟑𝑯 ww.𝟐T.⇋rTr
𝟐 𝑵𝑯𝟑 ; 𝑲𝟏 𝑵𝟐 +w𝑶 .T
w𝟐w⇋.T
rr
w
ww w w
ww 𝟏 w ww w w ww w ww w
𝟐 𝑵𝑶 ; 𝑲𝟐 𝑯𝟐 + 𝟐 𝑶𝟐 ⇋ 𝑯𝟐 𝑶 ; 𝑲𝟑 The equilibrium constant (K) for the reaction:
s c .cc.oc+mom𝟓
s c cm om
.cc.owill s c .cc.ocmom
s c .cc.ocm
om
b Tb
s
nTpnp 𝟑 𝟐 𝟐
2𝑵𝑯 𝑶 ⇋ 𝟐𝑵𝑶
b T
+
b
𝟑𝑯
nTpnp𝟐 s𝑶, be
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr 𝑲𝟑𝟐 𝑲𝟑 ww .T.rTr 𝑲𝟏 𝑲𝟑𝟑 ww.T.rTr 𝑲𝟐 𝑲𝟑𝟑 ww.T.rTr 𝑲𝟐 𝑲𝟑 ww.T.rTr
w
ww w a) 𝑲𝟏 ww w w b) 𝑲𝟐 ww
w w c) 𝑲𝟏 www w d) 𝑲𝟏 www w
25. A 20 liter
. c .ocmo mcontainer at 400 K .contains c.ocm o m 𝑪𝑶𝟐(𝒈) at pressure . c.oc0.4
m
o matm and an excess.cof.ocSrO m
o m (neglect
c
spscvolume of solid SrO). c
spscvolume of the container c c c
pnspsc the movable TnTpns
b T nTpnthe b T nTpnThe b T nTpnspsis now decreasedbby T nTmoving
w w
b
.T.rTr piston fitted inwthe w
b
.T.rTcontainer.
r The maximum w w
b
.T.rTrvolume of the container, w w
b
.T.rTrwhen pressure of w .T𝟐.rTbrb
𝑪𝑶
w
ww
ww ww ww ww ww wwww ww
attains its maximum value will be: Given that : Sr𝑪𝑶𝟑 (𝑺) ⇌ 𝑺𝒓𝑶 (𝑺) + 𝑪𝑶𝟐(𝒈) 𝑲𝑷 = 𝟏. w 𝟔w𝒂𝒕𝒎
a) 2.c
c ocm
litre
. om b) 5 litre.c.ocm
c om c) 10 litre .c.ocm
c om d) 4 litre .c.ocm
c om
s c s c s c s c
b TbnTpnp s
b TbnTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr ww .T.rTr Unit-w9w .rTr
.TSolutions ww.T.rTr ww.T.rTr
w
1. The molality of a solution containing 1.8 g of glucose dissolved in 250g of water is
a)
s c .cc.ocm
0.2M om b) o.01s c .cc.ocm
M om c) 0.02 M scs.cc.co
omm d) 0.04sM c .cc.ocm
om
b Tb
p s
nTpnWhich b TbnTpnp s
b Tb
pnp
nTindependent b T
b nTpnp s
b TbnTpns
ww.T.rTr 2. of the
ww .T.rTr
following concentration terms
ww.T.rTr
is/are of .T.rTr
temperature
ww ww.T.rTr
w
ww w a) Molalityww w w b) Molarity w w
ww c) Mole fraction ww w w d) (a) and (b) www w
3. Stomach acid, a dilute solution ofmHCl
c . c .ocmo m
c . c.ocom can be neutralized c . c.ocby
m
o mreaction with Aluminium
c . c.ocm
o
hydroxide
m
spsc 𝟑 + 𝟑𝑯𝑪𝒍(𝒂𝒒) →n𝑨𝒍𝑪𝒍
nTpnAl(𝑶𝑯) pnsps𝟑c+ 𝟑𝑯𝟐 𝑶 . How T c
nTpnspsmilliliters of 0.1 M
many c
nTpnsps 𝟑 solution are bTbnTpns
Al(𝑶𝑯)
b Tb b Tb T b b b T
b
ww.T.rTr needed to neutralize ww .T.rTr21 mL of 0.1 M HCl?ww .T.rTr ww.T.rTr ww.T.rTr
w
a) 14 mL ww b) 7mL ww c) 21mL ww d) none of these ww
4. The cpartial
c . .ocmo m pressure of nitrogen
c . c.ocinm
o m is 0.76 atm and its.c.Henry’s
air
c ocmo m law constant is 7.6×
c . c.ocm
o m𝟒 atm at
𝟏𝟎
spscK. What is the mole
nTpn300 spsc of nitrogen gasnpn
nTpnfraction sc solution obtainednwhen
inspthe pnspsc air is bubbled TnTpns
b T b T b T T b T T
w w
b
.T.rTr through water w atw.T .rTr
300
b
K? w .T.rTr
w
b
w .T.rTr
w
b
w .T.rTbrb
w
ww
ww ww ww ww ww wwww wwww
a) 7.6𝟏 × 𝟏𝟎−𝟒 b) 𝟏 × 𝟏𝟎−𝟔 c) 𝟐 × 𝟏𝟎−𝟓 d) 𝟏 × 𝟏𝟎−𝟓
5. The c ocmom law constant forc.cthe
.ccHenry’s
. c.ocm m
osolubility of nitrogenc.gas c.ocminm
o water at 350 K is 𝟖 c .× cm
o𝟒matm. The
c.o𝟏𝟎
s s s c c
b TbnTpnmoles
p fraction of nitrogen
b Tb
s
nTpninp air is 0.5. The number b Tb
s
nTpnofp moles of Nitrogenbfrom T
b
s
nTpnpair dissolved in 10 bTbnTpns
s
ww.T.rTr .T.rTr
watw ww.T.rTr ww.T.rTr ww.T.rTr
w
ww w moles of water
ww w w 350 K and 4 atm w w
pressure
ww is www w www w
a) 𝟒 × 𝟏𝟎−𝟒 b) 𝟒 × 𝟏𝟎𝟒 c) 𝟐 × 𝟏𝟎−𝟐 d) 𝟐. 𝟓 × 𝟏𝟎−𝟒
momof the following isc.incorrect
.cc.ocone c.ocm om for ideal solution? .cc.ocmom .cc.ocm
om
6. Which
s c s c s c c
b Tb
s
nTpna)p ∆𝑯 = 𝟎 b Tb
pnp
nT∆𝑼 s
b TbnTpnp − 𝑷s
b T
b
s
nTpnp = 𝟎 d) ∆𝑮 = bTbnTpns
s
ww.T.rTr 𝒎𝒊𝒙
ww .T.rTr b) 𝒎𝒊𝒙 = 𝟎 C) ∆𝑷
ww.T.rT𝒐𝒃𝒔𝒆𝒓𝒗𝒆𝒅
= 𝑷 r rTr 𝒍𝒂𝒘
.T.𝒓𝒂𝒐𝒖𝒍𝒕𝒔
𝒄𝒂𝒍𝒄𝒖𝒍𝒂𝒕𝒆𝒅 𝒃𝒚
ww 𝒎𝒊𝒙.T.r
ww T
r
w
ww w 𝟎 ww w w ww w w www w www w
7. Which one mof the following gases has
m the lowest value of.c.Henry’s m law constant? .c.ocm
c . c .ocmo c . c.ocm o c ocmo c om
s c s c s c s c
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 3 b T
b nTpns
ww.T.rTr ww .T.rTr ww.T.rTr ww.T.rTr ww.T.rTr
w
mm mm mm mm
n p p n p p nTnp p nTnp p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTr b Tb .T.rTrb T
b b
.T.rTr
T
b
wwww wwww w ww
w wwww w www
ww a) 𝑵𝟐
ww b) He
ww c) 𝑪𝑶 ww d) 𝑯𝟐
ww
𝟐
8. 𝑷𝟏 .𝒂𝒏𝒅
s c cc.ocmo𝑷m𝟐 are the vapour pressure
s c.cc.ocm omof pure liquid components.
s c .cc.ocm om 1 and 2 respectively c .cc.ocm man ideal
oof
T p s
nTpnbinary solution if 𝒙b 𝟏T nTpnp
representss the mole fraction T
s
nTpnpof component 1, the T
s
pnp pressure of the TnTpns
nTtotal s
b b
.T.rTr solution formedww b
.T.rT1 rand 2 will be .T.rTr b b .T.rTrb b .T.rTbrb
wwww ww by www w wwww ww w w
ww ww ww ww ww
a) 𝑷𝟏 + 𝒙𝟏 (𝑷𝟐 − 𝑷𝟏 ) b) 𝑷𝟐 − 𝒙𝟏 (𝑷𝟐 + 𝑷𝟏 ) c) 𝑷𝟏 − 𝒙𝟐 (𝑷𝟏 − 𝑷𝟐 ) d) 𝑷𝟏 + 𝒙𝟐 (𝑷𝟏 − 𝑷𝟐 )
9. Osmotic
s c .cc.ocm m
opressure (𝝅) of a solution
s c .cc.ocm oismgiven by the relation
s c .cc.ocm om
s c .cc.ocm om
b Tb
s
nTpna)p 𝝅 = 𝒏𝑹𝑻 b T
b)
bnT𝝅𝑽 s
pnp= 𝒏𝑹𝑻 c) 𝝅𝑹𝑻
b Tb nTp=n p𝒏s
d)
b T
bnone
s
nTpnpof these b T
b nTpns
ww.T.rTr ww .T.rTr ww.T.rTr ww.T.rTr ww .T.rTr
w
ww w 10. Which one of
www w
the following binary liquid
www w
mixtures exhibits positivewwwwdeviation from Raoults ww w w
law?
a) Acetone+ chloroform b) Water+ nitric acid c) HCl+ water d) Ethanol+ water
11. The c ocmom law constants cfor
.ccHenry’s
.
momgases A and B are
.cc.octwo c
mom y respectively. The
.ccx.ocand c cm om of mole
.cc.oratio
nTpnps s nTpnp s s nTpnp s s nTpnps s nTpns
b Tb b Tb b Tb b T
b b T
b
ww.T.rTr fraction of A and ww .BT.isrTr0.2. The ratio of mole ww T.rTr of B and A dissolved
.fraction ww.T.rTinr water will be ww .T.rTr
w
ww w a) 𝒚
𝟐𝒙 www w b) 𝟎.𝟐𝒙
𝒚 w w
ww c) 𝟎.𝟐𝒙 wwww d) 𝒚
𝟓𝒙 ww w w
𝒚
12. Atc𝟏𝟎𝟎
s .cc.ocm𝟎m
oC the vapour pressure
s c .cc.ocofm
om a solution containing
s c .ocm
.cc6.5g om a solute in 100g water
s c .cc.ocism
om732mm. If
b Tb
p p s
nTn𝑲𝒃 = 𝟎. 𝟓𝟐, the boiling b TbnT pn
point p s of this solution will
b Tb nTn
be p p s
b T
b nTnp p s
b T
b nTpns
ww.T.rTr a) 𝟏𝟎𝟐𝟎 𝑪 ww .T.rTrb) 𝟏𝟎𝟎𝟎 𝑪 ww T.rTr 𝟎
.c) ww.T.rTd)r 𝟏𝟎𝟎. 𝟓𝟐𝟎 𝑪 ww .T.rTr
w
ww w www w www w 𝟏𝟎𝟏 𝑪 wwww ww w w
13. According to Raoults law, the relative lowering of vapour pressure for a solution is equal to
a)
s c .cc.ocm
Mole
m
ofraction of solventscs.cc.oco
mm
b) Mole fraction s c .cc.ocm oofmsolute
s c .cc.ocm om
b Tb
s
nTpnc)pNumber of moles bofTbsolute nTpnp b Tb
s
nTpnp of moles of solventbTbnTpnp s
b T
b nTpns
ww.T.rTr ww .T.rTr ww.T.rTr
d) Number
ww.T.rTr ww .T.rTr
w
ww w 14. At same www w
temperature, which pair of ww
thew w
following solutions are wwww
isotonic? ww w w
a) 0.2 Mm𝑩𝒂𝑪𝒍𝟐 and 0.2 M urea m b) 0.1M glucosem and 0.2 M urea
s c .cc ocom
. s c .cc .ocom
s c .cc .ocom
s c .cc.ocm om
b Tb
c)
nTpnp 0.1
s M NaCl and 0.1
b
M
Tb
𝑲
nTpnp 𝟐 𝑺𝑶
s 𝟒 d) 0.1
b Tb
M
nTpnp Ba(𝑵𝑶
s 𝟑 ) 𝟐 and 0.1 M
b
𝑵𝒂
T
b nTpnp
𝟐 𝑺𝑶 s𝟒
b T
b nTpns
ww.T.rTr 15. The empirical formulaww .T.rTr of a non-electrolyte(X) ww.T.rTisr 𝑪𝑯𝟐 𝑶. A solution containing ww.T.rTr six gram of X exerts ww .T.rTr
w
ww w the same osmoticwww w pressure as that w w w
ofw0.025 M glucose solution ww
wwat the same temperature. w w
ww The
molecular
. c ocm
. o mformula of X is a).c.𝑪oc𝟐m o𝑯m 𝟒 𝑶𝟐 b) 𝑪𝟖 𝑯o
. c .
𝟏𝟔m
c o𝑶m 𝟖 c) 𝑪𝟒 𝑯𝟖 𝑶𝟒 d) 𝑪𝑯
. c.ocm o
𝟐 𝑶
m
s s s s nTpns
𝟒
b TbnTpnThe
16. p 𝑲𝑯 for the solution
b TbnTofpnpoxygen dissolved inbwater Tb nTpnpis 4× 𝟏𝟎 atm at a bgiven T
b nTpntemperature.
