DAI HQC Y DUQC THANH PHO HO cui MINH KHOA KHOA HOC CO BAN - BO MON HOA DE THI HOA DAI CUONG, NAM HQC 2006-2007 “Thai gian Him bai: 90 phiit Cho biét céng thirc e’ cia nguyen tw céia céc nguyén (6 lién quan dén 4é thi nay bao gbm: ‘Se: (Ar) 48°34" Mn: (Ar) 4s!3d° Co: (Ar) 48°34” Ti: (Ar) 48°30" Fe: (Ar) 4°34? Ni: (Ar) 43°34 a V: (Ar) 4853 1) 4s'34° Cu: (An) 4s'3a"? Zn: (Aris34"° Ag: (Kr) 5s'4d'® Cu t: chon céu ding ‘A> Nhiét chy (thigu nhidt) ciia mgt chat 1a nhigt tod ra tir phn img dét chy hon toan 1 mol chat 46 bing oxy 4 tyo ra cdc sin phim ld COz vi H20 & didu kign tigu chudn (25 °C, 1 atm). B- Nhiét chy (thigu nhigt) cia mt chit la nhiét cdn cung cdp cho phan ing abc hoin loan DL mol cl it dé bing oxy dé tgo ra céc sin phim ben 6 diéu kign tiéu chudn (25 °C,.1 atm). | Nhigt chéy (thigu nbigt) cia m6t cht ld nhigt tod ra tc phan img 46t chdy hodn toin 1 mol SS cht 46 bing ‘oxy dé tgo ra céc san phim bén 6 diéu kign tiéu chui iis ngs °C, | atm). 1D. Nhigt chy (thiéu nhiét) cia m6t cht IA nhi@t to8 ra tr phan ing dét chdy-hoan toin 1 mot chit 46 bang oxy dé tao ra cdc sin phdim CO; vi H,0 va cfc sin phim chay khde 6 didu ~ ign tidu chudn (25 °C, 1 atm). (Cu 2: chon cu ding Cic sin phd chéy ciia cdc nguyén tir cia nguy€n t6 C, H, S,N duge qui ube dé xéc dinh nhigt chay (thiéu mhiét) cila cdc chét c6 chira cdc nguyen tir dé nhu sau. ¢ hay tg0 ra. CO: (1). H chdy (go ra H,0(D, - § chy to ra Sr (I). D-N chy tg0 ra Ne (). ‘Ci 3: chon edu ding (a nvony cia céc chét nguyén chat du6i dang tinh thé hodn héo & khong 49 tuygt 46i bing B. Eee cla che chit nguyén chat duéi dang tinh thé hoan hao & khéng d6 tuyét 461 luén lon Cc oan pic ‘chat dui dang tinh thé hoan hdo ¢6 cdu trié rin chic va'cée tiéu phan sip xép D. noes pi tugmg nbigt dong Iyc hoc df trung cho mie 46 dn din tr ty eta he, (Cu 4: chon céu ding, Hod tin day phi thuyén con thoi ding nhién ligu fa hn hgp b6t nhdm va perchlorate amonium theo ti Ié phan img: TAL (1) + 3NHACIOs (.) —> AlOs (0) + AICH (1) +3 NO (k) +6 H:0 (&) ‘A ayg(Kd/mnol): = 2953 ~ 16756-7056 90,25 - 238,92 Lurgng nhigt phéng thich (kJ) 461 voi mét gam nhém phan img: ‘A- Li 885,87 Kl 4 2657,61 ks. 32,81 Kd, 4 88,59 kd 9atondl A\ - Can.637hon phvomg tinh phan ing sai (A. HgS + 2HCI = HgCh +15. B. CoO) + 6HCI = 2CoCh + Ch +3 HO C. MnO, +4HCI = Mnh +Cly+ 240 D. Hg(NOs): + 4K1 du = K2fHgls] + 2KNO3 t Chon phit bu ding ‘A. Mn” ki tham gia peng trong. ‘moi trong acid tao sin phim Mn" B. Mn kh tham pia phin img trong cau smi teyimg kid tgo sin phim Mn”? in” ki thar gia phin ing trong mi 1H, wo sin phim Mn'* . Mn‘ khitham gia phn dng trong ‘mi traémg kidm t9o sin phim Mn”? (Citu 65: Chon phét biéu ding ‘A. Pebbn &'6 oxi ha +4 B. Ptbin 6 oxi hos +2 C. Pthda tan trong nude cubng toan dé ton (pA cata ing ign ch how higu Z” ct dig tr} 4s cia nguyént6 Cu (2=29) la 7 B39 C56 D167 5 m= -12 ss ca nguyén ai" Fe(Z=26) B. Ni (228) <2) D. Mo(Z=25) ‘Cu 68: Nguyen tb S (216) o6 cfe sb lugng tir ota din tir cubi la ay igri 11; m= 4/2 1 sme Tat, mets m= 412 Iet, m= (Cin 69; Chon phe bigu dng nhdt Day Paschen c6 si chuyén dign tit tirquy dro n=4,5,6... ven=3 B. Diy Lyman 06 sy chuyén dig ttt Quy dy0 0-345... ven=2 . Day Balmer 66 sv chuyén dign tr ti U9 90 n=2,3.4,.véen=1 D. Tited A, B,C déu ding 3% (Chu 70: Chon phat bu ing nit ‘Ac: Hiu ing man chin edvg ib tl sing thugng ion hoa céng nhd B, Ning fig ton hi thir > Ning tugog, ‘ion hea thir IF> Ning lugrig'ion héa thir ion héa cing” (B Bign i cing 2a hat hin hug mL C. Bin ti-cing xa het nhin thi nag hagmg in HET wag gvak Ay Geet axe ot ahs . ae “ > GZ. win 0 Bing se : AA HEA We wht cho en (sare C48) £8 ot die + BY (od EE i Coy te tq Fas , Gaza a 2 AS GzCau 5: chon cfu ding ‘ai tung ndo sau day "dng phai ld him trang thai ‘A-NGi ning U. - Enthalpy H. os Entropy S Cau 6: chon cfu ding | Khi dét chay hoan toan | gam octan trong bomb nhiét Ivong ké, c6 chia 1200 g nuréc, nhigt dung cia bomb 1a 837 MK, Nhiét ké cho thdy nube thay 4éi nhiét 4 tir 25 dén 33,2 °C. Bidt 1 4,184 J. Két qua higu sig nit ota phan ting d6t chay 1 gam oétan bing: 48,033 KJ. 5475,76 Ks. Ce - 547,576 ki. D- - 41,170 (Cau 7: chon céu ding 2. NHS (k) + 5/2 Oz (k) —& 2NO (K) +3 H20(K) 6 AS> 0. Hangs —> CO2(K)+2H,O(N) ob AS> 0. Ha (k) + 1/203 (k) > 1,0 (I) 5 AS>0. - Cad (1) + C02 (k) —> CaCOs (0) 60S >0 ‘Cf 8: chon céu ding Phin img urdign bién khice AH 0. - Phin ing wr di bin Kh c6 AH > 