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9962_Carbon and its compounds
9962_Carbon and its compounds
9962_Carbon and its compounds
Carbon forms the largest number of compounds, next only to hydrogen. It ranks seventeenth in the
order of abundance in the earth’s crust. Carbon occurs in the free native state as well as in the
combined state. Carbon and its compounds are widely distributed in nature.
In its elemental form, carbon occurs in nature as diamond and graphite. Coal, charcoal and coke are
impure forms of carbon. The latter two are obtained by heating wood and coal in the absence of air,
respectively. In the combined state, carbon is present as carbonate in many minerals, such as
hydrocarbons in natural gas, petroleum etc. In air, carbon dioxide is present in small quantities, (0.03%).
Our food also contains carbon in the combined form. All living systems contain carbon compounds.
Indeed, life as we know today, would be impossible without such carbon compounds.
Carbon is a non-metallic element and the first member of group 4 of the periodic table
Allotropes of carbon
The existence of one element in different forms, having different physical properties, but similar
chemical properties is known as allotropy. Different forms of an element are called ‘allotropes’ or
allotropic forms. Carbon shows allotropy. The various allotropic forms of carbon can be broadly
• Crystalline form
• Amorphous form
Coal, coke, charcoal (or wood charcoal), animal charcoal (or bone black), lamp black, carbon black, gas
Diamond
Diamonds are chiefly found in the Union of South Africa, the Belgian Congo, Brazil, British Guiana, India
etc. Diamond was discovered for the first time in India. The famous ‘Kohinoor diamond’ (186 – carat)
and the ‘Regent or Pitt’ (studded in Napoleon’s state sword, 136.2 carat) were found near Kistna river in
South India. The ‘Cullinan diamond’, the largest ever found weighed 3025.75 carat (about 600 g) was
Diamonds occur in the form of transparent octahedral crystals usually having curved surfaces and do not
shine much in their natural form. To give them their usual brilliant shine they are cut at a proper angle
Moissan (1893) prepared the first artificial diamond by heating pure sugar charcoal and iron in a
Structure of diamond
In diamond, the carbon atoms are arranged tetrahedrally (sp3 hybridisation of C), each C atom is linked
to its neighbours by four single covalent bonds. This leads to a three-dimensional network of covalent
bonds.
Structure of diamond
It is due to this, that diamond is very hard, and has high melting and boiling points. In diamond, each
carbon atom is bonded to the other through regular covalent bonds. The electrons thus are held tightly
between the nuclei, and there are no mobile electron to conduct electricity i.e. all the valence electrons
of carbon are used up in forming the covalent bonds. Hence diamond does not conduct electricity.
Diamond is also denser than graphite (density: Diamond = 3.52 g cm -3 Graphite =2.25 g cm -3 ) as the
Diamond structure is a closely packed structure, while the layer-to-layer large distance makes graphite
Properties of diamond
• Insoluble in water
Uses of diamond
• The unusual brilliant shine of diamond makes it an invaluable precious stone in jewellery.
• Because of it’s hardness it is used in manufacturing tools/cutting drills for cutting glass and rock.
• In making dyes for drawing very thin wires of harder metals. Tungsten wires of thickness 1/6th
Graphite
Graphite is found widely distributed in nature, viz., in Siberia, Sri Lanka, USA, Canada.
Large quantities of graphite are also manufactured from coke or anthracite in electric furnaces.
Structure of graphite
In graphite, the carbon atoms are arranged in flat parallel layers as regular hexagons. Each layer is
bonded to adjacent layers by weak Van der Waals forces. This allows each layer to slide over the other
easily. Due to this type of structure graphite is soft and slippery, and can act as a lubricant. Graphite is
also a good conductor of electricity. In graphite, carbon atoms in each layer are bonded to three other
carbon atoms by special covalent bonds. This gives some double-bond character to the C-C bonds. This
gives it the presence of delocalized p-electron system. These mobile electrons explain the electrical
conductivity of graphite
Properties of Graphite
• It conducts electricity
Uses of graphite
• As a lubricant at higher temperatures.
• As a refractory material of making crucibles and electrodes for high temperature work.
• In electrotyping and in the manufacture of gramophone records: Graphite is used for making the
Diamonds and graphite are two crystalline allotropes of carbon. Diamond and graphite both are
covalent crystals. But, they differ considerably in their properties.These differences in the properties of
of high temperature, high pressure and in the absence of air is termed carbonization.