p If the
b T
b
ww.T.rTr partial pressurewof w
rTr
.T.oxygen in air is 0.4 atm, ww T.rTmole
.the r fraction of oxygen
ww.T.isrTrsolution is ww .T.rTr
w
ww w w w w w w
ww c) 1× 𝟏𝟎−𝟓 wwww ww w w
a) 𝟒. 𝟔 × 𝟏𝟎𝟑w b) 1.6× 𝟏𝟎𝟒 d) 1× 𝟏𝟎𝟓
s c .cc.ocm
17. Normality omof 1.25 M sulphuric
s c .ocm
.ccacid om is a) 1.25 N .c.o
s c c cm
b) m N
o3.75 c) 2.5 N .c.ocm
s c c
m2.25 N
od)
b TbnTpnTwo
18. s
p liquids X and Y onTmixing
b b
s
nTpnp gives a warm solution. b Tb
s
nTpnpThe solution is b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) Ideal ww
b)
T.rTr
.Non-ideal and showswpositive ww.T.rTr deviation from Raoults ww.T.rTrlaw c) Ideal and shows ww .T.rTr
w
ww w www w ww w wwww ww w w
negative deviation from Raoults law d) Non-ideal and shows negative deviation from Raoults law
19. The c ocmom lowering of vapour
.ccrelative
. c .cc.ocm m
opressure of a sugar csolution .cc.ocmom in water is 3.5×c𝟏𝟎 .cc.oc−𝟑m
o.mThe mole
s s
nTpnfraction
p nT pnp s s nTpnp s s nTpnps s nTpns
b Tb of water in b T
theb solution is b Tb b T
b b T
b
w
ww w a) 0.0035 www w b) 0.35 www w c) 0.0035/18 wwww d) 0.9965 ww w w
20. The mass of a non volatile solute(molar mass 80 g 𝒎𝒐𝒍−𝟏 ) which should be dissolved in 92 g of
c .cc.ocm
toluene
s
m
oto reduce its vapoure s c c.ocm om to 90%
.cpressure s c .cc.ocmom
s c .cc.ocm om
b TbnTpnp s
b TbnTpnp s
b Tb nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) 10g ww .T.rTrb) 20g ww T.rT9.2g
.c) r
ww.T.rTd)r 8.89g ww .T.rTr
w
ww w 21. For a solution, w w
ww the plot of osmotic pressure(𝝅) www w verses the concentration wwww (c in mol 𝑳 w −𝟏
)ww w
gives a
straight ocm line
m with slope 310R.cwhere ocm m ‘R’ is the gas constant. ocm mThe temperature at.cwhich o m m osmotic
c . c . o c . o c . c . o c . c o
spsc measured is a)n310×0.082
nTpnpressure pnspsc K b) 𝟑𝟏𝟎
c
nT𝟎pn𝑪sps c) 𝟑𝟕𝟎 𝑪
𝟑𝟏𝟎 s sc
nTpnpK
d)T𝟎.𝟎𝟖𝟐 nTpns
b Tb b Tb T b Tb b b b T
b
ww.T.rTr 22. 200 mL of an w w.T.rTr solution of a protein
aqueous ww.T.rTcontains
r
1.26 g ofww ww.T.rTr At 300K, the osmotic
protein. ww .T.rTr
w
ww w www w www w ww ww w w
pressure of this solution is found to be 2.52× 𝟏𝟎−𝟑 bar. The molar of protein will be (R=0.083 L
s c .cc.ocmom
s c .cc.ocm om
s c .cc.ocmom
s c .cc.ocm om
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 4 b T
b nTpns
w
ww w www w www w wwww ww w w
mm mm mm mm
n p p n p p p
nTn p p
nTn p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTrb T
b b
.T.rTr
T
b b
.T.rTr
T
b
wwww wwww w ww
w w ww
w wwww
ww bar 𝒎𝒐𝒍 𝑲 ) −𝟏ww
−𝟏 ww
a) 62.22 Kg 𝒎𝒐𝒍−𝟏 b) 12444 g 𝒎𝒐𝒍−𝟏
ww c) 300 g 𝒎𝒐𝒍−𝟏 d) none
ww
.cc.ocm
of these
s c om
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocm om
T nTpnThe
23.
s
p Van’t Hoff factor(i)TnT for
s
pnpa dilute aqueous solution T
s
nTpnpof the strong electrolyte T p s
nTpnbarium hydroxide is bTn Tpns
b b
.T.rTr a) 0 b b
.T.rTrb) 1 b
T.rT2 r
.c) b b b
.T.rTd)r 3 .T.rTr b
w ww
w w ww
w w ww
w w ww
w wwww
ww ww ww ww ww
24. What is the molality of a 10% w/w aqueous sodium hydroxide solution? a) 2.778 b) 2.5 c) 10 d)
0.4c.cc.ocom
m .cc.ocmom .cc.ocm
om .cc.ocm om
s s s c
s s cs s c
pwhich undergoes TnTpns
s
b T nTpnThep correct equation Tfor
b nTpnthe
p degree of an associating
b T nTpnp solute, ‘n’ molecules b T nTpn
.T.rTbrb
25.
b b b b of
w .T.rTr
w w .T.rTr
w w .T.rTr
w w .T.rTr
w w w
ww
ww associationwinw wsolution,
w is wwww wwww ww ww
𝒏(𝒊−𝟏) 𝒏(𝟏−𝒊) 𝒏(𝒊−𝟏) 𝒏(𝟏−𝒊)
a) 𝜶 = m𝒏−𝟏 b)𝜶𝟐 = (𝒏−𝟏) c) 𝜶 = 𝟏−𝒏 d) 𝜶 = 𝒏(𝟏−𝒊) mm
c . c .oc o m
c . c .ocm
o m
c . c ocm
. o m
cs.cc.oco
s c of the following aqueous s c solutions has the highest s c boiling point? s
b T26.
b
p
nTn p s
Which
b T
b nTnp p s
b T
b
p
nTn p s
b T
b
p
nTn p
b T
b nTpns
ww.T.rTr a) 0.1 M 𝑲𝑵𝑶𝟑ww .T.rTrb) 0.1 M 𝑵𝒂𝟑 𝑷𝑶𝟒 ww T.rT0.1
.c) r M Ba𝑪𝒍
ww.T.rTd)r 0.1 M 𝑲𝟐 𝑺𝑶𝟒 ww.T.rTr
w
ww w ww w w www w 𝟐
www w ww ww
27. The freezing point depression constant for water is 1.86 K Kg𝒎𝒐𝒍−𝟏 . If 5g 𝑵𝒂𝟐 𝑺𝑶𝟒 is dissolved in
45gc ocmomthe depression incfreezing
.ccwater,
. .cc.ocmom point is 𝟑. 𝟔𝟒𝟎 𝑪.cThe m
om Hoff factor for 𝑵𝒂
.cc.ocVant c ocm
.c𝟐c.𝑺𝑶 o𝟒mis
s s
nTpna)p 2.50 s
pnp
nT2.63 s nTpnps s nTpnps s nTpns
b Tb b T
b)
b c) 3.64
b T
b d)
b T
b5.50 b T
b
ww.T.rTr ww .T.rTr .T.rTr
wKCl
w ww.T.rTr .T.rTr
w𝟎w
w
ww w 28. Equimolal ww w w
aqueous solutions of NaCl w
and
ww w are prepared. If the
www w
freezing point of NaCl is ww
ww 𝑪,
−𝟐
the freezing point of KCl solution is expected to be
a)
s c .cc.o𝟎c𝑪m
−𝟐 om b) −𝟒s𝟎cs𝑪.cc.co
omm c) −𝟏𝟎 𝑪 scs.cc.co
omm d) 𝟎𝟎 𝑪scs.cc.co
omm
b TbnTpnp s
b T
b nTpnp b T
b nTpnp b T
b nTpnp b T
b nTpns
ww.T.rTr 29. Phenol dimerises ww
inrTbenzene
.T. r having Vant Hoff
ww.T.rTfactor
r 0.54. What is the.Tdegree
ww.T
r r of association? .T.rTr
ww
w
ww w a) 0.46 ww w w b) 92 w w
ww c) 46 www w d) 0.92 ww ww
30. Assertion m: An ideal solution .obeys mRaoults law Reason.c:.ocInm an
m ideal solution, Solvent-solvent as
c . c .ocmo c c .ocm
o c o c . c.ocmo m
spscas solute-solute interactions
nTpnwell
c
nTpnsps are similar tobsolute-solvent nTpnsps
c interactions. npspsc
n nTpns
b Tb b T
b T
b b T
b T b T
b
ww.T.rTr a) both assertion ww .rTr reason are true w
.Tand andww.T .rTrreason is the correction
the ww.T.rTexplanation
r .T.rTr
of assertion.
ww
w
ww w b) both assertion w w
ww and reason are true w
ww but reason is not thewcorrect w
w w explanation of assertion ww ww
c) assertion m is true but reason.cis.ocfalse. d) Both assertion and reason are false. mm
c . c .ocmo c
m
o m
c . c ocm
. o m
cs.cc.oco
s c s c s c s
b Tb
p
nTn p s
b T
b nTnp p s
Unit-10 - Chemicalb T
b
p p s
nTbonding
n b T
b
p
nTn p
b T
b nTpns
w
ww w ww w w www w www w ww ww
1. In which of the following compounds does the central atom obey the octet rule?
a) .𝑿𝒆𝑭
s c cc.ocm o𝟒m b) 𝑨𝒍𝑪𝒍𝟑.c.ocm
s c c om c) 𝑺𝑭𝟔
s c .cc.ocm
om d) 𝑺𝑪𝒍𝟐 .c.ocm
s c c om
b T2.n
b T
s
pnInp the molecule 𝑶𝑨 = T𝑪nT=pnp
b b
s
𝑶𝑩 , the formal charge b T
b
s
nTpn𝑶p𝑨 , C and 𝑶𝑩 are respectively
on b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) -1, 0, +1 ww .T.rTrb) +1, 0, -1 ww T.rT-2,r 0,+2
.c) ww.T.rTd)r 0,0,0 ww.T.rTr
w
3. Which of the following is electron deficient?
a)𝑷𝑯
s c .cc.𝟑ocmom b) (𝑪𝑯c𝟑.c
s
m
)c𝟐.ocom c) 𝑩𝑯𝟑
s c .cc.ocm
om d) 𝑵𝑯𝟑 c.cc.ocom
s
m
b T nTpnWhich
4.
b
p s
of the followingb T
b nTpnp s
molecule contain no 𝝅 b T
bond?
b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr w .T.rTr
w w .T.rTr
w w .T.rTr
w w .T.rTr
w
w
ww w a) 𝑺𝑶 𝟐 ww w w b) 𝑵𝑶 𝟐 www w c) 𝑪𝑶 𝟐 www w d) 𝑯 𝟐 𝑶 ww ww
5. The ratio of number of sigma (𝝈) and pi (𝝅) bonds in 2-butynal is a) 8/3 b) 5/3 c) 8/2 d) 9/2
m
omof the following isc.the
.cc.ocone c.ocm m
olikely .cc.ocm
omtetra fluoride molecule? .cc.ocm om
6. pWhich
s c s c bond angles of
s csulphur s c
b TbnTnp s
b T
b nTpnp 𝟎s
b T
b nTpnp s
b T
b
s
nTpn𝟎 p 𝟎 b T
b nTpns
.T.rTr a) 𝟏𝟐𝟎 , 𝟖𝟎 ww .T.rTrb) 𝟏𝟎𝟗 .28 T.rT𝟗𝟎r .T.rTd)r 𝟖𝟗 , 𝟏𝟏𝟕 .T.rTr
𝟎 𝟎 𝟎
ww ww.c) ww ww
w
ww w 7. Assertion :w ww w
Oxygen molecule is paramagnetic. www w www w ww ww
Reasonm
c . c .oco: m
It has two unpaired electron
c . c .ocm
o m in its bonding molecular
c . c ocm
. o morbital
c .cc.ocofm
om
s c s c s c s
b TbnTpnpa) s
both assertion and
b T
b nTpnp
reason s are true and the
b T
b nTpnp
reason sis the correction nTpnp
explanation
b T
b
s assertion.
b T
b nTpns
ww.T.rTr b) both assertion ww
rTr reason are true but
.T.and ww.T.rT r
reason is not the correct
ww.T.rTexplanation
r .T.rTr
of assertion
ww
w
ww w c) assertionwis w w
wtrue but reason is false. w w
ww d) Both assertion and w w
wwreason are false. ww ww
8. According ocm mto Valance bond theory, ocm a bond between two atoms
m ocm mis formed when .c.ocm
c .cc . o c .cc . o c .cc . o c c om
nTpnp s s nTpnps s nTpnps s nTpnps s nTpns
b T
P.VARATHARAJAN
b b T
b b T
b b T
b Page 5 b T
b
w
mm mm mm mm
n p p n p p nTnp p nTnp p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTrb T
b .T.rTr b Tb .T.rTrb Tb
wwww wwww w ww
w w ww
w wwww
ww ww
a) fully filled atomic orbital’s overlap w
w b) half filled atomic
ww orbital’s overlap ww
.cc.ocm om
c) non-bonding
s c
atomic orbital’s
s c cmom
.cc.ooverlap d) empty
s c .cc.ocm m orbital’s overlap
oatomic
s c .cc.ocm
om
b 9.n
T
b T
s
pnInp 𝑪𝒍𝑭𝟑 , 𝑵𝑭𝟑 and 𝑩𝑭𝟑Tmolecules
b b nTpnp s
T
b
s
nTpnp and boron atomsbare
the chlorine,bnitrogen TbnTpnp s
b TbnTpns
ww.T.rTr a) 𝒔𝒑𝟑 hybridized ww.T.rTr ww.T.rTr b) 𝒔𝒑𝟑 , 𝒔𝒑𝟑 and 𝒔𝒑 ww 𝟐.T.T
rr
respectively ww.T.rTr
w
ww w ww w w ww w w www w wwww
c) 𝒔𝒑𝟐 hybridized d) 𝒔𝒑𝟑 𝒅, 𝒔𝒑𝟑 and sp hybridized respectively
10. When
moms and three p orbitals
.cc.ocone m
om
.cc.ochybridized, .cc.ocm om .cc.ocm
om
s c s c s c s c
b T
b
s
nTpna)p four equivalent orbitals b T
b nTpnat s
p 𝟎
𝟗𝟎 to each other b T
b nTpnbe
will
p s
formed b TbnTpnp s
b TbnTpns
ww.T.rTr ww.T.rTr w .T.rTr
w ww .T.rTr ww.T.rTr
w
ww w b) four ww w
equivalent w orbitals at 𝟏𝟎𝟗 𝟎
.28ww w
to w
each other will be ww
formed w w wwww
c) four m equivalent orbitals, that are lying the same plane willmbe formed d) none of these
c . c.ocom c . c.ocmo m
c . c.ocom c . c.ocm
o m
c of these representspsthe ccorrect order of theirpincreasing c bond order pspsc
nTnsps nTnsps𝟐− nTpns
11.pWhich
b T
b b T
b nTnps b T
b b TbnTn b Tb
ww.T.rTr a) 𝑪𝟐 < 𝑪𝟐 <w𝑶w 𝟐−
.𝟐T.rT<r 𝑶𝟐
𝟐−
ww.T.rTr b) 𝑪𝟐 < 𝑪𝟐 < 𝑶w𝟐w +
.T<.rT𝑶r𝟐 𝟐−
ww.T.rTr
w
ww w c) 𝑶𝟐 < 𝑶w
𝟐− ww w 𝟐− + ww w w d) 𝑶𝟐 < 𝑪𝟐w<w𝑶𝟐 < 𝑪𝟐
𝟐− + w w 𝟐− wwww
𝟐 < 𝑪𝟐 < 𝑪𝟐
.cc.ocm m
c.oc𝑷𝑪𝒍 .cc.ocm .cc.ocm
12. Hybridization om of central atomc.cin om𝟓 involves the mixing ofoorbitals.
m om
s c s s c s c
b T
b
s
nTpna)p s, 𝑷𝒙 , 𝑷𝒚 , 𝒅𝒙𝒛 , 𝒅𝒙𝒛𝒚𝒛 b T
b nTpnp s
b T
b
s
nTpnp b) s, 𝑷𝒙 , 𝑷𝒚 , 𝑷𝒙𝒚b,Tb𝒅nT𝒙𝒛𝒚𝒛 pnp s
b TbnTpns
ww.T.rTr c) s, 𝑷𝒙 , 𝑷𝒚 , 𝑷𝒛 ,w𝒅w T.rTr
.𝒙𝒛𝒚𝒛 ww.T.rTr d) s, 𝑷𝒙w ,𝑷w𝒚w .,T𝒅.rT r
𝒙𝒚 , 𝒅𝒙𝒛𝒚𝒛 ww.T.rTr
w
ww w ww w w ww w w ww w wwww
13. The correct order of O-O bond length in hydrogen peroxide, ozone and oxygen is
a)c𝑯.c𝟐.o
s c 𝑶cm o m
𝟐 >𝑶𝟑 > 𝑶𝟐
s c .cc.ocmom b) 𝑶c𝟐.c>
s c .ocm
𝑶o𝟑m> 𝑯𝟐 𝑶𝟐
s c .cc.ocm
om
b T
b
s
nTpnc)p𝑶𝟐 > 𝑯𝟐 𝑶𝟐 > 𝑶𝟑bTbnTpnp s
b T
b
s
pnp𝑶 > 𝑶 > 𝑯 𝑶 TnTpnp
nTd) b b
s
b TbnTpns
ww.T.rTr 14. Which one of the ww.T .rTr ww.T.rTr 𝟑 𝟐 𝟐
ww .T.rTr
𝟐
ww.T.rTr
w
ww w ww w w following is diamagnetic?