0 va AS > 0 D- Phan img ti dién bién khi cé AH > 0 va AS <0. Cai 9: chon cd ding Cho phan img: CeHli05(F) +6.02(k) —& 6.CO2(K) + 6 HOC) SPrex (ImOLK): 212,13 205,03 213,64 69,94 Lan (Kd/mol): - 1274,45, - 393,51 - 285,84 \GPang * - 1878,88 KI, agg = ~2878,88 Kl ot =~ 3878.88 KI, D- AG's = -4878,88 KI. Caw 10: chon cau dking Xét phan tir CO theo phwong phép MQ A- Trong phan tit CO, cée AO cita oxi trén so dé nang Itong cao hon cic AO tuong img cia carbon B- Céng thite €” cia phan tir CO 18: (K.K) (6,)°(0,)"(n,)'(,)° (en) C- Phan tir CO 6 tinh thufin tir, c6 béec lim kat 183 Bjeove {hte cba phn 4 CO (KK) (6,)°(9,)"(R,)(%,Y" (6), CO 66 tinh nghich Cau 11: chon edu ding A. Trong phite chat K,[Ni(CN).], Ni?" értrang thai lai héa sp'd B- Trong ion phic [Cu(NH3)3]"*, Cu?” 6 trang thai lai héa sp” C- Trong phitc chit [Fe(CO)s], nguyén 16 tung tm 6 trang thai lai hoa sp'd rong phan tir PC, aguyén t6 trung tien & trang thd lai héa sp’ 2 2dCu 12: chon edu ding Xét phan tir BeH theo phuong phép MO, cic AO 2s, 2p ciia nguyén tir Be td hop vii céc ‘AO Is cia 2 nguyén tir H hinh thanh 6 MO, 46 li: A OOS my a ao, B. of", o!* at ni! eo o.oo. Tati A, B, C déu sai . ‘ Ha pha Hid Ket 1k: Ha lida két; kL: ba khég lidn ket (Cau 13: chon c&u ding 7 Xét phn tir CO, theo phuong phap MO, che AO 2s, 2p cia nguyén tir C 18 hop vdi cfc AO. 2s, 2p cia 2 nguyén ti: hinh thanh fc MO, 46 la (A}2MO 2s, 014, of, ay xy, ny, aE) 10,0, B-2MO 2s of ol, nyt ei ai Rm C-2MO 2s, of olt nitty att at mitt D- Tétcd A, B, C du sai Cau 14: chon cau ding ‘A- Trong phite chit [2Zn(NH3)4](OH)z, Zn” 6 trang thai Iai héa dsp” B. Trong phitc chat K[NiCla}, Ni” & trang thdi lai héa dsp” C+ Trong phite chit K2[Ni(CN)4], Ni?* & trang thdi lai héa dsp* D- Tat ca A, B, C déu sai (Cau 15: chon céu dang Cé 4 kigu lign két hidro sau day, kiéu nio e6 moi lién két hidro bén nbdt: Cy CH CHO A H--O-H 4 O- Ht ce CHy CH 7 city Note IS (~ -1Clu 16; chon edu ding aaa Trong nguyén tir €'. ning lugmg cia 6; (e" bi chin edn duge khio sit) duge tinh bing 6h, Zr2-Ai Ay=>- céng thite: B, ‘a, ; @ [8 higu ing chin cia e; d6i voi es ‘A- a; chi phy thug vio trang thai cia ¢; BB. a, chi phu thuge vio trang thi cia ¢; C: Ay cing Ion thi ¢; cang khé xim nap vio khu vue gan hat han {D> Ajcdng nhs thi e- cing cing khé x8m nhép vio khu vue gin hat nhén. 8%++ Caw 17: chon cfu ding CAH ting xin nhdp lim cho lye it gita hat nhin v6i echo ting len 8: ign ding x4m ap lam gidm ndng lugng lin ket cia ed cho véi hat nbn C- Higu img chin lim ting nding luong lign két cita e° d& cho voi hat nhan. * .D- Higu dng chin cing manh thi thé ion hée thr nhdt (1) cia nguyén tir cing cao, (Cu 18: chon clu ding Céc nguyén 16 Mg, Al, P, S c6 so dé €” bp ngoai Mg: [i } aki) of P; 3 ap? 3st 3p A: Ireia AI> I} cia Mg 1; chia $> I, ca P Qh ciaMg> Ir cia Al, h cia P> cia D- lycia Al> I, ola Al nur sau: i * 00 fy 3p 3p ‘Chu 19: chon cu ding . ? [Nauyén tir eda nguyen t6 (X) ¢6 3 ' 6 lop ngoai cing, cho bidt: Dign bi thir 1 c6: n= 3; A=O, m, =O; my=HU/2 Dién tir thir2 co: n= 3; 2=0, m, = 0; my=- 1/2 Dign ti thir 3 cé: = 41/2 ‘Tir 46 suy ra A: Neuyén t6 (X) thuge chu ky 3, nhém Itlp P)Naguyén t6 (X) thude chu ky 3, nhém I, C- Dign tir thir 2 va dién tir thér3 thude cing | orbital ‘D- Dién tir thir | va dién tir thir 2 gidng nhau hoan ton vé b9 cdc dai lugng vat li day da, det, my hm, Clu 20: chon edu ding . Nguyen tirngiyén t6 (¥) 06 5 €” lop ngodi cing, 5 & nay c6 tr s6 cia 4 s6 lugng ti nh sau: ign tir thir | cd: = 0, m, =O; m,=+1/2 22 bp? Bigm td thir2 6; n= 3; A= 0, m, =O; me=- 1/2 Bin tirthar3 06: n= 3; A= 1, my ==; my=4U2 Din tirthir4 c6:n=3; A= 1, m, =O; my=+1/2 ign irthir 5 06: n=3; A=, m, = +1; my= +172 Hay chon dap an diing nhdt trong s6 4 dip an sau: ‘A- Bin tir thir 1 va dign tr thit2 thugc cing 1 orbital B- Nguyén t6 (¥) thuge chu ky 3, nhém Va = tircita nguyén t6 (Y) c6 tng spin 18 cue dai (oy itca A, B,C déu ding. (C4u 21: chon céu ding ‘A- Trang thai cia mt h€ duge xe dinh bai tép hop céc dang khi, long, rn eta cde chit co trong hé, trang thai cla hé thay déi khi cdc dang khi, léng, rin thay di. B. Trang thdi cia mt hé duge xéc dinh bdi tp bgp cae gid tri thng $6 trang thai, trang thai ‘cia hé thay 46i khi cic dang khi, lang, cin thay 46i. C- Trang thai cia mot hé duge xéc dink boi tap hop cdc dang Khi, eng, rin eta cdc chdt 06 trong he, trang thai cha hé thay 48i khi cdc thong s6 trang thai