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Lakshya NEET (2024)

Electrochemistry DPP-09

1. According to to Kohlrausch law, the limiting value 6. A weak monobasic acid is 5% dissociated in 0.01
of molar conductivity of an electrolyte A2B is mol dm–3 solution. The limiting molar conductivity
(1) 𝜆∞ (𝐴⊕ )
+ 𝜆∞
(𝐵⊖ )
(2) 𝜆∞ (𝐴⊕ )
– 𝜆∞
(𝐵⊖ )
at infinite dilution is 4.00 × 10–2 ohm–1 cm2 mol–1.
1 What will be the conductivity (ohm−1 cm2 mol−1) of
(3) 2𝜆∞
(𝐴⊕ )
+ 2 𝜆∞
(𝐵⊖ )
(4) 2𝜆∞
(𝐴⊕ )
+ 𝜆∞
(𝐵2⊖ ) a 0.05 mol dm–3 solution of the acid?
(1) 8.92 × 10–4 (2) 8.29 × 10–4
2. The equivalent conductance of M/32 solution of a (3) 8.92 × 10–5 (4) 8.92 × 10–3
weak monobasic acid is 8.0 mho cm2 and at infinite
dilution is 400 mho cm2. The dissociation constant 7. Mark the correct choice of electrolytes represented
of this acid is: in the graph:
(1) 1.25 × 10–5 (2) 1.25 × 10–6
(3) 6.25 × 10–4 (4) 1.25 × 10–4

 m(scm mol )
–1
3. The equivalent conductance of Ba2+ and Cl– are

2
A
respectively 127 and 76 ohm–1 cm2 eq–1 at infinite
dilution. What will be the equivalent conductance of B
BaCl2 at infinite dilution?
(1) 139.5 (2) 101.5 c1/2 (mol–1)
(3) 203 (4) 279
(1) A→NH4OH, B → NaCl
(2) A→NH4OH, B → NH4Cl
4. The molar conductance’s of NaCl, HCl and
(3) A→ CH3COOH, B → CH3COONa
CH3COONa at infinite dilution are 126.45, 426.16
(4) A→ KCl, B → NH4OH
and 91 ohm–1 cm2 mol–1 respectively. The molar
conductance of CH3COOH at infinite dilution ( m ) 8. The conductivity of 0.001028 M acetic acid is
is 4.95 × 10–5 S cm–1. Calculate its dissociation
(1) 698.28 ohm–1 cm2 mol–1 constant if ⋀° for acetic acid is 390.5 S cm2 mol–1.
(2) 540.48 ohm–1 cm2 mol–1 (1) 1.77 × 10–4
(3) 201.28 ohm–1 cm2 mol–1 (2) 1.77 × 10–5
(4) 390.71 ohm–1 cm2 mol–1 (3) 1.77 × 10–3
(4) 1.77 × 10–2
5.  m for NaCl, HCl and NaA are 126.4, 425.9 and
100.5 S cm2 mol–1, respectively. If the conductivity 9. 0.05 M NaOH solution offered a resistance of 31.6
of 0.001 M HA is 5 × 10–5 S cm–1, degree of ohm in a conductivity cell at 298 K. If the cell
dissociation of HA is constant of the cell is 0.367 cm–1, calculate the molar
(1) 0.25 (2) 0.50 conductivity of the sodium hydroxide solution.
(3) 0.75 (4) 0.125 (1) 232.3 (2) 240.3
(3) 223.3 (4) 243.3
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (4) 6. (1)
2. (1) 7. (4)
3. (3) 8. (2)
4. (4) 9. (1)
5. (4)

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