ww w w www w wwww
a) 𝑶𝟐 b) 𝑶𝟐− 𝟐 c) 𝑶 +
𝟐 d) none of these
c o mo m c o m
o m c o mo m c o m
o m
n pn spcs.c.corder of a speciesnpnisspc2.5
15. Bond s.c.andc the number of electrons
n pn spcs.c.c in its bondingnpnmolecular spcs.c.c orbital is npns
T
rTbrbT formed to be 8. The T
rbTof electrons in its antibonding
rTbno T
rTbrbT molecular orbital T
rTisbrbT rTbrTbT
ww. T. . T.
ww b) four . T.
ww d) cannot be calculated . T .
wwfrom the given information ww. T.
ww
ww a) three ww ww ww
c) w w
zero wwww wwww
16. Shape and
. c.ocm o mhybridization of 𝟑𝑰𝑭.𝟐𝟓c.o are
cmom .cc.ocm om 𝟑sc.c c.ocm
om
s c c s c c s c
b T
b
a)
nTpnp s
Trigonal bipyramidal,
b T
b
𝒔𝒑
nT𝟑pn𝟐p s
𝒅
b T
b
b)
nTpnp s
Trigonal bipyramidal,
b Tb
𝒔𝒑
nTpnp 𝒅 s
b TbnTpns
ww.T.rTr c) square pyramidal, ww.T.rTr𝒔𝒑 𝒅 ww.T.rTr d) Octahedral, 𝒔𝒑ww 𝟑
.𝒅T.rTr
𝟐
ww.T.rTr
w
ww w w w
wincorrect w w w w ww
17. Pick out the w statement fromwthe w following ww ww
. c m
a) 𝒔𝒑c𝟑ohybrid
o m orbitals are equivalent . c ocmo mand are at an angle.cof.ocm 𝟏𝟎𝟗
o m 𝟎 𝟐𝟖′ with each other .cc.ocm
om
s c c . s c c . s c c s c
b T
b
s
nTpnb)p 𝒅𝒔𝒑 hybrid orbitals
𝟐
b T
b nT
are s
pnpequivalent and bondTangle
b b
s
nTpnp between any two bofTbthem s
nTpnp is 𝟗𝟎𝟎 b TbnTpns
ww.T.rTr c) all five 𝒔𝒑𝟑 𝒅whybrid .T.rTr orbitals are not equivalent
w ww.T.rTr out of these five 𝒔𝒑 ww .𝟑T𝒅.rThybrid
r orbitals, three .T.rTr
ware
w
w
at an angle of 𝟏𝟐𝟎𝟎 remainer two are perpendicular to the plane containing the other three
.cc.ocm
d)cnone
s
oofmthese
s c .cc.ocmom
s c .cc.ocm om
s c .cc.ocm
om
b T nTpnThe
18.
b
s
p molecules having Tsame
b b
s
nTpnphybridization, shape b T
band
s
nTpnpnumber of lone pairs b T
bof
pnp s
nTelectrons are b TbnTpns
ww.T.rTr a) 𝑺𝒆𝑭 , 𝑿𝒆𝑶 𝑭ww .T.rTr b) 𝑺𝑭 , 𝑿𝒆𝑭 ww.T.rTr c) 𝑿𝒆𝑶𝑭 , 𝑻𝒆𝑭 ww .T.rTr .T.rTr
w𝟒w
w
ww w 𝟒 ww w𝟐 w𝟐 𝟒 𝟐 ww w w 𝟒 www𝟒 w d) 𝑺𝒆𝑪𝒍 𝟐 , www
𝑿𝒆𝑭w
19. In which of the following molecules/ions 𝑩𝑭𝟑 , 𝑵𝑶− 𝟐 , 𝑯 𝟐 𝑶 the central atom is 𝒔𝒑 𝟐
hybridized?
c .
𝑵𝑯 c.oc−mo m
𝑯 𝑶 𝑵𝑶 − .c.o
c c m
o𝑯
m
𝑶 c
𝑩𝑭 ocm
.c𝟑c.andom 𝑵𝑶− c c.ocm
.c𝑩𝑭 om
a)
s c and b) s and
c c) s d) 𝟑 and 𝑵𝑯𝟐
b T
b nTpnSome
p s 𝟐 𝟐
b T
b
pnp s
𝟐
nTproperties 𝟐
b T
b nTpn𝑵𝑶 p−s 𝟐
+ b T
b
s
nTpnp below. Which bTbnTpns
s
ww.T.rTr 20. of the
w .T.rTr
following
w
of two
w .T.rTr
species,
w
𝟑 and 𝑯 𝟑 𝑶
w w.T.rTr
are described
w .T.rTr
w
w
ww w one of them ww w w
is correct? ww w w www w wwww
a) dissimilar m in hybridization for themcentral atom with different m structure
c . c.ocm o c . c.ocmo c . c.ocmo c .cc.ocm
om
s c s c s c s
b T
b
b)
nTpnp s
isostructural with
b
same
T
b nTpnp s
hybridization for the
b
Central
T
b nTpnp satom
b T
b nTpnp s
b TbnTpns
ww.T.rTr c) different hybridization ww.T.rTr for the central atom ww.T.rTwith
r same structure .T.rTr
ww d) none of these.T.rTr
ww
w
ww w 21. The types of ww w w
hybridization on the fivewcarbon
w
w w atom from right towleft
w w
w in the, 2,3 pentadieneww ww
a) 𝒔𝒑𝟑o, m m𝟐 , 𝒔𝒑, 𝒔𝒑𝟐 , 𝒔𝒑𝟑 ocm b) 𝒔𝒑𝟑 , o m 𝒔𝒑, 𝒔𝒑, 𝒔𝒑𝟑
.cc.ocm
𝒔𝒑
o o m 𝒔𝒑,
o m om
s c .cc. c s c .cc. s c .c c. c s c
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 6 b TbnTpns
ww.T.rTr ww.T.rTr ww.T.rTr ww .T.rTr ww .T.rTr
w
mm mm mm mm
n p p n p p p
nTn p nTnp p nTpns
.T.rTr
Tb b
.T.rTr
Tb b
.T.rTr
Tb
wwww ww
w𝟐 w w ww
w w www w ww
w
ww 𝟐 ww
c) 𝒔𝒑 , 𝒔𝒑, 𝒔𝒑 , 𝒔𝒑 , 𝒔𝒑 𝟐 𝟑 ww ww
d) 𝒔𝒑𝟑 , 𝒔𝒑𝟑 , 𝒔𝒑𝟐 , 𝒔𝒑𝟑 , 𝒔𝒑𝟑
ww
cm m ocmom𝟐 .cc.oc𝟐mom c) 𝑻𝒆𝑭𝟐 c.ocm
−m
22. Xe𝑭.c 𝟐.ois oisostructural with a) .cc.𝑺𝒃𝑪𝒍 b) 𝑩𝒂𝑪𝒍 d).𝑰𝑪𝒍 o
s c c s c s c c c 𝟐
b Tb
p p s
nTnThe percentage of s-character
23. b T
b
p p s
nTn of the hybrid orbitals b Tb
p p s
nTn in methane, ethane,bTbethene p s
nTn and ethyne are bTbnTpns
p s
ww.T.rTr respectively ww .T.rTra) 25,25,33.3,50 ww T.rT50,50,33.3,25
.b) r
c)ww .T.rTr
w
50,25,33.3,50 d) 50,25,25,50 ww.T.rTr
w
ww w ww w w www w www w
ww w
24. The following molecules, which have shape similar to carbon-dioxide?
.cc.ocm
a)c𝑺𝒏𝑪𝒍
s
o𝟐m b) 𝑵𝑶𝟐c.cc.ocom
s
m c) 𝑪𝟐 𝑯𝟐 c.cc.ocom
s
m
sd)
c .call m
om
c.ocof these
b T nT
25.
b
pn p s
According to VSEPR b T
b nTp
theory,n p s
the repulsion b
between Tb nTpn p s
different parts of b T
electronb nT pn p
obey
s
the order b TbnTpns
ww.T.rTr ww.T.rTr ww.T.rTr ww .T.rTr ww.T.rTr
w
ww w a) w w
l.p-l.p>b.p-b.p>l.p-b.p
ww www w b) w w
b.p-b.p>b.p-l.p>l.p-b.p
ww w
ww w
c) l.p-l.p>b.p-l.p>b.p-b.p d) b.p-b.p>l.p-l.p>b.p-l.p
.cc.ocofm
om ocmom
.cctriangular cm
.cc.oC) m
o‘T’ c.ocm
.cnoneom
s c
26.pShape 𝑪𝒍𝑭𝟑 is s c
a) planar . b) pyramidal s c shaped s c
d) of these
b TbnT n p s
b T
b nTpn p s
b Tb nTpn p s
b Tb nT pnp s
b TbnTpns
ww.T.rTr 27. Non-zero dipoleww .T.rTr is shown by ww
moment .T.rTr ww .T.rTr ww.T.rTr
w
ww w a) 𝑪𝑶𝟐 ww w w www w
b) p-dichlorobenzene w w
ww tetrachloride
c) carbon d) w w
w w
water
28. Which of the following conditionsm
c . c ocm
. o m
c . c.ocoismnot correct for resonating
c . c .ocmo mstructures?
c .cc.ocm
om
s c s c s c s
b Tb
a)
nTpnp sthe contributing structure
b T
b nTpnp s
must have the same
b Tb
number
nTpnp s of unpaired electrons
b Tb nTpnp s
b TbnTpns
ww.T.rTr b) the contributing ww.T.rstructures
Tr should have .T.rTr energies
wsimilar
w
ww w w w
ww hybrid should have higher w w
ww energy than any of w w w
w contributing structure ww w w
c) the resonance the
.cc.ocm oofmthese .cc.ocmom .cc.ocm om .cc.ocm

om
d) none
s c
s s cs s cs s cs s
b TbnTpnAmong
29. p the following,Tn
b b Tpnpcompound that contains,
the
b Tb nTpnp ionic, covalent and b Tb
pnp
nTcoordinate linkage is Tnp
b b T n
ww.T.rTr a) 𝑵𝑯𝟒 𝑪𝒍 ww.T.rTrb) 𝑵𝑯𝟑 ww.T.rTr c) NaCl ww .T.rTr d) none of these ww.T.rTr
w
ww w ww w w www w www w w
ww w
30. CaO and NaCl have the same crystal structure and approximately the same radii. It U is the lattice
.cc.ocm
energy
s c oofmNaCl, the approximate
s c
mom energy of CaO c.cc.oa)
.cc.oclattice s cmoUm b) 2U c) U/2 c.cc.ocm
s
od)m4U
b TbnTpnp s
b T
b nTpnp s
b Tb nTpnp s
b Tb nTpnp s
b TbnTpns
ww.T.rTr ww.T.rTr Unit-11 - Fundamentals ww.T.rTof
r organic chemistry .T.rTr
ww ww.T.rTr
w
ww w
1. Select the molecule which has only one 𝝅 bond
a)