thay £0} Trang thai cia mét hé duge xéc dinh boi tép hop céc gid tr cua ‘hing sé trang thai, trang thai cia hé thay di khi mot trong s6 cc théng s8 trang thai thay di 4 6%‘Cu 22: chon cfu ding dong lye hge fa: \ U=Q+Ww. “aU =8Q + 8W. dQ=8U + 8W. ‘Chu 23; chon edu ding ‘Acid etylen diamin tetraacetic (vid it la EDTA) £6 cbng thire eu tgo fi: HOOC—CH, f-COOH Cir Cl Hooc—cHy ‘CHls- COOH Khi téch 3 proton H’ ra khdi EDTA. anion gée acid con Iai déng vai trd mot phdi tir khi tao pice vi cation kim logi MM". Vidt tit anion géc acid néi trén 1a HY”. A-HY™ 6 dung ltrgng phdi tri ti da 1k 3 HY” 6 dung lugng phdi tritéi da 1a 4 HY” 06 dung jugng phéi tri tdi da la 5 1Y* 6 dung lurgmg phi tri ti da la 6 Cin 24: chon cd ding A- phife (P((NH3):Cly] 06 2 dng phan hinh hoe, 46 la: . o, Vie an c : aay cy ~ Déng phin trans ‘Dang phin cis B- ton phire [Co(NH;).Ch]’ c6 2 dbng phn hinh hye, 46 1: NH Hts a Ny a ny Go “ Ny’ ey xy NH Dang phan trans Bing phan cis C- Phite (Co(NHy).JCls cing 6 déng phan hinh hoc G Phite [Co(NH;),JC! khong c6 dng phn hinh hoe, (Cau 25: chgn edu ding : oan nhit la hé khéng trao di chit kh6ng trao d&i nang !wgng dudi dang céng nhung cb tra0 di nbigt voi mdi trudng, hé cé thé tich thay di, . B- HE mo la he trao ddi chat véi mdi trong ngoai, nhung nang lugng do hé nh§n hog sinh ra ers ge it Ui, hg c6 thé tic thay 41 ECHE kin la hg khéng tra0 d8i chit, 6 thé tra0 di ning lugmg dui dang nhigt va cing vi indi trurimg, he c6 thé tich thay d D- Hé cé lap 1a hé khéng cao Adi chat, khéng trao déi nang lugng dudi dang nhiét va cOng voi moi trudng, hé €6 thé tich thay 46%(Ciu 26: chon edu ding . ‘A- Nhiét igo thinh cla mét hgp chét 1a higu img nhigt cia phan img tao thanh | mol chét d6 tir cdc hop chat img vai trang thai oy do bén vong nhét. 7B Nhigt tgo thanh eda mt hgp chét la higu tng nbigt cita phan ding tgo thanh | mol chét d6 tir che don chat tuorig img. . (€-)Nhiét tao thanh ofa mt hoy chit Ia higu tng nhigt cia phan tng to thanh | mol chit 46 tir ic don chat img véi trang thai ty do ben ving nhl. . 'D- Nhigt tgo thénh céa m@t hgp chit & higu img nhiét cia phan img igo thinh 1 mol chét 46 tir ce nguyén tir eta nguyén t6 tuong tng c6 trong hgp chat do. (Cu 27: chon cu ding i@u tmg nhigt cia phan ng trong diéu kign ding 4p bing bién thin n6i ning cia he. iu img nhiét cita mt phan ting duong, 6 diéu kin ding tich thi bién Adi ndi ning cia he ©6 gid tr duong. C- Higu img nbiét cia mt phan ting duong, 6 diéu kign dang tich thi 6 gia tri im. D- Higu img nhiét ciia phan img trong diéu kin ding tich bang bién thién enthalpy ea hé. 48% noi ming cia he ‘Ci 28: chon cfu ding, ‘A~ Higu img nhigt cba mt phan img bing ting ahiét chdy eta cic sin phim tit ting nhigt chay cia cée chit tham gia phan img. B- Higu dng nhiét cita mt phan ting bing tng ning lugng lién két ca cdc san phdm trir tong ng lugng lin két cita céc chat tham gia phén tng. CC: Higu ing nhigt cba m6t phn img khng phy thuge vio ditu kién do va trang thi eée sin \phdm cing nhu cdc chat tham Hig ing ithe one . phan tg durge do trong digu kién ding tich bing bién thién noi ndng eda hé, ‘Céu 29: chen cfiu ding iu thttc todn hoc nguyén ly thir hai nit dOng tye hge li: 88 T Be OS=Q+T, a8 <8Q/T. A dQz (Cu 30: chon cfu ding ,_MOthé khi nhdo tt moi traimg ngodi nhiét lveng 50 KJ, hé Kh vida né sinh cong 30 KF chéng lai ap sudt bén ngoai. Vay bién ddi nOi nang oda hé kh sé la: A 80d. le(Cau 31: chon ciu ding A> M6t dai lurong duge goi ld ham trang thai, néu bién thién ca dai lung d6 chi phy thudc vio cach tién hanh qué trinh thudn nghich hay kh6ng thugn nghich ciia hé. B. M@tdgi lugmg duge goi la him trang thdi, néu bién thin cia dai long 46 chi phy thuge vio cach tién hanh qué trinh ma khdng phy thudc vao trang théi ddu va trang thai cubi cia hé. C- M6t dai lurgng duge goi ta him trang théi, néu bién thign cia dai lugng 46 khdng phy thud yao céch tién hanh qué trinh va trang thai dau va trang thai cudi cua hé. \Q..M6t dei lurgng duge goi li ham trang théi, néu bién thign cia dai ltngmg 46 khéng phy thude vio céch tién hanh qué trinh chi phy thudc vao trang thai diu va trang thai cudi cla hé. (Chu 32: chon céu ding Cho phan tng: 2Ha(k) + O2(k) —» 2H:0(1) S°x9q Wiemol.K) : 130,7 _205,3 69.9 4 A-Bidn thin entropy tidu chudn bing 326,9 J. B- Bién thién entropy tigu chudn bang 266,1 J. ién thin entropy tiéu chudn bing - 326,95. Bién thin entropy tiéu chudn bing - 266,1 J. (Cau 33: chon céu ding . 