Amongst coal varieties, anthracite is the purest form. It contains about 94 – 95% of carbon. The common
variety is bituminous coal; it is black, hard and burns with smoky flame.
Types of Coal
We have four types of coal namely:
• Lignite – Which is a brown soft coal having about 67% carbon by mass
• Bituminous – Which we use every day at home. It contains about 88% by mass of carbon
• Anthracite – This is tough and hard, having about 94% of carbon by mass
amount of nitrogen, sulphur, phosphorus and impurities. A wide variety of substances can be obtained
The chief and important products of this process are coal gas, ammoniacal liquor, coal tar and solid coke
1. Coal Gas: This is the volatile compound which contains about 50% hydrogen, 30% methane, 10%
carbon (II) oxide and small amount of other gases e.g. ethane and hydrogen sulphide
benzene. The ammonium compounds, can be used in the manufacture of nitrogenous fertilizers
while the benzene is used for the manufacture of pharmaceutical products and as a solvent
3. Coal Tar: Coal tar is a mixture of more than 200 different substances which can be separated by
fractional distillation. Most of these e.g. toluene, phenol and naphthalene are used in the
synthesis of important commercial products like dyes, paints, insecticides, drugs, plastics and
explosives
4. Coke: The solid residue, coke with its 98% carbon by mass burns smoothly without smoke and
with high calorific value. It is used in the manufacture of gaseous fuels such as producer gas and
water gas. It is also used as a reducing agent in metallurgy where it reduces metallic oxides to
their respective metals e.g. in the blast furnace for the extraction of iron from its ore
Uses
Coal is mainly used:
1. As an industrial fuel in steel, power generation plants etc. It is also a domestic fuel to a limited
extent.
2. For manufacture of producer gas and water gas, which are used as fuel gases.
Coke is a grey, hard, and porous coal-based fuel with a high carbon content and few impurities,
made by heating coal or oil in the absence of air—a destructive distillation process. It is an
important industrial product, used mainly in iron ore smelting, but also as a fuel in stoves and
forges when air pollution is a concern.
The unqualified term "coke" usually refers to the product derived from low-ash and low-sulphur
bituminous coal by a process called coking. A similar product called petroleum coke, or pet
coke, is obtained from crude oil in oil refineries. Coke may also be formed naturally by geologic
processes.[1]
Destructive distillation
Destructive distillation is a chemical process in which decomposition of unprocessed material is
achieved by heating it to a high temperature; the term generally applies to processing of organic
material in the absence of air or in the presence of limited amounts of oxygen or other reagents,
catalysts, or solvents, such as steam or phenols. It is an application of pyrolysis. The process
breaks up or 'cracks' large molecules. Coke, coal gas, gaseous carbon, coal tar, ammonia liquor,
and coal oil are examples of commercial products historically produced by the destructive
distillation of coal.
Historically the process of destructive distillation and other forms of pyrolysis led to the
discovery of many chemical compounds or elucidation of their structures before contemporary
organic chemists had developed the processes to synthesise or specifically investigate the parent
molecules. It was especially in the early days that investigation of the products of destructive
distillation, like those of other destructive processes, played parts in enabling chemists to deduce
the chemical nature of many natural materials. Well known examples include the deduction of
the structures of pyranoses and furanoses.
Process
The process of pyrolysis can be conducted in a distillation apparatus (retort) to form the volatile
products for collection. The mass of the product will represent only a part of the mass of the
feedstock, because much of the material remains as char, ash, and non-volatile tars. In contrast,
combustion consumes most of the organic matter, and the net weight of the products amount to
roughly the same mass as the fuel and oxidant consumed.
Destructive distillation and related processes are in effect the modern industrial descendants of
traditional charcoal burning crafts. As such they are of industrial significance in many regions,
such as Scandinavia. The modern processes are sophisticated and require careful engineering to
produce the most valuable possible products from the available feedstocks.
Applications
Destructive distillation of wood produces hundreds of compounds including tar, terpenes,
turpentine and methanol together with a solid residue of charcoal.
Destructive distillation of a tonne of coal can produce 700 kg of coke, 100 liters of liquor
ammonia, 50 liters of coal tar and 400 m3 of coal gas.
Destructive distillation is an increasingly promising method for recycling monomers
derived from waste polymers.
Destructive distillation of natural rubber resulted in the discovery of isoprene which led
to the creation of synthetic rubbers such as neoprene.