s c .cc.oc𝟑 m
𝑪𝑯 o−m𝑪𝑯 = 𝑪𝑯 − 𝑪𝑯 c.cc.ocm
s
om b) 𝑪𝑯
s c .cc𝟑.oc−m m
o𝑪𝑯 = 𝑪𝑯 − 𝑪𝑯𝑶 s c .cc.ocm
om
b TbnTpnp s
b T
b nTpnp
𝟑 s
b Tb nTpnp s
b Tb nTpnp s
b TbnTpns
ww.T.rTr c) 𝑪𝑯𝟑 − 𝑪𝑯 =w𝑪𝑯 .T.rT−r 𝑪𝑶𝑶𝑯
w .T.rTr d) All of these ww
w𝟒w .T.rTr w .T.rTr
w
w
ww w ww w w 𝟕 𝟔 www w 𝟑 𝟐 𝟏 w w
w state of hybridization ofww w w
the w
𝟓
2. In the hydrocarbon carbon
𝑪𝑯𝟑 −𝑪𝑯𝟑 −𝑪𝑯 =𝑪𝑯 −𝑪𝑯𝟐 −𝑪≡ 𝑪𝑯
s c .cc.ocm
1,2,3,4 om 7 are in the following
and s c .cc.ocmom
sequence. s c .cc.ocm om
s c .cc.ocm
om
b Tb
s
nTpna)p sp,sp,𝒔𝒑𝟑 , ,𝒔𝒑𝟐 , ,𝒔𝒑 b 𝟑n
T
b Tpnp s
b Tb
pnp 𝟐
nTb) s
, 𝒔𝒑, , 𝒔𝒑 𝟑
, , 𝒔𝒑 𝟐bTn
, b
𝒔𝒑 T pp
𝟑n
s
b TbnTpns
ww.T.rTr w .T.rTr𝟑
w w .T.rTr
w
,𝒔𝒑
w .T.rTr
w w .T.rTr
w
w
ww w c) sp,sp, ,𝒔𝒑 𝟐ww
ww, 𝒔𝒑, , 𝒔𝒑 www w d) none of these www w w
ww w
3. The general m formula for alkadiene isma) 𝑪𝒏 𝑯𝟐𝒏 b) 𝑪𝒏 𝑯𝟐𝒏−𝟏 c) 𝑪
m𝒏 𝑯𝟐𝒏−𝟐 d) 𝑪𝒏 𝑯𝒏−𝟐 .c.ocm
c . c ocm
. o c . c.ocmo c . c .ocmo c om
s c s c s c s c
b TbnTnp s
4. pStructure of the compound
b T
b nTpnp s
whose IUPAC name
b
is
Tb
s
5,6-dimethylhept-2-ene
nTpnp b T
is
b nTpnp s
b TbnTpns
w
ww w a) ww w w b) www w c) www w d) None of w w
these
ww
5. The c ocm
.ccIUPAC
. omname of the compound c .cc.ocmomis c .cc.ocm om c .cc.ocm
om
s s
nTpna)p 2,3-dimethyl heptanes s
nTpnp s pnp
nTb) s s nTpnps s nTpns
b Tb b T
b b Tb 3-Methyl-4-ethyloctane b Tb b Tb
w
ww w b) c) w w
5-ethyl-6-methyloctane
ww www w d) w
4-Ethyl-3-methyloctane
ww w w
ww w
6. Which one of the following names does not fit a real name?
a)
s c .cc.ocm om
3-Methyl-3-hexanone s c .cc.ocmom b) c .cc.ocm om
4-Methyl-3-hexanone
s s c .cc.ocm
om
b TbnTpnp s
b T
b nTpnp s
b Tb nTpnp s
b Tb nTpnp s
b TbnTpns
ww.T.rTr c) 3-Methyl-3-hexanol ww.T.rTr ww.T.rTr d) 2-Methyl cyclowhexanone .T.rTr
w ww.T.rTr
w
ww w 7. The IUPAC w w w
w of the compound 𝑪𝑯
name w w
w𝟑w− 𝑪𝑯 = 𝑪𝑯 − 𝑪 ≡ 𝑪𝑯wisw w w w
ww w
a) pent-4-yn-2-ene b) pent-3-en-1-yne c) pent-2-en-4-yne d) pent-1-yn-3-ene
c . c ocm
. o m
c . c.ocmo m
c . c .ocmo m
c .cc.ocm
om
s c s c s c s
T nTpnp s
P.VARATHARAJAN
b b T nTpnp s
b b b Tb nTpnp s
b Tb nTpnp s
Page 7 b T
b nTpns
w
ww w
mm mm mm mm
nTn p nTpns
.T.rTr
T
b b
.T.rTr
T
b b
.T.rTr
Tb
wwww wwww w ww
w w ww
w wwww
ww ww 𝑯 𝑪𝟒 𝑯𝟗 ww ww ww
8. IUPAConame
. c . c m
o m of 𝑪𝑯𝟑 - 𝑪 - .𝑪c.ocm -𝑪𝑯
o m 𝟑 is . c.ocm om . c.ocm
om
b TbnTpnp s
b
𝑪
T
b
𝑯
𝟐 np
T
𝟓p
n s
𝑪𝑯 𝟑
b T
b nTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr a) 3,4,4-Trimethylheptane ww .T.rTr ww.T.rTr b) 2-Ethyl-3,3-dimethylheptane
ww.T.rTr ww.T.rTr
w
ww w ww w w
c) 3,4,4-Trimethyloctane www w www w
d) 2-Butyl-2-methyl-3-ethyl-butane ww ww
𝑪𝑯𝟑mm
c . c .ocmo m
c .cc𝑪.oco− 𝑪𝑯 = 𝑪(𝑪𝑯𝟑 )𝟐 scs.cc.ocm om c .cc.ocm
om
s c s s
b T
9. pThe
bnTnp s IUPAC name of the
b T
b
𝑯 𝟑 𝑪-
nTpnp 𝑪𝑯s
b T
b nTpnp b T
b nTpnp s
b TbnTpns
ww.T.rTr ww .T.rTr 𝟑
ww.T.rTr ww.T.rTr ww.T.rTr
w
ww w a) ww w w
2,4,4-Trimethylpent-2-ene www w b) www w
2,4,4-Trimethylpent-3-ene ww ww
c) 2,4,4-Trimethylpent-4-ene d) 2,4,4-Trimethylpent-5-ene
c . c .ocmo m
c . c.ocm o m
c .cc𝟐.oc−m m
o𝑪𝑯 c .cc.ocm
om
s c s c s s
b T
10.pThe
bnTnp s IUPAC name of the
b T
b
compound
nTpnp s 𝑪𝑯 𝟑 − 𝑪𝑯
b
=
T
b
𝑪 −
nTpnp 𝑪𝑯 s 𝟑
b T
b nTpnp s
b TbnTpns
ww.T.rTr ww .T.rTr ww.T.rTr𝑪𝑯𝟐 − 𝑪𝑯𝟐 − 𝑪𝑯𝟑wisw .T.rTr ww.T.rTr
w
ww w ww
a) 3-Ethyl -2hexane w w b) 3-propyl-3-hexane www w c) 4-Ethyl-4-hexanewww w d) 3-propyl-2-hexane ww ww
11. The IUPAC ocm mname of the compound ocm 𝑪𝑯𝟐 − 𝑪𝑯 − 𝑪𝑶𝑶𝑯 omm
s c .cc . o
s c .c c. o m
s c .cc.co s c .cc.ocm
om
b TbnTpnp s
b T
b nTpnp s OH
b T
b nTpnp is s
b T
b nTpnp s
b TbnTpns
ww.T.rTr a) 2-Hydroxypropionic ww .T.rTr acid ww.T.rTr b) 2- Hydroxy Propanoic ww.T.rTr acid ww.T.rTr
w
c) Propan -2-ol-1-oic acid d) 1- Carboxyethanol
s c .cc.ocm om
s c .cc.ocm om
s c .cc.ocm om
s c .cc.ocm
om
b TbnTpnThe
12. s
p IUPAC name of TnTpnp is
b b
s
b T
b nTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr a) 2-Bromo-3-methylbutanoicww .T.rTr acid ww.T.rTr b) 2-methyl-3-bromobutanoicww.T.rTr acid ww.T.rTr
w
c) 3-Bromo-2-methylbutanoic acid d) 3-Bromo-2,3-dimethyl propanoic acid
13. The.c
c ocmom of isobutyl group
structure
. c ocm
.cc.in oanmorganic compound c .cisc.ocm
om c .cc.ocm
om
s c s s s
b Tb
s
nTpna)p 𝑪𝑯 − 𝑪𝑯 − 𝑪𝑯bTb−nT𝑪𝑯 pnp s
b T
b
pnp
nTb) s
b T
b nTpnp s
b TbnTpns
ww.T.rTr 𝟑 𝟐 .Tr
ww.T
𝟐r 𝟐 −
ww.T.rTr ww.T.rTr ww.T.rTr
w
c) d) 𝑪𝑯𝟑 − 𝑪𝑯 − 𝑪𝑯𝟐 − 𝑪𝑯𝟑
14. The c ocmom of stereoisomers
.ccnumber
. c .cof mom
c.oc1,2-dihydroxy c
cyclopentane .cc.ocm om c .cc.ocm
om
s s
nTpna)p 1 s
nT2pnp s s
nTc)pnp s nTpnps s nTpns
b Tb b Tb b T
b b T
b b T
b
ww.T.rTr w w.T.rTr b)
w .T.rTr
w
3
w .T.rTr
w
d) 4
w.T.rTr
w
w
ww w 15. Which of the w w
wwfollowing is optically active? www w www w ww ww
a) 3-Chloropentane b) 2-Chloro m propane c) Meso-tartaric m acid d) Glucose.c.ocm
c . c .ocmo m
c . c.ocom c . c .ocm
o c om
s c s c s c s c
b T
16.pThe
bnTnp s isomer of ethanol
b T
is
b nTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) acetaldehydeww .T.rTrb) Dimethylether ww .T.rTr c) Acetone ww.T.rTd)r Methyl carbinol ww .T.rTr
w
ww w 17. How manyw
w w
w and acyclic isomers w
cyclic
w w
w possible for the molecular
are
w w
ww formula 𝑪𝟑 𝑯𝟔 𝑶? ww ww
a) 4 om
.cc.ocm
c) 9 om
.cc.ocm
b) 5 d) 10
s c .cc.com s c om
s c .cc.com s c om
b T18.
b
p s
nTpnWhich one of the following
b Tb
s
nTpnpshows functional isomerism? b T
b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) Ethylene ww .T.rTrb) Propane ww.T.rTr c) Ethanol ww.T.rTd)r 𝑪𝑯𝟐 𝑪𝒍𝟐 .T.rTr
ww
w
⊝
19. -𝑪 − 𝑪𝑯𝟑 and 𝑪𝑯𝟐 = 𝑪 − 𝑪𝑯𝟑
𝑪𝑯𝟐 omm
s c .cc.coO s c .cOc.oc⊝mom
s c .cc.ocm om
s c .cc.ocm
om
b TbnTpnp s
b Tb nTpnp s are
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) Resonating w .T.rTr
structure
w b) Tautomers ww.T.rTr c) Optical isomers ww.T.rTd)r Conformers .T.rTr
ww
w
ww w ww w w www w w w ww
20. Nitrogen detection in an organic compound is carried out byww Lassaigne’ test. The blue wwcolour
s c .cc.ocm
formed oismdue to the formation
s c ocm
.cc.of. om
s c .cc.ocm om
s c .cc.ocm
om
b Tb
s
nTpna)p F𝒆𝟑 [𝑭𝒆(𝑪𝑵)𝟔 ]𝟐 bb) Tb
s
pn𝟒p[𝑭𝒆(𝑪𝑵)𝟔 ]𝟑
nTF𝒆 b T
b nTc)pnp s
F𝒆𝟒 [𝑭𝒆(𝑪𝑵)𝟔 ]𝟐 d)TF𝒆
b b
s
nTp𝟑n[𝑭𝒆(𝑪𝑵)
p 𝟔 ]𝟑
b T
b nTpns
ww.T.rTr 21. Lassaigne’s testwfor w.T.rT r
the detection of nitrogen ww
rTr
.T.fails in ww.T.rTr .T.rTr
ww
w
a)𝑯𝟐 𝑵 − 𝑪𝑶 − 𝑵𝑯. 𝑵𝑯𝟐 . 𝑯𝑪𝒍 b) . 𝑵𝑯𝟐 −. 𝑵𝑯𝟐 . 𝑯𝑪𝒍
c) c𝑪.𝟔c𝑯.oc𝟓m
o−m𝑵𝑯 − 𝑵𝑯𝟐 . 𝑯𝑪𝒍 c.cc.ocm om d) 𝑪c𝟔.𝑯 c.o m
om 𝟐
𝟓cCO𝑵𝑯 c .cc.ocm
om
s c s s c s
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 8 b T
b nTpns
w
mm mm mm mm
n p p n p p p
nTn p p
nTn p nTpns
.T.rTr
Tb b
.T.rTr
T
b b
.T.rTr
T
b
wwww wwww w ww
w w www w ww
w
ww ww
22. Connect pair of compounds which give
ww blue colourisation/ w w
precipitate and white precipitate
ww
.cc.ocm
respectively,
s c om when their Lassaigne’s
s c .cc.ocmomtest is separately done.
s c .cc.ocm
om
s c .cc.ocm om
b Tb
s
nTpna)p 𝑵𝑯𝟐 𝑵𝑯𝟐 𝑯𝑪𝒍 andbCl𝑪𝑯 T
b
s
nTpn𝟐p− 𝑪𝑯𝑶 b Tb
s
nTpnp b) 𝑵𝑯𝟐 𝑪𝑺𝑵𝑯𝟐band T
b nTpn𝑪𝑯 s
p 𝟑 − 𝑪𝑯𝟐 𝑪𝒍
b T
b nTpns
ww.T.rTr c) 𝑵𝑯𝟐 𝑪𝑯𝟐 𝑪𝑶𝑶𝑯 ww
rTr
.T.and 𝑵𝑯𝟐 𝑪𝑶𝑵𝑯𝟐 ww ww.T.rTr d) 𝑪𝟔 𝑯w ww
𝟓 𝑵𝑯
.T .rTr
𝟐 and Cl𝑪𝑯𝟐 − 𝑪𝑯𝑶 ww ww .T.rTr
w
ww w www w ww ww w ww
23. Sodium nitropruside reacts with sulphide ion to give a purple color due to the formation of
.cc.ocm
a)c[Fe(𝑪𝑵)
s
om𝟓 𝑵𝑶]𝟑− b) [Fe(𝑵𝑶)
s c .cc.oc𝟓m m+
o𝑪𝑵] .cc.ocm
c) [Fe(𝑪𝑵)
s c om𝟓 𝑵𝑶𝑺]
𝟒−
d) [Fe(𝑪𝑵)
s c
mom 𝟑−
.cc𝟓.oc𝑵𝑶𝑺]
T nTpnOn s
p organic compoundTnTweighing pnp s
T
s
nTpnp estimation, 0.12gbTbofnTpnsilver p bromide. The TnTpns
s
b
.T.rTr
24.
b b
.T.rTr b 0.15g gave b
on
.T.rTr bcarius
.T.rTr .T.rTbrb
www w percentagewof w w
wbromine
w in the compound www w
will be close to ww ww www w
ww w ww ww ww
a) 46% b) 34% c) 3.4% d) 4.6%
c o m
o m
.c.c of 0.5g of an organic c o m
o m
.c.c compound was treated c o m
o m
.c.c according to Kjeldahl’s mom
.cc.ocmethod.
25.pAscssample s c s c s c The
b TbnT n p
b T
b nT pn p s
b TbnTpn p s
b T
b nTpn p s
b T
b nTpns
ww.T.rTr ammonia evolved ww
rTr absorbed in 50mL of.T0.5M
.T.was ww.T
r r 𝑯𝟐 𝑺𝑶𝟒 . The remaining
ww.T.rTracid after neutralization ww .T.rTr
w
ww w by ammonia w w
wwconsumed 80 mL of w w w
w M NaOH, The percentage
0.5 w w
ww of nitrogen in theworganic w
w w
compound m is a) 14% mb) 28% m c) 42% d)
m56%
c . c.ocm o c . c.ocmo c . c.ocm
o c . c .ocmo
c spsc pnspsc c
b TbnTpnInspsan organic compound,
26.
b T
b nTpnphosphorus is estimatednas
b Tb T b T
b nTpnsps b T
b nTpns
ww.T.rTr a) 𝑴𝒈𝟐 𝑷𝟐 𝑶𝟕 ww .T.rTrb) 𝑴𝒈𝟑 (𝑷𝑶𝟒 )𝟐 ww .T.rTr c) 𝑯𝟑 𝑷𝑶𝟒 ww.T.rTd)r 𝑷𝟐 𝑶𝟓 ww .T.rTr
w
27. Ortho and w w
para-nitro phenol can be separated ww by ww ww
.cc.ocm om distillation c.cc.ocm om .cc.ocm
om distillation c.cc.ocm om
a) Azeotropic b) Destructive
s c s s c s
b Tb
s
nTpnc)pSteam distillation bTbnTpnp s
b Tb
s
pnpCannot be separatedTnTpnp
nTd) b b
s
b T
b nTpns
ww.T.rTr 28. The purity of anworganic .T.rTr compound is determined
w ww.T.rTr by ww.T.rTr ww .T.rTr
w
ww w www w ww w w w
ww w w
ww w
a) Chromatography b) Crystallisation c) melting or boiling point d) Both (a) and (c)
s c .cc.ocm
29. A liquid m a liquid which decomposes
owhich
s c .cc.ocmom .cc.ocm
at its boiling point
s c
m be purified by .c.ocm
ocan
s c c om
b Tb
s
nTpna)p distillation at atmospheric
b T
b
s
nTpnp pressure b Tb
s
pnpdistillation under reduced
nTb) b T
b
s
nTpnppressure b T
b nTpns
ww.T.rTr c) fractional distillation ww .T.rTr ww.T.rTr d) steam distillation ww.T.rTr ww .T.rTr
w
ww w www w ww w w w
ww w w
ww w
30. Assertion: 𝑪𝑯𝟑 − 𝑪−= 𝑪𝑯 − 𝑪𝑶𝑶𝑯
s c .cc.ocm om
s
m
COO𝑪𝟐 𝑯𝟓 c.cc.ocom 3-carbethoxy -2-butetoic
s c .cc.ocm
om acid c .cc.ocm om
b Tb
p s
nTpnReason: The principalb T
b nTpnp s
functional group gets b T
lowest
b
s
nTpnnumber
p followed byb T
double
b
s
nTpnp bond (or) triple bTbnTpns
s
w
ww w bond www w ww w w w
ww w w
ww w
a) both assertion and reason are true and the reason is the correction explanation of assertion.
b)
s c .cc.ocm
both
m
oassertion and reason s c ocm
.cc.areom true but reason siscs.not cc.ocm m correct explanation
othe
s c .cc.ocm omassertion
of
b Tb
s
nTpnc)p assertion is true but b T
b nT pnp s
b Tb
pnp
nTd) b T
b
s
nTpnpare false. b T
b nTpns
ww.T.rTr ww .T.rTr reason is false.
ww.T.rTr Both assertion
.T.rTr
and
ww
reason
ww .T.rTr
w
ww w www w ww w w w
ww w w
ww w
Unit-12- Basic concept of organic reaction
s c c.ocm
.cthe om
s c c.ocm
.c𝑪𝑯 om
s c .→
cc.ocm
om
s c .cc.oc𝑶mom
b T
1.npFor
b T n p s following reactions
b T
b nTpnp A.s 𝟑 𝑪𝑯 𝟐 𝑪𝑯 𝟐 𝑩𝒓
b
+
Tb
𝑲𝑶𝑯
nTpnp s 𝑪𝑯 𝟐 = 𝑪𝑯 𝟐 +
b
𝑲𝑩𝒓
T
b
+
nTpnp 𝟐 s𝑯
b T
b nTpns
ww.T.rTr B. (𝑪𝑯𝟑 )𝟑 𝑪𝑩𝒓w+w .T.rTr → (𝑪𝑯𝟑 )𝟑 𝑪𝑶𝑯w+w𝑲𝑩𝒓
𝑲𝑶𝑯 .T.rTrC.