6 Xét phin tr HF theo phurong php MO 4 és A- AO Is cia H tb hgp duge véi AO 2s cia F BP AO Is cba H t6 hop duge v6i céc AO 2py, 2p: cla F \€-AO Is eda H 18 hop dupe véi AO 2p, cia F dé hinh thinh MO o. vaMO Phan tt HF khdng c6 “ede MO khong lign kée” (Cm 34: chon cd ding . ‘Theo phuong phép MO, khi AO Is cia nguyén ti H td hop véi cée AO 2s, 2px, 2Py 2px cia nguyén tir F ta dugc 5 MO, trong d6 ¢6: ‘A-2.MO lién két, | MO phan lién két, 2 MO khdng lién két ® 1 MO lién két, 1 MO phan lién két, 3 MO kh6ng lien két “E Céng thie ¢* cia HF 1a: (K)(0,)°(0,)* (at D- Céng thie &* cia HF 1a: (K)(o!*)*(o, )'(n*"*)*(03)? Ki higu k.1.k ld: khOng lign két Ciu 3 chon edu ding Xét phin tt: NO theo phuong phdp MO ‘A: Phin tir NO kkhéng c6 e' de than, e6 tiah nghich ti Boog tha e* eda NO: (KK) (6,)°(04)°(,) (",)°(0,)' (5)! ~ C- Bic lign két cia NO khéc véi bac lién két cia ion phan ti 02" D- Vid dm dign cia O én hom 46 am din cia N nén AO 2s cia N khdng td hyp duge voi AO 2s cia. Chu 36: chon cfu ding Epi tC 6 16 €, trong sb od | ACB e' duge xép véo cdc MO khéng lign két, 8 e° duge xép vao cic MO lién két Bp 8 &' duge xép vio céc MO lign Ket, 8 € dugc xép vao cic MO phn lign két ‘G24 wrong cde MO lién Ket, 4 tong cée MO phi ign kit vi 8 tong céc MO kg lien Okt D- Tat ca A, B, C déu saiCiu 37: chon cfu dang, ‘A- Trong phiic chat Ke[Fe(CN)s], Fe™ & & trang thai Iai héa sp a B- Trong phife chét [Co(NH)«]Chs, Co™ & trang thai lai hoa sp ‘a ‘Cx Trong ion phitc [Co(CN).}”, Co™ & trang that lei hoa Prong phise chit Ky{CoF,}, Co™ & trang thd li ha ae (Cm 38: chon cd ding, A; Trong phite chat [Zi(NH,). (OH), Zn** & trang thai hoa dsp? B. Trong phite shit Ka{FeFs), Fe & trang thai lai ha d°sp? C- Trong phic chat Ks[CoF,]. Co”* 6 trang thai lai héa dsp” eres phite cht (Co(NH5),JCI, Co” & trang thai lai héa dsp’ Cfiu 39: chon cau ding ‘A: Lin két duge phan bé theo phuong tai dé sy sen phi Han nhau gitta céc orbital tham gia lién ‘kt 1a nb nha, Osrae hi cba 2 orbital cng mank thi ign kd cing ben DG xen phi gia cdc may e” s (xen phi s-s) lon hon d xen phi gitta céc may ”s va p (xen phi sp) D- BO xen phi gita cdc may e*p (xen phi p-p) nhd hon 4 xen phi s-p. Cu 40: chon cfu ding ét qua bai toan phan tir H, cia Heiler vi London nu sau: A- Khi 2 nguyén tit H c6 cdc e* véi spin nguge dau tién lai gan nhau, 1ge Gkhu vye gitta 2 tn gidm di Khi 2 nguyen tir H c6 céc e” v6i spin cing du tién lai gin nhau, ndng long ctia hé 2 nguyén tir H nim céch nhau mét khodng r hitu han tudn nhé hon nang long cita hé gdm 2 nguyén it H cf ap. Cofee nguyén tr H c6 céc €” véi m, nguge du tin Iai gin nhau, thé nang tuong tac (E) gidm dan va t6i khoang céch ry thi thé nang dat ti gid tri cc tiéu E, D- Khi 2 nguyén tir H cé cae e° voi m, cing déu tién Iai gan nhau, mat 46 €” o khu vyc gitta he fhat nbn Kin. (Cau 41; chon edu ding (C6 4 kidu lién két hidro du6i diy, kiéu néo c6 méi lién két hidro kém bén nat: CHy- Cho © O7 yo . 2) H I on-cteon-g , c H-Q-Cii- CCH. i a (Cau 42: chon céu ding ?) ‘As Hiing s6 chin a; chi phy thue vao gid tr cdc s6 long tira vaA ella €7 ~" B-Néu e/ c6Anhé hon 2 tia g thi tdc dung chin cia cing yéu _-C- Néu e; c6 m nh hon n cia e thi téc dung chin cia ej cfing yéu @yTions aay ie 5, p. d, F¢thi mite 46 chin ting dan khi di tire’ s dén ef 8 ee(Cau 43: chon céu ding Ac Trong day eée €'s, p.d, f, mite 49 bj chin gidm din khi di tice, Gén ef (BoWrong day cac e's, p, ye 48 chiin gidm din khi di tire,” dén e gj 66 58 Iuomg | thi sy xdm nh§p vio khu vue hat nhén cing manh. do 46 né bi ‘cic e'khdc chin cing ni D. Tat e& A,B, C déu sai Chu 44: chon céu dling Trong ciing 1 chu ky, nguyén tr cia kim logi kiém (nhém 14) c6 thé ion héa thir nde (1)) it. nguyén nhan do: A: Nguyén tir kim logi kiém o6 nhidu orbital tng & 16p ngoai cing B- Kim loai kiém o6 ban kinh nguyén tir nhd nat C3Do sy chin manh dign tich hat nhdn bai vé din tir e6 edu trie gidng khi hiém ciia lop tiép + ben trong lép ns! D-Do cé 3 nguyén nhan A, B,C who Ci 45: chon céu ding Phuong ttinh Schrodinger cé dang: a SY FEM Evy =0 Ta 6 thé dua phuong trinh trén vé dang gon hon 1a Hy = Ey, Laplace ( V*) va todn tir Halmilton (H). (Cu 46: chon cau diing Céng thie e* ctia ion Fe” 1a: (Ar}4s"34°, Fe” o6 ting spin la: Ad Bea C2 D-1 (Chiu 47: chon cau ding Thuyét Niels Bohr giai thich duge quang phé nguyén tir Hidro (quang phd vach) 'A-Khi € chuyén tir cde quit dgo 66 mite nding lunong c20 vé qui dao thip nhit (n = 1) cho dy é | -> phd nim trong ving nhin thdy (day Balmer) \B-Khi &' chuyén tir c&e qui d9o cé mac nang lugng cao vé qui dao thap nhét (n = 1) cho day phd ndm trong ving tir ngogi (day Lyman) - CC Khi e’ chuyén tir fe quT dao 6 mite nang lugng cao vé qui dgo thir2 (n= 2) cho day phd ndm tong viing héng ngoai (day passchen) D- Tin tir ngoai c6 46 dai séng (A) tom nd tia bi yogi o6 46 dai séng (A) ahd nhdt.Chiu 48: chon eau ding | ha [Nguyén tir eda nguyén t6 P cé céng thie el: (Ne)35°3p" A- Héa trj cao nbdt 461 v6i Hidro ota P18 5 B- Héa tr cao nhit 45i véi Oxi cia P13 C-5 6 &l6p dign ti ngodi cing cia P eb ting spin 1a 5/2 om ca A,B,C déu sai, Cau 49: chon cau ding A- Trong moi chét co méi lign két cng héa trj thi 1 lién két cng héa tr) luén hinh thinh day hit chi do | ep e° gép chung B- Kha ning tgo lién két céng héa tr] cia 1 nguyén t6 duy nhat chi do cfc e° dc thin cia nguyén tt ca nguyén 18 46, (C. Trong ion NH,’ khéng cé lign két phi ti (theo phuong phip VB) ha ning igo lién két céng héa tri ca | nguyén t8 khéng nhiing do céc ¢ doc thin ma con ‘Jo cic orbital tring va cén c& thé do che cdp €* ghép 481 cin nguyen tr eda nguyén Wd (Cau 50: chon edu ding ‘Az Entropy cita nue hoi nhé hon entropy cua nude long, nhé hon entropy eda nude rin, iniropy ca nude hai Ién hon entropy cia nude ling, Kin hon entropy eta nu ran. ‘Mite d5 hin dn cia cae tidu phan trong bg cang nl ‘De Qué trinh ty dign bign entropy cita hé ludn luén duong, ri entropy cing lon (Cu St: chon edu sai A- Xét phiin tir HF, khi AO Is ca nguyén tit H t6 hop véi AO (2s, 2px. 2p,, 2p,) clia nguyen tir F ta duge cée MO sau: ot!*,6, x8! xt! 07 B-AO Is cia nguyén tir H t6 hop duge voi AO 2p, cia nguyén tir F dé hinh thinh eé¢ MO: 0,vao, (Oeste ign két cia NO kc vi be itn kd ei ion phi 02" D- Cong thire €” cia NO l8: (K.K)(o,)'(6,)' (,)' (8,6) (RY ‘Cu 52: chon od sai A- Trong phan tir PCls, P 6 trang thai lai héa sp’d B- Trong phife chat [Co(NHs)JCh, chat tao phitc & trang thai Iai héa dsp? TyTrong phite chét (Co(NH)).]Brs, Co” 6 trang thai lai héa spd? rong phirechét Nas{CoC,}, Co! & trang tha lai héa sp ‘¢ (Cau $3: chon cau sai )Thé ion héa thir 1 (;) cda Be lin hon (Ih) cia B (nguyén tS Bohr) 'B- Thé ion ha thir! (1y) cta N nhé hom (13) ca O (C- Higu img xém nhgp lim ting nang lung lién ket ca €” 4 cho véi het nhan D- Higu img chin cng manh thi thé ion héa thir 1 (1)) ca nguyén tir cng who. Cau 54: chon cau sai ‘A: Si phan bé e° vio céc orbital cia chét tgo phite 66 trong ion [Co(NHa)e}” la: ae “ap B- Co” ciia ion phite (Co(NH,)o)” 66 dang lai hoa dsp” C- Ton phite (Co(NH3)<)°" 66 edu trie bat e Ion ne [CoF,]* khéng thé c6 cdu tric bat dign vi nguyén td trung tm co dang lai hoa 5 10 se‘Clu 55: chon cau sai Phétc chét NafAg(CN)] ‘A- Tén cia phiie chit Id: natridieyano argentat (I) B- Chit tg0 phic & trang thai lai ba sp C- 2 dam miy e' lai héa sp tréng cia Ag” nhfn 2 cp €* cha 2 ion CN Ds Phite NafAg(CN)z} c6 tinh thudn tir (Cf 56: chon cau sai ‘Ac Ton Fe™ hi & trang thai ty do (kh6ng tgo phitc), cd 5 orbital d eda né khéng bj téch mite nding luong Xét phite Ks{Fe(CN)4} (Sticcwtnind te tit, 5 orbital d ciia cht tg0 phite bj tach mite ning lugng. Cac orbital dys.d,s_. cba chit tgo phic @ mite n&ng Ivgng thip orbital dyy, dyz, dx cla chét tgo phite @ mic nding lugng thiip. “Dc (Chu $7: chon cfu sai ‘Trong phic chét bét dién (trong trutmg tinh thé bét dién) A- Khi ion trung tam cé cdu tgo d!®: phic chat luda 06 tinh nghich tir B. Cic tradmg hgp ion trung tim 6 cdu tgod’, dd, d¥,d®: phic chit lub cé tinh thun tr C- Truémg hop ion trung tdm 06 cu tao d*: néu céc phéi tir pay ra trudmg tinh thé yéu (4 nhd), phire chit 8 c6 tinh thufin tr, cn nguge Iai phire chit e6 tinh nghich tir ‘rudmg hgp ion trung tém cé cu tao d’, d’, d’: néu che ph6i tir gay ra tru’ng tinh thé yéu (4 ‘nhd), phire chat 6 spin thép, cdn ngugc lai phite cht cé spin cao. (C4u 58: chon cau sai Trong phitc chit bat dién: ‘A- Ton trung tim £6 cfu tao ~ Trong truéng tinh thé yéu, phite chét c6 tng spin la 2 va thudn tir - Trong trumg tinh thé manh, phitc chit ed tng spin lé I va thugin tir B- Ion trung tam c6 cdu tgo a: - Trong tntmg tinh thé yéu, phite chit o6 téng spin 15/2 va thufin tir ~.