w +𝑩𝒓𝟐 → ww .T.rTr ww .T.rTr
w
ww w www w ww ? w w
ww w w
ww w
which of the following statement is correct
a) (A)
s c .cc.ocism m
oelimination (B) and (C)co
s c cm
.c.are om substitution
s c .cc.ocm
om
s c .cc.ocm om
b Tb
s
nTpnb)p (A) is substitutionb(B) T
b
s
pnp (C) are elimination TnTpnp
nTand b b
s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr c) (A) and (B) are ww T.rTr
.elimination and (C) is w ww.T.rTreaction
adition
r
ww.T.rTr ww .T.rTr
w
ww w www w ww w w
ww w w
ww w
d) (A) is elimination, B is subsititution and (c) is addition reaction
2. What
s c .cc.ocism m hybridization state.c.of
othe
s c c
ocm m carbonium ion?.c.ocm
obenzyl
s c c om
s c .cc.ocm om
b Tb
s
nTpna)p 𝒔𝒑𝟐 b Tb
s
nTpnp b) 𝒔𝒑𝒅𝟐 b T
b
s
nTpnp c) 𝒔𝒑𝟑 b T
b nTpnp s d) 𝒔𝒑𝟐
𝒅 b T
b nTpns
ww.T.rTr 3. Decreasing order ww .T.rTnucleophilicity
r
ww.T.rTr ww.T.rTr ww .T.rTr
w
ww w www w of isww w w w
ww w w
ww w
a) 𝑶𝑯− > 𝑵𝑯− 𝟐 > −𝑶𝑪𝑯𝟑 > 𝑹𝑵𝑯𝟐 b) 𝑵𝑯𝟐− >𝑶𝑯− > −𝑶𝑪𝑯𝟑 > 𝑹𝑵𝑯𝟐
s c .cc.ocm om
s c .cc.ocmom
sc .cc.ocm
om
s c .cc.ocm om
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 9 b T
b nTpns
w
ww w www w ww w w w
ww w w
ww w
mm mm mm mm
b Tb
p
nTn p
b T
b
p
nTn p
b Tb
p
nTn p
b Tb
p
nTn p
b T
b nTpns
ww.T.rTr ww.T.rTr ww .T.rTr ww .T.rTr ww.T.rTr
w
ww w w
ww − w ww ww w w
ww − >𝑶𝑯− > 𝑹𝑵𝑯 wwww
c) 𝑵𝑯− 𝟐 > 𝑪𝑯𝟑 𝑶 > 𝑶𝑯 >> 𝑹𝑵𝑯𝟐
−
d) 𝑪𝑯𝟑 𝑶− > 𝑵𝑯 𝟐 𝟐
4. Which .cc.ocofm
om the following species.cis ocmomelectrophilic in nature?
not .cc.ocm om .cc.ocmom
s c s c c . s c s c
b Tb
s
nTpna)p 𝑪𝒍+ b b)
T
b
pnp𝟑
nT𝑩𝑯 s
b TbnTc)pnp s
𝑯𝟑 𝑶+ b Tb
s
nTpnpd) +𝑵𝑶𝟐 b T
b nTpns
ww.T.rTr 5. Hemolytic fission ww.T rr
of.Tcovalent bond leads w
tow
T.rTrformation of
.the ww .T.rTr ww.T.rTr
w
ww w ww w w ww ww www w wwww
a) Electrophile b) Nucleophile c) Carbo cation d) Free radical
6. Hyper m
om
.cc.occonjugation is also known m
om
.cc.ocas .cc.ocm om .cc.ocmom
s c s c s c c
b Tb
s
nTpna)p No bond resonance b T
bb)
s
nTpBaker-Nathan
n p effect b TbnTc)pnp s
Both (a) and (b) b Tb
s
nTpnpd) None of these bTbnTpns
s
ww.T.rTr ww.T.rTr ww .T.rTr ww .T.rTr ww.T.rTr
w
ww w 7. Which of the
ww w w
group has highest +I effect?
ww ww www w wwww
a) 𝑪𝑯𝟑− b) 𝑪𝑯𝟑 − 𝑪𝑯𝟐 − c) (𝑪𝑯𝟑 )𝟐 − 𝑪𝑯 − d) (𝑪𝑯𝟑 )𝟑 − 𝑪 −
.cc.ocofm
om ocm
.ccdoesomnot exert a resonance mom
.cc.oceffect? .cc.ocmom
8. Which
s c the following species s c . s c s c
b TbnTpnp s
b T
b nTpnp s
b TbnTpnp s
b TbnTpnp s
b T
b nTpns
ww.T.rTr a) 𝑪𝟔 𝑯𝟓 𝑶𝑯 ww .T.rTrb) 𝑪𝟔 𝑯𝟓 𝑪𝒍 ww .T.rTr c) 𝑪𝟔 𝑯𝟓 𝑵𝑯𝟐 ww .T.rTr d) 𝑪𝟔 𝑯𝟓 𝑵𝑯𝟑 .TrTr
ww.
w
ww w 9. –I effect is w w w
w by a) –Cl
shown ww
ww–Br
b) c) Both (a) and w
ww(b)w d) -𝑪𝑯𝟑 ww ww
10. Which of the following carbocation will be most stable? mm
c . c.ocm o m
c . c.ocmo m
c .cc.oc)o− 𝑪𝑯 c ocm
.cc𝑪𝑯
. om
s c −+
s c s s
b Tb
a)
nTpnp 𝟑 s
𝑷𝒉 𝑪
b
b)
T
b
𝑪𝑯
nTpnp𝟑 s− 𝑪𝑯 𝟐 −
b Tb
c) (𝑪𝑯
nTpnp 𝟑 𝟐s d)
b T
𝑪𝑯
bnTpn𝟐p= s − 𝑪𝑯𝟐
b T
b nTpns
ww.T.rTr 11. Assertion: Tertiary ww
rTr
.T.carbocations are generally
ww .T.rTformed
r more easily than ww
rTr
.T.primary carbocations ions. ww.T.rTr
w
ww w Reason: Hyper
w w ww
ww conjugation as well waswinductive effect due to w w
wwadditional alkyl group w www
stabilize
.cc.ocm .cc.ocm .cc.ocm .cc.ocm

tertiary ocarbonium
m ions. om om om
s c s c s c s c
b Tb
s
nTpna)p both assertion and b T
b
s
nTpnp are true and thebreason
reason
Tb
s
nTpnp is the correction bexplanation T
b nTpnp s of assertion.
b T
b nTpns
ww.T.rTr b) both assertion ww
rTr reason are true but
.T.and ww .T.rT r
reason is not the correct ww .T.rTexplanation
r .T.rTr
of assertion
ww
w
ww w w w ww w w ww
c) assertionwis wtrue but reason is false. ww d) Both assertion ww and reason are false.ww
.cc.ocm
12. Heterolytic
s c om fission of C-Br bond
s c cmom in the formationc.of
.cc.oresults s cc.ocm om c .cc.ocmom
T
s
nTpna)p Free radical T
s
nTpnp b) Carbanion bTbnTpnp c) Carbocation s
T nTd) s
pnp Carbanion and TnTpns
s
b b
.T.rTr Carbocation ww .T.rTr b b .T.rTr b
.T.rTr b .T.rTbrb
www w ww www w ww w w www w
ww ww
13. Which of the following represent a set of nucleophiles?
ww ww ww
.cc.o𝟑c,m
o𝑯m𝟐 𝑶, 𝑵𝑯𝟐− b) 𝑨𝒍𝑪𝒍c𝟑.cc, .𝑩𝑭 ocmo𝟑m mom −𝟐 , 𝑹𝑶𝑯 d) 𝑯+ , 𝑹𝑵𝑯 .cc.oc𝟑m
+ m
a) 𝑩𝑭
s c s
, 𝑵𝑯𝟑 c) 𝑪𝑵.−
s c cc.,oc𝑹𝑪𝑯 s c o, 𝑪𝑪𝒍𝟐
b T14.
b
p p s
nTnWhich of the following b T
b
p p
species
s
nTn does not acts asbaTbnucleophile? p
nTn p s
b T
b
p
nTn p s
b T
b nTpns
ww.T.rTr a) ROH ww.T.rTrb) ROR ww .T.rTr c) 𝑷𝑪𝒍 ww .T.rTr d) 𝑩𝑭 ww.T.rTr
w
ww w ww w w ww ww 𝟑 www w 𝟑 wwww
15. The geometrical shape of carbocation is
a)
s c .cc.ocm
Linear om .cc.ocm
b) Tetrahedral
s c om .cc.ocm
c) sPlanar
c om
sd)
c c.ocmom
.cPyramidal
b TbnTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr ww.T.rTr Unit-13 w- wT.rTr
.Hydrocarbons ww .T.rTr ww.T.rTr
w
1. The correct m statement regarding the
m comparison of staggered m and eclipsed conformations of
c . c.ocm o c . c.ocmo c . c. ocmo c . c ocm
. o m
spsc is
nTpnethane, nTpnsps
c
nTpnsps
c
nTpnsps
c
nTpns
b Tb b T
b b T
b b T
b b T
b
ww.T.rTr a) the eclipsedwconformation .T.rTr
w of ethane iswmore .T.rTr stable than staggered
w ww .rTr
.Tconformation even though
ww.T.rTr
w
ww w ww w w ww
wwstrain. www w wwww
the eclipsed conformation has torsional
s c .cc.ocm
b) the o m
staggered conformation
s c
m
omethane is more stable
.cc.ocof s c .cc.ocm m eclipsed conformation,
othan
s c .cc.ocmombecause
b Tb
p s
nTpnstaggered conformation
b T
b
s
pnp no torsional strain. TnTpnp
nThas b b
s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr c) the staggered ww .rTr
.Tconformation of ethane ww .Tis.rTless
r stable than eclipsed
ww .T.rTrconformation, because ww.T.rTr
w
staggered conformation has torsional strain.
.cc.ocm
d) the
s c
m
ostaggered conformation
s c .cc.ocmomethane is less stable
of
s c
mom eclipsed conformation,
.cc.octhan s c .cc.ocmom because
b Tb
p s
nTpnstaggered conformation b Tb
s
pnp no torsional strain. TnTpnp
nThas b b
s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr ww T.rT𝒆𝒕𝒉𝒆𝒓
.𝒅𝒓𝒚 r
ww .T.rTr ww .T.rTr ww.T.rTr
w
ww w 2. 𝑪𝟐 𝑯𝟓 𝑩𝒓 +w𝟐𝑵𝒂 w w
w → 𝑪𝟒 𝑯𝟏𝟎 + 𝟐𝑵𝒂𝑩𝒓 ww
ww The above reaction w w
wwis an example of whichwwof the ww
following
s c .cc.ocm om
s c .cc.ocmom
sc .cc.ocm om
s c .cc.ocmom
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 10 b T
b nTpns
ww.T.rTr ww.T.rTr ww .T.rTr ww .T.rTr ww .T.rTr
w
mm mm mm mm
n p p n p p p
nTn p nTnp p nTpns
.T.rTr
T
b b
.T.rTr
T
b b
.T.rTr
T
b
wwww wwww w www w ww
w wwww
ww ww
a) Reimer Tiemann reaction
w
b) wWurtz reaction c) Aldol
ww condensation d) Hoffmann ww
s c c.ocmom
.reaction
c s c .cc.ocmom
s c .cc.ocmom c .cc.ocmom
T3.n
TpnAn s
p alkyl bromide (A) reacts T
s
nTpnpwith sodium in ether T nTpnform
to s
p 4,5-diethyloctane,TnT the
s
pnpcompound (A) is TnTpns
s
b b
.T.rTr a) 𝑪𝑯𝟑 (𝑪𝑯𝟐 )𝟑 𝑩𝒓 b
.T.rTr b b b
.T.rTr b) 𝑪𝑯𝟑 (𝑪𝑯𝟐 )𝟓 𝑩𝒓 b
.T.rTr b .T.rTbrb
wwww www w ww w w www w wwww
ww ww ww ww ww
c) 𝑪𝑯𝟑 (𝑪𝑯𝟐 )𝟑 𝑩𝒓CH(Br) 𝑪𝑯𝟑 d) 𝑪𝑯𝟑 − (𝑪𝑯𝟐 )𝟐 − 𝑪𝑯(𝑩𝒓) − 𝑪𝑯𝟐
s c .cc.ocmom
s c .cc.ocmom
s c .cc.ocmom
s c .cc.oc𝟑m
𝑪𝑯 om
b T nTpnThe
4.
b
s
p C-H bond and C-C Tbond
b b
s
nTpnpin ethane are formed b T
b Tpnwhich
nby p s
of the following b T
b types
s
nTpnp of overlap b T
b nTpns
ww.T.rTr .T𝟑.rTr 𝟑
w𝒔𝒑w .T𝟐.rTr 𝟐
w𝒔𝒑
w
ww w a) 𝒔𝒑 𝟑
− 𝒔 w
and
ww w − 𝒔𝒑 b) 𝒔𝒑 𝟐
-s w
and
ww w − 𝒔𝒑 c) sp-sp
ww w w
and sp-sp d) p-s and w
p-p
ww w
𝑩𝒓𝟐
5. In the m
om
.cc.ocfollowing reaction c.ocm
.→𝒉𝒗 om major product obtained
The
.cc.ocmomis .cc.ocmom
s c s c c s c s c
b TbnTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) ww .T.rTr b) ww.T.rTr c) ww .T.rTr d) ww.T.rTr
w
ww w www w www w ww w w ww ww
6. Which of the following is optically active
s .cc.ocm
a)c2-methyl om pentane b) citriccacid
s .cc.ocmom .cc.ocm
c) Glycerol
s c om d)
c c.ocm
.cnone om of these
b T7.