- Trong triémg tinh thé manh, phic chét 6 tng spin la 1/2 va thug tir Con trang tim e6 eu to “A Trong trang tinh thd yb, phe chit 6 ng spin La 32 va thubo ti - Trong trutmg tinh thé yéu, phic 6 ting spin ld 1/2 va nghich tir — D- Chi eé Csai, A va B ddu ding Cin 89: chon cds sai wt, ba Phite chit (Zn(NHs)4](OH)2 Ay Ten cba phic 1a: tetraamin zincat (If) hidroxyl B- fon phic e6 céu tric tt dign déu C- Tit ca céc ed ciia Zn” déu duge ghép 40i o nhém th, va nhém eg. D: Phite (Zn(NH}),)(OH)2 06 tinh thugin tir, (Cau 60: chon céu sai Trong nuéc, clu ndi ciia phitc chéit phan li nhur mt chét dign ly yéu. Hing s6 khéng bén (K) cia cation (Ag(NH3)2]" = 10°, K cia [Ag(CNs] = 10? Ap {AR(CN)) === Agh + 2CN B. [Ag(NHy)J’ === Ag’ + 2NHy (Co hite (Ag(NH,)2]CI bén hon phic K[Ag(CN)3 D- Phiie K[Ag(CN),] bén hon phite [Ag(NH)2]Ct(Cu 61: chon cfu sai Phise chdt Ka{Fe(CN)} ‘A: Sy phn b6 cde € vio fc orbital cia Fe" wa HUTT TT] Le Sy phan b6 cdc evo cée orbital cba Fe” a: noon) 3d a ap (C- Fe" trong phic chit & trang thai lai héa d?sp? D- Phite Ka{Fe(CN),] c6 tinh nghjch tir £1) Cin 62: chon cfu sai a Xét lién két héa hoc cia ion phite (CoF4]” theo phucmg phép MO, ta biét 9 AO cita Co” té hop véi 6 AO ciia 6 phdi tr F’ tgo ra 15 MO, trong $6 6 c6: A 6 MO lite kat, 46 65, Sx, Oy Si Byes Oy B- 6 MO phan lign kat, d6 la: 61, ,,0%,03,0;,0,,0, MO Khéng lién két, 46 18: they, Rees Ty Cz € dau da duge ghép déi trong cée MO nén phic Ks[CoFe}” 6 tinh nghich ti ‘Cit 63: chon edu sai . \s 4 fet ok ets? ‘A: Bic ign két cia 03" bing 25# Gig 6, Egy “U,, % x Béc ign két cia Oz bing 2h SB te )Béc lién két cia Oy bang 1, D- Bc lign két cia 0,” bing 1 (Clu 64: chon edu sai ‘A: Ning lugng ign két ting dn theo tht: Egy. < Eg, Hz0(K) Hye = - 241,83 ki/mol ) Biét nhiét hod hoi cia rirde biing 44,01 ki/mol. ‘Nhigt tg0 thanh chuan ctia CO; (k) bang ~ 393,51 ki/mol. JNhigt tg thanh Ehudn cia HO (1) bing - 285,84 klimol. A rve-C Oy Nhat chy tu chudn cba C (gy) bing 393,51 W/mol. - Nhiet chy tigu chudn cit Hy (k) bing ~ 241,83 k3/mol]/ ‘Citu 66: chon cfu sai Cie dai luong sau day 1a ham trang thai: ‘A: Thé ding dp ding nhiét G. B. Enthalpy H. C- Entropy S. ‘D3Cong W. 12 fi(Cu 67: chon cdu sai A- V6i hé 06 Ip, trong qué trinh thugn nghich (can biing), entropy cia hé ld khong di, B. Véi ba c6 Mp, trong qua trinh khéng thugn nghich, entropy cita he tang. C- Vi he 66 Igp, qua trinh ty din bign theo chidu tang entropy, cho t6i khi entropy dat gid tr coe dai va hé dat ti trang thdi cin bing, . D- Véi hé 66 lap, trong qué Linh thugn nghjch (can bing), entropy cita hé duong hod am tuy Ss thude vio 46 tat ty cia he. ‘Clin 68: chon cu sai A Nhiét phan img phai c6 lién h¢ dén nding lugng cat dist fién két cii va nding lwgng hinh thin Tign két méi. B- Nang lugng lign két ciia mét phan tir chat li ning Iugng cin cung cap dé phan tich 1 mol voyghdt 46 & trang thai ki tg0 ra cde nguyén tr 6 trang thai khi C- ‘Trong phan tir khi metan, nang lugng can dé cét dirt mi fién két C-H tude sau Ja nhu nhav. D- V6i phan tir nhigu ngnyén tir, nhiét dong luc hoc chi gidp xéc dinh n&ng long lién két trung binh. (Cw 69: chou cfu sai A- Nhiét hod hoi mol cia hod chit, 1a nhigt Ingng cin cung cap 4é 1 mol had chat tir dang long + hod thinh hoi 6 nhigt 49 s6i duéi dp suit | atm, . {B? Sy truydn nhigt tir nguén néng sang ngubn Lanh 1a ty dign bign va 1a bién 8i thudn nghich. ‘Sy déng de cita nurée & 0°C, Latm 1d mot bién 48; thuan nghich. D- Nhigt néng chay mol cia hoa chit, la nhidt hugng cin cung cp 48 1 mol hod chat tir dang rin hod thanh long @ nhigt €9 néng chy &p sudt 1 atm. (C4u 70: chon cit sai ‘A- Bin déi ding tich 18 bién 4éi duge thyc hign trong diéu kign thé tich cia hé khéng 44i. B. Phan img trong binh cfu thing dp sult voi kh quyen, sy bién dBi phn img trong didu kién indy a ding 4p. a 5 G~ Bién ddi ding nhidt 1a bién di due thyc hign trong didu kin nhigt 46 khdng 44i. £D-'Bikn Adi dogn nhiét la bién Adi duge thyc hign trong diéu kign c6 sy trao di nhigt lugng git Né vi moi trcdmg ngoai Gt céch gidn dogn. (Caw 71: chon edu sai ‘Dun ndng NO; 0.3 M trong binh kin dén nhigt 45 ndo 46 cin bing duge thiét \gp: _ ZNO (kK) SE 2NO(k) + 01 (k) bing thyc nghigm quang phd xic dinh durge néng 46 NOz hic cén bing 18 0,06 M ‘A-Néng d® ban diu cia NO; 10,3 M. B Nang d® lic cén bing cia O; 1a 0,12 M. $C Hiing 86 cin bing Ke = 1,06, rh ‘D- Hing sé cdn bing Ke = 1,92. “ (Ciu 72: chon ciu sai ‘Ac Céng c6 thé bién hoain todn than nidt, ti fat nit khéng thé bign hodn todn thanh cbng. B. Khong thé 06 qui trinh trong 46 nhigt ldy tr mt ngudn éuge chuyén thanh céng ma khéng, 6 sy bd sung, Gz Khéng thé €6 dng co vinh citu Logi H. {Ds Nhigt o6 thé trayén tir vét néng sang vat lanh. Nit c6 thé truyén tis vat anh sang vat néng. BCw 73: chon cfu sai A- Bc lién két ciia 0,” bing 1 cine thitc ¢" cia ion phan tir O2" a: (0,,)°(0;,)* (Osx) (4) (ry, (PLY OY ‘C-Céng thite e* eta phn tir O2 18: (65.)