b
p p s
nTnThe compounds formed b T
b
p
nTatn p s
anode in the T
electrolysis
b b
p p s
nTn of an aquous solution b T
b
p s
nTofn potassium acetate bTbnTpns
p s
ww.T.rTr are a) 𝑪𝑯 andw𝑯w .T.rTrb) 𝑪𝑯 and 𝑪𝑶 ww .T.rTr c) 𝑪 𝑯 and 𝑪𝑶 ww .T.rTr ww.T.rTr
w
ww w 𝟒 www w 𝟐 𝟒 ww
𝟐 w w 𝟐 𝟔 ww w w
𝟐 d) 𝑪 𝟐 𝑯 𝟒 and w
ww 𝟐𝑪𝒍
w
8. The general formula for cyclo alkanes a) 𝑪𝒏 𝑯𝒏 b) 𝑪𝒏 𝑯𝟐𝒏 c) 𝑪𝒏 𝑯𝟐𝒏−𝟐 d) 𝑪𝒏 𝑯𝟐𝒏+𝟐
c oc m
o m
.ccompound c o
.cmost m
o m
c readily with gaseous c oc m
o
.cbrominem .cc.ocmom
9. Thes c . that will react s c . s c . has the formula s c
b Tb
s
nTpna)p 𝑪 𝑯 b T
b
b)
nT𝑪pnp𝑯 s
b T
b nTc)pnp
𝑪
s
𝑯 b T
b
s
nTpnpd) 𝑪 𝑯 b T
b nTpns
ww.T.rTr 𝟑 𝟔
ww .T.rTr 𝟐 𝟐 .T.rTr
wnot
w
𝟒 𝟏𝟎
w .T.rTr
w
𝟐 𝟒
ww.T.rTr
w
ww w 10. Which of ww
thew w
following compounds www
shellw produce propene ww w
by w
reaction with HBr ww
ww by
followed
elimination
. c.ocmo m (or) only direct elimination
. c ocm
. o m reaction cm
.cc.oc)om ocm
.cc.𝑪𝑯 om
s c c s c c s c s c
b TbnTpnp
a) s
b
b)
T
b
𝑪𝑯
nTpnp𝟑 s− 𝑪𝑯 𝟐 − 𝑪𝑯 𝟐 −
b
𝑶𝑯
T
b nTpnp s 𝑯 𝟐 𝑪 = 𝑪 =
b
𝑶
T
b nTpnp d)s 𝟑 − 𝑪𝑯𝟐 −
b T
b nTpns
ww.T.rTr 𝑪𝑯𝟐 𝑩𝒓 ww .T.rTr ww.T.rTr ww .T.rTr ww.T.rTr
w
ww w w w
wwthe following alkenes on w w
wwreductive ozonolysis produces w w
ww only propanone? ww ww
11. Which among
.cc.ocmom propene .cc.ocmom .cc.ocmombut -2- ene .cc.ocmom

a) 2-Methyl b) 2-Methyl
s c s c s c s c
b Tb
s
nTpnc)p2,3-Dimethyl but -1-ene b TbnTpnp s
b T
b
s
pnp2,3 – Dimethyl but -2-ene
nTd) b T
b nTpnp s
b T
b nTpns
ww.T.rTr 12. The major product ww
rTr
.T.formed when 2-bromo .T.rTr
w-2-methyl
w butane is refluxed ww
rTr ethanolic KOH is .T.rTr
.T.with ww
w
ww w www w w w
w w w ww w w www
a) 2-methylbut-2-ene b) 2-methyl butan-1-ol
m m
.cc.oco but -1-ene scs.cc.oco
c) 2-methyl m m .cc.ocm
d) 2-methyl ombutan -2-ol .cc.ocmom
s c s c s c
b Tb
p s
nTpnMajor b TbnTpnpmentioned reaction b T
b nTp(𝑪𝑯
n p s 𝑰𝑪𝒍
b T
b nTpnp s
b T
b nTpns
ww.T.rTr 13. product
w
of.T.rTr
w
the below
w .T.rTr
w
is, )
𝟑 𝟐 𝑪 = 𝑪𝑯 𝟐 .Tr
w
→
w .Tr ww.T.rTr
w
ww w www w
a) 2-chloro-1-iodo-2-methyl propane ww w w ww
b) 1-chloro-2-iodo-2- w w methyl propane ww ww
c) 1,2-dichloro
m -2- methyl propane d) 1,2-diiodo-2- m methyl propane.c.ocm
c . c.ocmo c . c ocm
. o m
c . c.ocmo c om
s c s c s c s c
b T nTpnThe
14.
b
s
p IUPAC name of theTnT
b b
pnp s
following compound isbT b nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) trans-2-chloro-3-iodo-2-pentane
ww .T.rTr ww.T.rTr b) cis-3-iodo-4-chloro-3- ww .T.rTr pentane ww.T.rTr
w
c) trans-3-iodo -4-chloro-3- pentene d) cis-2-chloro-3-iodo-2-butene
.cc.ocm
15. Cis-2-butene
s c om and trans-2-butene
s c
m
om
.cc.ocare s c .cc.ocmom
s c .cc.ocmom
b Tb
s
nTpna)p Conformational isomers b Tb
s
nTpnp b) Structural isomers b T
b
s
nTpnp c) Configurational b T
b
pnp s
nTisomers d) Optical b T
b nTpns
ww.T.rTr ww .T.rTr ww.T.rTr ww .T.rTr ww.T.rTr
w
ww w isomers www w www w ww w w ww ww
c .cc.ocm
16. Identify
s
m
othe compound (A) sincs.the c.ocm
c om
following reaction scs.cc.co
omm 𝒊) 𝑶𝟑 →
s c .cc.ocmom
b TbnTpnp s
b TbnTpnp b T
b nTpnp 𝒊𝒊) 𝒁𝒏/𝑯𝟐 𝑶 Tnp
b b T n p s
b T
b nTpns
ww.T.rTr ww .T.rTr ww.T.rTr ww .T.rTr ww.T.rTr
w
a) b) c) d)
s c .cc.ocmom
s c .cc.ocmom
sc .cc.ocmom
s c .cc.ocmom
T nTpnp s
P.VARATHARAJAN
b b T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 11 b T
b nTpns
ww.T.rTr ww .T.rTr ww.T.rTr ww .T.rTr ww .T.rTr
w
mm mm mm mm
n p p n p p p
nTn p p
nTn p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTrb Tb .T.rTrb T
b .T.rTrb Tb
wwww wwww w ww
w w ww
w w ww
w
ww ww ww ww ww
(𝑨)
→m
17.
c . c oco𝑪𝑯
. m ≡ 𝑪𝑯 Where a is.c.ocm
c o ma) Zn b) Conc 𝑯𝟐 𝑺𝑶
c . c.
𝟒 mm 𝒄) 𝒂𝒍𝒄. 𝑲𝑶𝑯
oco d) dil 𝑯
c . c.ocmo m𝑺𝑶𝟒
𝟐
18. spsc
nTpnConsider the nitration nofpsp
n sc
benzene using mixed ncon pnsps𝑯c𝟐 𝑺𝑶𝟒 and 𝑯𝑵𝑶𝟑TifnTpnasplarge sc quantity of npns
b T
b
rTr 𝑲𝑯𝑺𝑶𝟒 is added.to b T
b
rTthe T b
rTr
r mixture, the rate of.Tnitration Tb T b
rTr b rTbrTbT
ww. T. ww T. ww . will be ww. T. ww. T.
ww
ww a) Unchanged ww ww b) Doubled wwww c) Faster wwww d) Slowerww
ww
.cc.ocmom .cc.ocm
omall atoms are Co-planar .cc.ocmom .cc.ocmom
19. In which of the following molecules,
s c s c s c s c
b T
b nTpnp s
b T
b nTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr a) ww.T.rTrb) ww.T.rTr c) ww.T.rTr d) Both (a) and ww.T.rTr
(b)
w
20. Propyne onwpassing w through red hot iron ww tube gives ww ww
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocmom c .cc.ocmom
b T
b nTpna)p s
b
b)np
T
b T n p s
b TbnTc)pnp s
b T
b
s
nTpnpd) None of these bTbnTpns
s
ww.T.rTr ww.T.rTr ww.T.rTr ww.T.rTr ww.T.rTr
w
ww w 𝑯𝑪𝒍 ww
wwis www w w w
ww(b) www w
21. → (A) a) b) c) both (a) and d)
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocmom
s c .cc.ocmom
b 22.
T
b
p s
nTpnWhich one of the following
b T
b
s
nTpnpis non aromatic? a)bTbnTpnp b) s c)Tn
b b T
s
pnp d)
b TbnTpns
ww.T.rTr 23. Which of the following ww.T.rTr compounds will not ww T.rTr Friedal-crafts reaction
.undergo ww.T.rTr easily? ww.T.rTr
w
ww w ww w w www w www w www w
a) Nitro benzene b) Toluene c) Cumene d) Xylene
24. Some
s c .cc.ocmom
meta-directing .cc.ocm
substituents
s c omin aromatic substitution
s c .cc.ocmom are given. Which
s c
m
om is most
.cc.ocone
b T
b
p s
nTpndeactivating? b T
ba)
pnp
nT–COOH s
b) -𝑵𝑶 b TbnTc)pnp s
-C≡N d) -𝑺𝑶 b𝑯T
b nTpnp s
b TbnTpns
ww.T.rTr 25. Which of the following ww.T.rTr can be used as thewhalide .T.rTr component for friedal-crafts
𝟐
w ww.T.rTr reaction?
𝟑
ww.T.rTr
w
a) Chloro benzene b) Bromo benzene c) Chloro ethane d) Isopropyl Chloride
26. Ans c .cc.ocm
alkane s c .cc.ocm
omis obtained by decarboxylation om
s c
of sodium propionate. .cc.ocmom Same alkane canc.be
s c
m
om
c.ocprepared by
b T
b nTpn p s
b T
b nT pn p s
b TbnTpn p s
b T
b nTpn p s
b TbnTpns
ww.T.rTr a) Catalytic
.T.rTr
hydrogenation
w1-Chloro
w
of propene
ww.T.rTr b) Action of sodium
ww.T.rTr
metal on iodomethane
ww.T.rTr
w
ww w c) Reduction ww w
ofw propane www w d) Reduction www
of w
bromomethane www w
27. Which of the following is aliphaticmsaturated hydrocarbon m
c . c ocm
. o m
c .cc.ocom c .𝑯c.ocom c .cAll m
om
c.ocof
s c s s c s
b T
b
a)
nTpnp 𝑪
s 𝟔 𝑯 𝟏𝟖
b
b)
T
b
𝑪
nTpnp
𝟗 𝑯 s
𝟏𝟖
b Tb
c)
nTpnp 𝑪 s
𝟖 𝟏𝟒
b T
b nTpnpd)s these
b TbnTpns
ww.T.rTr 28. Identify the compound ww.T.rTr ‘Z’ in the followingwreaction
.T.rTr 𝑪𝟐 𝑯𝟔 𝑶 𝟔𝟐𝟑𝑲
w
𝑨𝒍 𝑶
𝟐 𝟑
→w T.r𝟑Tr→Y 𝒁𝒏/𝑯𝟐 𝑶 → (z) ww
.𝑶
𝑿w .T.rTr
w
a) Formaldehyde b) Acetaldehyde c) Formic acid d) none of this
s c .cc.ocm
29. Peroxide om effect (Kharasch effect)
s c .cc.ocm
ombe studied in casec.of
can
s cc.ocmom
s c .cc.ocmom
b T
b
s
nTpna)p Oct-4-ene b T
b)
b
pnp s
nTHex-3-ene b TbnTc)pnp s
Pent-1-ene b T
b
s
nTpnpd) But-2-ene b TbnTpns
ww.T.rTr 30. 2-butyne on chlorination
ww.T.rTr gives ww.T.rTrbutane ww.T.rTb)r 1,2-dichloro butane ww.T.rTr
w
ww w ww w w a)
www
1-chloro
w www w www w
c) 1,1,2,2-tetrachloro butane d) 2,2,3,3-tetrachloro butane
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocmom
s c .cc.ocmom
b T
b nTpnp s
b T
b
s
nTpnpUnit-14 HaloalkanesbT b
s
nTpnhaloarenes
and p
b T
b nTpnp s
b TbnTpns
w
ww w 1. The IUPAC w w w
w of
name www w www w www w
a) 2-Bromo
ocm m pent -3-ene b) 4-Bromo ocm mpent -2- ene c) 2-Bromo ocm pent
m -4-ene d) 4-Bromo opent
m m-1- ene
c . c . o
c following compounds, c .cc. o c . c. o c . c. c o
2.np nspsthe
Of nTpnspswhich has the highest spsc point?
nTpnboiling nTpnsps
c
nTpns
b T
b T b T
b b Tb b T
b b Tb
ww.T.rTr a) n-Butyl chloride ww.T.rTrb) Isobutyl chlorideww T.rTt-Butyl
.c) r chloride d)w .T.rTr chloride
n-propyl
w ww.T.rTr
w
ww w w w
wfollowing w w w w w w
3. Arrange the w compounds in w w
increasing order of their density ww ww
s c .cc.oc𝟒m
a) 𝑪𝑪𝒍 om b) 𝑪𝑯𝑪𝒍𝟑cocm
s c .c. om c) 𝑪𝑯c
s c ocm
.c𝟐.𝑪𝒍 o𝟐 m
s .cc.ocm
d) 𝑪𝑯
c
m
o𝑪𝒍
𝟑
b T
b
s
nTpna)p D<C<B<A b b)
Tb
pnp s
nTC<B<A<D b T
b nTc)pnp s
A<B<C<D
b T
b
s
nTpnpd) C<A<B<D b TbnTpns
ww.T.rTr 4. With respect towthe .T.rTposition
w
r of –Cl in the .T.rTr
wcompound
w 𝑪𝑯𝟑 − 𝑪𝑯 = w .T.−rTr𝑪𝑯𝟑 − 𝑪𝒍, it is classified
𝑪𝑯
w ww.T.rTr
w
as a) Vinyl b) Allyl c) Secondary d) Aralkyl
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocmom
s c .cc.ocmom
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 12 b TbnTpns
w
mm mm mm mm
nTn p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTrb Tb .T.rTrb T
b b
.T.rTr
Tb
wwww wwww w www w ww
w w ww
w
ww ww
5. What should be the correct IUPAC name
ww of diethyl chloromethane? ww ww
s c .cc.ocmom
a) 3-chloropentane
s c .cc.ocm
om .cc.ocmom
b) 1-chloropentane
s c s c .cc.ocm
om
b Tb
s
nTpnc)p1-chloro-1,1,diethyl b T
b nTpnp
methane s
b Tb
s
pnp1-chloro-1-ethyl propane
nTd) b T
b nTpnp s
b TbnTpns
ww.T.rTr 6. C-X bond is strongest ww.T.rTrin ww.T.rTr ww.T.rTr ww .T.rTr
w
a) chloromethane b) Iodomethane c) Bromomethane d) Fluoromethane
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocmom
s c .cc.ocm
om
b TbnTpnp s
b T
b nTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr 7. In the reaction w Xw.isT.rTr 𝑪𝒖
+ 𝑯𝑪𝒍
ww .rTr 𝟐 a)
.T→X+𝑵 b) ww.c)T.rTr d) ww .T.rTr
w
8. Which of the following compounds will give racemic mixture on nucleophilic substitution by OH-
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocmom
s c .cc.ocm
om
b TbnTpnp s
b T
b nTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr ion? i) ww.T.rTr ii)
ww.T.rTr iii) ww.T.rTr ww .T.rTr
w
ww w a) (i) www w b) (ii) (iii) www w c) (iii) ww w w d) (i) and (ii) www w
m cm .cc.ocm .cc.ocm
s c .ocom of ethyl formate
.cctreatment s c om
.cc.owith s c om
s c om
b T
9. pThe
bnTnp s
b T
b nTpnp s excess of RMgX
b TbnTpnp gives
s a) b)
b T
b
c)
nTpnpR-CHO
s d) R-O-R
b TbnTpns
ww.T.rTr 10. Benzene reactswwith .T.rT𝑪𝒍
w
r 𝟐 in the presence of .𝑭𝒆𝑪𝒍 rr
wwT.T 𝟑 and in absencewofw .T.rTr to form
wsunlight
w ww .T.rTr
w
ww w a) Chlorobenzenewww w b) Benzyl chloride www w c) Benzal chlorideww ww
d) Benzene hexachloride
w w
11. The name
. c .ocm
o mof 𝑪𝟐 𝑭𝟒 𝑪𝒍𝟐 is a) Freon-112 . c.ocm
o m b) Freon-113 o
. c.
c)m
c
Freon-114
om d) Freon-115
.cc.ocm
om
s c c s c c s c c c
b Tb
p s
nTpnWhich
12. of the followingnreagents
b T
b Tpnp s
b TbnTpnp
is helpful to differentiate s ethylene dichloride
b T
b
s
nTpnp and ethylidene bTbnTpns
s
ww.T.rTr chloride? a)
ww T.rTr
.Zn/methanol .T.rTr c) aqueous KOH ww
b) KOH/ethanol
ww .T.rTd)r Zn𝑪𝒍𝟐 /conHCl ww .T.rTr
w
13. Match the w w
following ww ww ww
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocm
om
s c .cc.ocm
om
b TbnTpnp s Column
b
I
T
b
s
(compound)
nTpnp b TbnTpnp s
Column II (uses)
b T
b nTpnp s
b TbnTpns
ww.T.rTr A Iodoform
w .T.rTr
w w .T.rTr 1 Fire extinguisher
w w .T.rTr
w w w.T.rTr
w
ww w w w
B wwCarbon tetra chloride ww w w 2 Insecticide ww w w www w
C CFC 3 Antiseptic
s c .cc.ocmomD DDT s c .cc.ocm
om .cc.ocm
om
4 scsRefrigents s c .cc.ocm
om
b Tb
s
nTpna)p A-2 B-4 C-1 D-3 bb) T
b
pnp
nTA-3 s
B-2 C-4 D-1 b TbnTc)pnp
A-1 B-2 C-3 D-4 b
d)T
b nTpnB-1
A-3
s
p C-4 D-2
b TbnTpns
ww.T.rTr ww.T.rTr ww.T.rTr w .T.rTr
w ww .T.rTr
w
ww w 14. Assertion:In www w
mono haloarenes, w w
electrophilic
ww substitution occurs
ww w w
at ortho and para w w
positions.
ww
Reason: Halogen atom is a ring deactivator
m
om assertion and reason
.cc.ocboth .cc.ocm
om .cc.ocm
omis the correctionc.ccexplanationocm
om
a)
s c If s c are true and the s c reason s . of
b TbnTpn p s
b T
b nTpn p s
b TbnT pn p s
b T
b nTpn p s
b TbnTpns
ww.T.rTr assertion. b) If .T.rTr
both
wassertion
w
assertion and reason
ww.T.rTr
are true but reason is .T.rTr
not
ww
the correct explanation
ww .T.rTr
of
w
ww w assertion ww
c)w w
If is true but www w
reason is false. d) ww
Both w w
assertion and reason ww
arew w
false.
15. Consider the reaction, 𝑪𝑯𝟑 𝑪𝑯𝟐 𝑪𝑯𝟐 𝑩𝒓 + 𝑵𝒂𝑪𝑵 → 𝑪𝑯𝟑 𝑪𝑯𝟐 𝑪𝑯𝟐 𝑪𝑵 + 𝑵𝒂𝑩𝒓 This reaction will
m
om in
.cc.ocfastest .cc.ocm
om .cc.ocm
om .cc.ocm
om
be
s cthe s c s c s c
b TbnTpnp s
b T
b nTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpns
ww.T.rTr a) Ethanol ww.T.rTrb) Methanol ww T.rTDMF(N,N’-dimethyl
.c) r .T.rTr )
formanide
ww
d) Water.T.rTr
ww
w
ww w w w
16. Freon-12 iswmanufactured
w from tetrachloro w w
ww methane by ww w w wwww
a) wurtz ocmreaction
m b) swarts reaction
ocm m c) haloform reaction ocm m d) Gattermann ocm reaction
m
c . c . o c . c. o c . c. o c . c. o
spscmost easily hydrolysed
nTpnThe
17. sc
nTpnspmolecul nTpnsps is
under SN1 condition c
nTpnsps
c
nTpns
b Tb b T
b b Tb b T
b b Tb
ww.T.rTr a) allyl chlorideww .T.rTrb) ethyl chloride ww T.rTisopropyl
.c) r chloride ww .T.rTd)r benzyl chloride ww .T.rTr
w
ww w w w
ww formed in SN1 reaction w w
ww of alkyl halide in the slow w w
ww step is www w
18. The carbo cation
. m
a) 𝒔𝒑c𝟑ochybridised
o m .cc.ocm
b) 𝒔𝒑𝟐 hybridised om c) sp hybridised
.cc.ocm
om .c.ocm
d) none ofcthese om
s c c . s c s c s c
b TbnTpnThe
19. s
p major products obtained
b T
b
s
nTpnp when chlorobenzene b T
b nTp n
is s
pnitrated with 𝑯𝑵𝑶𝟑 T
b nTpncon
and
b
s
p 𝑯𝟐 𝑺𝑶𝟒
b TbnTpns
ww.T.rTr a) 1-chloro-4-nitrobenzene ww.T.rTr ww.T.rTr b) 1-chloro-2-nitrobenzene ww.T.rTr ww .T.rTr
w
c) 1-chloro-3-nitrobenzene d) 1-chloro-1-nitrobenzene
s c .cc.ocmom
s c .cc.ocm
om
s c .cc.ocm
om
s c .cc.ocm
om
T nTpnp s
P.VARATHARAJAN
b b T nTpnp s
b b b T
b nTpnp s
b T
b nTpnp s
Page 13 b T
b nTpns
ww.T.rTr ww.T.rTr ww.T.rTr ww.T.rTr ww .T.rTr
w
mm mm mm mm
nTn p nTpns
.T.rTr
T
b b
.T.rTr
T
b
wwww wwww w ww
w wwww w ww
w
ww ww
20. Which one of the following is most reactive
ww towards nucleophilic wwsubstitution reaction? ww
s c .cc.ocm
om
s c .cc.ocmom
s c .cc.ocm om
s c .cc.ocm om
b TbnTpnpa)s
b
b)
T
b nTpnp s
b Tb
C)
nTpnp s d)
b T
b nTpnp s
b T
b nTpns
ww.T.rTr 21. Ethylidene chloride ww.T.rTonr treatment with aqueous ww.T.rTrKOH gives .T.rTr
ww ww .T.rTr
w
ww w a) acetaldehyde ww w w b) ethylene glycol www w c) formaldehyde wwww d) glycoxal www w
.cc.ocm m .cc.ocmom .cc.ocm om .cc.ocm om

22. The raw omaterial for Rasching process
s c s c s c s c
b Tb
s
nTpna)p Chloro benzene bb) T
b
pnp s
nTPhenol b Tb nTc)pnp s
Benzene
b b nTpnp
d)TAnisole s
b T
b nTpns
ww.T.rTr 23. Chloroform reacts ww
rTr nitric acid to produce
.T.with ww.T.rTr .T.rTr
ww ww .T.rTr
w
ww w ww w w w w w w ww w w w
a) Nitro toluene b) Nitro glycerinew c) Chloropicrinw d) Chloropicric acidw
.cc.ocm
24. acetone
s c s
ocm
o𝒊)m𝑪𝑯𝟑𝑴𝒈𝑰−𝟏 →X, X is ca).cc.2-propanol om .cc.ocm
b) 2-methylc2-propanol
s
om c) 1-propanolcd).cc.Acetonol
s
ocmom
b TbnTpnp s 𝒊𝒊) 𝑯 𝟐 𝑶/𝑯
b T
b nTpnp s
b Tb nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr 25. silverpropionate ww T.rTr refluxed with bromine
.when ww.T.rTinr carbon tetrachloride T.rTr
.gives
ww ww .T.rTr
w
ww w a) Propionic ww w w
acid b) Chloro ethane www w c) Bromo ethane w
ww w d) Chloro propane www w
s c .cc.ocm
om
s .cc.ocm
Unit-15
c om- Environmental chemistry
s c .cc.ocm om
s c .cc.ocm om
b TbnTpnp s
b T
b nTpnp s
b Tb nTpnp s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr 1. The gaseous envelope ww.T.rTr around the earthwisw .rTr as atmosphere.
.Tknown .T.rTregion
wThe
w
r lying between ww T.rTr
.an
w
ww w ww w w www w w
ww w www w
altitudes of 11-50 km is ………
s .cc.ocm
om
a)cTroposphere .cc.ocm
b) Mesosphere
s c om c) Thermosphere
s c .cc.ocm om .cc.ocm
d) Stratosphere
s c om
b T2.
b
p s
nTpnWhich of the following b T
b is p s
nTpnnatural and human T
disturbance
b b
s
nTpnp in ecology? bTbnTpnp s
b T
b nTpns
ww.T.rTr a) Forest fire ww .T.rTrb) Floods ww T.rTr
.c) .T.rTd)r Green house effectww
ww .T.rTr
w
ww w ww w w www w Acid rain w
ww w www w
3. Bhopal Gas Tragedy is a case of …….
a)
s c .cc.ocm
Thermalom pollution b) Air pollution
s c .cc.ocmom c) Nuclearspollution
c .cc.ocm om d) Landsc .cc.ocm
pollution om
b Tb
4.
p s
nTpnHemoglobin of the b T
b
blood
p s
nTpnforms carboxyl b
hemoglobinTb
s
nTpnpwith…. b T
b nTpnp s
b T
b nTpns
ww.T.rTr ww.T.rTr ww.T.rTr .T.rTr
ww ww .T.rTr
w
ww w a) Carbon ww w w
dioxide b) Carbon tetra w w
chloride
ww c) Carbon monoxide w
ww w d) Carbonic acid www w
5. Which sequence for green house gases is based on GWP?
a)
s c .cc.ocm
CFC>𝑵
om𝑶>𝑪𝑶 >𝑪𝑯 b) CFC>𝑪𝑶
s c .cc.ocmom >𝑵 𝑶>𝑪𝑯 c) CFC>𝑵
s c
m
om >𝑪𝑶 d) CFC>𝑪𝑯
.cc𝟐.oc𝑶>𝑪𝑯 s c .cc𝟒.oc>m
om𝑁𝟐 𝑶>𝑪𝑶𝟐
b TbnTpnp s 𝟐 𝟐
b T
b
𝟒
nTpnp s 𝟐 𝟐 𝟒
b Tb nTpnp s 𝟒 𝟐
b T
b nTpnp s
b T
b nTpns
ww.T.rTr 6. Photo chemicalwsmog .T.rTrformed in congested
w ww T.rTr
.metropolitan cities mainly.T r r of
consists
ww.T ww .T.rTr
w
ww w a) Ozone, 𝑺𝑶 w w w
ww𝟐 and hydrocarbons ww b) Ozone, PAN and 𝑵𝑶 w w
ww𝟐w www w
c) PAN,
. c.ocm
o m and 𝑺𝑶𝟐
smog
. c.ocmo m d) Hydrocarbons,
. c .ocmo 𝑺𝑶𝟐 and 𝑪𝑶𝟐
m . c.ocm om
b T
7.np
b T nThes
p pH of normal rainTwater
b b
s
nTpnp is a) 6.5 b) 7.5 np
b Tb T n s
p c) 5.6
b T
b nTpnp
d) 4.6 s
b T
b nTpns
ww.T.rTr 8. Ozone depletion ww T.rTrcause…………….. ww
.will .T.rTr .T.rTr
ww ww .T.rTr
w
ww w ww w w w w
ww c) Bio magnificationww w w www w
a) Forest fire b) Eutrophication d) Global warming
s c .cc.ocm
9. Identify m wrong statement.in
othe
s c c
m
omfollowing
c.octhe s c .cc.ocm om
s c .cc.ocm om
b Tb
s
nTpna)p The clean water would b T
b
s
nTpnhave
p a BOD value of more
b Tb nTpnthan s
p 5 ppm
b T
b nTpnp s
b T
b nTpns
ww.T.rTr b) Green houseweffect .T.rTr is also called as Global
w ww
rTr
.T.warming .T.rTr
ww ww .T.rTr
w
ww w ww w w www w w
ww w www w
c) Minute solid particles in air is known as particulate pollutants
.cc.ocm
om is the protectivec.cblanket
d)cBiosphere
s s c.ocmom of gases surrounding
s c .cc.ocm omearth
the
s c .cc.ocm om
b T10.
b
s
nTpnLiving
p in the atmosphere
b Tb nTpof
n s
pCO is dangerous because
b Tb nTpnpit s
b T
b nTpnp s
b T
b nTpns
ww.T.rTr a) Combine with ww.𝑶T.rTpresent
r
ww T.rTr
.𝑪𝑶 T.rTr
.organic
ww ww .T.rTr
w
ww w ww w w 𝟐 inside towww
formw 𝟐 b) w
Reduces
ww w matter of w
tissues
ww w
c) Combines with haemoglobin and makes it incapable to absorb oxygen d) Dries up the blood
.cc.ocm
11. Release
s c omof oxides of nitrogen s c
m
om hydrocarbons into
.cc.ocand s c cm
.cc.otheomatmosphere by motor
s c .cc.ocm m
ovehicles is
b TbnTpn p s
prevented by using…. b Tb nT pn p s
b Tb nT p
n p s
b T
b nTpn p s
b T
b nTpns
ww ww .T.rTr
w
ww w a) grit ww
chamber w w b) scrubbers www w c) trickling filters w
ww w d) catalytic www
convertors w
12. Biochemical
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o m oxygen demand .value c.ocmo mless than 5 ppm indicates
. c .ocmo
a water sample to be m
m .cc.ocom
s c c s c c sc c s c
T nTpnp s
P.VARATHARAJAN
b b T nTpnp s
b b b Tb nTpnp s
b T
b nTpnp s
Page 14 bTbnTpns
ww ww .T.rTr
w
ww w ww w w www w w
ww w www w
mm mm mm mm
nTn p nTpns
. T.rTbrTbTn . T.rTbrTbTn .T.rTr b T
b b
.T.rTr
Tb b
.T.rTr
Tb
wwww wwww w ww
w w ww
w w ww
w
ww ww
a) Highly polluted b) Poor in dissolved
ww oxygen c) Rich in dissolved ww oxygen d) Low COD ww
13. Match momfollowing
.cc.octhe .cc.ocm om .cc.ocm
om .cc.ocm
om
s c s c s c s c
b TbnTpnp s List I bTn
b T pnp s
b T
b
pnpII
nTList s
b TbnTpnp s
b TbnTpns
ww.T.rTr ww
A) Depletion .T.rTrof ozone layer ww.-T.1.rTr 𝑪𝑶𝟐 ww .T.rTr ww .T.rTr
w
ww w www w w
ww w ww w w www w
B) Acid rain - 2. NO
s c .cc.ocm omPhoto chemical smog
C)
s c .cc.ocm om - 3. 𝑺𝑶𝟐c.cc.ocm
s
om
s c .cc.ocm
om
b TbnTpnp s
D) Green house
b Tb
pnp
nTeffects
- 4. b T
b
pnp
nTCFC s
b TbnTpnp s
b TbnTpns
w
ww w A www w
B C D w
ww w ww w w www w
a) 3 4 1 2
b)
s c .cc.ocm2o
m 1 4 s c3.cc.oco
mm
s c .cc.ocm
om
s c .cc.ocm
om
b TbnTpnc)p s
4 3 b T
2bnTpnp 1 s
b T
b nTpnp s
b TbnTpnp s
b TbnTpns
w
ww w d) 2 www w
4 1 3 w
ww w ww w w www w
14. Match the following
s c .cc.ocm om List I
s c .cc.ocm om List
s c
mm
II.cc.oco s c .cc.ocm
om
b TbnTpnp s
b TbnTpnp s
b T
b
pnp s
nTleprosy b TbnTpnp s
b TbnTpns
ww.T.rTr D) Stone
w .T.rTr
w w .T.rTr
w
- 1.
w .T.rTr
w w .T.rTr
w
w
ww w E) w w
w w
Biological magnification ww - 2. w w Green housewgases ww w www w
F)mGlobal warming - 3. Acid rainmm
c . c ocm
. o c . c . ocm
o m
c .cc.oco c .cc.ocm
om
s c s c s s
b TbnTpnp s D) Combination
b Tb
with
nTpnp shaemoglobin - 4.