°(6;,)*(63,)° (3,) (ry, YY (°C) D-Nang hong lién két tang din theo thirty: E,, Higu ting chin cin e; d6i véi g; ki higu la, a; phy thufe vio trang thai cia cd gj vie” rated A, B, C déu sai Cw 71: chon cfu sai ‘A) Phurong trinh Schrédinger dang rit gon la: Hy = Ey B) H=-22 +V (H la toin tt Halmilton) ’n'm > 8 a oye &, (¥? tatoin tr Laplac ) Ber (7 loin tir Laplace) ay x “Dif cf A,B, Cabu sai Chu 78: chon cu sai (@Preovs ion phite (NIC, NP* 6 tang th lai da dsp? vi thE ion (NICHI? €6 edu trie vung phang. B- lon phire [Ni(CN)4]*, c6 cu trie vudng phing vi chil tao phite ob dang lai héa dsp* C- Ni?" c6 trong ion phite [NiCl4]* 06 dang lai h6a sp? D- Su phan bé e* vio cée orbital eta chat tgo phite c6 trong [Ni(CN).]* theo phuong phép VB la: HTT] | 4(Cw 79: chon cau sai __° Trong phife chét K,{Fe(CN)s) (B70 trung tim fey 6 gc tga d6 trong trudng bat dién cia cée phéi ti. 7B Cie orbital 4... cia ion tung tim hung dén cdc phéi tir nén ching 6 mic ndng lugng x0 Cie orbital d,,, daz, dy. hug gita céc phdi tir nén chiing & mire nang tugng th4p it c& A, B, C déu sai (Cu 80: chon céu sai Trong phir chit tr dién (trong trudng tinh thé ta dign) A- Cie orbital diy, das dy cia ion trung tm hung dén cdc phi ti, bi cc phdi ti dm dign diy manh nén chiing & mite nang lwgng cao. B- Cic orbital 6 nhém eg cita ion trung tim hudng gifta céc phéi tir, bj cdc phdi {it nén ching & mize ning lugng thip. C- Ion trung tam nim & géc toa 46 trong trubng tir dign cue phéi tir fDatie cf A,B, Cddu sai im dign diy (Cu 81: chon cd sai ‘Trong ion phite (CoF.}”, ion Co” cé cdu tgo d*, phdi tir F’ gay ra thong s6 téch & nbd, nén: A- lon Co™ 66 2 € d a mite eg va 4 € & mite tag B- lon Co™ 06 4 ¢'d dc than pene [CoP.}* thugn tirc5 spin cao, (@B_Phite (CoFe}* thugn tirc6 spin thép (Cu 82: chon cdu sai ‘Trong ion phic [Co(CN)«]”, chét tao phitc c6 edu tao d°, phdi tic CN’ gay ra thong 96 téch ‘lon, nén: Jon trung tim 06 6 ed & mite tg ‘Belon trung tim c6 2 €'d & mite eg va 4 €'6 mirc tay C- Phite (Co(CN).}” nghich tir a D- Ion (Co(CN),]” c6 ting spin bing bing khong. ee (Chiu 83: chon cd sai Phitc chit Nas{FeF,) Ss ‘A: Su phan bd € vio céc orbital cia Fe’ li ig TOE GE 3d 4 ap ad ‘Chit tao phic & trang thdi lai héa sp’? (CB Surphin bb e vio céc orbital cba Fe™ li Why Ee] 3d cn ‘Chat tgo phite & trang thai lai hda dsp? C- Cac e'd.cia Fe" duge sip xép: (t,)'(ca)” D- Phitc cht c6 cu tric bat dién, tinh thudn tir va spin cao (Cau 84: chon cfu sai Phitc chét Nas[FeF} A. Phe may o6 tin thug tir : Bz Cie € d cia chit tao phitc duge sip xép: ta)"(eg)* (C-Cac € d ciia chit tao phire duge sip xép: (t2,)> D- Phitc Nas{FeF¢} c6 spin cao 15 oFClu 88: chon edu sai Ion phic [Co(NH3)s]”*, theo phuomg phap MO ciing c6 15 MO, céc €” d ciia Co™ va cc cp e' tyrdo cia ede phi tit (6NH3) durge xép vio cée MO nhu sau: Ae (9 (6,16, (6) (p(y)? dy la 6 MO lin ket Be (ay)" tes)" (Moa)*, Gy 14 3 MO Kehdng Hin két (2.2) 2)'()(6,)"(65)°(01)” dy 1a 6 MO phan lien két D- Phe (Co(NH3),]Ct; c6 tinh nghich tir (Cia 86: chon céu sai Oxi ¢6 s6 thi ty nguyén 16 18 & ST) A Gin thdee ca phn WO theo phuong php MO ti: (6,.)°()* (a) Gry, 2) 05) 06) (1)! B4COng thic ¢* cia phan tir 03 theo phuong phép VB 1a: Phan tir Oz ¢6 1 néi 3, trong 46 c6 I lin két o 2c" va 2 lién két x 3e° C- Cing thite €" cia phan tir O; theo Lewis la: D-CA 3 cdng thir e° nay (b A, B, C) giti thich duge tinh thu tired Oz (Cau 87; chon edu sai ‘A- Cong thie e* cia ion phan tir O2" la: (6,,)*(,)?(,)*(05,) (0p) (.) CG)?! B-COng thie €° PY (625) (63.) ry, PRY YO OY” =)Céng thi cia ion phi ts O;" th: (6,)*(05,)"(,) (Oa) (°C) CR) ,) {Cong thite e* cia ion phan ti O3" la: (0,,)°(6},)*(r.)