b T
b
DDT
nTpnp s
b TbnTpnp s
b TbnTpns
ww.T.rTr A B .T.rTrC
ww D
ww.T.rTr ww .T.rTr ww .T.rTr
w
ww w a) 1 ww2
w w 3 4
w
ww w ww w w www w
b) om 3m 4 2 1 omm
s c . c
c . c o
s c .cc.co s c .cc.ocm
om
s c .cc.ocm
om
b TbnTpnp
c) s 2 3
b
4
TbnTpnp s1
b T
b nTpnp s
b TbnTpnp s
b TbnTpns
ww.T.rTr d) 4 2 .T.rTr1
ww 3
ww.T.rTr ww .T.rTr ww .T.rTr
w
ww w The questions
w w
ww gives below consists ofww w w
an assertion the reason.wChoose ww w the correct option
w w
wwout of
the choices om given below eachc.question
s c .cc.ocm s cc.ocm om
s c .cc.ocm
om
s c .cc.ocm
om
b TbnTpni.p s Both (A) and (R) nare
b Tb T
s
pnpcorrect and (R) is theTcorrect
b b
s
nTpnp explanation of (A) b TbnTpnp s
b TbnTpns
ww.T.rTr ii. ii. Both w (A)w .rTr (R) are correct and
.Tand .T.isrTrnot the correct explanation
w(R)
w ww .T.rTr of (A) ww .T.rTr
w
ww w w w
ww (A) and (R) are not correct w
ww w ww w w www w
iii. iii. Both
iv. .cocm om(A) is correct but (R)
iv. m
omcorrect
.ccis.ocnot .cc.ocm
om .cc.ocm
om
s c c . s c s c s c
b T15.
b
p s
nTpnAssertion (A) : If BOD level
b Tb
s
nTpnpof water in a reservoir b T
b isp
nT n
mores
p than 5 ppm it is highly
b Tb
s
nTpnppolluted b TbnTpns
ww.T.rTr Reason (R): High ww T.rTr
.biological oxygen demand ww.T .rTr high activity ofwbacteria
means ww .T.rTr in water ww .T.rTr
w
ww w www w w
ww w ww w www w
a) i b) ii c) iii d) iv
.cc.ocm
16. Assertion
s c s
ocm
om(A) : Excessive usecof.cc.chlorinatedom pesticide causes
s c .cc.ocm m and water pollution
osoil
s c .cc.ocm
om
b Tb
p s
nTpnReason (R): Such T
pesticides
b b
s
nTpnpare non-biodegradable b T
b nTpnp s
b TbnTpnp s
b TbnTpns
ww.T.rTr a) i ww .T.rTrb) ii ww T.rTr
.c) .T.rTr
wivw ww .T.rTr
w
ww w www w w
ww w iii ww w
d)w www w
17. Assertion (A) : Oxygen plays a key role in the troposphere
s c .cc.ocm
Reason
m Troposphere is not.c.responsible
o(R):
s c c
ocm
om for all biological
s c .cc.ocm m
oactivities
s c .cc.ocm
om
b TbnTpna)p s
b TbnTiipnp s
b T
b nTpnp s
b TbnTpnp s
b TbnTpns
ww.T.rTr i
ww .T.rTrb)
ww.T.rTr
c) iii d) iv
ww .T.rTr ww .T.rTr
w
ww w www w w
ww w ww w w www w
s c .cc.ocm om
s c .cc.ocm om
s c .cc.ocm
om
s c .cc.ocm
om
b TbnTpnp s
b TbnTpnp s
b T
b nTpnp s
b TbnTpnp s
b TbnTpns
w
ww w www w w
ww w ww w w www w
s c .cc.ocm om
s c .cc.ocm om
s c .cc.ocm
om
s c .cc.ocm
om
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
b b b T
b nTpnp s
b TbnTpnp s
Page 15 b T
b nTpns
w
ww w www w w
ww w ww w w www w
mm mm mm mm
n p p n p p p
nTn p p
nTn p nTpns
.T.rTr
Tb b
.T.rTr
Tb b
.T.rTr
Tb
wwww wwww w ww
w w ww
w w ww
w
ww ww
Unit- 8 - Physical and
ww
15. [A][B][C][D]
ww 26. [A][B][C][D]
ww
chemical m
om
.cc.ocequilibrium .cc.ocm m [A][B][C][D]
o16. .cc.ocm
om .cc.ocm
27. [A][B][C][D] om
s c s c s c s c
b TbnTpnp s
b T
b nTpnp s 17. [A][B][C][D]
b TbnTpnp s 28.
b TbnTpnp s
[A][B][C][D] b TbnTpns
ww.T.rTr 1. [A][B][C][D] ww .T.rTr ww.T.rTr
18. [A][B][C][D] ww
rTr
.T.29. [A][B][C][D] ww .T.rTr
w
ww w 2. [A][B][C][D]ww
w w www w w
ww w www w
19. [A][B][C][D] 30. [A][B][C][D]
3. [A][B][C][D] om m [A][B][C][D]
o20. om om
s c s c s c s c
b T4.np
b T n p s
[A][B][C][D]
b TbnTpnp s
21. b T
[A][B][C][D]bnTpnp s Unit-11
b Tb
s
nTpn- Fundamentals
p of
b TbnTpns
ww.T.rTr 5. [A][B][C][D] ww .T.rTr ww.T.rTr ww.T.rTrorganic chemistry ww .T.rTr
w
ww w w w w 22. w w
[A][B][C][D]
ww w
ww w www w
6. [A][B][C][D] w
23. [A][B][C][D] 1. [A][B][C][D]
7. [A][B][C][D]
c . c.ocm
o m
c . c.ocm
o m
c . c.ocm
o m
c .cc.ocm
om
s c s c 24. [A][B][C][D] s c s
b T8.n
b T
s
pn[A][B][C][D]
p
b TbnTpnp s
b TbnTpnp s 2.
b TbnTpnp s
[A][B][C][D]
b TbnTpns
ww.T.rTr 9. [A][B][C][D] ww .T.rTr .T.rTr
25. [A][B][C][D]
ww ww
rTr [A][B][C][D]
.T.3. ww .T.rTr
w
ww w www w 26.w w
w w
[A][B][C][D] w
ww w 4. [A][B][C][D] ww
w w
10. [A][B][C][D]
27.
m [A][B][C][D]
c . c ocm
11. [A][B][C][D]
. o m
c . c.ocm
o c .cc.ocm
om 5. [A][B][C][D]
c .cc.ocm
om
s c s c s s
b T12.
b
s
nTpn[A][B][C][D]
p
b TbnTpnp s 28. [A][B][C][D]
b TbnTpnp s
b bnTpnp s
6. T[A][B][C][D]
b TbnTpns
ww.T.rTr ww.T.rTr .T.rTr
29. [A][B][C][D]
ww ww
rTr [A][B][C][D]
.T.7. ww .T.rTr
w
ww w 13. [A][B][C][D] www w 30.w
w
w w
[A][B][C][D]
w
ww w www w
8. [A][B][C][D]
14. [A][B][C][D]
c .cc.ocm
15. [A][B][C][D]
s
om
s c cm
om - Chemical bonding
.cc.oUnit-10 s c .cc.ocm
om 9. [A][B][C][D]
s c .cc.ocm
om
b TbnTpnp s
b TbnTpnp s
b TbnTpnp s 10.
b TbnTpnp s
1. [A][B][C][D] ww
rTr
.T.11. [A][B][C][D] ww .T.rTr
w
ww w 17. [A][B][C][D]ww w w www w w
ww w www w
2. [A][B][C][D] 12. [A][B][C][D]
18. [A][B][C][D]
s c .cc.ocm
om
s c .cc.ocm
o3.m [A][B][C][D]
s c .cc.ocm
om .cc.ocm
13. [A][B][C][D]
s c om
b TbnTnp s
19.p[A][B][C][D]
b TbnTpnp s
4. T
[A][B][C][D]
b bnTpnp s
14.
b T nTpnp s
[A][B][C][D]
b b TbnTpns
ww.T.rTr 20. [A][B][C][D] ww .T.rTr ww.T.rTr ww.T.rTr ww .T.rTr
w
ww w 21. [A][B][C][D]ww
w w 5. w w
[A][B][C][D]
ww w
ww w 15. [A][B][C][D] www w
6. [A][B][C][D] 16. [A][B][C][D]
22. [A][B][C][D] om o7.m [A][B][C][D] om om
s c s c s c c
17. [A][B][C][D]
s
b T23.
b
p s
nTpn[A][B][C][D] b TbnTpnp s
b TbnTpnp s
b TbnTpnp s
b TbnTpns
ww.T.rTr 24. [A][B][C][D] ww .T.rTr 8. .T.rTr
[A][B][C][D]
ww ww.T.rTr
18. [A][B][C][D]
ww .T.rTr
w
ww w w w w 9. w w w w
ww w 19. [A][B][C][D] ww w w
25. [A][B][C][D] w w
[A][B][C][D]
10.
m [A][B][C][D] 20. [A][B][C][D]
c . c.ocm
o m
c . c.ocm
o c . c.ocm
o m
c .cc.ocm
om
s c s c s c s
b TbnTpnp s
Unit- 9 Solutions
b TbnTpnp s 21.
b TbnTpnp s
[A][B][C][D]
b TbnTpns
ww.T.rTr ww.T.rTr .T.rTr
12. [A][B][C][D]
ww ww
rTr [A][B][C][D]
.T.22. ww .T.rTr
w
ww w 1. [A][B][C][D] www w 13.w
w
w w
[A][B][C][D]
w
ww w 23. [A][B][C][D] ww
w w
2. [A][B][C][D]
.cc.ocm .cc.ocm
o14.
m [A][B][C][D] .cc.ocm .cc.ocm
om om 24. [A][B][C][D] om
c
3. [A][B][C][D]
s s c s c s c
b Tb
p s
nTpn[A][B][C][D] b TbnTpnp s 15. [A][B][C][D]
b TbnTpnp s
b bnTpnp s
25.T[A][B][C][D]
b TbnTpns
ww.T.rTr 4.
w .T.rTr
w w .T.rTr
16. [A][B][C][D]
w w w
rTr [A][B][C][D]
.T.26. w .T.rTr
w
w
ww w 5. [A][B][C][D]ww w w www w w
ww w www w
17. [A][B][C][D] 27. [A][B][C][D]
6. [A][B][C][D]
s c .cc.ocm
om
s c .cc.ocm m [A][B][C][D]
o18.
s c .cc.ocm
om .cc.ocm
28. [A][B][C][D]
s c om
b TbnTnp s
7. p[A][B][C][D]
b TbnTpnp s 29.
b TbnTpnp s
20. [A][B][C][D] ww
rTr
.T.30. [A][B][C][D] ww .T.rTr
w
w w www w w
ww w www w
21. [A][B][C][D]
10. [A][B][C][D] om m [A][B][C][D]
o22. om om
s c s c s c s c
b T11.
b
p s
nTpn[A][B][C][D] b TbnTpnp s
23. T
[A][B][C][D]
b bnTpnp s
b TbnTpnp s
b TbnTpns
w
ww w w w w 24. w w
[A][B][C][D]
ww w
ww w www w
13. [A][B][C][D] w
25. [A][B][C][D]
.cc.ocm
14. [A][B][C][D]
s c om
s c .cc.ocm
om
sc .cc.ocm
om
s c .cc.ocm
om
T nTpnp
P.VARATHARAJAN
b b
s
T nTpnp s
T nTpnp
b b b b
s
b TbnTpnp s
Page 16 b T
b nTpns
w
ww w www w www w w
ww w www w
mm mm mm mm
c.cc.oco c.cc.oco c.cc.oco c.cc.oco
http://www.trbtnpsc.com/2018/06/latest-plus-one-11th-study-materials-tamil-medium-english-medium-new-syllabus-based.html
n p p n p p p
nTn p p
nTn p nTpns
.T.rTr
Tb b
.T.rTr
Tb b
.T.rTr
Tb
wwww wwww w ww
w w ww
w w ww
w
ww ww
Unit-12- Basic concept of
ww
14. [A][B][C][D]
ww 14. [A][B][C][D]
ww
ocm
organic.creaction
c . om c.cc.ocm m [A][B][C][D]
o15. c .cc.ocm
om .cc.ocm
15. [A][B][C][D]
c om
s c s s s
b T
b nTpnp s
b T
b TbnTpnp s 16.
b TbnTpnp s
17. [A][B][C][D] ww
rTr
.T.17. [A][B][C][D] ww .T.rTr
w
w w ww w w w
ww w www w
18. [A][B][C][D] 18. [A][B][C][D]
3. [A][B][C][D] om m [A][B][C][D]
o19. om om
c c c 19. [A][B][C][D]
c
4.np n s
p s
[A][B][C][D] s
nTpnp s s
nTpnp s s
nTpnp s nTpns
b T
b T b T
b 20. [A][B][C][D]
b Tb 20.
b T[A][B][C][D]
b b Tb
w
ww w w ww 21. w w
[A][B][C][D]
ww w
ww w 21. [A][B][C][D] www w
6. [A][B][C][D] w
22. [A][B][C][D] 22. [A][B][C][D]
.cc.ocm
7. [A][B][C][D]
s c om
s c .cc.ocm m
o23. [A][B][C][D] scs.cc.co
omm
s c .cc.ocm
23. [A][B][C][D] om
b T
b8.n
T p s
pn[A][B][C][D]
b T
b nTpnp s
b TbnTpnp b TbnTpnp s
b TbnTpns
24. [A][B][C][D]
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rTr [A][B][C][D]
.T.24. ww .T.rTr
w
ww w wwww 25.w w
w w
[A][B][C][D] w
ww w 25. [A][B][C][D] ww w w
10. [A][B][C][D]
26.
m [A][B][C][D]
c . c ocm
11. [A][B][C][D]
. o m
c . c.ocm
o c .cc.ocm
om m
Unit-15scs- .cc.ocom
s c s c s
b T
b12.
s
nTpn[A][B][C][D]
p
b T
b TbnTpnp s
b TbnTpnp b TbnTpns
ww.T.rTr .T.rTr
ww .T.rTr
28. [A][B][C][D]
ww ww
rTr
.T.Environmental ww .T.rTr
w
ww w 13. [A][B][C][D] wwww 29.w
w
w w w
ww w www w
[A][B][C][D] chemistry
14. [A][B][C][D]
s c .cc.ocm
15. [A][B][C][D] om
s c .cc.ocm
o30.
m [A][B][C][D]
s c .cc.ocm
om c .cc.ocm
[A][B][C][D]
s
om
nTpns
s s s 1. s
b TbnTpnp b T
b nTpnp b TbnTpnp b TbnTpnp b Tb
ww.T.rTUnit-13-
r .T.rTr
ww
Hydrocarbons ww.T.rTr
Unit-14 Haloalkanes and
ww
rTr [A][B][C][D]
.T.2. ww .T.rTr
w
ww w wwww ww w w w
ww w 3. [A][B][C][D] ww w w
haloarenes
ocm ocm ocm 4. [A][B][C][D]
1. [A][B][C][D]
s c .cc. o m
s c .cc. o m
s c .cc. o m
s c .cc.ocm
om
b T2.n
b T
s
pn[A][B][C][D]
p
b T
b TbnTpnp s
b TbnTpnp s
5. [A][B][C][D]
b TbnTpns
2. [A][B][C][D]
ww ww
rTr [A][B][C][D]
.T.6. ww .T.rTr
w
ww w wwww 3. w w w w
ww w w w
4. [A][B][C][D]
w
[A][B][C][D] 7. [A][B][C][D] ww
ocm ocm4.m [A][B][C][D]
s c cc
5. [A][B][C][D]
. . o m
s c .cc. o
s c .cc.ocm
om
s c .cc.ocm
8. [A][B][C][D] om
b T6.
b
p s
nTpn[A][B][C][D] b T
b nTpnp s 5. [A][B][C][D] np
b Tb T n p s
b bnTpnp s
9. T[A][B][C][D]
b TbnTpns
6. [A][B][C][D]
ww ww
rTr
.T.10. [A][B][C][D] ww .T.rTr
w
ww w wwww w w w w w w
7. w w
[A][B][C][D] ww
11. [A][B][C][D]
ww
8. [A][B][C][D]
c .cc.ocm
9. [A][B][C][D]
s
om
s c .cc.ocm
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