* (4) (Op, F (HY (RY YOY hon cfu sai | i D \Trong phan tir Bz, phuong phép VB cho ring: 2 nguyén tir B lién két véi nhau bing 2 lién két x (mi lin két x gdm | e'), hinh anh 2 lign két n 46 OQ B- Lién két trong phan tir B mé td trén la logi lién két thiéu e” C- Cong thite e° cia Bz theo phuong phép MO Id: (K.K) (0,)*(0;)"(n,)'(n,)', Br 06 bée lign két la) D- Lin két trong phan tt By theo phuong phép VB va MO néu trén, giai thich duge By o6 tinh nghich ti, ‘Cau 89: chon c&u sai 2C (gh) +02(K) — 2.CO(k) Cw) +O2(k) — COr(0) (K) + Or (Kk) > 2CO2k) 2c00 A OH, C- Nhigt chéy cia CO (k) la AH 294) ® Nhiét chay cia C (gr) 1a AH 25,‘C4u 90: chon cau sai . Cac biéu thie sau day biéu din mdi quan hé zita cde dai luong nhigt dong: fy iS ait Tas (Bu~H+Pv. C- AH = Qe. D-G=U+PV-TS. Ciu 91; chon cau sai Cho phan img: Na (Kk) + 3.Ha (k) 0. B- Hg thu nhigt theo quy wre Q> 0. CC. HE sinh c6ng theo quy uée W <0. D- Hé nhén céng theo quy ure W > 0 (Cau 93: chon cau s . [Nhiét tao thank tiéu chun SH": (kJ/mol) cia cfc chat sau: G2CO} (k) AHP ay (Ki/mol) <0. B- Cl, (k) AHz93 (kJ/mol) = 0. C- O2 (k) AHYroe (/mnol) = 0. D- Bry (k) AH%o4 (ki/mol) = 0. (Cu 94: chon edu sai ‘A- Néu hg dang 6 trang thai cén bing bj thay 46i ml trong cc théng sé trang thai, thi cin bing ‘st chuyén dich theo chigu cé tac dung chéng lai sur thay 481 46. B- Néu phan ting dang @ trang thai can bang, Khi ting nhiét do cn bing phan tng sé chuyén dich theo chigu thu nbigt aC-; Néu phan ting dang 6 trang thhi cin biing, khi gidm nhigt 45 cn bing phan img s€ chuyén “>adich theo chiu thu nit .2. {D> Néu phan Ging dang «trang thdi can bing, khi tang ap suit edn bang phi dich theo chiéu gdm thé tich img s€ chuyén ‘Ci 95: chon cfu sai A> Khéng thé ché tau dng co vinh ciru Logi I cai ma sinh cong lin tue ma khéng cdn cung cép thém nang lung tir bén ngod. B. bi véi hé cd lip ndi nding cia hé duvac bdo todn, & NOi nding U ta him teqng thai va vi phén cia ham U ld vi phan toa phan. (D- Cong W fa ham trang thii nén dW 18 vi phn todn phin. w‘Caw 96: chon cfu sai ‘Cho 1 mol lod phan img véi 1 miol hydro theo phan img: hagk) + Ha (k) SE 2HU(k) biét Ke = 55,3 4x - NGhg 49 Nac can bing 130,21 M . oes. = QRH ener dee (aay 048 )Néng 46 Hy khic néng 49 cia Ip Iie cn biing. Hing so cin bing 6 thé Cuye xic du bt nb dic cht rangi etn bing (Cau 97; chon eu sai CaCO; (1) SE CaO (+ COs tk) AH >O A; Phan dmg thu nhigt B- Phan img tao ra di vbi toa nhiet, C- Ting nhigt d@ va hit khi COz ra khdi phan ding thi sé thu duge nhiéu C20. (0) Gi hig d6 va hin ki CO, ra kha pha dng thi s& chu durge nhidu CaO. (Cau 98: chon cfu sai A. dU TS ~ Pav + dW" Sd - PAV, ‘SdT + VAP, (Cu 99: chon cau sai ‘A. NOiining U fa him trang théi. ning hé o6 lap durgc bio tofn Out 66 d6ng cor vinh city Jogi 1. 6 Ling ndi nang cia hé ding bing ting nhigt tugng va cong ma hé nh tir moi resem, (Ciw 100: chon ctu sai Quy ude vé diu cia cng W va nbiét Q nhur sau: B Cony do he te d6ng lin mei rung e6 du W > 0. B+ Nhiét do bé hép thy tir m6i truéng o6 diu Q> 0, C- Céng va nhiét do hé tac dong 18n mdi trubng 06 déu W <0, Q <0. D- Nhiét va cng do mai trung.tée dng len hé 06 du Q> 0, W > 0. evDE THI HOA DAI CUONG - LAN 1-CNLT * “thai gian 45 pht.(thu tgi dé) (Chu 1: Dign tich hw higu Z’ cis diga uk jrndnt d tdnig 3 oda nguy@n't6 Cl (Z=17) a A.12,85 yes c79 | Daas Cau 2rn=3; 12; my=:2; m= -1/2, 1a che 86 lug cia ditn tit cudi ciia nguyen ye Fe(Z=26) B.Ni(Z=28). C. Cr(Z=24) D. Mo(é=25) Ciu3: Nguyen t6 Cl (Z=17) 06 eft 98 tugng tit ca ign tt cub 1a 7 Lat; m=O; ms-12 zl mel m=-12 math; m=O; iu 4: Cia Binh din td cba nguyén 16 Cu (2=29) 1d A. 1 2e!2pe3ph4s3? : x 18°25?2p%3s23p%4s!3d C. [Ne}4s'34' D. Ca B.C aiing ‘Cu 5: Chon phat biéu dang abit ‘A. Trong'chu 10 i tir trfi sang phii bn kinh tng dan va tfnb kim Jogi gidni din, B. Trong chu Ki di a trdi sang phdi ban kinh gidm din va ning lgng ion hod. gidm dan. C. Trong chu Ki di tiy tri sang phdi bén kinh gidm dan va di lye ign tit ting din. JAD. Th cd abu sai, ‘Chu 6: Chon phat bidu Ging-ahdt ~~ A Diy Lyman of echuyén digs guy dio 14,56... ven = 3 B, Day Balmer c6 sy chuyén dita ur tir quy dao n=3,4,5. vén=2 €. Day Paschen c6 sy-chuyén ditn tity quy dgo n=2,3,4... vn = 1 D. Tét cd A, B,C du ding Cin 7: Phin ti #30 c6. a : ee A. Tap chiing sp’ v6i 2 cp dign tir lién két va 2 cp dign ti khOng lién két B. Tap chiing sp’ véi 3 c&p dign ui liga két va 1 cp dita tit khOng lig k&t C. Tep ching sp’ vi { c&p dita oi lite két va 3 clip dign nk khidng lign k6t chiing sp? vai 2 cp dign ti lin k&t va 2 cp dign tit khiOng tien ket (Clu 8; Cong thie ditnteda phn WO, 1a A helt Oa 2 aps My Ot Ripe apy! 3B. ou. ou Say 02 Rae Map Sie Rag Crow? oe on Ont Cape Rape 2 Fon Rm, Ras FAD one 0's? on “oa ape! Mapa? Rapy? W apnt w